Colormaker Permaset Cold Cure Additives

Colormaker Permaset Cold Cure Additives
FujiFilm
Chemwatch Hazard Alert Code: 3
Chemwatch: 4673-12
Version No: 3.1.1.1
Material Safety Data Sheet according to NOHSC and ADG requirements
Issue Date: 01/01/2013
Print Date: 11/07/2014
Initial Date: Not Available
S.Local.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name
Chemical Name
Synonyms
Colormaker Permaset Cold Cure Additives
Not Applicable
Not Available
Proper shipping name
Not Applicable
Chemical formula
Not Applicable
Other means of identification
CAS number
Not Available
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Cross linking agent for Permaset Fabric Printing Colours.
Details of the manufacturer/importer
Registered company name
Address
Telephone
Fax
Website
FujiFilm
114 Old Pittwater Road Brookvale NSW
Australia
+61 2 9466 2600
+61 2 9938 1975
http://www.fujifilm.co
Email
Not Available
Association / Organisation
Not Available
Emergency telephone numbers
Not Available
Other emergency telephone numbers
Not Available
Emergency telephone number
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.
CHEMWATCH HAZARD RATINGS
Min
Flammability
Toxicity
Body Contact
Reactivity
Chronic
Max
1
2
3
2
3
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Label elements
Relevant risk statements are found in section 2
Poisons Schedule
Not Applicable
Continued...
Chemwatch: 4673-12
Version No: 3.1.1.1
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Issue Date: 01/01/2013
Colormaker Permaset Cold Cure Additives
Print Date: 11/07/2014
R20/21/22
R37/38
Risk Phrases
[1]
R42/43
May cause SENSITISATION by inhalation and skin contact.
R52/53
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R41
Risk of serious damage to eyes.
R45(2)
May cause CANCER.
R68(3)
Legend:
Indication(s) of danger
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to respiratory system and skin.
Possible risk of irreversible effects.
R48/22
Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R18
In use, may form flammable/ explosive vapour-air mixture
R19
May form explosive peroxides.
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
T, Xn
SAFETY ADVICE
S01
Keep locked up.
S07
Keep container tightly closed.
S09
Keep container in a well ventilated place.
S13
Keep away from food, drink and animal feeding stuffs.
S18
Handle and open container with care.
S20
When using do not eat or drink.
S23
Do not breathe gas/fumes/vapour/spray.
S25
Avoid contact with eyes.
S26
In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Centre.
S28
After contact with skin, wash immediately with plenty of water
S29
Do not empty into drains.
S35
This material and its container must be disposed of in a safe way.
S36
Wear suitable protective clothing.
S37
Wear suitable gloves.
S38
In case of insufficient ventilation, wear suitable respiratory equipment.
S39
Wear eye/face protection.
S40
To clean the floor and all objects contaminated by this material, use water and detergent.
S45
In case of accident or if you feel unwell IMMEDIATELY contact Doctor or Poisons Information Centre (show label if possible).
S46
If swallowed, seek medical advice immediately and show this container or label.
S51
Use only in well ventilated areas.
S53
Avoid exposure - obtain special instructions before use.
S56
Dispose of this material and its container at hazardous or special waste collection point.
S57
Use appropriate container to avoid environmental contamination.
S63
In case of accident by inhalation: remove casualty to fresh air and keep at rest.
S64
If swallowed, rinse mouth with water (only if the person is conscious).
Other hazards
Cumulative effects may result following exposure*.
R48/20?
Vapours potentially cause drowsiness and dizziness*.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No
%[weight]
Name
64265-57-2
74.7
trimethylolpropane tris(2-methyl-1-aziridine)propionate
110-00-9
25
furan
108-01-0
<0.5
dimethylethanolamine
Continued...
Chemwatch: 4673-12
Version No: 3.1.1.1
75-55-8
Page 3 of 9
Issue Date: 01/01/2013
Colormaker Permaset Cold Cure Additives
Print Date: 11/07/2014
<0.5
propylene imine
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
Skin Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper
and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.
Perform CPR if necessary.
Transport to hospital, or doctor.
Inhalation
IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.
For advice, contact a Poisons Information Centre or a doctor.
Urgent hospital treatment is likely to be needed.
In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive measures as
indicated by the patient's condition.
If the services of a medical officer or medical doctor are readily available, the patient should be placed in his/her care and a copy of the
MSDS should be provided. Further action will be the responsibility of the medical specialist.
If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of the MSDS.
