platinum mineralization of the great dyke, zimbabwe

SESSION 7. NEW ADVANCES IN THE UNDERSTANDING OF PGE MINERALOGY FROM MAGMATIC TO SUPERGENE ENVIRONMENTS
271
PLATINUM MINERALIZATION OF THE GREAT DYKE,
ZIMBABWE, AND THE BUSHVELD COMPLEX, SOUTH
AFRICA – THE FATE OF PGM FROM SULFIDE ORES VIA THE
WEATHERING CYCLE (OXIDIZED ORES) INTO PLACERS
Oberthür, T.1, Melcher, F.2, Locmelis, M.3, Weiser, T.W.1 & Junge, M.1
1
Bundesanstalt für Geowissenschaften und Rohstoffe (BGR), Stilleweg 2, D-30655 Hannover, Germany
2
Dept. Geowissenschaften, Montanuniversität Leoben, Peter Tunner Str. 5, A-8700 Leoben, Austria
3
Centre for Exploration Targeting, The University of Western Australia, 6009 Crawley, Australia
e-mail: [email protected]
ABSTRACT. The world’s prime sources of metallurgical chromite and platinum-group elements (PGE) are
layered intrusions of Proterozoic and Archean age (e.g. the Bushveld Complex, South Africa; the Great Dyke,
Zimbabwe; and the Stillwater Complex, USA). This contribution summarizes previous studies of our working
group on pristine and oxidized platinum-group element (PGE) ores as well as related placer accumulations on
the Great Dyke and the Bushveld Complex.
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Fig. 1. Assemblage of sulfides (cpy, pn, mil, py) and various PGM
(moncheite, braggite, malanite, kotulskite and temagamite)
in the UG-2. Lebowa Mine (AS 7631), reflected light, in oil
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12-TH INTERNATIONAL PLATINUM SYMPOSIUM
REFERENCES
Fig. 2. BSE image of eluvial Pt-Fe alloy grain (4-59),
Onverwacht Pipe downslope
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1. JUNGE, M., OBERTHÜR, T. & MELCHER, F. (2014):
Cryptic variation of chromite chemistry, platinumgroup-element and -mineral distribution in the UG-2
chromitite – an example from the Karee Mine, western
Bushveld Complex, South Africa. Economic Geology,
109, 795-810.
2. KUHLMANN, G., OBERTHÜR, T., MELCHER, F. &
LODZIAK, J. (2006): Bushveld Komplex, Südafrika:
UG2-Chromitithorizont, Mineralogisch - geochemische Feinstratigraphie - Schwerpunkt Platinmetall-Verteilung. Internal Report, BGR Tgb.-Nr. 11327/06, 166 p.
3. LOCMELIS, M., MELCHER, F. & OBERTHÜR, T.
(2010): Platinum-Group Element Distribution in the
Oxidized Main Sulfide Zone, Great Dyke, Zimbabwe.
Mineralium Deposita, 45, 93-109.
4. MELCHER, F., OBERTHÜR, T. & LODZIAK, J. (2005):
Modification and alteration of detrital platinum-group
minerals from the Eastern Bushveld Complex, South
Africa. Canadian Mineralogist, 43, 1711-1734.
5. OBERTHÜR, T., MELCHER, F., BUCHHOLZ, P.
& LOCMELIS, M. (2013): The oxidized ores of the
Main Sulfide Zone, Great Dyke, Zimbabwe: Turning
resources into minable reserves – mineralogy is the
key. Journal of the Southern African Institute of Mining and Metallurgy (SAIMM), 133, 191-201.
6. OBERTHÜR, T., MELCHER, F., GAST, L., WÖHRL,
C. & LODZIAK, J. (2004): Detrital platinum-group
minerals in rivers draining the eastern Bushveld
Complex, South Africa. Canadian Mineralogist, 42,
563-582.
7. OBERTHÜR, T., WEISER, T.W., GAST, L. & KOJONEN, K. (2003a): Geochemistry and mineralogy of
the platinum-group elements at Hartley Platinum
Mine, Zimbabwe. Part 1: Primary distribution patterns in pristine ores of the Main Sulfide Zone of the
Great Dyke. Mineralium Deposita, 38, 327-343.
8. OBERTHÜR, T., WEISER, T.W., GAST, L. & KOJONEN, K. (2003b): Geochemistry and mineralogy of
the platinum-group elements at Hartley Platinum
Mine, Zimbabwe. Part 2: Supergene redistribution in
the oxidized Main Sulfide Zone of the Great Dyke, and
alluvial platinum-group minerals. Mineralium Deposita, 38, 344-355.
9. OBERTHÜR, T., WEISER, T.W., MELCHER, F.,
GAST, L. & WÖHRL, C. (2013): Detrital platinum-group minerals in rivers draining the Great
Dyke, Zimbabwe. Canadian Mineralogist 51, 197-222.
10. OSBAHR, I., KLEMD, R., OBERTHÜR, T. & BRÄTZ,
H. (2013): Platinum-group element distribution in
base-metal sulfides of the Merensky Reef from the
Bushveld Complex, South Africa. Mineralium Deposita, 48, 211-232.