C190-E138 Shimadzu UHPLC packed column Shim-pack XR-ODSⅢ A new lineup has been added to the Shim-pack XR series of columns to better suit your analysis goals. Available at particle sizes of 1.6 µm and 2.2 µm, in varying lengths, the Shim-pack XR-ODSⅢ was designed to accommodate demands for shorter analysis times while maintaining the high resolution that only a UHPLC can provide. Achieves even higher speeds while maintaining resolution in ultra fast analysis : XR-ODSⅡ 75 mmL. × 2 mmI.D., 2.2 µm The sample analysis at left compares results between the Shim-pack XR-ODSⅡ and the Shim-pack XR-ODSⅢ. Analysis times have been reduced in proportion to the decrease in column length. Further, while the theoretical plate number is essentially the same, with the Shim-pack XR-ODSⅢ, there is basically no impact from the flow rate. As a result, the Shim-pack XR-ODSⅢ column is capable of achieving higher speed in a conventional ultra fast analysis, while maintaining the theoretical plate number. : XR-ODSⅢ 50 mmL. × 2 mmI.D., 1.6 µm 0.4 mL/min Comparison of Retention Times 0.0 0.5 1.0 1.5 1.0 mL/min 2.0 2.5 3.0 3.5 4.0 min Mobile phase : 65 % aqueous acetonitrile solution Oven : 50°C Sample : Octanophenone Injection volume : 0.5 µL 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Flow Rate XR-ODSⅡ XR-ODSⅢ 0.4 mL/min 4.16 min 2.70 min 1.0 mL/min 1.60 min 1.01 min Increase in Speed Approx. 1.5x Comparison of Theoretical Plate Numbers Flow Rate XR-ODSⅡ XR-ODSⅢ 0.4 mL/min 13733 11026 1.0 mL/min 10400 10858 Rate of Reduction 24.3% 1.5% 4.0 min Select a column to suit your purpose, whether shorter analysis times or high resolution The Shim-pack XR-ODSⅢ lineup features two columns: a short one utilizing a packing material with a particle size of 1.6 µm; and a long one utilizing a 2.2 µm particle size, which is equivalent to the conventional XR column. This extensive lineup ensures that you can select a column to suit your analysis objectives, whether it's a short size to further shorten analysis times, or a long size to achieve high resolution while retaining the ease of use of the conventional XR column. Shim-pack VP-ODS 150 mmL. × 4.6 mmI.D., 5 µm Flow rate Mobile phase : 1.0 mL/min : 55 % aqueous acetonitrile solution Oven : 40 °C Injection volume : 5 µL 1 1. 2. 3. 4. 5. N for Peak 5 = 12,918 Rt for Peak 5 = 14.79 min 2 3 4 0.0 2.5 5.0 Shim-pack XR-ODSⅢ 50 mmL. × 2 mmI.D., 1.6 µm Flow rate Mobile phase : 1.1 mL/min : 55 % aqueous acetonitrile solution Oven : 40 °C Injection volume : 0.5 µL 1 2 3 4 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.8 0.9 10.0 5 12.5 15.0 min Shim-pack XR-ODSⅢ 200 mmL. × 2 mmI.D., 2.2 µm Flow rate Mobile phase 1 2 3 : 0.6 mL/min : 55 % aqueous acetonitrile solution Oven : 50 °C Injection volume : 0.5 µL 4 5 0.7 7.5 Acetophenone Propiophenone Butyrophenone Valerophenone Hexanophenone 1.0 1.1 1.2 min 5 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 min Rt for Peak 5 = 0.93 min N for Peak 5 = 32,504 16 fold increase in speed 2.5 times the resolution Shim-pack XR Column Lineup There are three types of Shim-pack XR columns, offering a pressure tolerance of 35 MPa (XR-SIL is 20 MPa), 60 MPa, or 100 MPa. The XR-ODS (-C8, -Phenyl, -SIL) enables ultra fast analysis, even with conventional systems. The XR-ODSⅡ aims for further resolution and ease of use. And the XR-ODSⅢ achieves even shorter analysis times than the conventional XR column, while maintaining resolution. By offering a diverse choice of columns, Shimadzu is able to provide an ultra fast analysis environment to a wide range of users. Stationary Phase Name of Column Particle Size Pressure 1.6 µm Shim-pack XR-ODSⅢ 100 MPa Column Size 1.5 mmI.D. 50 mm 228-59922-91 75 mm 228-59922-92 150 mm 228-59910-91 200 mm ODS 60 MPa Shim-pack XR-ODSⅡ Shim-pack XR-ODS 2.2 µm C8 Phenyl SIL Shim-pack XR-C8 35 MPa Shim-pack XR-Phenyl Shim-pack XR-SIL 20 MPa 2.0 mmI.D. 3.0 mmI.D. 4.6 mmI.D. 228-59910-92 30 mm 228-59907-91 50 mm 228-59907-92 228-41623-94 75 mm 228-59907-93 228-41623-91 228-41624-91 100 mm 228-59907-94 228-41623-92 228-41624-92 150 mm 228-59907-95 228-41623-93 228-41624-93 30 mm 228-41605-91 228-41606-91 228-41607-91 50 mm 228-41605-92 228-41606-92 228-41607-92 75 mm 228-41605-93 228-41606-93 228-41607-93 100 mm 228-41605-94 228-41606-94 228-41607-94 30 mm 228-59901-91 228-59902-91 50 mm 228-59901-92 228-59902-92 75 mm 228-59901-93 228-59902-93 100 mm 228-59901-94 228-59902-94 30 mm 228-59903-91 228-59904-91 50 mm 228-59903-92 228-59904-92 75 mm 228-59903-93 228-59904-93 100 mm 228-59903-94 228-59904-94 50 mm 228-59905-91 228-59906-91 75 mm 228-59905-92 228-59906-92 100 mm 228-59905-93 228-59906-93 JQA-0376 Founded in 1875, Shimadzu Corporation, a leader in the development of advanced technologies, has a distinguished history of innovation built on the foundation of contributing to society through science and technology. We maintain a global network of sales, service, technical support and applications centers on six continents, and have established long-term relationships with a host of highly trained distributors located in over 100 countries. For information about Shimadzu, and to contact your local office, please visit our Web site at www.shimadzu.com SHIMADZU CORPORATION. International Marketing Division 3. Kanda-Nishikicho 1-chome, Chiyoda-ku, Tokyo 101-8448, Japan Phone: 81(3)3219-5641 Fax. 81(3)3219-5710 URL http://www.shimadzu.com Printed in Japan 3295-10007-30A-IK The contents of this brochure are subject to change without notice.