Chairs of Urban Water Management Master Thesis Possible Topics in Urban Water Management Updated: 22.06.2016 You find the responsible contact in the contact information at the end of each topic description. If you are looking for a topic related to a given topic, you may as well contact the responsible person. If none of the listed topics fits you, you are encouraged to inform yourself about the different research fields at Eawag. If you are interested in a master thesis in one of the groups, please contact the responsible researcher directly. In any case, make sure that a clear formulation of your tasks is done and arranged with the responsible professor (Prof. Maurer or Prof. Morgenroth) before you start with your thesis! You can find the different research groups under the following links: http://www.eawag.ch/forschung/eng/schwerpunkte/index_EN http://www.eawag.ch/forschung/sww/schwerpunkte/index_EN 1/60 Chairs of Urban Water Management Identification of geogenic and anthropogenic sources of technology-critical trace elements in Swiss waste waters Background Trace elements are of increasing commercial importance for a variety of applications in electronics, catalysts, ceramics, metallurgy and pharmaceuticals. Particularly in high-tech applications, many trace elements (e.g., Ga, In, Te, Nb, Ta, platinum group elements, rare earth elements and certain heavy metals, Figure 1a) fulfil crucial roles. The global use and environmental fluxes of these socalled ‚technology-critical trace elements’ have increased tremendously due to economic and population growth over the last decades. Therefore, it may be assumed that the loads of these elements have risen correspondingly in waste waters and sewage sludge worldwide, but this has yet to be confirmed. As part of an ongoing effort to create a national inventory for trace element fluxes, we are measuring the concentrations of >60 major and trace elements in waste water treatment plants (WWTP) in Switzerland (Figure 1b). Figure 1. Periodic table of the elements with ‘Technology-Critical Elements’ highlighted (A) and a map of Switzerland with the locations of over 700 WWTPs and corresponding catchment areas (B). Objectives of the suggested topic The main goal of this Master thesis project is to quantitatively explain observed geographical element distributions as a function of natural and anthropogenic sources. The student will use a combination of state-of-the-art chemical analytics, GIS and statistical modelling to correlate observed concentrations with geological, lithological and mineralogical data, with population sizes or 2/60 Chairs of Urban Water Management presence of specific industries in the WWTP catchments or with meteorological/climatic datasets. Knowing the sources of these trace elements and emerging pollutants is highly relevant as it enables us to focus the attention of monitoring programs and to suggest treatment options that could increase the elimination or potential recovery of these valuable elements from waste streams. Specific tasks include: Participating in the sample collection campaign and with sample preparation Participating in the measurement of technology critical elements in waste water and sludge samples at the (ultra)trace level Identifying the relevant anthropogenic (industrial) sources and natural sources of a selected number of Technology-Critical elements Collecting suitable statistics on these potential sources (e.g., from geological maps and climatic and industrial data) and processing this data in GIS Statistical modelling to evaluate the relevance of these sources to observed elemental concentrations Requirements Interest in the occurrence and fate of emerging micro-pollutants in wastewater treatment plants and a good amount of motivation and initiative Experience with script oriented programming environments (R, Matlab), basic knowledge of statistical modelling and GIS is an asset Good knowledge of English This project will be performed in the department of Water Resources and Drinking Water at Eawag in collaboration with BAFU. Office space with computer will be provided. Advisors Prof. Dr. Eberhard Morgenroth Dr. Michael Berg (Eawag) Dr. Bas Vriens (Eawag) Contact information Bas Vriens, Eawag Email: [email protected] Phone: +41 058 765 6795 3/60 Chairs of Urban Water Management Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 4/60 Chairs of Urban Water Management The fluxes and behavior of mercury in waste water treatment plants in Switzerland Background Mercury and its (organo)compounds are extremely toxic substances to humans and other organisms. Because of its volatility, extensive atmospheric transport, persistence in the environment, bioaccumulation and associated negative impacts on entire ecosystems, mercury has been known as a pollutant of global concern for decades. In 2013, Switzerland ratified the Minamata Convention, which prohibits a number of mercury-containing products and their trade from the year 2020 onwards. In addition, ratifying countries need to identify sources of mercury, reduce the amount of mercury used and support mercury-free alternatives. In order to comply with the agreements of the convention, the mercury fluxes in Switzerland must be quantified, including those in waste streams. Although WWTPs could also play an important role in the control of mercury emissions into the environment, there is currently little quantitative knowledge on the fluxes and fate of mercury compounds in WWTPs in Switzerland. Figure 1. Overview of a mass balance of mercury in a WWTP and potentially relevant mercury compounds. 5/60 Chairs of Urban Water Management Objectives of the suggested topic Depending on the start date, the student will be involved in the sampling and analysis of total mercury concentrations and fluxes of individual mercury species in WWTPs in Switzerland. After quantification of the relevant mercury compounds, the student will perform mass balance calculations and budgeting exercises (Figure 1) to characterize the elimination of mercury from the waste water during the various treatment steps. This information will allow us to identify the mercury transformation processes and potential sources and sinks of mercury during the waste water treatment process. Specific tasks include: Participating in sample collection and sample preparation Assisting in the measurement of total mercury concentrations and individual mercury compounds in waste water and sludge samples at the (ultra)trace level Performing mass balance calculations and budgeting exercises Requirements Interest in the occurrence and fate of mercury in wastewater treatment plants and a good amount of motivation and initiative Solid laboratory skills, experience with chemical analyses an asset Previous experience with sample collection in the field is beneficial Good knowledge of English This project will be performed in the department of Water Resources and Drinking Water at Eawag in collaboration with BAFU. Office space with computer will be provided. Advisors Prof. Dr. Eberhard Morgenroth Prof. Dr. Lenny Winkel Dr. Michael Berg (Eawag) Dr. Bas Vriens (Eawag) Contact information Bas Vriens, Eawag Email: [email protected] Phone: +41 058 765 6795 6/60 Chairs of Urban Water Management What is the impact of heavy rainfalls on a potential river contamination by engineered nanomaterials? Background Although wastewater treatment plants (WWTP) have a very high removal efficiency concerning engineered nanomaterials (ENMs), occasional heavy rainfalls (storm events), during which the wastewater bypasses the WWTPs, may compromise the operational efficiency of WWTPs in Switzerland. Thus, we will investigate to what extent ENMs entering the surface water during storm events contribute to the overall ENMs budget of WWTPs in Switzerland. Objectives of the suggested topic 1. Literature study on urban sources, removal efficiency on WWTP and selection of relevant, engineered nanomaterials. 2. Developing a stochastic model for predicting the emissions of ENMs during storm events (geographically resolved on a river section level). 3. Collecting and analyzing data to assess the expected wastewater treatment efficiencies as well as the annual direct discharges (bypasses) during heavy rainfall events. 4. Performing a model sensitivity analysis to evaluate the annual contribution of storm events to the total emission budget of ENMs. Addressing these main objectives will lead to the development of a generalized model to asses untreated, direct discharges of ENMs. The particular challenge of this work will be collecting empirical information as well as unraveling the frequency and predictability of storm event based emissions of ENMs. Specific information This project will be performed in the department of Urban Water Management at Eawag in collaboration with ETSS. Office space with computer will be provided. 