SESSION 7. NEW ADVANCES IN THE UNDERSTANDING OF PGE MINERALOGY FROM MAGMATIC TO SUPERGENE ENVIRONMENTS 271 PLATINUM MINERALIZATION OF THE GREAT DYKE, ZIMBABWE, AND THE BUSHVELD COMPLEX, SOUTH AFRICA – THE FATE OF PGM FROM SULFIDE ORES VIA THE WEATHERING CYCLE (OXIDIZED ORES) INTO PLACERS Oberthür, T.1, Melcher, F.2, Locmelis, M.3, Weiser, T.W.1 & Junge, M.1 1 Bundesanstalt für Geowissenschaften und Rohstoffe (BGR), Stilleweg 2, D-30655 Hannover, Germany 2 Dept. Geowissenschaften, Montanuniversität Leoben, Peter Tunner Str. 5, A-8700 Leoben, Austria 3 Centre for Exploration Targeting, The University of Western Australia, 6009 Crawley, Australia e-mail: [email protected] ABSTRACT. The world’s prime sources of metallurgical chromite and platinum-group elements (PGE) are layered intrusions of Proterozoic and Archean age (e.g. the Bushveld Complex, South Africa; the Great Dyke, Zimbabwe; and the Stillwater Complex, USA). This contribution summarizes previous studies of our working group on pristine and oxidized platinum-group element (PGE) ores as well as related placer accumulations on the Great Dyke and the Bushveld Complex. 7KH*UHDW'\NHRI=LPEDEZHKRVWVWKHZRUOG¶V VHFRQGODUJHVWUHVHUYHRI3*(DIWHUWKH%XVKYHOG &RPSOH[LQQHLJKERXULQJ6RXWK$IULFD(FRQRPLF 3*(PLQHUDOL]DWLRQLVUHVWULFWHGWRVXO¿GHGLVVHPL QDWLRQV LQ S\UR[HQLWHV RI WKH 0DLQ 6XO¿GH =RQH 06= VLWHG VRPH PHWUHV EHORZ WKH WUDQVLWLRQ RI WKH 0D¿F DQG WKH 8OWUDPD¿F 6HTXHQFH RI WKH *UHDW '\NH 7KH JHRFKHPLFDO DQG PLQHUDORJLFDO ¿QHVWUXFWXUHRIWKH06=LVUHJDUGHGWRUHÀHFWSUL PDU\ PDJPDWLF IHDWXUHV RI FRQVHFXWLYH EDWFKHV RI VXO¿GH DFFXPXODWLRQ FRQFRPLWDQW VFDYHQJLQJ RI 3*( DQG IUDFWLRQDWLRQ HJ 2EHUWKU HW DO D E 2EHUWKU ,Q WKH %XVKYHOG &RPSOH[WKH3*(RUHVDUHODUJHO\UHODWHGWRVXO ¿GH PLQHUDOL]DWLRQ 7KH WKUHH PDMRU RUH ERGLHV PLQHG DUH WKH 0HUHQVN\ 5HHI WKH 8* FKUR PLWLWHDQGWKH3ODWUHHI 0LQHUDORJLFDOO\ LQ WKH SULVWLQH VXO¿GH RUHV RI ERWK WKH *UHDW '\NH DQG WKH %XVKYHOG PRVW RIWKH3GDQG5KDUHKRVWHGLQSHQWODQGLWHHJ 2EHUWKU HW DO D .XKOPDQQ HW DO 2EHUWKU2VEDKUHWDO-XQJHHWDO ZKHUHDV 3W LV GRPLQDQWO\ SUHVHQW LQ WKH IRUPRIGLVFUHWHSODWLQXPJURXSPLQHUDOV3*0 OLNH VSHUU\OLWH FRRSHULWHEUDJJLWH PDODQLWH FXSURUKRGVLWH DQG 3W3GELVPXWKRWHOOXULGHV )LJ7KHVH¿QGLQJVLQGLFDWHWKDWDODUJHSUR SRUWLRQ RI WKH 3*( SULPDULO\ FRQFHQWUDWHG LQ VXO¿GHXQGHUPDJPDWLFFRQGLWLRQVZDVUHGLVWULE XWHGLQWKHVXEVROLGXVVWDJHDQGIRUPHGGLVFUHWH 3*0 ZLWK DYDLODEOH UHDFWLRQ SDUWQHUV &KHPL FDO JUDGLHQWV DQG PDJPDWLFK\GURWKHUPDO ÀXLGV SUREDEO\OHGWRVPDOOVFDOHUHGLVWULEXWLRQRI3*( ZLWKLQWKH06= 7KH EHKDYLRXU RI WKH 3*( LQ WKH H[RJHQLF F\FOHZDVH[DPLQHGLQDQXPEHURISUR¿OHVRIR[L GL]HG06=RUHVDQGZRUNRQR[LGL]HG0HUHQVN\ 5HHI DQG 3ODWUHHI RUHV LQFOXGLQJ HOXYLDO DFFXPX ODWLRQV )LJ LV LQ SURJUHVV *HRFKHPLFDOO\ LQ WKHR[LGL]HGRUHVRIERWKWKH*UHDW'\NHDQGWKH %XVKYHOG WKH JHQHUDO PHWDO GLVWULEXWLRQ SDWWHUQV RI WKH SULVWLQH RUHV DUH JURVVO\ SUHVHUYHG +RZ HYHU DW VLPLODU 3W JUDGHV VLJQL¿FDQW SURSRUWLRQV RI3GKDYHEHHQORVWIURPWKHV\VWHP/RFPHOLVHW DO2EHUWKUHWDOZRUNLQSURJUHVV Fig. 1. Assemblage of sulfides (cpy, pn, mil, py) and various PGM (moncheite, braggite, malanite, kotulskite and temagamite) in the UG-2. Lebowa Mine (AS 