SAFETY DATA SHEET (SDS)

38.1.4
Page 1/7
SAFETY DATA SHEET (SDS)
according to 1907/2006/EC, Article 31
Printing Date: 02.06.2014
*
Version number 9
Revision: 02.06.2014
1 Identification of the substance/mixture and of the company/undertaking
Trade name: TSF 6522RH TACKY SOLDER FLUX
Relevant identified uses of the substance or mixture and uses advised against
Soldering Flux
Professional use of solder
Details of the supplier of the safety data sheet
This Safety Data Sheet has been updated in accordance with the Globally Harmonized System (GHS).
Manufacturer/Supplier:
Kester
800 West Thorndale Avenue
Itasca, IL 60143
Tel (630) 616-4000
Fax (630) 616-4044
Further information obtainable from: Product Compliance: [email protected]
Emergency telephone number:
CHEMTREC 24-Hour Emergency Response Telephone Number : (800) 424-9300
CHEMTREC 24-Hour Emergency Response (Outside US & Canada) Telephone Number : (703) 527-3887
*
2 Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS08 health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
GHS05 corrosion
Eye Dam. 1
H318 Causes serious eye damage.
GHS07
Skin Sens. 1
H317 May cause an allergic skin reaction.
Label elements
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
Hazard pictograms
GHS05 GHS08
Signal word Danger
Hazard-determining components of labelling:
bis(2-butoxyethyl) ether
Rosin, polymerized
Rosin, modified
Hazard statements
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
(Continued on page 2)
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38.1.4
Page 2/7
SAFETY DATA SHEET (SDS)
according to 1907/2006/EC, Article 31
Printing Date: 02.06.2014
Version number 9
Revision: 02.06.2014
Trade name: TSF 6522RH TACKY SOLDER FLUX
(Continued from page 1)
H317 May cause an allergic skin reaction.
Precautionary statements
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P304+P341
IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable
for breathing.
P302+P352
IF ON SKIN: Wash with plenty of soap and water.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
*
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description: Mixture of substances listed below with nonhazardous additions.
Chemical components:
25-35%
CAS: 65997-05-9
Rosin, polymerized
Skin Sens. 1, H317
25-35%
CAS: 65997-06-0
Rosin, modified
Resp. Sens. 1, H334
Skin Sens. 1, H317
CAS: 112-73-2
bis(2-butoxyethyl) ether
25-35%
EINECS: 204-001-9
Eye Dam. 1, H318
Acute Tox. 4, H312
2.5-5.0%
CAS: 126-86-3
2,4,7,9-tetramethyldec-5-yne-4,7-diol
EINECS: 204-809-1
Eye Irrit. 2, H319
CAS: 27136-73-8
1H-Imidazole-1-ethanol, 2-(heptadecenyl)-4,5-dihydro2.5-5.0%
EINECS: 248-248-0
Aquatic Chronic 2, H411
Acute Tox. 4, H302
1.0-2.5%
CAS: 872-50-4
N-methyl-2-pyrrolidone
EINECS: 212-828-1
Skin Irrit. 2, H315; Eye Irrit. 2, H319
Additional information:
(CAS: 872-50-4 N-methyl-2-pyrrolidone) is a Substance of Very High Concern (SVHC) according to REACH, Article 57.
Kester solder products are not classified as articles. This product is a mixture that is further processed by industrial users
at temperatures that exceed 217C (Celsius) during the soldering procedure. Volatile substances evaporate during the
soldering procedure and are no longer present in the finished part.
*
4 First aid measures
Description of first aid measures
General information: Follow general first aid procedures.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing: Seek immediate medical advice.
Information for doctor:
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed No further relevant information available.
GB
(Continued on page 3)
38.1.4
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SAFETY DATA SHEET (SDS)
according to 1907/2006/EC, Article 31
Printing Date: 02.06.2014
Version number 9
Revision: 02.06.2014
Trade name: TSF 6522RH TACKY SOLDER FLUX
(Continued from page 2)
*
5 Firefighting measures
Extinguishing media
Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Nitrogen oxides (NOx)
Carbon dioxide (CO2)
Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.
*
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation
Environmental precautions: Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
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7 Handling and storage
Handling:
Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
Information about fire - and explosion protection: No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: None.
Specific end use(s) No further relevant information available.
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8 Exposure controls/personal protection
Additional information about design of technical facilities: No further data; see item 7.
Control parameters
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the
workplace.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Respiratory protection:
When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or self-contained
breathing apparatus should be worn.
(Continued on page 4)
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38.1.4
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SAFETY DATA SHEET (SDS)
according to 1907/2006/EC, Article 31
Printing Date: 02.06.2014
Version number 9
Revision: 02.06.2014
Trade name: TSF 6522RH TACKY SOLDER FLUX
(Continued from page 3)
Protection of hands:
Protective gloves
Material of gloves
Nitrile rubber, NBR
Natural rubber, NR
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection:
Safety Glasses with Side Shields Required
Face Shield with Safety Glasses when refilling.
