SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr Version Revision date Print Date Page 115621 4.1 / GB 31.07.2012 14.02.2014 1 / 14 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product information Trade name Oxooil HS9 Octene, hydroformylation products, high-boiling Company Evonik Industries AG Performance Intermediates Product Stewardship POSTFACH D-45764 Marl Telephone Telefax +49 (0)2365/49-6172 +49 (0)2365/49-2670 [email protected] +49 (0)2365/49-2232 +49 (0)2365/49-4423 Email address Emergency telephone number Emergency telephone number(Telefax) (Werkfeuerwehr, Infracor GmbH) Use of the Substance / Preparation intermediate Solvent REACH-No. 01-2119486463-31-0001 2. HAZARDS IDENTIFICATION Classification according to Regulation (EC) No. 1272/2008 [CLP] Labelling not required according to EU-CLP Ordinance (1272/2008). GHS-Labelling Labelling not required according to EU-CLP Ordinance (1272/2008). Statutory basis Classification as per Directive 67/548/EC or Directive 1999/45/EC No labelling required Other Hazards Vapours can form explosive mixtures with air. Not a PBT, vPvB substance as per the criteria of the REACH Ordinance. 3. COMPOSITION/INFORMATION ON INGREDIENTS Information on ingredients / Hazardous components as per EU-CLP Regulation (EC) No. 1272/2008 • Octene, hydroformylation products, high-boiling CAS-No. 68526-89-6 EC-No. 271-237-7 REACH-No. 01-2119486463-31-0001 Information on ingredients / Hazardous components as per Directive 67/548/EC or Directive 1999/45/EC • Octene, hydroformylation products, high-boiling EU-GHS(R11/011) / 31.07.2012 14:46 SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr CAS-No. Version Revision date Print Date Page 115621 68526-89-6 EC-No. 4.1 / GB 31.07.2012 14.02.2014 2 / 14 271-237-7 REACH-No. 01-2119486463-31-0001 Other information Mixture of oxygen-containing compounds. Texts of H phrases, see in Chapter 16 See chapter 16 for text of risk phrases 4. FIRST AID MEASURES Description of first aid measures Take care of your own personal safety. Remove affected persons from the hazard area. Remove contaminated or soaked clothing immediately and dispose of safely. Keep warm, position comfortably, and cover well. Do not leave affected persons unattended. Inhalation Remove to fresh air. Monitor breathing, give oxygen if necessary. If symptoms persist, call a physician. Skin contact Wash off with plenty of water and soap immediately, seek medical advice if necessary. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses if this can be easily done. Seek medical advice. Ingestion Rinse out mouth. Seek medical advice immediately. Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed No specific antidote known. Symptomatic treatment. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Water spray, foam, CO2, dry powder. Unsuitable extinguishing media high volume water jet Special hazards arising from the substance or mixture In case of fire cool endangered containers with water. Closed container may rupture if strongly heated. Formation of flammable or explosive vapour/air mixtures possible. Keep away from sources of ignition - No smoking. Special protective equipment for fire-fighters In the case of respirable dust and/or fumes, use self-contained breathing apparatus. EU-GHS(R11/011) / 31.07.2012 14:46 SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr 115621 Version Revision date Print Date Page 4.1 / GB 31.07.2012 14.02.2014 3 / 14 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear personal protective equipment; see section 8. Avoid contact with skin and eyes. Do not inhale vapours / aerosols. Ensure adequate ventilation. Keep away from sources of ignition - No smoking. Environmental precautions Do not allow entrance in sewage water, drainage systems, stretches of water, soil. Avoid penetration into drainage system or in rooms situated at a lower level because of danger of explosion. Issue an immediate alarm report to the company environmental protection department if the product unintentionally leaves the production area. Methods and material for containment and cleaning up Take up mechanically or with an absorbent material. Fill into marked, sealable containers. To be disposed of in compliance with existing regulations. Suitable binder: universal absorbent, sand (for damming up) 7. HANDLING AND STORAGE Handling Precautions for safe handling Wear personal protective equipment; see section 8. Avoid contact with skin and eyes. Do not inhale vapours / aerosols. Provide