7/60 Chairs of Urban Water Management Requirements Affinity to modeling and system analysis (programming environment R). Basic knowledge of GIS is an asset. Advisors Prof. Dr. Max Maurer Dr. Fadri Gottschalk (ETSS AG) Dr. Christoph Ort (Eawag) Dr. Ralf Kägi (Eawag) Lena Mutzner (Eawag) Contact information Name: Dr. Fadri Gottschalk Email: [email protected] Phone: +41 81 860 10 85 Name: Email: Phone: Lena Mutzner [email protected] +41 58 765 59 29 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 8/60 Chairs of Urban Water Management Innovative Wasserkreislaufsysteme für den Wohn- und Gewerbebau „Zollhaus“ Hintergrund Die Genossenschaft Kalkbreite plant per 2020 eine neue Wohn- und Gewerbesiedlung am HB Zürich. Zu den Zielsetzungen der Genossenschaft gehören, neben dem Erstellen und Vermieten von preiswertem Wohn- und Gewerberaum, auch die Förderung einer nachhaltigen Entwicklung gemäss den Zielen der 2000-Watt-Gesellschaft. Während beim Bau der ersten Siedlung an der Kalkbreite der reduzierte Raumverbrauch und der Autoverzicht mit Mobilitätskonzept im Zentrum der Suffizienzerwägungen standen, möchte die Genossenschaft mit dem Bau der zweiten Siedlung einen Schritt weiter gehen und einen möglichst geschlossenen Wasserkreislauf (mit der Rückgewinnung von Nährstoffen aus Urin und Fäkalien) prüfen, sowie dessen Wirtschaftlichkeit und Ökobilanz. Die Erkenntnisse der vorliegenden Arbeit wird der Bau- und Nutzungskommission vorgestellt und dient als Grundlage für die Weiterbearbeitung und Umsetzung von einem innovativen System in die Planung des Bauprojekt. Inhalt der Arbeit Anhand des Projektes „Zollhaus“ soll der Wasserverbrauch aufgezeigt werden und unterschiedliche alternative und innovative Wasserkreislaufsysteme erarbeitet, evaluiert und bewertet werden. Inhalt: These/Fragestellung bezüglich Ressource „Wasser“ als Beitrag zur Ökobilanz einer Liegenschaft Allgemein: Geschlossene Wasserkreislaufsysteme innerhalb einer Liegenschaft im Vergleich – Referenzprojekte als Grundlage? „Zollhaus - IST“: Voraussichtlicher Wasserverbrauch, Anfallende Abwassermengen Evtl. Vergleichsstudie:, zB. Planungsprojekt Areal Thurgauerstrasse West, oder bereits abgeschlossenes Bauprojekt. Konzepte zu Wasserkreislaufsystemen für das „Zollhaus“ mit Angaben zur Reduktion von Wasserverbrauch und Abwasser, Einspeisung von Meteorwasser, Speicherung, Warmwassererzeugung durch Abwärme Heizung udgl., Aufbereitung und Wiederverwendung von Abwasser (qualitativ und quantitativ), bauliche und planerische Massnahmen, Kostenbilanz (Investition, Ertrag, Kostenreduktion), Schnittstellen Angabe von „must have“ and „nice to have“ , mögliche Schwierigkeiten bei der Umsetzung. Beurteilung der Konzepte nach folgenden Kriterien: Ökobilanz, Wirtschaftlichkeit (Grösse der Liegenschaft, Grenzwerte, Minimale 9/60 Chairs of Urban Water Management Grösse der Anlage und Rentabilität in Bezug zur Hauptnutzfläche, Umsetzbarkeit), Finanzierbarkeit, Baurechtliche Rahmenbedingungen. Fragestellungen: - Relevanz im nationalen und urbanen Kontext? - Welche Ansätze gibt es um den Wasserverbrauch zu minimieren? - Welche Abwasser können wie wieder zu Brauchwasser werden? - Wie viele getrennte „Wasserkreise“ müssen geführt werden? Welche? Ziel: - Erarbeitung 2-3 unterschiedliche Konzepte und deren Beurteilung Voraussetzungen Die Studie basiert auf dem Vorprojekt »Zollhaus« von Enzmann Fischer Partner AG und zeigt Systeme, resp. Konzepte für die autarke Aufbereitung von Grau-, Gelb- und Schwarzwasser und einen Kanalisations-unabhängigen Betrieb der Siedlung auf. Die nötigen Pläne, Anzahl an Anschlüsse, Wasserwerte und Berechnungen zum Verbrauch werden seitens der Bauherrschaft, resp. Sanitärplaner zur Verfügung gestellt. Leitung / Betreuung Leitung: Prof. Dr. Max Maurer Betreuer: Bastian Etter, Eawag Externe Ansprechperson bei der Genossenschaft Kalkbreite: Nina Schneider 078 871 75 79 Kontakt Bastian Etter, Eawag Email: [email protected] Tel.: +41 58 765 50 48 Assistenz für Siedlungswasserwirtschaft Angelika Hess, Sara Engelhard, Jonas Eppler Büro: HIL G 31.2 Email: [email protected], [email protected] [email protected] Tel.: +41 44 633 30 73 10/60 Chairs of Urban Water Management Methoden der Nährstoffrückgewinnung aus Urin, Wohn- und Gewerbebau Zollhaus Hintergrund Die Genossenschaft Kalkbreite plant per 2020 eine neue Wohn- und Gewerbesiedlung am HB Zürich. Zu den Zielsetzungen der Genossenschaft gehören, neben dem Erstellen und Vermieten von preiswertem Wohn- und Gewerberaum, auch die Förderung einer nachhaltigen Entwicklung gemäss den Zielen der 2000-Watt-Gesellschaft. Während beim Bau der ersten Siedlung an der Kalkbreite der reduzierte Raumverbrauch und der Autoverzicht mit Mobilitätskonzept im Zentrum der Suffizienzerwägungen standen, möchte die Genossenschaft mit dem Bau der zweiten Siedlung einen Schritt weiter gehen und einen möglichst geschlossenen Wasserkreislauf mit der Rückgewinnung von Nährstoffen aus Urin und Fäkalien prüfen, sowie dessen Wirtschaftlichkeit und Ökobilanz. Die Erkenntnisse der vorliegenden Arbeit wird der Bau- und Nutzungskommission vorgestellt und dient als Grundlage für die Weiterbearbeitung und Umsetzung von einem innovativen System in die Planung des Bauprojekt. Inhalt der Arbeit Die Evaluation wird in drei thematische Bereiche und Vertiefungen aufgeteilt: a) Auslegeordnung und Wirtschaftlichkeitsbewertung der Möglichkeiten zur nachhaltigen Wasserwirtschaft im städtischen Siedlungsneubau. b) Methoden zur Nährstoffrückgewinnung, Aufbereitung und Verwertung von Urin im städtischen Siedlungsneubau c) Methoden zur Nährstoffrückgewinnung, Aufbereitung und Verwertung von Fäkalien im städtischen Siedlungsneubau Nach Wunsch können die Bereiche b) und c) zusammengefasst werden. Wobei die Aufgabenstellung b) eine vertiefte Auseinandersetzung mit der Rückgewinnung und Verwendung von Nitraten in Zusammenarbeit mit ExpertInnen des Gewürz-, Gemüse-, und Obstanbaus erfordert. Ziel ist es Methoden für die Sammlung und Rückgewinnung von Nährstoffen aus Urin aufzuzeigen. Erwartet werden eine Studie zu Sanitärgeräten mit optimaler Urin-Rückgewinnung, Hochrechnungen zur anfallenden Menge, Erwägungen zur technischen/chemischen Umwandlung in Dünger, resp. eine allfällige direkten Verwendung zum Anbau von Zier- und Nutzpflanzen im Siedlungsaussenraum (oder einer Pflanzenkläranlage). Ausserdem wird eine Literaturstudie zu verschiedenen Verfahren zur Urinbehandlung (Vakuumverdampfung, Ozonisierung, UV-bestrahlung etc.) erwartet. Ein grosses Augenmerk ist auf die Kosten, den Energiebedarf und den Platzbedarf der Anlage zu legen. Ausgehend von der Studie sind Empfehlungen zur Ökobilanz, Finanzierbarkeit und Relevanz einer solchen Anlage abzugeben. 11/60 Chairs of Urban Water Management Voraussetzungen Die Studie basiert auf dem Vorprojekt »Zollhaus« von Enzmann Fischer Partner AG und zeigt angewandt Lösungen für die autarke Aufbereitung von Grau-, Gelb- und Schwarzwasser und einen Kanalisations-unabhängigen Betrieb der Siedlung auf. Für eine möglichst direkte Verwendung der aus Urin rückgewonnenen Nährstoffe ist die Zusammenarbeit im der ZHAW und/ oder PraktikerInnen aus dem Gemüsebau erforderlich. Die nötigen Pläne, Anzahl an Anschlüsse, Wasserwerte und Berechnungen zum Verbrauch werden seitens der Bauherrschaft, resp. Sanitärplaner zur Verfügung gestellt. Leitung / Betreuung Leitung: Prof. Dr. Eberhard Morgenroth Betreuer: Bastian Etter, Eawag Externe Ansprechperson bei der Genossenschaft Kalkbreite: Nina Schneider 078 871 75 79; [email protected] Kontakt Bastian Etter, Eawag Email: [email protected] Tel.: +41 58 765 50 48 Assistenz für Siedlungswasserwirtschaft Angelika Hess, Sara Engelhard, Jonas Eppler Büro: HIL G 31.2 Email: [email protected], [email protected] [email protected] Tel.: +41 44 633 30 73 12/60 Chairs of Urban Water Management Methoden der Nährstoffrückgewinnung aus Fäkalien, Wohnund Gewerbebau Zollhaus Hintergrund Die Genossenschaft Kalkbreite plant per 2020 eine neue Wohn- und Gewerbesiedlung am HB Zürich. Zu den Zielsetzungen der Genossenschaft gehören, neben dem Erstellen und Vermieten von preiswertem Wohn- und Gewerberaum, auch die Förderung einer nachhaltigen Entwicklung gemäss den Zielen der 2000-Watt-Gesellschaft. Während beim Bau der ersten Siedlung an der Kalkbreite der reduzierte Raumverbrauch und der Autoverzicht mit Mobilitätskonzept im Zentrum der Suffizienzerwägungen standen, möchte die Genossenschaft mit dem Bau der zweiten Siedlung einen Schritt weiter gehen und einen möglichst geschlossenen Wasserkreislauf mit der Rückgewinnung von Nährstoffen aus Urin und Fäkalien prüfen, sowie dessen Wirtschaftlichkeit und Ökobilanz. Die Erkenntnisse der vorliegenden Arbeit wird der Bau- und Nutzungskommission vorgestellt und dient als Grundlage für die Weiterbearbeitung und Umsetzung von einem innovativen System in die Planung des Bauprojekt. Inhalt der Arbeit Die Evaluation wird in drei thematische Bereiche und Vertiefungen aufgeteilt: d) Auslegeordnung und Wirtschaftlichkeitsbewertung der Möglichkeiten zur nachhaltigen Wasserwirtschaft im städtischen Siedlungsneubau. e) Methoden zur Nährstoffrückgewinnung, Aufbereitung und Verwertung von Urin im städtischen Siedlungsneubau f) Methoden zur Nährstoffrückgewinnung, Aufbereitung und Verwertung von Fäkalien, resp. deren Nutzung als Biogas und Wärme-/Energiequelle im städtischen Siedlungsneubau Nach Wunsch können die Bereiche b) und c) zusammengefasst werden. Wobei die Aufgabenstellung c) eine vertiefte Auseinandersetzung mit Sanitärlösungen zur Sammlung und Aufbewahrung von Fäkalien und ev. deren Mischung mit Küchenabfällen, sowie den erforderlichen Bewilligungen seitens des AWEL erfordert. Zu prüfen ist auch die Vergasung als Wärme- und Heizenergie. Ziel ist es Methoden für die Sammlung und Kompostierung von Fäkalien aufzuzeigen. Hochrechnungen zur anfallenden Menge und zur Dauer der Kompostierung anzustellen, wie auch die Verwertbarkeit für den eigenen Anbau von Zier- und Nutzpflanzen im Siedlungsaussenraum aufzuzeigen, resp. die Verwendung als Biogas zu prüfen. Ein grosses Augenmerk ist auf die Kosten, den Energiebedarf und den Platzbedarf der Anlage zu legen. Ausgehend von der Studie sind Empfehlungen zur Ökobilanz, Finanzier- und Wünschbarkeit einer solchen Anlage abzugeben. 13/60 Chairs of Urban Water Management Voraussetzungen Die Studie basiert auf dem Vorprojekt »Zollhaus« von Enzmann Fischer Partner AG und zeigt angewandt Lösungen für die autarke Aufbereitung von Grau-, Gelb- und Schwarzwasser und einen Kanalisations-unabhängigen Betrieb der Siedlung auf. Die nötigen Pläne, Anzahl an Anschlüsse, Wasserwerte und Berechnungen zum Verbrauch werden seitens der Bauherrschaft, resp. Sanitärplaner zur Verfügung gestellt. Leitung / Betreuung Leitung: Prof. Dr. Eberhard Morgenroth Betreuer: Bastian Etter, Eawag Externe Ansprechperson bei der Genossenschaft Kalkbreite: Nina Schneider 078 871 75 79; [email protected] Kontakt Bastian Etter, Eawag Email: [email protected] Tel.: +41 58 765 50 48 Assistenz für Siedlungswasserwirtschaft Angelika Hess, Sara Engelhard, Jonas Eppler Büro: HIL G 31.2 Email: [email protected], [email protected] [email protected] Tel.: +41 44 633 30 73 14/60 Chairs of Urban Water Management Modelling in-sewer transformation of illicit drugs FIG 1. What happens to excreted drug residues during transport in gravity sewers? Background After consumption, drugs such as cocaine, amphetamine and heroin are metabolized in the human body, excreted as parent compound or metabolites (biomarkers) and flushed through toilets into sewers. During the transport in sewer pipes, many of the targeted biomarkers undergo chemical and biological transformations. FIG 2. Transformation of amphetamine (left) and ketamine (right) in four different sewers over 24h under aerobic conditions at 22°C. If we back-calculate illicit drug consumption based on biomarker concentrations measured in a 24h composite sample from the influent to a sewage treatment plant, we have to account for the loss of biomarkers during transport in sewers. Different drugs are being transformed to varying degrees in sewer (FIG 2). Further, catchments around the world differ in size, design, operation mode and are operated under different environmental conditions. 