Ingestion
Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or unless
instructed otherwise:
INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
NOTE: Wear a protective glove when inducing vomiting by mechanical means.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
As in all cases of suspected poisoning, follow the ABCDEs of emergency medicine (airway, breathing, circulation, disability, exposure), then the
ABCDEs of toxicology (antidotes, basics, change absorption, change distribution, change elimination).
For poisons (where specific treatment regime is absent):
-------------------------------------------------------------BASIC TREATMENT
-------------------------------------------------------------Establish a patent airway with suction where necessary.
Watch for signs of respiratory insufficiency and assist ventilation as necessary.
Administer oxygen by non-rebreather mask at 10 to 15 L/min.
Monitor and treat, where necessary, for pulmonary oedema.
Monitor and treat, where necessary, for shock.
Anticipate seizures.
DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water (5 ml/kg recommended) for dilution where
patient is able to swallow, has a strong gag reflex and does not drool.
-------------------------------------------------------------ADVANCED TREATMENT
-------------------------------------------------------------Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred.
Positive-pressure ventilation using a bag-valve mask might be of use.
Monitor and treat, where necessary, for arrhythmias.
Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications.
Drug therapy should be considered for pulmonary oedema.
Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications.
Treat seizures with diazepam.
Proparacaine hydrochloride should be used to assist eye irrigation.
BRONSTEIN, A.C. and CURRANCE, P.L.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Special hazards arising from the substrate or mixture
Continued...
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Version No: 3.1.1.1
Fire Incompatibility
Page 4 of 9
Issue Date: 01/01/2013
Colormaker Permaset Cold Cure Additives
Print Date: 11/07/2014
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
Advice for firefighters
Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Use water delivered as a fine spray to control fire and cool adjacent area.
Fire Fighting
Fire/Explosion Hazard
WARNING: In use may form flammable/ explosive vapour-air mixtures.Combustion products include:
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Major Spills
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by all means available, spillage from entering drains or water courses.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Other information
Contains low boiling substance:
Storage in sealed containers may result in pressure buildup causing violent rupture of containers not rated appropriately.
Check for bulging containers.
Vent periodically
Always release caps or seals slowly to ensure slow dissipation of vapours
DO NOT allow clothing wet with material to stay in contact with skin
The substance accumulates peroxides which may become hazardous only if it evaporates or is distilled or otherwise treated to concentrate the
peroxides. The substance may concentrate around the container opening for example.
Store in original containers.
Keep containers securely sealed.
No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.
Conditions for safe storage, including any incompatibilities
Suitable container
Storage incompatibility
Metal can or drum
Packaging as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Reacts vigorously with acids
Several derivatives of the highly reactive aziridine (a strained ring compound) show explosive instability.
In the presence of acids these compounds may be chemically reactive and may be subject to aqueous auto-catalysed exothermic
polymerisation, which may be violent if uncontrolled by dilution, slow addition or cooling.
Carbon dioxide may produce sufficiently acidic solutions to produce such reactions.
Silver and its alloys may produce explosive compounds.
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source
Ingredient
Material name
TWA
STEL
Peak
Australia Exposure Standards
dimethylethanolamine
Dimethylaminoethanol
7.4 mg/m3 / 2 ppm
22 mg/m3 / 6 ppm
Not Available
Notes
Not Available
Australia Exposure Standards
propylene imine
Propylene imine
4.7 mg/m3 / 2 ppm
Not Available
Not Available
Sk
EMERGENCY LIMITS
Ingredient
TEEL-0
TEEL-1
TEEL-2
TEEL-3
furan
1.25 ppm
4 ppm
6.8 ppm
19 ppm
Continued...
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Version No: 3.1.1.1
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Issue Date: 01/01/2013
Colormaker Permaset Cold Cure Additives
Print Date: 11/07/2014
dimethylethanolamine
12.5 ppm
35 ppm
150 ppm
150 ppm
propylene imine
2 ppm
2 ppm
12 ppm
23 ppm
Ingredient
Original IDLH
Revised IDLH
trimethylolpropane tris(2-methyl1-aziridine)propionate
Not Available
Not Available
furan
Not Available
Not Available
dimethylethanolamine
Not Available
Not Available
propylene imine
500 ppm
100 ppm
Exposure controls
Appropriate engineering controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls
can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically
"adds" and "removes" air in the work environment.
Personal protection
Eye and face protection
Skin protection
Hands/feet protection
Body protection
Other protection
Thermal hazards
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing
the wearing of lenses or restrictions on use, should be created for each workplace or task.
See Hand protection below
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to
manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance
and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when
making a final choice.
Suitability and durability of glove type is dependent on usage.
See Other protection below
Overalls.
P.V.C. apron.
Barrier cream.
