DAITOSOL www.daitokasei.com No.5 改定日:2013年9月26日 大東化成工業株式会社 DAITOSOL I. DAITOSOLとは? 現在、アクリル酸アルキル共重合体エマルションはアイライナー・マスカラの被膜剤として 代表的なものの1つに挙げられます。 当社のDAITOSOL 5000ADとDAITOSOL 5000SJはこのアクリル酸アルキル共重合体エ マルションを代表する製品で,日本では、35年間以上もの販売実績を誇ります。 II. DAITOSOLの特徴 DAITOSOLをアイライナー・マスカラに配合すると以下のような効果が期待されます。 (1) 柔軟で強い被膜が得られる (2) 薄い被膜で光沢が長持ちする (3) 耐水性のある被膜が形成される また、35年間以上の使用実績から、安全性についても優れていることがわかります。 最近では、この柔軟な被膜特性を活用した、スキンケア・パック・フットケア製品などの新 たな市場も開拓されています。 III. 当社のDAITOSOLは残存モノマーが非常に少ない アクリル酸アルキル共重合体はアクリルの残存モノマー低減の要求が強く、当社はその ニーズに応えるために、独自の製造技術で以下の値を達成しています。 ・規格項目及び規格値 規格項目 DAITOSOL 5000AD DAITOSOL 5000SJ 残存モノマー 40ppm以下 (アクリル酸エチルとして) 80ppm以下 (n-アクリル酸ブチルとして) 参考 粧配規規格 1.5%以下 1.5%以下 DAITOSOL 製品名 DAITOSOL 5000AD DAITOSOL 5000SJ DAITOSOL 4000SJT DAITOSOL 5000STY INCI Name アクリレーツコポリマー (アクリレーツ/アクリル酸 エチルヘキシル) コポリマー (アクリレーツ/アクリル酸 エチルヘキシル) コポリマー (スチレン/アクリレーツ) コポリマー 外観 乳白色エマルション 5000AD 5000SJ 4000SJT 5000STY 5500GM 皮膜外観 透明、艶のある皮膜 粘着性 5000GM > 5000AD > 5000STY = 5000SJ = 4000SJT > 3000VP3 > 3000SLPN-PE1 粒子径 (nm) 140 130 60 125 粘度 (mPa・s) 50-150 50-200 50 600 pH 5.5 - 7.5 2.0 - 5.0 2.0 - 5.0 6.5 - 7.5 固形分 (%) 50 50 40 50 Tg (℃) -14 -13 -13 7 防腐剤 デヒドロ酢酸Na なし (低pHのため) なし (低いpHのため) デヒドロ酢酸Na 特徴 - 柔軟で柔らかい皮膜 -柔軟性 - 優れた付着性 - 耐水性とクレンジン - ファイバー、ビーズと グ性の優れたバラン の組み合わせで付着 ス 性アップ - 防腐剤フリー -2- - 柔軟性 - ロングラスティング - 耐水性とクレンジング - 優れた耐水性 性の優れたバランス - 優れた肌への付着性 - 防腐剤フリー - 耐摩擦性 DAITOSOL DAITOSOL 5500GM DAITOSOL 3000SLPN-PE1 DAITOSOL 3000VP3 (アクリレーツ/アクリル酸エチルヘ キシル)コポリマー アクリレーツコポリマー アクリレーツコポリマー 乳白色エマルション 乳白色液体 透明液体 製品名 INCI Name 外観 3000SLPN 3000VP3 皮膜の透明性 3000VP3 > 3000SLPN –PE1> 4000SJT > 5000SJ = 5000STY = 5500GM > 5000AD 皮膜外観 透明、艶のある皮膜 粘着性 5000GM > 5000AD > 5000STY = 5000SJ = 4000SJT > 3000VP3 > 3000SLPN-PE1 粒子径 (nm) 160 50 20 粘度 (mPa・s) 3000 30 15,000 7.0 - 8.5 7.0 - 9.0 7.0 - 9.0 固形分 (%) 55 30 30 Tg (℃) -67 37 25 防腐剤 デヒドロ酢酸Na フェノキシエタノール フェノキシエタノール pH - 優れた粘着性 特徴 - 肌への付着性 - 高いTg、固い皮膜 - つけまつ毛の糊として - 優れた透明性 - 二重まぶたの固定化剤とし - タックフリー て -3- - 固い皮膜 - 高粘度 - 優れた透明性 - タックフリー DAITOSOL DAITOSOL Map Tg(℃) 固い皮膜 3000SLPN-PE1 3000VP3 5000STY 0℃ 4000SJT 5000SJ 柔らかい皮膜 5000AD 5500GM 高い 低い 耐水性 Mechanical Property Modulus (Mpa) 1.80 1.50 5000AD 1.20 5000SJ 0.90 4000SJT 5000STY 0.60 0.30 0.00 0 500 1000 1500 2000 2500 Elongation (%) -4- 3000 3500 4000 Suggested Formula 1. 皮膜剤として 2. 糊剤として BODY GLIMMER For False Eye Lash MASCARA&EYE LINER POINT MAKE-UP FOUNDATION & SUN SCREEN For Double Eye Lid DAITOSOL 3. ピーリング剤として PEELING MOUSSE 4. リフティング剤として LIFTING GEL PEELING CREAM Tightening Effect -5- 1. 