Anaerobe zuivering van huishoudelijk afvalwater

Anaerobe zuivering van huishoudelijk
afvalwater; energie produktie &
grondstoffen terugwinning
22-04-2014, Grietje Zeeman; WUR-ETE
[email protected]
Industrialized
countries
large quantities of
water for toilet
flushing
Dilution of toilet
waste water
Basic setup of
aerobic treatment
screens
grit
chamber
primary
activated
secondary
sedimentation sludge sedimentation
tank
tank
tank
Raw sewage
Treated effluent
Sludge
sludge
digestion
sludge
dewatering
Basic setup of
anaerobic treatment
screens
grit
chamber
high-rate
anaerobic
treatment
effluent
polishing
pond
Raw sewage
Treated effluent
Sludge
sludge
drying
beds
AWWT plant
Bucaramanga,Colombia
UASB
UASB (Upflow
Anaerobic Sludge
Bed) reactor
•
Developed by
Lettinga (1970’s)
Low temperature
& low
concentration
Large UASB reactors
Low
temperature &
low
concentration
UASB-sludge digester
Under development
Mahmoud N, Zeeman G, Gijzen H, Lettinga G. 2004. Anaerobic sewage treatment in a one-stage UASB reactor and a combined UASB-Digester
system. Water Research 38: 2347-2357.
Lei Zhang, Tim L.G. Hendrickx, Weiguang Li, Christel Kampman, Hardy Temmink, Grietje Zeeman (2013). Co-digestion to support low temperature
anaerobic pre-treatment of municipal sewage in a UASB-Digester. Bioresource technology 148, 560-566
energy
Separation at source
‘New Sanitation’
food
organic
feritilizer
Recovery
system
BW
K
GW
treatment
‘New Sanitation’; restore the cycle with agriculture
Barrel system
End of the 19th
century:
Feces & urine
collected in barrels
Hygienic ?
Barrel system
Abraham: ’’what, not yet forbidden….?’’
Van Zon, 1986
Raw materials; BW & KW
Black water &
Kitchen waste
(g p-1d-1)
% of total domestic
Wastewater &
Kitchen waste
N
12.3 g
92
P
1.6 g
80
K
3.9 g
84
organics
111 g COD
69
adapted from Zeeman & Kujawa-Roeleveld, 2011
The potential for recovery
BW + KW
(tons
per year)
P
3.9*106
Fertilizer
production
(tons per year)
#14.9*106
%
coverage
Energy
equivalent
27
World Population:6,911,750,810 people (http://www.census.gov/main/www/popclock.html)
#Cordell, D., Drangert, J.-O., and White, S. , (2009). ##J. N. Galloway et al, (2008); + Haber-Bosch:35kJ/gN;
conversion; 0.0378 MJ/LCH4 .
++anaerobic
treatment: 70%
Phosphorus is a finite resource
..
Cordell, D., Drangert, J.-O., and White, S. (2009). The story of phosphorus: Global food security and food for thought.
Global Environmental Change, 19, 292-305.
Recovery and
reuse of nitrogen
needed?
78%
..
Haber-Bosch
process
N2 + 3 H2 → 2NH3
Energy use :
*
37-45 kJ/g N;
*Maurer, M., Schwegler, P., and Larsen, T. A. (2003). Nutrients in urine: energetic
aspects of removal and recovery.
Water Science and Technology, 48 (1), 37-46.
The potential for recovery
BW + KW
(tons
per year)
P
N
3.9*106
*30.9*106
Fertilizer
production
(tons per year)
#14.9*106
##121*106
%
coverage
Energy
equivalent
27
25
World Population:6,911,750,810 people (http://www.census.gov/main/www/popclock.html)
#Cordell, D., Drangert, J.-O., and White, S. , (2009). ##J. N. Galloway et al, (2008); + Haber-Bosch:35kJ/gN;
conversion; 0.0378 MJ/LCH4 .
1.1*103 PJ/y
++anaerobic
treatment: 70%
The potential for recovery
BW + KW
(tons
per year)
COD
280*106
%
coverage
Energy
equivalent
±cooking
energy
69*109
m3 CH4 per
year
‘New Sanitation’
•
Collection (WC) &
transport with
minimal water use
•vacuum toilets
•water free urinals
•urine separation toilets
•
Separation at source
•BW separate from GW
DESAH BV
Modern vacuum
collection and
transport
•
comfort
•
minimal water
use (≤ 1Litre per
flush)
EET & STOWA supported
‘New Sanitation’
Full scale
application
Vila Flora; Venlo
DESAH BV
‘New Sanitation’
Full scale
application
Sneek; 250 houses
DESAH BV
New sanitation in NIOO building
New sanitation‘Brouwershuis’
New sanitation ‘Brouwershuis’
Black water UASB treatment,
nitritation-anammox & struvite-precipitation
1.8 m3 CH4/m3
UASB
Autotrophic
N-removal
N2
P-recovery
De Graaff et al.(2010), Water ;De Graaff et al., (2010), Water Research;De Graaff et al., (2011),Water Research 2*;De Graaff et al., (2011),WS&T
Black water treatment
Biogas
MP & Pathogens
Sludge
UASB
UASB
Local use
Phosphorus
Nitrogen
MP & Pathogens
Effluent
Air
Black water treatment
Biogas
MP & Pathogens
Sludge
UASB
UASB
Phosphorus
Nitrogen
MP & Pathogens
Effluent
Agriculture
Simultaneous AD & Ca-phosphate precipitation
Energy
Liquid Eff.