15/60 Chairs of Urban Water Management Objectives of the suggested topic Based on an extensive laboratory dataset, we estimated in-sewer transformation rates for a set of different illicit drugs. Using these rates, you will develop a stochastic model to assess the effect of in-sewer transformation on the illicit drug concentration measured at the treatment plant. This involves the following tasks: 1. Understand existing sewer models for two catchments of different sizes (available software, e.g. Mike Urban, WEST, SWIM, City Drain) and derive necessary catchment characteristic (e.g. residence time distribution, water levels, biofilm areas). 2. Develop a simplified, stochastic reactor model reflecting the real catchments to calculate effect of transformations. 3. For the two different catchments, you apply stochastic model and calculate 24h composite sample concentrations for different scenarios. 4. Asses the effect of transformations under varying environmental conditions (e.g. oxygen concentrations). Specific information You will have a workspace at Eawag and as part of the research team you can attend relevant group meetings. Contributing to research at the intersection of urban water management and process engineering, the results of this master thesis will advance the field of wastewater-based epidemiology. You can start the project the earliest in January 2016 and the latest by May 2016. Feel free to contact us to ask further questions. Requirements High motivation to model Good knowledge of software such as R and e.g. WEST, SWIM, Mike Urban Good knowledge of English Advisors Prof. Dr. Eberhard Morgenroth Dr. Christoph Ort (Eawag) MS Ann-Kathrin McCall (Eawag) Contact information Ann-Kathrin McCall Email: [email protected] Phone: +41 (0)58 765 5041 16/60 Chairs of Urban Water Management Tutors (assistants) of Chairs of Urban Water Management: Jonas Eppler, Angelika Hess, Sara Engelhard Office: HIL G 31.2 Email: [email protected], [email protected], [email protected] Tel.: +41 44 633 30 73 17/60 Chairs of Urban Water Management Measure nitrite with UV-Vis spectrometry in a urine nitrification system. Background Nutrient recovery from source separated urine is a promising technology to move wastewater collection and treatment into a more sustainable future. One process chain to recover nutrient includes the biological nitrification of urine in order to stabilise the nitrogen content (Udert & Wächter, 2012). Under varying urine loads, the nitrification process accumulates nitrite on a regular basis. Without fast remediation, this accumulations leads to irreversible inhibition of the nitrite oxidizing bacteria within days which usually requires a complete new start-up of the reactor. Within the SoDAN (Soft-Sensing, Diagnosis and Automation for Nutrient Recovery) project, we aim to implement a control strategy to prevent these accumulations automatically under fluctuating inflow schemes. To enable a controller to stabilise this process it is essential that all required information for the control decision is available with a high enough accuracy and frequency. In the case of urine nitrification nitrite is this key compound. One promising sensing technique is the in-situ Figure 1 ultraviolet and visible light (UV-Vis) spectrometry. Urine nitrification reactor. This technique is already in use to monitor conventional (waste) water systems. However, the use of such a spectral probe as a sensor for process control is more demanding in terms of reliability and accuracy of the extracted information. Previous work at Eawag shows that information about nitrite concentration in urine can be extracted from the recorded absorbance spectra in batch tests despite the high nitrate concentrations which prevent the analysis of the normally used wavelength range (Masic et al., 2015). Figure 2 UV-Vis spectrolyser in a flow cell. Other studies at Eawag investigated the influence of particles and sensor fouling on the nitrite prediction performance. Since we know that also organics and particles will absorb light in the UV-Vis range we are currently working on a long-term validation experiment in a continuously operated urine nitrification system. This will expose the sensor 18/60 Chairs of Urban Water Management to the background dynamics the sensor also would experience in a real world application. Objectives of the suggested topic The goal of this master thesis is to better understand the stability of the underlying model we use to predict nitrite with the spectral data in a continuously operated reactor with artificially induced background dynamics. a. Validate the model prediction with regular sampling in a fed- batch wise operated urine nitrification reactor. b. Add artificial dynamics to the background spectra and evaluate model prediction performance. c. Add continuous operation phases into the current batch mode and study the effect on the model prediction performance Specific information Office space with computer and an existing urine nitrification reactor will be provided at Eawag in Dübendorf. For the data processing Matlab will be used. Literature Udert, K.M., Wächter, M. Complete nutrient recovery from source-separated urine by nitrification and distillation (2012) Water Research, 46, pp. 453-464. Mašić, A., Santos, A.T.L., Etter, B., Udert, K.M., Villez, K. Estimation of nitrite in source-separated nitrified urine with UV spectrophotometry (2015) Water Research, 85, pp. 244-254. Advisors Prof. Dr. Eberhard Morgenroth Dr. Kris Villez (Eawag) Christian Thürlimann (Eawag) Contact information Dr. Kris Villez Email: [email protected] Phone: +41 765 52 80 http://www.eawag.ch/de/abteilung/eng/schwerpunkte/sensorenautomatisierung/ Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 19/60 Chairs of Urban Water Management Modelling Electrochemical Nitrite Removal Concentration [mg N∙L-1] Background Nitrite is a harmful compound and has to be removed from wastewaters to protect aquatic environments. It has been shown in our laboratory that nitrite can be removed from wastewater by electrochemical oxidation on simple graphite anodes (Figure 1). The electrochemical nitrite oxidation may be especially useful for on-site wastewater treatment since electricity is the only input that is required for this process. A recent feasibility study showed that electrochemical nitrite oxidation could be useful for on-site urine treatment (Sutter, 2014). However, the results of that study also suggested that a mathematical model of the electrochemical process would be beneficial for upscaling of this application. 1600 1400 1200 1000 800 600 400 200 0 NH4+ NO3NO2- 0 2 4 6 8 Time [h] 10 12 Figure 1: Electrochemical nitrite removal in a batch electrolysis cell. Objectives and Project Description In this master thesis it will be your goal to develop a mathematical model of the electrochemical nitrite oxidation process in synthetic urine. The development will include the following steps: 1. Develop an electrochemical reaction model (Goodridge and Scott, 1995) 2. Perform experiments to estimate model parameters (calibration) 3. Validate the model with existing data from nitrite electrolysis in real urine (validation) Specific Information Office space and laboratory space will be available at Eawag. You will develop the mathematical model, presumably in MATLAB, such that it is compatible with other models that have been developed in our department. In the beginning of the work, you will have to get familiar with some basic concepts of electrochemistry and electrochemical engineering. You will be 20/60 Chairs of Urban Water Management guided through this learning step with appropriate literature and regular meetings. You may start earliest in January 2016 and latest on 1st of March 2016. We expect a motivated student with some modelling experience. In the laboratory, we expect safe and precise work. Do not hesitate to contact us via the contact information if you have further questions. Advisors Prof. Dr. Eberhard Morgenroth Dr. Kai M. Udert (Eawag) Hanspeter Zöllig (Eawag) Contact Information Hanspeter Zöllig Email: [email protected] Phone: +41 58 765 54 34 Tutors (assistants) of Chairs of Urban Water Management: Jonas Eppler, Angelika Hess, Sara Engelhard Office: HIL G 31.2 Email: [email protected], [email protected], [email protected] Tel.: +41 44 633 30 73 References Goodridge, F., Scott, K., 1995. Electrochemical process engineering : a guide to the design of electrolytic plant. New York [etc.] : Plenum Press. Sutter, A., 2014. A hybrid MBBR-electrolysis urine nitrification system: the interplay of electrolysis and bacteria. Master's thesis. ETH Zürich 21/60 Chairs of Urban Water Management Obtaining Sludge Settling Properties via Image Analysis Background Secondary clarifiers are a key element of the activated sludge process for biological wastewater treatment. By providing both clarifying and thickening functions, a secondary clarifier ensure adequate effluent quality while ensuring efficient and stable operation in the long term [1]. Unfortunately, the performance of secondary settling tanks in conventional biological wastewater treatment systems is difficult to predict under realistic conditions. As a result, monitoring and optimal operation of settlers is challenging in practice. This leads to losses in efficiency which could be prevented by applying novel monitoring and modelling concepts. Most commonly, sludge settler operation is based on modelling of the sludge settling flux curve by means of correlation with measurement of the sludge volume index (SVI) [2]. More advanced and presumably accurate methods are based on empirical modelling of the sludge settling velocity as a function of the sludge concentration [3]. It remains a challenge however to collect empirical data to the point that online updating of the settling velocity function is possible and settler performance monitoring becomes practical [4]. At Eawag, a novel method to register the sludge blanket during batch settling experiments has been developed. Each of such batch settling experiments leads to an estimate for the sludge settling velocity at a single sludge concentration. By means of repeated batch experiments following sample concentration and dilution the sludge settling velocity curve can be obtained and modelled. Currently available results have been obtained for a granular sludge reactor at Eawag. In this project, the effects of variations of the batch settling experiments will be investigated. Such variations relate to the mixing conditions (e.g., with or without mixing) and the sampling method (e.g., bucket, gravity, or pumping). 