色素増感太陽電池における 発電効率の改善

Investigations on the Extension of the
Life-span of a Dye-sensitized Solar Cell
Asada Fumiya
MNCT Nakagawa Lab’s
Purpose
Dye-sensitized solar cell (DSSC)
→ Low cost
→ A variety of colors and forms
Problems
→ Low power
generation efficiency
→ Short-lived
Source :Aisin Seiki
MNCT Nakagawa Lab’s
Purpose
Previous work by Yonago Kosen:
Using a shell membrane
→ Longer operating life DSSC
→ An experiment with only food pigment
Absorption of various pigments
and extension of life-span
MNCT Nakagawa Lab’s
Extraction of shell membranes
Extraction work of egg membranes
which requires time
→Consideration of how to carry out extensive
extraction and to save egg membranes
The rate of pigment absorption
conditioned by methods of preservation
→ Investigation immediately after extraction,
room temperature (23 ℃), and freezing
MNCT Nakagawa Lab’s
Extraction of shell membranes
Results of the investigation
① Immediately after extraction and frozen storage
→ Dyed at the rate of almost 100%
② Room temperature preservation
→ Dyed at the rate of about 90%
Determination of frozen storage
MNCT Nakagawa Lab’s
Power generation principle
③Electric charge which moves
Pigment
①Pigment which
receives light
② Emitting the electron
(Oxidization of pigment)
Light
IElectrolysis solution
I2
Power generation
electrode
Titanium oxide
④Reproduction of
pigment by
electrolysis solution
Opposite
electrode
MNCT Nakagawa Lab’s
Production of DSSC (Comparison)
Pigment:
Stuck to
titanium oxide
Titanium oxide
Transparent
electrode
Pigment:
Stuck to a shell
membrane
Titanium oxide
Shell
membrane
MNCT Nakagawa Lab’s
Production of DSSC (Not using egg membrane)
①
One day after
Extraction of pigment
(Hibiscus)
③
②
Opposite electrode:
Carbon is applied.
Power generation electrode :
Pigment is applied to titanium oxide.
Iodine liquid applied to both
power generation electrodes
→Combining electrodes
MNCT Nakagawa Lab’s
Production of DSSC (Using egg membrane)
①
②
Applying titanium oxide
to a transparent electrode
③
Power generation electrode :
sticking ② on ①
Opposite electrode:
Applied carbon
Absorbed pigment into egg membrane
→Dipping in titanium oxide solution
④
The additional iodine liquid to a
power generation electrode
→Setting electrodes
MNCT Nakagawa Lab’s
Measurement of DSSC
Power generation characteristics
ISC[μA]
With no shell membrane
76.6
With a shell membrane
77.9
VOC[mV]
294
298
The problem of measurement
Fall in power
generation
caused by heat
Using ventilation to
prevent rising
temperature
Hastening of the
evaporation of
electrolysis solution
using ventilation
The necessity
for
encapsulation
MNCT Nakagawa Lab’s
Conclusion
Investigation on the method
of the preservation of egg membrane
→ Increased efficiency
in egg membrane extraction
Production of two kinds of DSSCs, one with
shell membrane and the other without it
→① To check power generation characteristics
② Decision on a manufacture method
and a measuring method
MNCT Nakagawa Lab’s