Not Available
Recommended material(s)
Respiratory protection
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computergenerated selection:
Colormaker Permaset Cold Cure Additives
Material
CPI
PVA
A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final
selection must be based on detailed observation. * Where the glove is to be used on a short term, casual or infrequent basis, factors such as
"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise
be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
Type KAX-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI
Z88 or national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection
Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES
KAX-AUS
P2
-
KAX-PAPR-AUS /
Class 1 P2
up to 50 x ES
-
KAX-AUS /
Class 1 P2
-
up to 100 x ES
-
KAX-2 P2
KAX-PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
Continued...
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Version No: 3.1.1.1
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Colormaker Permaset Cold Cure Additives
Print Date: 11/07/2014
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance
Physical state
Clear yellowish liquid with an amine like odour; partly mixes with water.
Liquid
Relative density (Water = 1)
1.06
Odour
Not Available
Partition coefficient n-octanol / water
Not Available
Odour threshold
Not Available
Auto-ignition temperature (°C)
Not Available
pH (as supplied)
9.5-11.5
Melting point / freezing point (°C)
Initial boiling point and boiling range
(°C)
Flash point (°C)
Evaporation rate
Flammability
Decomposition temperature
Not Available
Viscosity (cSt)
200
Molecular weight (g/mol)
96
Not Applicable
Not Available
Not Applicable
Taste
Not Available
Not Available
Explosive properties
Not Available
Not Applicable
Oxidising properties
Not Available
Upper Explosive Limit (%)
Not Available
Surface Tension (dyn/cm or mN/m)
Not Available
Lower Explosive Limit (%)
Not Available
Volatile Component (%vol)
Not Available
Vapour pressure (kPa)
Not Available
Gas group
Not Available
pH as a solution(1%)
Not Available
VOC g/L
Not Available
Solubility in water (g/L)
Partly Miscible
Vapour density (Air = 1)
Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity
Chemical stability
See section 7
Unstable in the presence of incompatible materials.
Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous reactions
See section 7
Conditions to avoid
See section 7
Incompatible materials
See section 7
Hazardous decomposition products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful.
Inhalation hazard is increased at higher temperatures.
Inhaled
Material is highly volatile and may quickly form a concentrated atmosphere in confined or unventilated areas. The vapour may displace and
replace air in breathing zone, acting as a simple asphyxiant.
Ingestion
Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce
serious damage to the health of the individual.
Considered an unlikely route of entry in commercial/industrial environments. The liquid may produce gastrointestinal discomfort and may be
harmful if swallowed. Ingestion may result in nausea, pain and vomiting.
Skin contact with the material may be harmful; systemic effects may result following absorption.
Skin Contact
The material produces severe skin irritation; evidence exists, or practical experience predicts, that the material either:
produces severe inflammation of the skin in a substantial number of individuals following direct contact, and/or
produces significant and severe inflammation when applied to the healthy intact skin of animals (for up to four hours), such inflammation
being present twenty-four hours or more after the end of the exposure period.
Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The
dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation),
scaling and thickening of the epidermis.
Eye
Evidence exists, or practical experience predicts, that the material may cause severe eye irritation in a substantial number of individuals and/or
may produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental animals. Eye
contact may cause significant inflammation with pain. Corneal injury may occur; permanent impairment of vision may result unless treatment is
prompt and adequate. Repeated or prolonged exposure to irritants may cause inflammation characterised by a temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Chronic
Limited evidence shows that inhalation of the material is capable of inducing a sensitisation reaction in a significant number of individuals at a
greater frequency than would be expected from the response of a normal population.
Pulmonary sensitisation, resulting in hyperactive airway dysfunction and pulmonary allergy may be accompanied by fatigue, malaise and aching.
Significant symptoms of exposure may persist for extended periods, even after exposure ceases. Symptoms can be activated by a variety of
nonspecific environmental stimuli such as automobile exhaust, perfumes and passive smoking.