22/60 Chairs of Urban Water Management Objectives of the suggested topic 1. Experimental evaluation of the effect of mixing conditions and sampling methods on the obtained sludge blanket measurements, sludge settling velocity, and sludge settling flux curves. 2. Test the robustness of the available image analysis software (Matlab) against visual reference readings of the sludge blanket height. 3. Evaluate the experimental and image analysis methods with different wastewaters, sampled at different wastewater treatment plants and at different times. Specific information Experiments and modelling tasks are executed at Eawag and at different WWTPs in the Zürich area. For experimentation, all hardware will be provided. For data analysis and modelling, the Matlab environment will be used. References [1] Henze, M.; van Loosdrecht, M. C. M. ; Ekama, G. A. ; Brdjanovic, D. (2008). Biological wastewater treatment: Principles, modelling and design. IWA Publishing. [2] Daigger, G. T. ; Roper Jr, R. E. (1985). The relationship between SVI and activated sludge settling characteristics. Journal (Water Pollution Control Federation), 57(8), 859-866. [3] Ramin, E. ; Wágner, D. S. ; Yde, L. ; Binning, P. J. ; Rasmussen, M. R. ; Mikkelsen, P. S. ; Plósz, B. G. (2014). A new settling velocity model to describe secondary sedimentation. Water Research, 66, 447-458. [4] Plosz, B.G.; Nopens, I., Rieger, L. ; Griborio, A. ; De Clercq, J. ; Vanrolleghem, P.A. ; Daigger, G.T., Takacs, I. ; Wicks, J. ; Ekama, G.A., 2012. A critical review of clarifier modelling: State-of-the-art and engineering practices. Proceedings of the 3rd IWA/WEF Wastewater Treatment Modelling Seminar (WWTmod2012), Mont-Sainte-Anne, Quebec, Canada. Advisors Professor Dr. Eberhard Morgenroth Kris Villez (Eawag) Contact information Kris Villez Email: [email protected] Phone: +41 58 765 55 11 23/60 Chairs of Urban Water Management Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 24/60 Chairs of Urban Water Management Growth of microorganisms in treated grey water as part of Blue Diversion AUTARKY project Background and Objectives Blue Diversion AUTARKY toilet (BDT, http://www.bluediversiontoilet.com/, Figure 1) developed at EAWAG is a source separating toilet developed as part of the Reinvent the Toilet challenge from the Bill and Melinda Gates Foundation. The BDT has urine and feces separately collected and treated for resource recovery. The goal of the toilet is to provide a safe and affordable sanitation technology for the billions of people who lack of access. Toilet flushing, hand washing and personal hygiene water are treated and recycled within the system. A biologically activated membrane bioreactor (BAMBi) has been employed as primary treatment to efficiently remove organic materials and nitrogen from toilet wastewater. We are currently evaluating state-of-art post treatment technologies, including ozone, electrolysis, UV, and granular activated carbon (GAC) for polishing primary treated wastewater to reach safe level for hand washing and personal cleansing. The choice of post treatment technologies is based on their performance in treating the remaining organic materials and inactivating (and/or removing) pathogens with consideration of energy and cost efficiency. Additionally, regrowth of pathogens is considered as one of the criteria for the best post treatment technology due to the possibility of pathogen regrowth within the storage tank of post-treated water. The goal of this project is to ensure the safety of grey water use for hand hygiene. The student will specifically evaluate the growth potential of fecal bacteria (used as indicators for bacterial pathogens) in water within the toilet after each post treatment technology listed above. Results of this project will be used to choose the final post treatment technology for the BDT. 25/60 Chairs of Urban Water Management Figure 2 Picture of Blue Diversion prototype toilets installed in an existing structure. Project description We are looking for a highly motivated Master’s student to study the growth potential of two fecal indicator bacteria Escherichia coli and Enterococcus faecalis in water from the BDT. The Master thesis will provide answers for three main research questions: 1. 2. 3. Can the bacteria grow in water within the BDT? Does the bacterial growth depend on water characteristics? Can the bacterial growth be inhibited by adjusting water characteristics? The Master’s student will use culture and molecular based methods to quantify the growth potential of the bacteria. (More information of growth potential bioassay can be found in Vital et al. (2010).) The thesis will include discussion on how different post treatment technologies influence the growth potential of the bacteria. Results will be integrated into the ongoing developments of the BDT. Reference Vital, M., Stucki, D., Egli, T. & Hammes, F. Evaluating the growth potential of pathogenic bacteria in water. Appl. Environ. Microbiol. 76, 6477–6484 (2010). 26/60 Chairs of Urban Water Management Additional information Work will be performed in collaboration with the Pathogens and Human Health research group at Eawag (Dübendorf). Further information about our facilities and approaches are provided at http://www.eawag.ch/forschung/eng/index_EN Further information about the Blue Diversion AUTARKY Project is available at http://forum.susana.org/forum/categories/106-user-interface-technologyinnovations/13529-blue-diversion-autarky-a-self-sustaining-toilet-off-the-grideawag-switzerland http://www.bluediversiontoilet.com/ Advisors Prof. Dr. Eberhard Morgenroth Dr. Mi Nguyen Dr. Tim Julian Contact information Mi Nguyen Email: [email protected] Tutors (Assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 27/60 Chairs of Urban Water Management Mechanisms of retention of particulate organic substrates (XS) during feeding of aerobic granular sludge systems Background Aerobic granular sludge (AGS) represents a relevant technology for the treatment of municipal wastewaters (WW) (van Loosdrecht and Brdjanovic, 2014. AGS allows for simultaneous removal reduced reactor volume and energy of organic matter, nitrogen and consumption (Giesen et al., 2013). phosphorus in a single sequencing batch reactor, whereas with conventional activated sludge systems three reactors would be required. Compared to conventional activated sludge, the advantages of AGS also include: (i) fast settling velocity (i.e. easier separation between the treated water and the biomass), (ii) higher Solid Retention Time (allowing for the growth of slow growing bacteria), (iii) Figure 3: picture of aerobic granules fed with acetate higher biomass concentration and thus (iv) Many studies that aimed at identifying the mechanisms of granulation were performed at the laboratory-scale and using synthetic wastewater (Figure 1). Lab-scale studies helped to identify several mechanisms that influence the granulation process: the nature of the carbon source, the hydrodynamic shear force, the feast–famine regime, the feeding strategy, etc. However, only little information is available with regard of the formation and performances of AGS during treatment of complex influents such as municipal wastewater. Municipal wastewater contains a significant fraction of particulate organic substrate (XS) that influences the properties of the AGS (e.g. fraction of granules, morphology) and ultimately the system performances. Especially, AGS fed with real municipal WW always contains a significant fraction of flocs (20%) whereas full granulation is achieved with synthetic WW. It is unclear if this fraction of flocs is beneficial or not to the system operation e.g. for the retention of XS 28/60 Chairs of Urban Water Management Objectives of the suggested topic The main goal of this master thesis will be to understand to what extent this fraction of flocs is important or not for the system performances (e.g. retention of Xs).The specific objectives of this project will be: To better understand how the composition (fraction of granules) influence the retention of XS during the anaerobic feeding. To evaluate how the nature and physical properties (e.g. size) of XS influence its retention during the anaerobic feeding To identify how the feeding rate influence the retention of XS To ultimately better define the operation of sequencing batch reactors used for the treatment of municipal WW with AGS. Since few years, Eawag researchers are successfully operating a 200 L SBR column for the cultivation of AGS on real municipal WW (currently 80% granulation). Several 10 L SBR reactors are also in operation for the cultivation of AGS on synthetic WW (full granulation). Retention experiments using these different types of AGS will conducted in 5 L column reactors. Different AGS composition (ratio of granules vs. flocs) and different types of particulate organic substrate (e.g. fluorescent model substrates, real particulate substrate isolated from WW, etc.) will be tested. The retention efficiency will be quantified using Flow Cytometry (for fluorescent compounds) or chemical analysis (for real XS). Specific information This project will be performed in the department of Process Engineering at Eawag. Office space with computer and an existing experimental facility will be provided. Advisors Prof. Dr. Eberhard Morgenroth Nicolas Derlon (Eawag/External advisor) Contact information Nicolas Derlon Email: [email protected] Phone: +41 44 823 5378 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 29/60 Chairs of Urban Water Management References Giesen, A., L. M. M. de Bruin, R. P. Niermans and H. F. van der Roest (2013). Advancements in the application of aerobic granular biomass technology for sustainable treatment of wastewater. Water Practice & Technology. 