D SCIENTIFIC MEASUREMENTS Poster concept and design by Valerie Nicoulaud Acknowledgements I would like to thank Dr. Kimberly Smith for supporting the development of this poster, letting me use her slides, and kindly reviewing my work. CHM130 Chapter PSS Scientific Measurements Adding and Subtracting Measurements MEASUREMENTS quantity estimated using an instrument, number with a unit. SIGNIFICANT FIGURES: final answer is limited by the number with the fewest decimal places. ROUNDING UP: If needed, round up your final answer. EXAMPLES OF QUANTITIES MEASURED Examples Correct answer A- Calculator answer 2 dec. pl. 1 dec. pl. B- Calculator answer Correct answer 1 dec. pl. 4 dec. pl. 3.0 mL . Keep only 1 dec. p.l Keep only 1 dec. pl. . 19.1 g . 1 dec. pl. rounded up Round up . EXAMPLE OF MEASUREMENT 0 1 2 3 4 5 cm 0 1 2 3 4 5 cm Multiplying and Dividing Measurements 2.4 cm SIGNIFICANT FIGURES: final answer is limited by the number with the least number of significant figures. 2.46 cm ROUNDING UP: If needed, round up your final answer. All measurements have some uncertainty involved since instruments can never give exact measurements! SCIENTIFIC NOTATION: If needed, use the scientific notation to express the answer with the right number of significant figures. Significant digits (also called Significant Figures or “Sig figs”): All known digits in a measurement plus 1st uncertain or estimated digit. Examples Correct answer C- Calculator answer Determining Significant Figures 4 sig figs 2 sig figs • First eliminate the non-significant digits WHOLE NUMBERS Keep only 2 sig figs 2 3 0 0 5 1 0 0 Trailing zeroes are not significant xx . Round up . 33 . Only 1 sig fig! We want to express this number with 2 sig figs. . 1.0 x 101 cm3 . 2 sig figs Use the scientific notation . . Scientific Notation Leading zeroes are not significant ONE DIGIT FOLLOWED BY A DECIMAL POINT: this is a number between 1 and 9. • Then count the remaining (significant) digits 23005100 xx 0. 0 0 2 3 0 0 5 1 0 0 x. x x xx Correct answer 2 sig figs 3 sig figs 2 sig figs rounded up Pay attention to the unit DECIMAL NUMBERS 0. 0 0 2 3 0 0 5 1 0 0 x. x x x x cm2 D- Calculator answer EXPONENTIAL TERM THAT IS 10 RAISED TO A POWER: For big #’s > 1 positive exponent, for small #’s < 1 negative exponent. 6 sig figs Examples 8 sig figs Rounding Off Non-significant Digits 1. < 5, don’t round up 2. ≥ 5, round up 3. Don't change the magnitude of the number use placeholder zeroes Examples Round these numbers off to 3 significant figures: 100.03 = 1.0003 x 102 0.000340 = 3.40 x 10-4 Exact Numbers • either DEFINE NUMBER: e.g., one meter is defined as 100 centimeters. • or RESULT OF A COUNT: e.g. 3 apples. Links Why are Significant Figures Important? Converting Units using Multiple Conversion Factors Scientific Notation and Significant Figures Unit Conversion & Significant Figures: Crash Course Chemistry #2 Apple retrieved from http://www.publicdomainpictures.net/view-image.php?image=37301&picture=red-apple-clipart&large=1 They have no uncertainty. They do not affect the number of significant figures in calculations. Example 100 cm 5.35 m 535 cm 1m Keep 3 sig figs Additional information Accuracy how close the measurement is from a correct value Precision consistency of repeated measurement . link: Accuracy and precision
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