Colormaker Permaset Cold Cure
Additives
TOXICITY
IRRITATION
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Version No: 3.1.1.1
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Colormaker Permaset Cold Cure Additives
Print Date: 11/07/2014
Not Available
trimethylolpropane tris(2-methyl1-aziridine)propionate
Not Available
TOXICITY
IRRITATION
Oral (Rat) LD50: 3038 mg/kg
Eye (rabbit): SEVERE corrosive
Skin (rabbit): SEVERE abraded skin
Not Available
Not Available
TOXICITY
IRRITATION
Inhalation (mouse) LC50: 120 mg/m3/1h
furan
Inhalation (rat) LC50: 3398 ppm/1h
Intraperitoneal (mouse) LD50: 7 mg/kg
Intraperitoneal (rat) LD50: 5.2 mg/kg
Not Available
dimethylethanolamine
propylene imine
Not Available
TOXICITY
IRRITATION
Inhalation (rat) LC50: 1641 ppm/4h
Eye (rabbit):0.75 mg(open)-SEVERE
Oral (rat) LD50: 2000 mg/kg
Skin (rabbit): 445 mg(open)-mild
Not Available
Not Available
TOXICITY
IRRITATION
Intraperitoneal (mouse) LD50: 355 mg/kg
Eye (rabbit):0.25 mg(open)SEVERE
Oral (rat) LD50: 19 mg/kg
Not Available
Not Available
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Colormaker Permaset Cold Cure
Additives
TRIMETHYLOLPROPANE TRIS(2METHYL-1-AZIRIDINE)PROPIONATE
FURAN
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may
produce conjunctivitis.
The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) thickening of the epidermis.
The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of
contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact
urticaria, involve antibody-mediated immune reactions.
For furan:
Mice and rats treated with furan in corn oil by gavage for 5 days/week, for 2 weeks died by day 8 when dosed at 80 and 160 mg/kg. Mottled
and enlarged livers were seen at necroscopy in male rats dosed at levels exceeding 20 mg/kg and in female rats receiving more than 40
mg/kg. No lesions determined to be related to furan exposure were observed in mice.
Rats and mice receiving furan in corn oil by gavage 5 days/week for 13 weeks showed toxic lesions of the liver (bile duct hyperplasia,
cholangiofibrosis, cytomegaly and degeneration of hepatocytes) following doses of 4 mg/kg.
Ptosis, somnolence, dyspnea, acute pulmonary oedema, nausea, vomiting, haemorrhage, hepatitis, changes in kidney tubules, jaundice, liver
tumours, angiosarcoma, paternal and maternal effects recorded.
Skin (rabbit) LD50: 1370 mg/kg Subcutaneous (Mouse) LD50: 961 mg/kg Intraperitoneal (Guinea pig) LD: 450 mg/kg Intraperitoneal (Rat)
LD50: 1080 mg/kg Inhalation (Mouse) LC50: 3250 mg/m3/4h Intraperitoneal (Mouse) LD50: 234 mg/kg
DIMETHYLETHANOLAMINE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic
condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating
compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with
abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern,
on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal
lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS.
Skin (guinea) pig: LD50 43 mg/kg
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may
produce conjunctivitis.
PROPYLENE IMINE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic
condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating
compound.
Propyleneimine is a carcinogen in animals and is considered a potential human carcinogen. This chemical has also produced corneal injury
when tested in the eyes of rabbits. Exposure of rats to 500 ppm of PI vapor for four hours was fatal, but inhalation for two hours resulted in no
deaths. Rats administered 20 mg/kg of PI orally twice per week suffered from advanced flaccid paralysis after 18 weeks along with a high
mortality rate.
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Colormaker Permaset Cold Cure Additives
Print Date: 11/07/2014
Acute Toxicity
Carcinogenicity
Skin Irritation/Corrosion
Reproductivity
Serious Eye Damage/Irritation
STOT - Single Exposure
Respiratory or Skin sensitisation
STOT - Repeated Exposure
Mutagenicity
Aspiration Hazard
Legend:
– Data required to make classification available
– Data available but does not fill the criteria for classification
– Data Not Available to make classification
CMR STATUS
CARCINOGEN
propylene imine
SKIN
propylene imine
Australia Exposure Standards - Carcinogens
Carc. 1B
Australia Exposure Standards - Skin
Sk
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment
wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
Persistence and degradability
Ingredient
Persistence: Water/Soil
Persistence: Air
Not Available
Not Available
Not Available
Bioaccumulative potential
Ingredient
Bioaccumulation
Not Available
Not Available
Mobility in soil
Ingredient
Mobility
Not Available
Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Authority for disposal.
Bury or incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.
Product / Packaging disposal
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant
HAZCHEM
NO
Not Applicable
Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Transport in bulk according to Annex II of MARPOL 73 / 78 and the IBC code
Source
Ingredient
Pollution Category
IMO MARPOL 73/78 (Annex II) - List of
Noxious Liquid Substances Carried in Bulk
dimethylethanolamine
Y
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
trimethylolpropane tris(2-methyl1-aziridine)propionate(64265-57-2) is
found on the following regulatory lists
"Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory"
Continued...