8(1): 47-54. van Loosdrecht, M. C. M. and D. Brdjanovic (2014). Anticipating the next century of wastewater treatment. Science. 344(6191): 1452-1453. 30/60 Chairs of Urban Water Management Determinants for faecal sludge dewaterability Worldwide, the sanitation needs of 2.7 billion people are met by onsite sanitation technologies, such as septic tanks and pit latrines. These technologies can provide appropriate sanitation if the transport, treatment and enduse or disposal of the faecal sludge collected is in place. In urban areas of low-income countries, informal faecal sludge collection and transport services frequently exist, but adequate faecal sludge treatment and safe enduse or disposal is mostly absent. This results in large amounts of untreated faecal sludge being discharged in urban environments, jeopardizing public and environmental health. Faecal sludge is typically >90% water, which makes dewatering an important treatment goal as this reduces transport costs and increases the resource potential of treatment endproducts (e.g., soil conditioner, biochar or solid fuel). Settlingthickening tanks and drying beds are the most commonly employed large-scale faecal sludge dewatering technologies in low-income countries (see Photo 1). Although they require low capital and operational resources, they are very land Photo 1: Faecal sludge dewatering in Kampala. intensive and locating space in urban areas for faecal sludge treatment is a challenge. Hence, faecal sludge dewatering needs to be optimized to reduce transport costs and to make treatment and resource recovery feasible within urban areas. The use of mechanical dewatering devices, such as filter presses or centrifuges and conditioners, is commonplace in wastewater treatment. And it is well known that different wastewater sludge types (e.g., primary, secondary, digested sludge, and anaerobic vs. aerobic) require differing dewatering technologies and conditioners. In contrast to wastewater sludge, faecal sludge characteristics are very different. They typically have one or two orders of magnitude higher solid, organic and nutrient concentrations, and are also highly variable, which influences dewaterability. For example, faecal sludge can be unstabilized when collected from public toilets or partially stabilized when collected from septic tanks. Because of these reasons, it cannot be assumed that the dewatering technologies and conditioners used with wastewater sludge can be transferred to faecal sludge. For wastewater sludge, total volatile solids, sand content, surface charge, particle size distribution, protein content and viscosity have been identified as the major parameters influencing dewaterability. And capillary suction time and sludge moisture content after laboratory centrifugation can be used to evaluate sludge dewaterability. The influence of these parameters on faecal sludge dewaterability, however, has not yet been investigated, and further research is necessary to optimize faecal sludge dewatering. The results from this study are expected to contribute to the design of appropriate faecal sludge dewatering technologies and conditioners for dense urban areas and to the decrease in the indiscriminate discharge of faecal sludge into urban environments. 31/60 Chairs of Urban Water Management Objectives of the suggested topic The objective of this Master’s thesis is to investigate the influence of physical and bio-chemical parameters on faecal sludge dewaterability in order to understand and optimize faecal sludge dewaterability. The tasks of this Master’s thesis will be: To characterize faecal sludge from onsite sanitation technologies in Switzerland and quantify its dewaterability (total solids, chemical oxygen demand, pH, temperature, total volatile solids, sand content, surface charge, particle size distribution, protein content, viscosity, capillary suction time, and sludge moisture content after centrifugation). To identify the influence of faecal sludge characteristics on dewaterability in Switzerland and to compare the results with research being done in Japan, Uganda and Vietnam (see below) and from doing a literature review. To evaluate the accuracy of particle size distribution and surface charge analysis methods used in low-income countries (Uganda, Vietnam). To critically discuss how to best optimize, transfer and design appropriate faecal sludge dewatering technologies for low-income countries. Specific information Faecal sludge will be collected from vacuum trucks at wastewater treatment plants in Switzerland. This will be coordinated by the Master’s thesis supervisor. The laboratory research will be conducted at the Department of Process Engineering at Eawag. Office space will be provided at the Department of Water and Sanitation in Developing Countries (Sandec). Parallel research is being conducted in Japan, Uganda and Vietnam for cross-comparison. Requirements Experience and interest in laboratory analysis. Interest in understanding fundamental engineering processes. Duration September to December 2015 Advisors Professor Dr. Eberhard Morgenroth (ETHZ/Eawag); Dr. Linda Strande (Eawag/Sandec) Co-advisors Mr. Moritz Gold (Eawag/Sandec); Dr. Hidenori Harada (Kyoto University) Contact Information Mr. Moritz Gold, [email protected], +41 58 765 5015 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 32/60 Chairs of Urban Water Management How does urbanization influence groundwater recharge of alluvial aquifers? Background and Objectives Alluvial aquifers are a main source of drinking water in Switzerland but under pressure by increasing urbanization and intense agriculture. It is often assumed that urbanization leads to a decrease in groundwater recharge due to sealing of surfaces and as a consequence to a lower groundwater availability. In comparison, recharge rates are expected to be higher in agricultural areas. These assumptions are however rarely challenged and verified, and the opposite might actually be true. Current urban drainage rules require infiltration of clean meteoric water into the subsurface wherever possible, which might lead to an increase rather than a decrease in recharge. In reverse, intense agriculture could reduce recharge due to tile drainage, soil compaction, and stronger evapotranspiration associated with crops. The cultivation of intermediate crops to reduce nitrate loss to groundwater can further decrease recharge due to higher evapotranspiration as indicated by lysimeter studies. The objective of the Master thesis is to contribute “facts” to this groundwater recharge debate and to challenge common views on how recharge is related to land use based on a case study. Possible research approach and methods The study will focus on a well-characterized alluvial aquifer that has seen rapid urbanization but still contains large zones with intense agriculture, the Gäu aquifer between Oensingen and Olten. The following research approach could be used: - Development of conceptual models/schemes of how urban areas influence groundwater recharge - Establishment of water balances for agricultural and urbanized zones using existing data and complementary field measurements - Comparison of older and more recently urbanized areas to evaluate how different urban drainage approaches influence the water balance and groundwater recharge - Integration of study results into existing water balances of the entire aquifer to evaluate how strongly urbanization influences the overall groundwater dynamics 33/60 Chairs of Urban Water Management Research partners As the study relies on knowledge from urban water systems as well as hydrogeology, it will be carried out in close collaboration between the Urban Water Management Laboratory of the ETHZ (Prof. M. Maurer) and the CHYN (Prof. D.Hunkeler). Advisors Prof. Dr. Max Maurer (ETH Zürich, UWM) Prof. Dr. Daniel Hunkeler (Université de Neuchâtel, Centre d’hydrogéologie) Contact information Prof. Dr. Daniel Hunkeler Email: [email protected] Phone: +41 32 718 25 60 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 34/60 Chairs of Urban Water Management Moderner Gewässerschutz bei Regenwetter durch eine intelligente Bewirtschaftung von Mischwasserbehandlungsanlagen Schlüsselworte Gewässerschutz bei Regenwetter, Mischwasserbehandlung, Regenbecken, Datenanalyse, Abflussregelung Ausgangslage Bei Regenwetter wird häufig unbehandeltes Abwasser unsere Gewässer eingeleitet, was diese zum Teil stark belastet. Um solche Mischwasserentlastungen quantitativ reduzieren zu können, werden oft bauliche Massnahmen in Form von neuen Regenbecken realisiert, was in der Regel sehr teuer ist. Alternativ bietet sich eine vertiefte Analyse der bestehenden Anlagen an, um Gewässerbelastungen durch eine intelligente Bewirtschaftung zu reduzieren. Dies ist vor allem dort vielversprechend, wo die Regenbecken mit Messtechnik ausgestattet sind und die Messdaten im Prozessleitsystem aufgezeichnet werden. Ziel In dieser Arbeit sollen in enger Zusammenarbeit mit einem renommierten Ingenieurbüro die Grundlagen für eine intelligente Bewirtschaftung der Mischwasserbehandlungsanlagen für das Abwassersystem in Wohlen (AG) erarbeitet werden. Dieses umfasst die folgenden Teilaufgaben: Wissenschaftliche Analyse der Entlastungsaktivität, u.a. Überprüfung und Auswertung der vorhandenen Regenbeckendaten Erarbeiten eines Bewirtschaftungskonzeptes zur Reduktion von Gewässerbelastungen durch eine optimale Ausnutzung der bestehenden Abwasserinfrastruktur Vorschläge zur allfälligen Optimierung der Instrumentierung und der Regelung abgeben. 