皮膜剤として Long Lash & Volume-up Mascara No. DM/014 <Phase> <%> <Ingredient> 5.50 9.00 2.00 2.00 2.00 2.00 5.00 A A A A A A A CARNAUBA BEESWAX STEARIC ACID GLYCERYL STEARATE SE B B B B B WD-IOB50 DE-IONIZED WATER MAKILENE GC AMINOMETHYL PROPANEDIOL PRESERVATIVE C DAITOSOL 5000STY PROPYLENE GLYCOL STEARATE POLYISOBUTENE DIMETHICONE <Trade Name> <Supplier> LUNAC S-98 RHEODOL MS165V HOMOTEX PS-200 Kao Chemicals Kao Chemicals Kao Chemicals KF-96L-2CS Shin Etsu 20.00 19.70 2.00 0.50 0.30 DAITO KASEI 30.00 100.00 DAITO KASEI TOTAL : TOTAL : 97.00 3.00 100.00 (FINAL COMPOUND) MASCARA BASE NFCB-17D-6R DKE DAITO KASEI <MANUFACTURING PROCEDURE> 1. Heat the mixture of Phase A and Phase B to 80C separately. +28.7 % longer 2. Adjust loss of water and dimethicone evaporated during heating. 3. Add Phase A into Phase B, and keep stirring until the mixture is homogeneous. 4. Add Phase C under stirring below 50C. 5. M ix well fiber in mascaea base. Eye Lash Model Length: 9.92mm Length: 7.71mm Volume: 17.60mm 2 Volume: 10.57mm 2 +66.5 % volume-up Super Long Lasting Eye Liner No. DE/001 <Phase> A A A A <%> 8.50 0.20 1.00 0.30 <Ingredient> DE-IONIZED WATER XANTHAN GUM MAKILENE GC PRESERVATIVE B WD-CB2 C C DAITOSOL 3000SLPN DAITOSOL 3000VP3 TOTAL : <Trade Name> <Supplier> KELTROL CG-T SANSHO DKE 20.00 DAITO KASEI 20.00 50.00 100.00 DAITO KASEI DAITO KASEI <MANUFACTURING PROCEDURE> 1. Prepare Phase A. 2. Add Phase B, and Phase C into Phase A under stiring. Applying running water -6- Rubbing: 10 times Rubbing: 30 times Volumizing Separate Mascara No. DM/015 <Phase> <%> <Ingredient> A A A A A A A CARNAUBA BEESWAX STEARIC ACID GLYCERYL STEARATE SE B B B B B B WD-IOB50 DE-IONIZED WATER MAKILENE GC MAKIMOUSSE 12 AMINOMETHYL PROPANEDIOL PRESERVATIVE C DAITOSOL 5000STY 5.50 9.00 2.00 2.00 2.00 2.00 5.00 PROPYLENE GLYCOL STEARATE POLYISOBUTENE DIMETHICONE <Trade Name> <Supplier> LUNAC S-98 RHEODOL MS165V HOMOTEX PS-200 Kao Chemicals Kao Chemicals Kao Chemicals KF-96L-2CS Shin Etsu 20.00 19.60 2.00 0.10 0.50 0.30 DAITO KASEI 30.00 100.00 DAITO KASEI TOTAL : TOTAL : 97.00 3.00 100.00 (FINAL COMPOUND) MASCARA BASE CELLULOBEADS D-10(CB2-15) DKE DAITO KASEI DAITO KASEI <MANUFACTURING PROCEDURE> 1. Heat the mixture of Phase A and Phase B to 80C separately. 2. Adjust loss of water and dimethicone(2cs) evaporated during heating. +18.0 % longer 3. Add Phase A into Phase B, and keep stirring until the mixture is homogeneous. 