Black Water
N,K
P-granules
Sludge
COD
Taina H. Tervahauta, Renata D. van der Weijden, Roberta L. Flemming, Luc´ıa Hern´andez Leal, Grietje Zeeman,,Cees J. N. Buisman (submitted)
Calcium phosphate precipitation in anaerobic treatment of black water: a new approach to phosphorus recovery. Water Research 48 (2 014 ) 632-642
Simultaneous AD & Ca-phosphate
precipitation
Granule formation in black water UASB reactor (a) dried granule (b) and inorganic core of
granule (burned at 550"C) (c)
Taina H. Tervahauta, Renata D. van der Weijden, Roberta L. Flemming, Luc´ıa Hern´andez Leal, Grietje Zeeman,,Cees J. N. Buisman (submitted)
Calcium phosphate precipitation in anaerobic treatment of black water: a new approach to phosphorus recovery. Water Research 48 (2 014 ) 632-642
33
NH3-recovery; microbial fuel cell
• migrational ion flux to
the cathode
• driven by electron
production
• anaerobic degradation
of organic matter in
urine.
Kuntke, P., Śmiech, K.M. , Bruning, H., Zeeman, G., Saakes, M. , Sleutels, T.H.J.A. , Hamelers, H.V.M., Buisman, C.J.N. (2012).
Ammonium recovery and energy production from urine by a microbial fuel cell. Water Research, 46-8, 2627-2636
N & P recovery; microalgae growth on
urine
Kanjana Tuantet, Marcel Janssen, Hardy Temmink, Grietje Zeeman, René H. Wijffels, and Cees J.N. Buisman (2013). Nutrient removal and
microalgal biomass production on urine in a short light-path photobioreactor. Water R e search 5 5, 1 6 2 -1 7 4
N & P recovery; microalgae growth on BW
N&P
C
Biogas
LNV, 2007
To develop
DBW
BW
Vacuum
toilet
PBR
effluent
polishing
UASB
Algae
harvesting
NIOO-KNAW
NIOO-KNAW
H2O
Wetland
Schematic representation of current and future black water according to new sanitation concepts. Tania Fernandes, NIOO
Water scarcity
20th century:
•
6* increase
water use
•
> 2* population
growth
..
2025
1.8 billion people
live in countries
with an absolute
water shortage
(UN, 2007)
..
Bio-flocculation of grey water (GW)
biogas
Biogas
Bioflocculation
unit
membrane
Effluent
Grey
Greywater
water
UASB
Black water and
BW
&KW
kitchen
refuse
Bioflocculated and
concentrated
organic matter
GW-sludge
Hernandez Leal L., Temmink H., Zeeman G., Buisman C.J.N. (2010b). Bioflocculation of Grey Water for improved energy recovery within
decentralized sanitation concepts. Bioresource Technology, Volume 101, Issue 23, 9065-9070
Treated grey; potential water source
Grey water management at community level (Hernandez, 2010)
Micro-pollutants
41
Micro-pollutants
(MPs)
*almost 200 micropollutants from
personal care
products in GW
**190
different
pharmaceutical
substances recorded
DESAH BV
*Eriksson, E.; Auffarth, K.; Eilerse, A. M.; Henze, M.; Ledin, A (2003). Household chemicals and personal care products as sources
for xenobiotic organic compounds in grey wastewater. Water SA, 29, 135–146.
**Winker, M., Faika, D., Gulyas, H. and Otterpohl, R. (2008). A comparison of human pharmaceutical concentrations in raw
municipal wastewater and yellow water. Science of the total environment
Fate MPs in
biological BW- or
GW-treatment
Lucia
Marthe
Graaff
TitiaHernandez
de Mes
*Personal care
products in GW
**Pharmaceutical
residues &
estrogens in BW
*Hernandez Leal L., Vieno, N., Temmink H., Zeeman G., Buisman C.J.N. (2010). Occurrence of Xenobiotics in Grey Water and Removal in Three
Biological Treatment Systems. Environ. Sci. Technol., 2010, 44 (17): 6835–6842
**de Graaff, M.S., Vieno, N.M., Kujawa-Roeleveld, K., Zeeman, G.; Temmink, H.; Buisman, C.J.N. (2011).
Fate of hormones and pharmaceuticals during combined anaerobic treatment and nitrogen removal by nitritation-anammox in vacuum collected
black water. Water Research, Volume 45, Issue 1;
**T.Z.D. de Mes, K. Kujawa-Roeleveld, G. Zeeman and G. Lettinga (2007). Fate of oestrogens during anaerobic blackwater treatment with microaerobic post-treatment. Water Science & Technology Vol 56 No 5.
Conclusies; anaerobe zuivering van
huishoudelijk afvalwater;
3 ‘Nieuwe Sanitatie’ toepassingen in Nederland
Verbeteringen ‘Nieuwe Sanitatie’ in ontwikkeling
Ontwikkeling UASB-slibvergisting systeem
Conclusies; anaerobe zuivering van
huishoudelijk afvalwater;
VRAGEN?