35/60 Chairs of Urban Water Management Das Abwassersystem in Wohlen (AG) Das Einzugsgebiet der ARA in Wohlen (AG) verfügt über neun Anlagen zur Mischwasserspeicherung: ein Regenbecken auf der ARA, zwei Fangkanäle im Zulauf der ARA und sechs weitere Regenbecken im Kanalnetz. Da alle Anlagen mit dem Prozessleitsystem auf der ARA verbunden sind, liegen für diese Arbeit umfassende Daten von Entlastungsverhalten, Füllhöhen, Weiterleitungsmengen, etc. für einen Zeitraum von 1 - 2 Jahren mit einer maximalen Auflösung von 3-5 Minuten vor. Ablauf Zur Erarbeitung der Aufgaben sind folgende Arbeitsschritte vorgesehen: 1. Begehung des ARA-Einzugsgebietes und Erfassung aller Behandlungsanlagen, Entlastungsstellen im Vorfluter, sowie der Messtechnik 2. Sichtung der GEP-Daten und Einleitungsschemata; insbesondere konzeptionelle und technische Erfassung der vorhandenen Entwässerungsinfrastruktur und der vorhandenen Datengrundlagen 3. Analyse der historischen Messdaten aus dem Prozessleitsystem der ARA zur Bewertung der aktuellen Leistung der Regenwasserbewirtschaftung: i) Ermittlung des Füllungs- und Entlastungsverhaltens jeder Behandlungsanlage und des Verbunds, ii) Ermittlung von Jahres-Kennzahlen, iii) Bei Bedarf detaillierte Betrachtung von einzelnen Regenereignissen und Regentypen. 4. Bei Bedarf Überprüfung der aktuellen Weiterleitungsmengen mit Hilfe der Technischen STORM-Richtlinie. Vergleich der aktuellen Regenwasserbewirtschaftung mit im GEP festgeschriebenen Werten. Analyse des Zusammenspiels der Entleerung der Regenbecken und der ARA-Kapazität. 5. Aufzeigen des Handlungsbedarfs aus den erzielten Erkenntnissen (Entlastungsverhalten, Weiterleitungsmengen, Instrumentierung etc.). 6. Optional: Vereinfachte Modellierung des ARA-Einzugsgebietes mit Integration aller Speicherorte auf Basis der aktuell vorhandenen Regenbeckeneinstellungen, historischen Regenbeckendaten und Regenserien in einem hydrologischen oder hydrodynamischen Niederschlags-Abfluss Modell (z.B. CityDrain, MIKEUrban oder SWMM) Optional: Kalibration und Validation des Simulationsmodells an Messdaten für ausgewählte Ereignisse 7. 8. Ausarbeiten von einer oder mehreren Lösungsvarianten; wenn möglich mit quantitativen Empfehlungen zur Optimierung hinsichtlich Entlastungsverhalten, Weiterleitungsmengen und evtl. Instrumentierung etc. 9. Präsentation und Diskussion der Ergebnisse mit dem Abwasserverband ARA Wohlen 10. Aufbereitung und Dokumentation der erzielten Resultate 36/60 Chairs of Urban Water Management Voraussetzungen Interesse an Urbanhydrologie, Genereller Entwässerungsplanung, modernem Gewässerschutz und Datenanalyse Hohe Motivation und Initiative Programmierkenntnisse (R, Matlab etc.) sind von grossem Vorteil Kenntnisse zu hydrologischen und hydrodynamischen Berechnungsprogrammen (City Drain, Mike Urban, SWMM, etc.) und Langzeitseriensimulationen sind von Vorteil Kenntnisse im Bereich von mathematischen Optimierungsaufgaben wie globaler Optimierung oder Mehrkriterienoptimierung sind von Vorteil Termine, Dauer Die Masterarbeit beginnt ab Januar 2015, bzw. in gegenseitiger Absprache Die Masterarbeit dauert 16 (+2) Wochen Es sind regelmässige Zwischenbesprechungen mit den Betreuern vorgesehen (ca. 5-7) Betreuung Dr. Jörg Rieckermann, Eawag Michael Brögli und Gian Levy, HOLINGER AG Prof. Dr. Max Maurer, ETH Zürich und Eawag Kontakt Name: Jörg Rieckermann Email: joerg.rieckermann @eawag.ch Tel.: +41 (0)58 765 53 97 Assistenz Siedlungswasserwirtschaft: Angelika Hess, Jonas Eppler, Sara Engelhard Büro: HIL G 31.2 Email: [email protected], [email protected], [email protected] Tel.: +41 44 633 30 73 37/60 Chairs of Urban Water Management Overland Flow Network delineation allowing for flow divergence Keywords: Digital Elevation Model, flow momentum and divergence, overland flow network, raster analysis Overland flow models require good 1D overland flow representation! High-intensity rainfall events can generate flooding in urban areas, which in turn cause serious social (e.g. injuries), economical and infrastructural damages. It is therefore desirable to have accurate flood predictions (flood extent and water depth). Current research in urban flood modeling is generally focused into the area of 1D/2D modeling: the coupling of one-dimensional (1D) hydrodynamic models of the sewer system with two-dimensional (2D) overland flow models. While 1D/2D models generate more accurate flood predictions, they come at the cost of a computation time when compared to the alternative 1D/1D flood model - a prohibitive price for Swiss engineering companies. One of the main strengths of 2D overland flow models over current 1D overland flow models is the faithful representation of diverging flow paths, a task that is currently impossible for 1D models due to the complexity of delineating flow paths over a DEM. Objectives The main goal of this thesis is to develop a novel 1D overland flow path delineation method able to take into account flow divergence. The new method should be based on the aspect driven kinematic routing algorithm presented by Lea (1992). This algorithm, also known as the “rolling ball algorithm”, uses the aspect raster to delineate flow paths. Flow paths delineated using the new method should be compared and assessed towards the results obtained using other available 1D overland flow network generators (see Wilson et al. (2008) for different 1D overland flow network generation algorithms). The new method should delineate preferential flow paths as well as secondary flow paths that only appear at higher flow regimes. The method should represent divergent flow in a way that is compatible with the EPA StormWater Management Model (SWWM) (Rossman, 2007). Suggested tasks 11. Literature review on overland flow, urban drainage modelling, and input data requirements; 12. Development of a novel method to generate 1D overland flow networks that takes into account flow divergence (and flow momentum); 13. Comparison of the obtained overland network using the proposed 38/60 Chairs of Urban Water Management method with networks obtained using other algorithms, on the basis of a field test, e.g. in Adliswil; 14. Discussion of the obtained results, with a special focus on usability of the proposed method to improve 1D overland flow/ flood modelling in urban areas. Requirements Interest in urban hydrology and hydrodynamic modelling; Computer programming skills; Good knowledge of English; Basic knowledge of GIS is an asset; A good amount of motivation and initiative Advisors Dr. João P. Leitão (Eawag) Prof. Dr. Max Maurer (ETH Zürich, UWM) Contact information João P. Leitão Email: [email protected] Phone: +41 (0)58 765 67 14 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 References Lea, N.L., (1992), An aspect driven kinematic routing algorithm. In Parsons, A.J., Abrahams, A.D. (eds.): Overland Flow: Hydraulics and Erosion Mechanics, UCL Press, London, UK, 393– 407Rossman, L.A. (2007). Storm Water Management Model User’s Manual, EPA/600/R05/040, U.S. Environmental Protection Agency, Cincinnati, OH, USAWilson, J.P., Aggett, Yongxin, D., Lam, C.S. (2008). Water in the landscape: a review of contemporary flow routing algorithms. In Zhou, Q., Lees, B., Tang, G. (Eds.), Advances in Digital Terrain Analysis, Springer, New York, USA, 213–236 39/60 Chairs of Urban Water Management Taking into account future uncertainty when designing urban water supply systems: a flexible approach Keywords: Water Supply Systems, Flexibility in Engineering Design, Hydraulic Modelling, Uncertainty Background How does future influence water supply system design and decision making? In the face of uncertainty about future socio-economic and climate changes, it makes sense to keep ones' options open. This can be done by incorporating flexibility in decisions that have long-term implications, such as the planning and design of infrastructure systems. Flexibility, however, often comes at a cost, so decision makers have to weight up the benefits of flexibility against the up-font costs. Flexibility in engineering design concept (de Neufville and Scholtes, 2011) provides a framework for evaluating the benefits of keeping one's options open, allowing decision makers to switch resources, adapt or abandon decisions in future. Recent years have seen a few examples of uncertainty impact analysis on urban water systems design and planning (e.g., Hug and Maurer, 2010; Woodward et al., 2014; Marques et al., 2015). Objectives The proposed thesis will explore the flexibility in engineering design concept in order to evaluate design and planning decisions that might have long-term implications. The thesis will explore how differing states of uncertainty may modify decisions in future. Different ways of representing uncertainty, with probabilities and sets of possibilities, will be explored. Although Net Present Value only represents the economic view of the problem, in this study it will be used as the evaluation metric for the different water supply system design and planning alternatives. Suggested tasks 1. Literature review on water supply system design, which includes pipe, pump and reservoir design; 2. Identification of the relevant circumstances that influence water supply systems design and their implications in the designing process 3. Evaluation of the applicability of the flexible engineering design concept to the improvement of existing (and not expanding) UWS. 4. Discussion of the obtained results, with a special focus on the benefit of explicitly considering future uncertainty when designing water supply systems. 