4. Add Phase C under stirring below 50C. 5. M ix well CELLULOBEADS in mascaea base. Eye Lash Model Length: 9.10mm Length: 7.71mm Volume: 18.13mm 2 Volume: 10.57mm 2 +71.5 % volume-up Pearly Eye Liner No. DE-0032-WDFB40 <Phase> <Ingredient> A DE-IONIZED WATER A MAKILENE GC A XANTHAN GUM A HECTORITE A PRESERVATIVE Blue Light Blue Green Violet <%> <%> <%> <%> 51.10 47.50 51.80 56.60 1.00 1.00 1.00 1.00 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.30 0.30 0.30 0.30 <Trade Name> <Supplier> KELTROLCG-T LAPONITE XLS DKE SANSHO ROCKWOOD B B B B WD-FB40 WD-Ti50 WD-IOY50 WD-IOR50 12.00 4.20 - 10.00 9.80 - 3.60 2.00 3.90 - 2.60 1.40 0.70 DAITO KASEI DAITO KASEI DAITO KASEI DAITO KASEI C C C DK PEARL-GFIF WHITE DK PEARL GOLD DK PEARL BORDEAUX 10.00 - 10.00 - 16.00 - 16.00 DAITO KASEI DAITO KASEI DAITO KASEI D DAITOSOL 5000STY 20.00 TOTAL : 100.00 20.00 100.00 20.00 100.00 20.00 100.00 DAITO KASEI <MANUFACTURING PROCEDURE> 1. Disperse Xanthan gum and Hectorite in butylene glycol and preservative. 2. Add water, heat to 40-50C, and disperse well. 3. Add Phase B into Phase A, and keep stirring until the mixture is homogeneous. 4. Add Phase C into Phase A+B, and keep stirring until the mixture is homogeneous. 5. Add Phase D under stirring. -7- Body Glimmer Gel No. DO-0065-SJ <Phase> A A A <%> 61.20 5.00 1.00 <Ingredient> DE-IONIZED WATER MAKILENE GC MAKIMOUSSE 12 B DAITOSOL 5000SJ C ETHANOL D D D DK PEARL SILVER2 DK PEARL BRONZE DK PEARL GOLD <Trade Name> <Supplier> DKE DAITO KASEI 5.00 DAITO KASEI 25.00 TOTAL : 1.50 0.80 0.50 100.00 DAITO KASEI DAITO KASEI DAITO KASEI <MANUFACTURING PROCEDURE> 1. Disperse MAKIMOUSSE 12 in MAKILENE GC, and add water to prepare gel. 2. Add Phase B and C one after another. 3. Add Phase D and keep stirring until the mixture is homogeneous. Mousse Jelly Eye Shadow No. DO/015 <Phase> A A A A <Ingredient> DE-IONIZED WATER MAKILENE GC PRESERVATIVE MAKIMOUSSE 25 B B B B B B OTS-2 TALC JA-46R OTS-2 DK PEARL VIOLET OTS-2 DK PEARL-SY COPPER OTS-2 DK PEARL-SY GOLD OTS-2 DK PEARL-GFIF WHITE CELLULOBEADS D-10 C DAITOSOL 4000SJT <MANUFACTURING PROCEDURE> VIOLET COPPER GOLD <%> <%> <%> <Trade Name> <Supplier> 73.70 5.00 0.30 1.00 73.70 5.00 0.30 1.00 73.70 5.00 0.30 1.00 4.00 4.00 4.00 3.00 4.00 4.00 4.00 3.00 4.00 4.00 4.00 3.00 DAITO KASEI DAITO KASEI DAITO KASEI DAITO KASEI DAITO KASEI DAITO KASEI 5.00 5.00 5.00 TOTAL : 100.00 100.00 100.00 DAITO KASEI DKE DAITO KASEI 1. Disperse MAKIMOUSSE 25 in MAKILENE GC and preservative, and add water to prepare gel. 2. Add Phase B into Phase A under stirring. 