good ventilation or extraction. Advice on protection against fire and explosion Take precautionary measures against static charges, keep away from sources of ignition. Ensure explosion proofness. Storage Conditions for safe storage, including any incompatibilities Keep container tightly closed. Unsuitable materials zinc Unsuitable materials light metals Advice on common storage Observe prohibition against storing together! German storage class 10 - Combustible liquids neither in Storage Class 3A nor 3B 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters DNEL/DMEL values End Use Routes of exposure Possible health damage EU-GHS(R11/011) / 31.07.2012 14:46 Workers Inhalation Long-term - systemic effects Repeated dose toxicity SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr Version Revision date Print Date Page 115621 4.1 / GB 31.07.2012 14.02.2014 4 / 14 Exposure time Value 8h 41.14 mg/m3 End Use Routes of exposure Possible health damage Workers dermal Long-term - systemic effects Repeated dose toxicity 11.67 mg/kg bodyweight/day Value End Use Routes of exposure Possible health damage Exposure time Value End Use Routes of exposure Possible health damage Value End Use Routes of exposure Possible health damage Value general populace Inhalation Long-term - local effects Repeated dose toxicity 8h 8.7 mg/m3 general populace Oral Long-term - systemic effects Repeated dose toxicity 2.5 mg/kg bodyweight/day general populace dermal Long-term - systemic effects Repeated dose toxicity 5 mg/kg bodyweight/day PNEC values Value surface water 0.1 mg/l Value marine water 0.01 mg/l Exposure controls Further information ACGIH (American Conference of Governmental Industry Hygienists) Personal protective equipment Respiratory protection In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded: use respiratory equipment with suitable filter (filter type A) or wear a self contained respiratory apparatus Hand protection Chemical-resistant protective gloves (EN 374) When handling for a short time: Glove material nitrile-butadiene rubber (NBR) gloves Selection of protective gloves to meet the requirements of specific workplaces. Suitability for specific workplaces should be clarified with protective glove manufacturers. The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials. Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to EN 374 due to the many different influential factors involved (e.g. temperature). Eye protection Safety glasses with side-shields EU-GHS(R11/011) / 31.07.2012 14:46 SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr Version Revision date Print Date Page 115621 4.1 / GB 31.07.2012 14.02.2014 5 / 14 Skin and body protection Select materials and equipment for physical protection depending on the concentration and volume of hazardous substances and the workplace involved. Hygiene measures Take off all contaminated clothing immediately. Avoid contact with skin and eyes. Do not inhale vapours / aerosols. Smoking, eating and drinking should be prohibited in the application area. Wash hands before breaks and at the end of workday. Use barrier cream regularly. Protective measures Wear suitable protective clothing. Environmental exposure controls Emissions from venting and processing equipment should be checked in order to ensure that the requirements of the Environmental Protection Law are satisfied. In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease emissions to acceptable values. See sections 6 and 7. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour Smell threshold: liquid Colourless to light yellow aromatic No data available Information on basic physical and chemical properties Melting point/range < -100 °C OECD TG 102 DSC analysis Method: Boiling point/range 235 - 370 °C (1013 hPa) Method: ASTM-D-1078 Method: Flash point > 85 °C (1013 hPa) DIN EN ISO 2719 (Pensky-Martens, Closed Cup) Varying value The percentile proportions of the content substance may vary. Method: Flammability (solid, gas) not applicable liquid Ignition temperature 240 °C (1007 hPa) Method: DIN 51 794 Varying value Thermal decomposition > 250 °C Oxidizing properties Not to be expected in view of the structure Explosiveness Not explosive as defined by EU hazardous substance law. EEC method 92/69/EEC, A 14 The method includes tests for mechanical sensitivity (impact, friction) and thermal sensitivity under inclusion (steel sleeve or Koenen test). Method: EU-GHS(R11/011) / 31.07.2012 14:46 SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr Version Revision date Print Date Page 115621 4.1 / GB 31.07.2012 14.02.2014 6 / 14 Vapours can form explosive mixtures with air. 7 hPa Vapour pressure Method: (20 °C) OECD Test Guideline 104 Density (20 °C) 0.84 - 0.87 g/cm3 Method: DIN 51757 Relative density 0.8566 Method: (20 °C) OECD Test Guideline 109 Not to be expected. Information derived from practical experience. metal corrosion < 1.3 mg/l Water solubility Method: Partition coefficient (n-octanol/water) log Pow: Method: (20 °C) OECD Test Guideline 105 8.5 - 8.9 (25.5 - 26.0 °C) OECD 117 max. 30 mPa.s (20 °C) Method: DIN EN ISO 3104 Viscosity, dynamic 28.5 mm2/s (20 °C) OECD 114 Viscosity, kinematic Method: 12.1 mm2/s (40 °C) Method: OECD 114 Further information OECD 115 Cannot be determined due to low level of solubility in water. Surface tension Method: 10. STABILITY AND REACTIVITY Reactivity no data available Chemical Stability no data available Possibility of hazardous reactions Vapours may form explosive mixture with air. Conditions to avoid Keep away from heat and sources of ignition. Incompatible materials not known Hazardous decomposition products unknown 11. TOXICOLOGICAL INFORMATION Acute oral toxicity EU-GHS(R11/011) / 31.07.2012 14:46 LD50 Rat(female): > 2000 mg/kg Method: OECD TG 420 (Solid Dosing Method) Own study SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr 115621 Version Revision date Print Date Page 4.1 / GB 31.07.2012 14.02.2014 7 / 14 No labelling required Acute inhalation toxicity No test results available. Acute dermal toxicity LD50 Rat(male/female): > 2000 mg/kg Method: OECD Test Guideline 402 Skin irritation Rabbit / 4 h slightly irritating Method: OECD Test Guideline 404 No labelling required Own study May be irritating on frequent or long-term contact. Eye irritation Sensitization Rabbit / 72 h Mild eye irritation Method: OECD Guide-line 405 No labelling required Own test result. (Magnusson-Kligman test) guinea pig: not sensitizing to the skin Method: OECD Test Guideline 406 Repeated dose toxicity Oral Rat(male) / 4 weeks Number of exposures: daily NOAEL: 300 mg/kg Method: OECD Test Guideline 407 Symptoms: Reduced bodyweight gain. Oral Rat(female) / 4 weeks Number of exposures: daily NOAEL: 1000 mg/kg Method: OECD Test Guideline 407 Assessment of STOT single exposure Assessment of STOT repeat exposure Risk of aspiration toxicity No data available Labelling not required by GHS regulation. No Aspiration toxicity classification Gentoxicity in vitro Ames test S. typhimurium / E. coli no evidence of mutagenic effects Metabolic activation: with or without Method: OECD TG 471 Carcinogenicity No test results are on file regarding carcinogenicity. Toxicity to reproduction No test results available. Teratogenicity No test results available. Toxicology Assessment Acute effects Sensitization Repeated dose toxicity EU-GHS(R11/011) / 31.07.2012 14:46 The substance must be classified as non-toxic in accordance with the EUCLP Ordinance if swallowed once or in case of brief skin contact. May cause slight irritant effects on skin/eyes. Not to be expected. Low-level long-term toxicity. No relevant effects up to NOAEL SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr Version Revision date Print Date Page 115621 4.1 / GB 31.07.2012 14.02.2014 8 / 14 (see Toxicity in case of repeated exposure) CMR assessment Carcinogenicity Mutagenicity Teratogenicity Toxicity to reproduction No test results are on file regarding carcinogenicity. The substance showed no genotoxic properties in bacteria. No data available No data available 12. ECOLOGICAL INFORMATION Elimination information (persistence and degradability) Biodegradability aerobic Exposure time: 28 d Result: 80 - 90 % biodegradable Method: OECD TG 301 B (CO2; Sturm test / OECD 301 B) aerobic inoculum: Activated sludge Exposure time: 28 d Result: 56 % Method: (CO2; modif. Sturm test - 92/69/EEC part C.4-C) Own study aerobic inoculum: Activated sludge Exposure time: 28 d Result: 60 % biodegradable Method: CO2 Evolution Test ISO 9439 (draft) System not adapted Own study Behaviour in environmental compartments Bioaccumulation Due to the distribution coefficient n-octanol/water, accumulation in organisms is possible. log Pow: see chapter 9 Mobility Due to the high octanol / water coefficient, adhesion to soil components, and thus a low mobility level in the soil, is to be expected. Ecotoxicity effects Toxicity to fish Toxicity to daphnia LL50 semi-static test Oncorhynchus mykiss (rainbow trout): > 100 mg/l / 96 h Analytical monitoring: yes Method: OECD TG 203 Water Accomodated Fraction (WAF) EL50 static test Daphnia magna (Water flea): > 100 mg/l / 48 h Analytical monitoring: yes Method: OECD TG 202 Water Accomodated Fraction (WAF) Toxicity to algae EL50 static test Desmodesmus subspicatus: > 100 mg/l / 72 h Analytical monitoring: yes EU-GHS(R11/011) / 31.07.2012 14:46 SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr Version Revision date Print Date Page 115621 4.1 / GB 31.07.2012 14.02.2014 9 / 14 Method: OECD TG 201 Water Accomodated Fraction (WAF) Toxicity to bacteria EC50 Respiration inhibition Community sewage sludge: > 1000 mg/l / 3 h Analytical monitoring: yes Method: OECD TG 209 chronic toxicity in fish No test results available. chronic toxicity in daphnia No test results available. Toxicity in organisms which live in LC50 artificial soil Eisenia foetida: > 1000 mg/kg / 14 d the soil Method: OECD 207 NOEC artificial soil Eisenia foetida: 1000 mg/kg / 14 d Method: OECD 207 Toxicity in terrestrial plants EC50 Avena sativa (Gramineae): > 1000 mg/kg Test period: 21 d End point: Height growth seedling, shoot fresh weight, emerged seedlings Method: OECD 208 EC50 Brassica napus (Brassicaceae): > 1000 mg/kg Test period: 21 d End point: Height growth seedling, shoot fresh weight, emerged seedlings Method: OECD 208 EC50 Glycine max (Leguminosae): > 1000 mg/kg Test period: 21 d End point: Height growth seedling, shoot fresh weight, emerged seedlings Method: OECD 208 Ecotoxicology Assessment Acute aquatic toxicity The substance does not show acute toxicity in aquatic organisms. Aquatic toxicity is unlikely due to low solubility. Chronic aquatic toxicity No test results available. Based on acute toxicity and biodegradation data no classification as chronic toxic to waterorganisms. Toxicity Data on Soil The substance does not show any effects on terrestrial organisms. Other Environmental Relevant No data available Organisms Impact on Sewage Treatment Not to be expected. Inherently biodegradable. Properly treated effluents containing low concentrations of the product are not expected to inhibit the activated sludge in a sewage plant. Results of PBT assessment Not a PBT, vPvB substance as per the criteria of the REACH Ordinance. 13. DISPOSAL CONSIDERATIONS Product With respect to local regulations, e.g. dispose of to waste incineration plant EU-GHS(R11/011) / 31.07.2012 14:46 SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr Version Revision date Print Date Page 115621 4.1 / GB 31.07.2012 14.02.2014 10 / 14 No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer. The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority. 14. TRANSPORT INFORMATION Inland waterway transport ADN/GGVSEB (Germany) Class 9 ADR/RID-Labels UN-No / Substance number 9003 Description of the goods (Technical name) STOFFE MIT EINEM FLAMMPUNKT ÜBER 60°C UND HÖCHSTENS 100 °C Loading instructions/Remarks ADR Not classified as dangerous for conveyance in the meaning of the Carriage of Dangerous Goods by Road and Rail (ADR / RID). Not classified as dangerous for conveyance in the meaning of the Carriage RID of Dangerous Goods by Road and Rail (ADR / RID). IMDG Not classified as hazardous sea cargo (IMDG code) FOR USA ONLY: In packagings exceeding 450 L, this product must be classified, placarded, marked and shipped as Combustible Liquid to the USA. IATA_C Not hazardous freight in air traffic (ICAO-TI / IATA-DGR). Not hazardous freight in air traffic (ICAO-TI / IATA-DGR). IATA_P ADN Dangerous goods class 9, Identification-No. 9003 ADN, when only transported by inland waterways tanker. 15. REGULATORY INFORMATION REACH Chemical Safety Assessment No substance safety assessment is required for this product. National legislation Prohibited Chemicals Ordinance Comply with restrictions according to Annex XVII of the REACH Directive (1907/2006). 