*
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form:
Viscous
Colour:
Amber coloured
Odour:
Mild
pH-value:
Not determined.
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 260 °C
Flash point:
> 100 °C
Ignition temperature:
190 °C
Self-igniting:
Product is not selfigniting.
Danger of explosion:
Product does not present an explosion hazard.
Density:
Not determined.
Solubility in / Miscibility with
water:
Not miscible or difficult to mix.
*
10 Stability and reactivity
Reactivity
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No further relevant information available.
Incompatible materials: Strong acids, strong oxidizers.
Hazardous decomposition products: No dangerous decomposition products known.
GB
(Continued on page 5)
38.1.4
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SAFETY DATA SHEET (SDS)
according to 1907/2006/EC, Article 31
Printing Date: 02.06.2014
Version number 9
Revision: 02.06.2014
Trade name: TSF 6522RH TACKY SOLDER FLUX
(Continued from page 4)
*
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values relevant for classification:
65997-06-0 Rosin, modified
Oral
LD50 > 4000 mg/kg (Rat)
Dermal LD50 >2500 mg/kg (rabbit)
112-73-2 bis(2-butoxyethyl) ether
Oral
LD50 3900 mg/kg (rat)
126-86-3 2,4,7,9-tetramethyldec-5-yne-4,7-diol
Oral
LD50 4600 mg/kg (rat)
872-50-4 N-methyl-2-pyrrolidone
Oral
LD50 3914 mg/kg (rat)
Dermal LD50 8000 mg/kg (rabbit)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Strong irritant with the danger of severe eye injury.
Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification Guidelines
for Preparations as issued in the latest version:
Harmful
Irritant
*
12 Ecological information
Toxicity
Aquatic toxicity: No further relevant information available.
Ecotoxical effects:
Remark: Harmful to fish
Additional ecological information:
General notes:
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Harmful to aquatic organisms
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
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13 Disposal considerations
Waste treatment methods
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
*
14 Transport information
UN-Number
Not regulated
(Continued on page 6)
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38.1.4
Page 6/7
SAFETY DATA SHEET (SDS)
according to 1907/2006/EC, Article 31
Printing Date: 02.06.2014
Version number 9
Revision: 02.06.2014
Trade name: TSF 6522RH TACKY SOLDER FLUX
UN proper shipping name
ADR, IMDG, IATA
Transport hazard class(es)
(Continued from page 5)
Not regulated
ADR, IMDG, IATA
Class
Not regulated.
Environmental hazards:
Not applicable.
No
Marine pollutant:
Special precautions for user
Not applicable.
Transport in bulk according to Annex II of MARPOL73/78
and the IBC Code
Not applicable.
*
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
All ingredients are listed on the following Government Inventories:
China:
Korea:
Europe:
Japan:
Philippines:
USA:
Inventory of Existing Chemical Substances in China (IECSC)
Korea Existing Chemicals List (ECL)
European Inventory of Existing Commercial Chemical Substances (EINECS)
Inventory of Existing and New Chemical Substances (ENCS)
Philippine Inventory of Chemicals and Chemical Substances (PICCS)
TSCA (Toxic Substances Control Act) TSCA Inventory of Chemical Substances
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
Hazard pictograms
GHS05 GHS08
Signal word Danger
Hazard-determining components of labelling:
bis(2-butoxyethyl) ether
Rosin, polymerized
Rosin, modified
Hazard statements
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
Precautionary statements
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P304+P341
IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable
for breathing.
P302+P352
IF ON SKIN: Wash with plenty of soap and water.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations:
Other regulations, limitations and prohibitive regulations
Substances of very high concern (SVHC) according to REACH, Article 57
872-50-4 N-methyl-2-pyrrolidone
(Continued on page 7)
GB
38.1.4
Page 7/7
SAFETY DATA SHEET (SDS)
according to 1907/2006/EC, Article 31
Printing Date: 02.06.2014
Version number 9
Revision: 02.06.2014
Trade name: TSF 6522RH TACKY SOLDER FLUX
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
*
(Continued from page 6)
16 Other information
The information contained herein is based on data considered accurate and is offered solely for information, consideration
and investigation. Kester extends no warranties, makes no representations and assumes no responsibilty as to the
accuracy, completeness or suitability of this data for any pur chaser's use. The data on this Safety Data Sheet (SDS)
relates only to this product and does not relate to use with any other material or in any process. All chemical products
should be used only by, or under the direction of, technically qualified personnel who are aware of the hazards involved
and the necessity for reasonable care in handling. Hazard communication regulations require that employees must be
trained on how to use a Safety Data Sheet (SDS) as a source for hazard information.
Department issuing MSDS: Product Compliance / EHS Department
Contact: [email protected]
Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International
Transport of Dangerous Goods by Rail)
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of
Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Resp. Sens. 1: Sensitisation - Respirat., Hazard Category 1
Skin Sens. 1: Sensitisation - Skin, Hazard Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
* Data compared to the previous version altered.
GB

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