7631), reflected light, in oil 272 12-TH INTERNATIONAL PLATINUM SYMPOSIUM REFERENCES Fig. 2. BSE image of eluvial Pt-Fe alloy grain (4-59), Onverwacht Pipe downslope 7KLVLQGLFDWHVWKDW3GLVPRUHPRELOHWKDQ3WDQG LVGLVSHUVHGLQWKHVXSHUJHQHHQYLURQPHQW0LQHU DORJLFDOO\ LQ WKH R[LGL]HG RUHV RI ERWK WKH *UHDW '\NH DQG WKH %XVKYHOG VSHUU\OLWH DQG FRRSHULWH EUDJJLWHDUHVWDEOHZKHUHDVWKH3W3GELVPXWKR WHOOXULGHVFRPPRQLQWKHSULVWLQHRUHVKDYHGLVLQ WHJUDWHGDQGLOOGH¿QHG3W3GR[LGHVRUK\GUR[ LGHVKDYHIRUPHG)XUWKHUPRUHHOHYDWHGFRQWHQWV RI 3W DQG 3G DUH IRXQG LQ LURQ DQG LURQPDQJD QHVHR[LGHVK\GUR[LGHV06=GDWD7KHUHVRXUFH RI a 0W RI R[LGL]HG 06= 2EHUWKU HW DO DQG VLJQL¿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ÜR, T. & MELCHER, F. (2014): Cryptic variation of chromite chemistry, platinumgroup-element and -mineral distribution in the UG-2 chromitite – an example from the Karee Mine, western Bushveld Complex, South Africa. Economic Geology, 109, 795-810. 2. KUHLMANN, G., OBERTHÜR, T., MELCHER, F. & LODZIAK, J. (2006): Bushveld Komplex, Südafrika: UG2-Chromitithorizont, Mineralogisch - geochemische Feinstratigraphie - Schwerpunkt Platinmetall-Verteilung. Internal Report, BGR Tgb.-Nr. 11327/06, 166 p. 3. LOCMELIS, M., MELCHER, F. & OBERTHÜR, T. (2010): Platinum-Group Element Distribution in the Oxidized Main Sulfide Zone, Great Dyke, Zimbabwe. Mineralium Deposita, 45, 93-109. 4. MELCHER, F., OBERTHÜR, T. & LODZIAK, J. (2005): Modification and alteration of detrital platinum-group minerals from the Eastern Bushveld Complex, South Africa. Canadian Mineralogist, 43, 1711-1734. 5. OBERTHÜR, T., MELCHER, F., BUCHHOLZ, P. & LOCMELIS, M. (2013): The oxidized ores of the Main Sulfide Zone, Great Dyke, Zimbabwe: Turning resources into minable reserves – mineralogy is the key. Journal of the Southern African Institute of Mining and Metallurgy (SAIMM), 133, 191-201. 6. OBERTHÜR, T., MELCHER, F., GAST, L., WÖHRL, C. & LODZIAK, J. (2004): Detrital platinum-group minerals in rivers draining the eastern Bushveld Complex, South Africa. Canadian Mineralogist, 42, 563-582. 7. OBERTHÜR, T., WEISER, T.W., GAST, L. & KOJONEN, K. (2003a): Geochemistry and mineralogy of the platinum-group elements at Hartley Platinum Mine, Zimbabwe. Part 1: Primary distribution patterns in pristine ores of the Main Sulfide Zone of the Great Dyke. Mineralium Deposita, 38, 327-343. 8. OBERTHÜR, T., WEISER, T.W., GAST, L. & KOJONEN, K. (2003b): Geochemistry and mineralogy of the platinum-group elements at Hartley Platinum Mine, Zimbabwe. Part 2: Supergene redistribution in the oxidized Main Sulfide Zone of the Great Dyke, and alluvial platinum-group minerals. Mineralium Deposita, 38, 344-355. 9. OBERTHÜR, T., WEISER, T.W., MELCHER, F., GAST, L. & WÖHRL, C. (2013): Detrital platinum-group minerals in rivers draining the Great Dyke, Zimbabwe. Canadian Mineralogist 51, 197-222. 10. OSBAHR, I., KLEMD, R., OBERTHÜR, T. & BRÄTZ, H. (2013): Platinum-group element distribution in base-metal sulfides of the Merensky Reef from the Bushveld Complex, South Africa. Mineralium Deposita, 48, 211-232.
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