3. Add phase C into the mixture of phase A+B, and keep stirring until the mixture is homogeneous. Soufflé Touch Blush No. DO/018 <Phase> A A A A <Ingredient> DE-IONIZED WATER MAKILENE GC PRESERVATIVE MAKIMOUSSE 12 B B B B B B B MST-1 TiO2 R250 MST-1 YELLOW No.602P MST-1 RED No.211P MST-1 BLACK No.710P SI-2 D&C RED No.30 MST-3 DK PEARL-IF RED MST-3 DK PEARL SILVER2 C DAITOSOL 4000SJT <%> <Trade Name> <Supplier> 83.95 5.00 0.30 0.70 DKE DAITO KASEI DAITO DAITO DAITO DAITO DAITO DAITO DAITO 0.50 0.15 0.20 0.10 0.10 3.00 1.00 KASEI KASEI KASEI KASEI KASEI KASEI KASEI DAITO KASEI 5.00 TOTAL : 100.00 <MANUFACTURING PROCEDURE> 1. Disperse MAKIMOUSSE 12 in MAKILENE GC and preservative, and add water to prepare gel. 2. Mix well pigments (Phase B) to obtain a shade, and add Phase B into Phase A under stirring. 3. Add phase C into the mixture of phase A+B, and keep stirring until the mixture is homogeneous. -8- Aqueous Manicure No. DO/037 Red <Phase> A A A <Ingredient> (MANICURE BASE) DAITOSOL 3000SLPN-PE1 HECTORITE 10% ARGININE solution <%> TOTAL: A B B B B B B (FINAL COMPOUND) MANICURE BASE WD-R7-15(BP) WD-CB2 WD-FB40 WD-IOY50 WD-IOR50 DK PEARL-SY SILVER TOTAL : Black <%> Blue <%> Pearl <%> Beige <%> <Trade Name> 93.00 7.00 100.00 93.00 7.00 100.00 98.50 1.50 100.00 100.00 100.00 98.00 Laponite XLS 2.00 100.00 90.00 10.00 100.00 93.00 7.00 100.00 95.00 5.00 100.00 97.50 2.50 100.00 97.67 0.06 0.22 0.25 1.80 100.00 <MANUFACTURING PROCEDURE> 1. Prepare Phase A, disperse HECTORITE into DAITOSOL3000SLPN under stirring at 500rpm for 30 minutes. 2. Prepare Phase A, add 10% ARGININE solution into DAITOSOL 3000SLPN under simple mixing. 3. Add Phase B into Phase A and keep stirring at 500rpm for 1 minutes. -9- <Supplier> DAITO KASEI ROCKWOOD DAITO DAITO DAITO DAITO DAITO DAITO KASEI KASEI KASEI KASEI KASEI KASEI Aqueous Wet Effect Lipgloss No. DLP/021 <Phase> A A A A A A A <Ingredient> OCTYLDODECANOL MAKIGREEN GF DK-PGT PASTE R7 DK-PGT PASTE Y5L DK-PGT PASTE IOR OTS-2 DK PEARL-SY SILVER OTS-2 DK PEARL-GFIF WHITE B B B DE-IONIZED WATER DAITOSOL 3000VP3 PRESERVATIVE C ALCOHOL Beige <%> 30.20 11.25 0.04 0.36 0.45 1.80 5.40 Red <%> 35.00 13.00 1.50 - 5.20 44.00 0.30 5.20 44.00 0.30 <Trade Name> KALCOL 200GD <Supplier> Kao DKE DAITO KASEI DAITO KASEI DAITO KASEI DAITO KASEI DAITO KASEI DAITO KASEI 1.00 1.00 TOTAL: 100.00 100.00 <MANUFACTURING PROCEDURE> After 30 Minutes 1. Heat Phase A until 80C, mix well, and cool to room temperature. 2. Add Phase B to Phase A under stirring. 