Solar Energy 80 (2006) 1498–1508 www.elsevier.com/locate/solener A computational study of salt diffusion and heat extraction in solar pond plants Celestino Angeli a, Erminia Leonardi b,* , Luca Maciocco c a b Dipartimento di Chimica, Universita` di Ferrara, Via Borsari 46, I-44100 Ferrara, Italy CRS4, Center for Advanced Studies, Research and Development in Sardinia, Parco Scientifico e Tecnologico, POLARIS, Edificio 1, 09010 Pula, CA, Italy c ADACAP, Advanced Acceleration Applications, Technoparc-rue Diesel 20, Fr-D1630 St. Genis Pouilly, France Received 15 March 2005; received in revised form 26 August 2005; accepted 20 October 2005 Available online 2 February 2006 Communicated by: Associate Editor Aliakbar Akbarzardeh Abstract The problem of the development of salt concentration profiles in a solar pond is investigated, the thermodiffusion contribution is also taken into account, using a one-dimensional mathematical model and a finite-difference approach. A novel scheme of heat extraction from the solar pond is presented, along with preliminary two-dimensional computational fluid dynamics (CFD) simulations. 2006 Elsevier Ltd. All rights reserved. Keywords: Solar pond; Salt diffusion; Finite difference 1D numerical methods; Thermodiffusion 1. Introduction A solar pond is an artificially constructed water pond several meters deep, filled with stratified brine varying in concentration from near saturation at the bottom to approximately sea water concentration at the surface. About 25% of the solar radiation incident at the surface penetrates to the bottom of the pond and is absorbed there, causing the adjacent brine to heat up. It consists of three distinct regions: two convective regions at the top (upper convective * Corresponding author. Tel.: +39 070 925 0328; fax: +39 070 925 0216. E-mail address: [email protected] (E. Leonardi). zone, UCZ) and the bottom (lower convective zone, LCZ), separated by a quiescent region (nonconvective zone, NCZ) characterized by strong temperature and salinity gradients, which prevent the occurrence of convection currents. The salt diffusion caused by both molecular diffusion and thermodiffusion (also known as Soret effect, Soret, 1879) tends to homogenize the system and therefore must be carefully put under control. In previous papers (Angeli and Leonardi, 2004, 2005), a one-dimensional model based on a finite difference scheme was used to describe the salt diffusion within a solar pond. In the present work, the analysis of the behaviour of the solar pond has been extended by considering other effects besides the salt 0038-092X/$ - see front matter 2006 Elsevier Ltd. All rights reserved. doi:10.1016/j.solener.2005.10.015
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