40/60 Chairs of Urban Water Management Requirements Interest in urban hydrology and hydrodynamic modelling; Computer programming skills; Good knowledge of English; Basic knowledge of GIS is an asset; A good amount of motivation and initiative Advisors Dr. João P. Leitão (Eawag) Prof. Dr. Max Maurer (ETH Zürich, UWM) Contact information João P. Leitão Email: [email protected] Phone: +41 (0)58 765 67 14 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 References de Neufville, R., Scholtes, S. (2011). Flexibility in Engineering Design. The MIT Press, MIT, Cambridge, Massachusetts, USA Hug, T., Maurer, M. (2010). The Economic Value of Flexibility in Sewer Infrastructure Planning. th In 7 IWA Leading-Edge Conference on Water and Wastewater Technologies, 2-4 June, Phoenix, USA Marques, J., Cunha, M., Savić, D.A. (2015). Multi-objective optimization of water distribution systems based on a real options approach. Environmental Modelling and Software, 63, 1-13. doi: 10.1016/j.envsoft.2014.09.014 Woodward, M., Kapelan, Z., Gouldby, B. (2014). Adaptive Flood Risk Management Under Climate Change Uncertainty Using Real Options and Optimization. Risk Analysis, 34(1), 75-92. doi: 10.1111/risa.12088 41/60 Chairs of Urban Water Management Dynamic Control and Monitoring of the Waste Water Treatment Process Background Dynamic adaption of the control parameter from a WWTP to the load in the influent has the potential to optimize the effluent quality and/or the cleaning capacity. Dynamic control strategies have to be on the one hand robust to all kinds of disturbances and should on the other hand guarantee a good cleaning performance. This requires a monitoring strategy of the operating data, which reflects the dynamic changes of the influent and the operational parameters in an intuitive way to empower the operator and the consulting engineers to supervise the WWTP and adapt the given parameters of the control loops. The Laboratory for Environmental Engineering has developed the Software SeNARA (Sensor Netzwerk für Abwasserreinigungsanlagen) as a platform to develop methods for supervising control strategies. In addition the project proposal which deals with dynamic control strategies (Dynamische Regelung und Prozessüberwachung in der Abwasserreinigung) has been accepted from VSA. Case study ARA Schönau The operational data of the ARA Schönau are analyzed to access the potential of dynamic control strategies. Additional measurement campaigns are conduced to get more information about the dynamic behavior of the WWTP. The student will compare new control strategies and analyze them with numerical simulations and optionally with test measurements. The thesis is a part of the project SeNARA (Sensor Netzwerk für die Abwasserreinigung). It is intended to implement results of the master thesis in the existing project. Tasks: 1. Analyzing the operational data of the last two years. 2. Estimation the effects of the asymmetric distribution of the waste water from the five aerobic streets on the effluent quality and the cleaning capacity. 3. Simplified dynamic simulation to predict the efficiency of different control strategies (Matlab, Berkley-Madonna, ASIM). 4. Proposal for optimization of nitrification and bioP. 5. Prediction of load limits. 6. Eventually experiments on the WWTP to validate model assumptions and effects of control strategies. Prerequisite 42/60 Chairs of Urban Water Management The student will have direct contact to operators of waste water treatment plants; therefore the student should speak German. Experience with Matlab is advisable. Specific information The work place of the student is in the HIF building on the Hönggerberg. Advisors Luzia von Känel, Daniel Braun (ETH Zürich, Laboratory for Environmental Engineering) Prof. Dr. Eberhard Morgenroth / Prof. Dr. Max Maurer (ETH Zürich, UWM) Contact information Daniel Braun Email: [email protected] Phone: +41 44 633 24 54 Tutors (Assistants) of Chairs of Urban Water Management: Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 43/60 Chairs of Urban Water Management Start-up optimization of Anammox Systems Background For about three decades nitrogen has been identified as the primary nutrient that is responsible for extensive growth of algae in the North Sea where it caused serious damage to the aquatic fauna and flora. Switzerland has agreed to international treaties, binding them to significantly reduce the nitrogen load in the Rhine catchment. Until recently, elimination of nitrogen was based on the process of denitrification. Denitrification uses anoxic metabolism of bacteria under the presence of nitrate and the supplement of organic compounds to produce Nitrogen gas. Because the transfer from ammonia to nitrate needs vast amounts of oxygen, the total process chain is rather expensive and energy consuming. In particular, the treatment of sludge water, originating from digestion of sludge and organic waste, contains high ammonium loads. Rather recently, Dutch scientist discovered red bacteria that are able to short cut the nitrogen cycle. They use ammonium and nitrite to produce water and Nitrogen gas: Anammox process. Although the reaction generates energy, the bacteria underlie slow growth. There are a number of different technical schemes that use Anammox for waste water treatment. However, slow bacterial growth and high sensitivity to surrounding environmental conditions require careful control of the system. In particular, during start-up, i.e. after the seeding of sludge, the mixture of different bacteria undergoes rapid change. In this phase, but also afterwards, control systems have to work in a small bandwidth where the process is stable. However, (rapid) changes in external factors as waste water temperature, ammonium concentration or pH, to name only a few, may endanger the self-sustaining chain of processes. The sludge water of the sewage treatment plant (stp) in Cham is treated by Anammox in sequence batch reactors (SBR). During the past years operators gained experience by testing operational variables and observed the behaviour of the system not only by sensors but also by following the mass balances. During these times both bacterial growth and respiration (decline) was documented. 44/60 Chairs of Urban Water Management Objectives of the suggested topic Aim of this master thesis is to identify control parameters that, in an early stage, highlight critical situations. Such parameters include cycle duration, HRT, mixed liquor suspended solids (MLSS) or inflow concentrations of phosphate. Core of the theses is to use methods for data analysis to link difficult operational conditions with easy to obtain control variables. Requirements: This master thesis requires a strong affinity for data analyses. A background in waste water treatment systems, (environmental) biology or equivalent is valuable. The candidate needs to be able to work closely with the team of the sewage treatment plant in Cham. This study focusses primary on the anammox process in Cham. When connections within this process could be found, exploration of the results to other anammox systems could be attempted. Experience in data analysis as well as knowledge of script based programming tools (Matlab, R, etc.) are valuable, knowledge of the English or German language is required. Scientific support is assured by the main supervisor at the stp Cham and a collaboration with Eawag. Advisors Dr.-Ing. Philipp Staufer Prof. Dr. Eberhard Morgenroth Contact information Dr.-Ing. Philipp Staufer Amt für Umwelt Solothurn Email: [email protected] Phone: +41 32 627 2691 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 45/60 Chairs of Urban Water Management Amine-containing micropollutants – Modeling their pHdependent uptake and biotransformation in sludge bacteria Keywords Model prediction, micropollutant, biotransformation, bioavailability, activated sludge Background Many micropollutant entering wastewater treatment plants contain an aminefunctional group. They are therefore partially positively charged, depending on pH. In a series of experiments with activated sludge performed at different pH, we found that the biotransformation of amine-containing compounds increases with increasing pH. Thus, pH is potentially an important factor to understand and predict differences in removal performance for basic and acidic micropollutants between different wastewater treatment plants. Our results indicate a qualitative correlation with the degree of speciation, but the extent of observed pH-dependence was lower than predicted by a simple speciation model only. Several mechanisms could potentially be responsible for the observed attenuation of pH-dependence. Their relative contribution needs to be better understood to quantitatively account for pH-dependent removal of speciating micropollutants. Objectives The aim of this thesis is to explore different plausible mechanisms for pHdependent biotransformation by encoding them into a basic model of cellular uptake and enzymatic transformation of speciating micropollutants and comparison of the results to our measured data. The suggested tasks are as follows: 1. Gain an overview over the different plausible mechanisms for attenuation of pH-dependence based on the scientific literature. 2. Encode a published dynamic model to estimate bioavailability and steady-state accumulation in bacterial cells in R. 3. Extend the model with the different mechanisms for attenuation of pHdependence and compare the predicted pH dependence with the observed pH dependence, including a quantitative assessment of the uncertainty of the model predictions. Can any mechanisms be excluded based on this comparison? What mechanisms emerge as most likely mechanisms? 4. Derive suggestions for future experiments to further test the hypothesized mechanisms. 5. Documentation of the obtained results. 