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Version No: 3.1.1.1
furan(110-00-9) is found on the
following regulatory lists
Page 9 of 9
Issue Date: 01/01/2013
Colormaker Permaset Cold Cure Additives
Print Date: 11/07/2014
"International Maritime Dangerous Goods Requirements (IMDG Code)","International Maritime Dangerous Goods Requirements (IMDG
Code) - Substance Index","FisherTransport Information","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action
Codes","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)","OECD List of High
Production Volume (HPV) Chemicals","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC
Monographs","Australia Inventory of Chemical Substances (AICS)","Belgium Federal Public Service Mobility and Transport, Regulations
concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","International Air
Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and Cargo Aircraft","International Society of
Automotive Engineers (SAE) Declarable Substances Chemical List - ARP9536","International Chemical Secretariat (ChemSec) SIN List
(*Substitute It Now!)","Australia National Pollutant Inventory","Australia National Implementation Plan - Persistent Organic Pollutants (POPs) in
Australia","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Spanish)","Australia Dangerous
Goods Code (ADG Code) - Dangerous Goods List","International Air Transport Association (IATA) Dangerous Goods Regulations","Australia
Hazardous Substances Information System - Consolidated Lists"
dimethylethanolamine(108-01-0) is
found on the following regulatory lists
"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","IMO MARPOL 73/78 (Annex II) - List of
Noxious Liquid Substances Carried in Bulk","International Maritime Dangerous Goods Requirements (IMDG Code)","Australia Standard for the
Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","International Maritime Dangerous Goods Requirements
(IMDG Code) - Substance Index","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4","Australia
Exposure Standards","Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","Australia
Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","United Nations Recommendations on the Transport of Dangerous
Goods Model Regulations (English)","OECD List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for
Substitution – Norway","Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their
Destruction (French)","Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their
Destruction (Spanish)","Australia Inventory of Chemical Substances (AICS)","Belgium Federal Public Service Mobility and Transport,
Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013
(Dutch)","Australia Chemical Weapons (Prohibition) Act 1994 - Schedule 2","Australia National Pollutant Inventory","OECD Existing Chemicals
Database","Sigma-AldrichTransport Information","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations
(Spanish)","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","Australia Standard for the Uniform Scheduling of
Medicines and Poisons (SUSMP) - Appendix E (Part 2)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","International Air
Transport Association (IATA) Dangerous Goods Regulations","Australia Hazardous Substances Information System - Consolidated
Lists","Australia Customs (Prohibited Imports) Regulations 1956 - Schedule 11- Chemical compounds - Part 3","IMO IBC Code Chapter 17:
Summary of minimum requirements","Acros Transport Information"
propylene imine(75-55-8) is found on the
following regulatory lists
"Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold
Quantity) Table 2","International Maritime Dangerous Goods Requirements (IMDG Code)","Australia - Victoria Occupational Health and Safety
Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 1","International Maritime Dangerous
Goods Requirements (IMDG Code) - Substance Index","Australia Exposure Standards","Australia - Tasmania - Work Health and Safety
Regulations 2012 - Hazardous Chemicals at Major Hazard Facilities (and their Threshold Quantity) - Table 15.1","Australia - New South Wales
- Work Health and Safety Regulation 2011 - Hazardous chemicals at major hazard facilities (and their threshold quantity) - Table 15.1","Australia
- South Australia - Work Health and Safety Regulations 2012 - Schedule 15—Hazardous chemicals at major hazard facilities (and their
threshold quantity) Table 15.1","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","United Nations
Recommendations on the Transport of Dangerous Goods Model Regulations (English)","United Nations Consolidated List of Products Whose
Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments","Wassenaar Arrangement Munitions List - "Energetic materials", and related substances","International Agency for Research on Cancer (IARC) - Agents Classified by
the IARC Monographs","Australia Inventory of Chemical Substances (AICS)","Belgium Federal Public Service Mobility and Transport,
Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013
(Dutch)","International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and Cargo
Aircraft","International Chemical Secretariat (ChemSec) SIN List (*Substitute It Now!)","International Society of Automotive Engineers (SAE)
Declarable Substances Chemical List - ARP9536","Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be
Transported","Australia National Pollutant Inventory","United Nations Recommendations on the Transport of Dangerous Goods Model
Regulations (Spanish)","Australia Work Health and Safety Regulations 2011 - Hazardous chemicals at major hazard facilities and their
threshold quantity","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","International Air Transport Association (IATA)
Dangerous Goods Regulations","Australia Hazardous Substances Information System - Consolidated Lists","Australia - Queensland Work
Health and Safety Regulation - Hazardous chemicals at major hazard facilities (and their threshold quantity)"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any
process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
end of SDS

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