3. Add Phase C into Phase A+B, and mix well. Magic Lip Gloss No. DLP/022 <Phase> A <Ingredient> MAKIFLUID OL <Red> <Beige> <%> <%> <Trade Name> <Supplier> DAITO KASEI 80.50 80.50 3.00 3.00 10.00 10.00 DAITO KASEI (POLYISOBUTENE (AND) PENTAERYTHRITYL TETRAISOSTEARATE (AND) PHENYL TRIMETHICONE (AND) CETYL PEG/PPG-10/1 DIMETHICONE (AND) POLYGLYCERYL-2 ISOSTEARATE (AND) HEXYL LAURATE) RHEOPEARL KL2 CHIBA FLUOR B DEXTRIN PALMITATE C DAITOSOL 4000SJT D OTS-2 DK PEARL-GFIF WHITE 1.50 1.50 DAITO KASEI E E E SUGARCAPSULE MAGIC RED SP 5.00 SUGARCAPSULE MAGIC YELLOW SP SUGARCAPSULE MAGIC BLACK SP TOTAL : 100.00 2.75 1.00 1.25 100.00 DAITO KASEI DAITO KASEI DAITO KASEI <MANUFACTURING PROCEDURE> 1. Heat Phase A and disperse DEXTRIN PALMITATE well. 2. Add Phase C under stirring. 3. Add phase D and mix well. 4. Add phase E and mix well. -9- Long Lasting O/W Liquid Foundation No. DL/045 <Phase> A A A A <%> <Ingredient> STEARIC ACID GLYCERYL STEARATE SE CETYL ALCOHOL MINERAL OIL 2.50 1.80 0.50 9.90 B B B B B ASI TiO2 CR-50 ASI YELLOW LL-100P ASI RED R-516P ASI BLACK BL-100P CELLULOBEADS D-10 8.50 1.00 0.30 0.20 3.00 C C C C C DE-IONIZED WATER MAKILENE GC XANTHAN GUM TRIETHANOLAMINE (90%) PRESERVATIVE D DAITOSOL 5000STY 51.60 9.00 0.20 1.20 0.30 TOTAL : <Trade Name> <Supplier> Kao Chemicals LUNAC S-98 RHEODOL MS165V Kao Chemicals DAITO DAITO DAITO DAITO DAITO KELTROL CG-T KASEI KASEI KASEI KASEI KASEI DKE SANSHO DAITO KASEI 10.00 100.00 DL/045 (STY 10%) <MANUFACTURING PROCEDURE> BLANK 1. Mix well pigments (phase B) to obtain a shade. 2. Add Phase B into Phase A Under stirring. 3. Prepare Phase C to prepare gel. 4. Heat the mixture of Phase A and Phase C to 80C degree separately. 5. Adjust loss of water evaporated during heating. 6. Add Phase A+B into Phase C , and keep stirring until the mixture is homogeneous. 7. Add Phase D below 40C degree, and mix well. 30 Minutes Later Stretch Sun Screen No. DS/002 <Phase> A A A A DS/002 BLANK <%> <%> <Ingredient> PHENYLTRIMETHICONE TRIDECYL ISONONANOATE CELLULOBEADS D-10 DIMEHICONE/VINYL DIMETHICONE CROSSPOLYMER (AND) DIMETHICONE 1.00 3.00 3.00 1.00 1.00 3.00 3.00 1.00 A A A Daitopersion Zn-50 Daitopersion Ti-30 CYCLOMETHICONE 30.00 20.00 5.00 30.00 20.00 5.00 B B B B B DE-IONIZED WATER 1,3-BUTYLENE GLYCOL SODIUM CHLORIDE PRESERVATIVE DISODIUM EDTA 19.65 6.00 1.00 0.30 0.05 29.65 6.00 1.00 0.30 0.05 C DAITOSOL 5000SJ 10.00 100.00 100.00 TOTAL : <Trade Name> <Supplier> KF-56 SALACOS 913 KSG-16 Shin Etsu Nisshin Oillio DAITO KASEI Shin Etsu KF-995 DAITO KASEI DAITO KASEI Shin Etsu PHENONIP DAITO KASEI <MANUFACTURING PROCEDURE> 1. Prepare Phase A and Phase B separately. 2. Add Phase B to Phase A and keep stirring until the mixture is homogeneous. 