16. OTHER INFORMATION Risk phrase (R phrase) texts Texts of the H-phrases Further information Changes since the last version are highlighted in the margin. This version replaces all previous versions. EU-GHS(R11/011) / 31.07.2012 14:46 SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr 115621 Version Revision date Print Date Page 4.1 / GB 31.07.2012 14.02.2014 11 / 14 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. EU-GHS(R11/011) / 31.07.2012 14:46 SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr 115621 Version Revision date Print Date Page 4.1 / GB 31.07.2012 14.02.2014 12 / 14 Legend ADR ADN ASTM ATP BCF BetrSichV c. c. CAS CESIO ChemG CMR DIN DNEL EINECS GefStoffV GGVSEB GGVSee GLP GMO IATA DGR ICAO-TI IMDG Code ISO LOAEL LOEL NOAEL NOEC NOEL o. c. OECD OEL PBT PEC PNEC RID TA TPR TRGS VCI vPvB VOC VwVwS WGK WHO EU-GHS(R11/011) / 31.07.2012 14:46 European Agreement concerning the International Carriage of Dangerous Goods by Road European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways American Society for Testing and Materials Adaptation to Technical Progress Bioconcentration Factor German Ordinance on Industrial Safety and Health closed cup (geschlossenes Gefäß) Chemical Abstract Services European Committee of Organic Surfactants and their Intermediates German Chemicals Act Carcinogenic-Mutagenic-toxic for Reproduction German Institute for Standardization Derived No Effect Level European Inventory of Existing Commercial Chemical Substances German Ordinance on Hazardous Substances German ordinance for road, rail and inland waterway transportation of dangerous goods German ordinance for sea transportation of dangerous goods Good Laboratory Practice. Genetic Modified Organism International Air Transport Association – Dangerous Goods Regulations International Civil Aviation Organisation - Technical Instructions International Maritime Dangerous Goods Code International Organization For Standardization Lowest Observed Adverse Effect Level Lowest Observed Effect Level No Observed Adverse Effect Level No Observed Effect Concentration No Observed Effect Level open cup (offenes Gefäß) Organisation for Economic Cooperation and Development Occupational Exposure Limit Persistent, Bioaccumulative, Toxic Predicted Effect Concentration Predicted No Effect Concentration Regulations concerning the International Carriage of Dangerous Goods by Rail Technical Instructions (German Ordinance) Third Party Representative (Art. 4) Technical Rules for Hazardous Substances (German Regulations) German "Verband der Chemischen Industrie e. V." Very Persistent, Very Bioaccumulative Volatile Organic Compounds German Administrative Regulation on the Classification of Substances Hazardous to Waters into Water Hazard Classes German Water Hazard Class World Health Organization SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr Version Revision date Print Date Page 115621 4.1 / GB 31.07.2012 14.02.2014 13 / 14 ANNEX Exposure scenario ES1: General exposure scenario 1. Short title of exposure scenario ES1: General exposure scenario 2. Description of activities/process(es) covered in the Exposure Scenario Sector of use Product category Process category Article category Cat. release to the environment SU10 Formulation [mixing] of preparations and/or re-packaging (excluding alloys) SU0 Other fuel PC13 Fuels PC19 Intermediate PROC1 Use in closed process, no likelihood of exposure PROC2 Use in closed, continuous process with occasional controlled exposure PROC3 Use in closed batch process (synthesis or formulation) Use in batch and other process (synthesis) where PROC4 opportunity for exposure arises PROC5 Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact) PROC8a Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities PROC16 Using material as fuel sources, limited exposure to unburned product to be expected NOT_APPL not applicable IC ERC1 Manufacture of substances ERC2 Formulation of preparations ERC8e Wide dispersive outdoor use of reactive substances in open systems ERC9b Wide dispersive outdoor use of substances in closed systems 3. Application conditions Assumes a good basic standard of occupational hygiene has been implemented. See Section 6 of the Safety Data Sheet. See Section 7 of the Safety Data Sheet. See Section 8 of the Safety Data Sheet. 3.1 Duration and frequency Not required 4.1 Physical form Not required 4.2 Concentration of substance in preparation Remarks Not required 4.3 Amount used per time or per activity EU-GHS(R11/011) / 31.07.2012 14:46 SAFETY DATA SHEET (EC 1907/2006) Oxooil HS9 Material no. Specification VA-Nr Version Revision date Print Date Page 115621 Remarks Not required 5. Other operational conditions Remarks Not required 6. RISK MANAGEMENT MEASURES 6.1.1 Occupational Measures Not required 6.1.2 Consumer related measures Not required 6.2 Environment related measures Not required 7. Waste related measures Remarks Not required 8. Prediction of exposure Remarks 9. Guidance to downstream user Not required EU-GHS(R11/011) / 31.07.2012 14:46 Not required 4.1 / GB 31.07.2012 14.02.2014 14 / 14