3. Add phase C, and keep stirring until the mixture is homogeneous. Flexibility of Sun Screen Applied on the artificial skin (0.08g/40cm2), dried for 1 hour, stretched the artificial skin, and checked the appearance. DS/002 (+5000SJ 10%) - 10 - Blank 2. 糊剤として Eyelash Glue No. DE-0024-GM <Phase> A <Ingredient> DAITOSOL 5500GM <%> <Trade Name> 100.00 TOTAL : 100.00 <Supplier> DAITO KASEI <MANUFACTURING PROCEDURE> 1. Put Phase A into a suitable container. Eyelash Glue (Black) No. DE-0025-GM <Phase> A A <%> <Ingredient> DAITOSOL 5500GM WD-CB2 TOTAL : <Trade Name> 90.00 10.00 100.00 <Supplier> DAITO KASEI DAITO KASEI <MANUFACTURING PROCEDURE> 1. Mix well Phase A and put into a suitable container. Eyelash Glue Gel No. DE-0026-GM <Phase> A A A B <%> <Ingredient> DE-IONIZED WATER 1,3-BUTYLENE GLYCOL MAKIMOUSSE 12 <Trade Name> 18.65 1.00 0.35 DAITOSOL 5500GM TOTAL : <Supplier> DAITO KASEI 80.00 100.00 DAITO KASEI <MANUFACTURING PROCEDURE> 1. Disperse MAKIMOUSSE 12 in 1,3-Butylene Glycol and add water to prepare gel. 2. Add phase B into Phase A and mix well. - 11 - 3. ピーリング剤として Peeling Massage Lotion/Cream No. DO-0066-AD <Phase> A A A A A <Ingredient> (CREAM BASE) MAKILENE GC MAKIMOUSSE 12 DE-IONIZED WATER ALCOHOL PRESERVATIVE B B PHENYL TRIMETHICONE DAITOSOL 5000AD TOTAL : Lotion <%> Cream <%> +Scrub <%> 10.00 6.70 10.00 0.30 10.00 1.00 28.70 0.30 10.00 1.00 28.70 0.30 20.00 53.00 100.00 20.00 40.00 100.00 20.00 40.00 100.00 <Trade Name> <Supplier> DKE DAITO KASEI KF-56 Shin Etsu DAITO KASEI (FINAL COMPOUND) CREAM BASE CELLULOBEADS D-200 95.00 5.00 100.00 DAITO KASEI <MANUFACTURING PROCEDURE> 1. Disperse MAKIMOUSSE 12 in MAKILENE GC, add the rest of Phase A, and prepare gel. 2. Prepare Phase B (Add PHENYL TRIMETHICONE to DAITOSOL 5000AD under stirring). 3. Add Phase B into Phase A, and keep stirring until the mixture is homogeneous. 4. リフティング剤として Lifting Gel No. DO-0069-SJ <Phase> A A A A <%> 5.00 0.50 0.50 84.00 <Ingredient> MAKILENE GC MAKIMOUSSE 12 PRESERVATIVE DE-IONIZED WATER B SACRAN-05 C C DAITOSOL 5000SJ DIMETHICONE (6cs) <Trade Name> 2.00 5.00 3.00 100.00 TOTAL : <Supplier> DKE DAITO KASEI DAITO KASEI KF-96A 6cs DAITO KASEI Shin Etsu <MANUFACTURING PROCEDURE> 1. Prepare Phase A, disperse M AKIM OUSSE 12 in M AKILENE GC and preservative, and add water to prepare gel. 2. Add Phase B, and keep stirring until the mixture is homogeneous. 4. Prepare Phase C (Add DIM ETHICONE to DAITOSOL 5000SJ under stirring). 5. Add Phase C, and keep stirring until the mixture is homogeneous. - 12 -
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