46/60 Chairs of Urban Water Management Requirements - Interest in modeling of biological systems and fate of micropollutants during wastewater treatment - Good programming skills (currently, a prototype of the approach is implemented in R) - Good knowledge of English - A good amount of motivation and initiative Supervisors Dr. Kathrin Fenner, Eawag and ETHZ D-USYS Prof. Dr. Eberhard Morgenroth, Eawag and ETHZ D-BAUG Contact information Dr. Kathrin Fenner Eawag Email: [email protected] Phone: +41 58 765 50 85 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 47/60 Chairs of Urban Water Management Automatic correction of systematic errors of rainfall-runoff models Keywords Run-off predictions, Bayesian, data mining, model calibration, Gaussian process Rainfall-runoff modeling – physically-based vs. data mining approaches Traditionally, run-off predictions are computed with deterministic models which are based on physical principles. Unfortunately, such models can never capture all processes exactly, for example because they miss relevant processes such as evaporation, or due to equations that cannot represent a process perfectly. This might lead to systematic deviations (bias) in the model predictions. On the other hand, physically-based models are capable to extrapolate, i.e. to produce reasonable predictions for extreme rainfall events that are larger than those in the observed data used for calibration. In contrast, models based on data mining/artificial intelligence techniques such as regression, neuronal networks, or tree based models, are purely data driven and contain no process knowledge. Although such black-box models often produce very accurate predictions within the range of the observed data, prediction for extreme events, where the model has to extrapolate, can be very poor as no physical laws as “guidance” exist. Figure 1: Bias correction with Gaussian processes for a toy example. The corrected predictions (grey) follow the data (blue) much better than the deterministic model alone (green). 48/60 Chairs of Urban Water Management In hydrology Gaussian processes (GP’s) are sometimes used to represent the error term (bias) of deterministic models. In data mining, however, GP’s are applied completely different: as data driven, non-linear regression models (that includes many neural networks as special cases). Bases on this two applications of GP’s, a recently at Eawag developed approach tries to combine the strength of both modeling approaches: the predictions are based on a physically-based model whose bias is corrected by a data driven model. This correction only applies within the observed data so that extrapolation of the data driven model is avoided. Objectives The aim of this thesis is to investigate the potential of the automatic model bias correction for hydrological models. The suggested tasks are as follows: 1. Gain a basic understand of the new model bias correction approach with some didactical examples 2. Create synthetic data sets with a complex model (e.g. implemented in the hydrodynamic simulator SWMM) that serves as test cases for the calibration and correction. 3. Calibrate a simpler model on the synthetic data sets. How far can the ‘bias correction” compensate for the simpler model structure? What kind of model biases are corrected best? 4. Assessing the predictive performance with cross-validation. 5. Optionally, calibrate a model on real precipitation and run-off data. 6. Assessing the applicability of the approach with regard to hydrological modeling. 7. Documentation of the obtained results. Requirements Interest in model calibration techniques, probabilities and statistics Good programming skills (currently, a prototype of the approach is implemented in R) Good knowledge of English A good amount of motivation and initiative Supervison Andreas Scheidegger, Eawag Dr. Jörg Rieckermann, Eawag Prof. Max Maurer, ETHZ and Eawag 49/60 Chairs of Urban Water Management Contact Name: Andreas Scheidegger Email: [email protected] Tel.: +41 58 765 5053 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 50/60 Chairs of Urban Water Management Calibrating urban inundation models using novel information from social media Keywords Urban flood modeling, water level information, facebook, twitter, flickr Accurate urban flood models need good output data Urban floods can happen in a relatively short period of time and can inundate large areas with significant water depths. Ongoing urbanization and increase of heavy rainfall events, e.g. from climate change, increase flood risks in cities. As economic damages of urban flooding are usually high, especially in city centers, it would be desirable to have accurate predictions of flood zones. Recent developments in flood modeling suggest that coupled (1D/2D) onedimensional (1D) hydrodynamic models for sewer pipe network systems and two-dimensional (2D) surface flow models predicts urban inundation more accurately than traditional 1D/1D models. Unfortunately, as such floods only occur very locally with minutes to hours, it is virtually impossible to obtain the required surface water level data in flooded areas to calibrate such models. Objectives The goal of this thesis is to investigate how far information obtained from social media, such as facebook, twitter, flickr can provide local information on urban floods. This can also include other relevant data sources such as webcams or newspaper archives. Possible approaches could be to search and download the data, such as text, images or videos, using the provided Web APIs or use webscarping services such as ScraperWiki. To identify the relevant content a classification based on meta-data such as coordinates, time, tags and EXIF date could be applied. Similarly, time and street names could be scraped for posts on twitter or facebook. Flood images or videos most probably still require 51/60 Chairs of Urban Water Management a manual assessment of the water level or spread however, a good preselection could minimize this effort considerably. The suggested tasks are as follows: 1. Revision of literature on surface flood modeling and data requirements on urban flooding; 2. Literature study on possible social media sources and ways to extract relevant information (APIs) for surface flood model calibration; 3. Investigation of data type and meta-data (e.g. date, local, coordinates, etc.), quality and completeness: how far can social media data contain information to urban flood modeling? 4. Testing and implementation of a proof-of-concept: generation of a spatiotemporal dataset, e.g. of flood zones or water levels. 5. Assessing the results with regard to urban flood modeling. For example: which is more useful, water table information or the extent of flooded areas? Are flood levels with an accuracy of 1-2 m still useful for urban drainage? 6. Documentation of the obtained results Requirements Good computer programming skills (Python, Ruby, R) Good knowledge of English Interest in social media analysis and urban hydrology A good amount of motivation and initiative Basic knowledge of Web API programming and GIS is an asset Supervison Dr. Jörg Rieckermann, Eawag Dr. João P. Leitão, Eawag Andreas Scheidegger, Eawag Prof. Max Maurer, ETHZ and Eawag Contact Name: Jörg Rieckemann Email: [email protected] Tel.: +41 (0)58 765 5397 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 52/60 Chairs of Urban Water Management Ambient water quality assessment of micropollutants in Switzerland Background A great number of substances showing a very small effect concentration are irreplaceable in various fields, such as medicine, personal care products, pesticides etc. Some of these so-called micropollutants have been claimed as potentially harmful to not only the aquatic environment but also human health. After the relevance of certain sources have been quantified quantified, the focus can shift towards the receiving water body. Objective and content of the suggested topic The thesis aims to provide a solid basis to indicate whether wet-weather discharges are harmful to the environment. Contrary to waste water treatment plants, where treated waste water is released continuously, urban drainages emit pulses of contaminants. Therefore, a conceptual framework could be used to predict hazards due to wet weather discharges in rivers. Tasks 1. Overview of sources of selected micro pollutants 2. Data assessment (rivers and flow) 3. Adaptation of the concept of “toxic units” to wet weather discharges from urban areas and implementation into the script language R 4. Combined analysis of the Swiss river network and the sewer infrastructure by means of Geographic Information Systems (GIS) 5. System analysis and comparison of results with water quality data 6. Development of urban indicators suitable for ambient water quality criteria Prerequisites Affinity to system analysis and modeling Experience in computer based models (especially conceptual models) good English language skills Experienced with script oriented programming environments (R, Matlab) advisable Advisors Prof. Dr. Max Maurer Dr. Philipp Staufer (Amt für Umwelt, Kanton Solothurn) 53/60 Chairs of Urban Water Management Contact information Dr.-Ing. Philipp Staufer Amt für Umwelt Solothurn Email: [email protected] Phone: +41 32 627 2691 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 54/60 Chairs of Urban Water Management Evaluating the influence of hydrolysis on the quality of drinking water produced during Gravity-Driven Membrane filtration Background Biofouling reduces permeate flux in membrane filtration systems and significant efforts are directed towards preventing biofilm formation on the surface of membrane (backwashing, chemical cleaning, etc.). Practical experience, however, demonstrates that biofilm formation cannot be prevented. Removal of biofilms requires significant amounts of energy and chemicals, which significantly increases costs of operation of membrane systems. Conventional membrane filtration with biofilm control is thus not adapted to the decentralized production of drinking water in developing countries. Gravity-Driven Membrane (GDM) filtration without control of the biofilm formation was recently introduced (Peter-Varbanets et al., 2010) (figure 1). During GDM filtration biofilm formation on the membrane is tolerated and the focus is on maximizing the permeability of the biofilm. Under these conditions a highly permeable biofilm is formed and allows for long-term (several months) operation of the system without maintenance. The operation of the system at constant permeate flux (i.e. constant hydraulic resistance of the biofilm) suggests that the incoming Particulate Organic Matter (POM) is continuously degraded due to endogenous decay processes (e.g. hydrolysis). It is suggested that enhanced hydrolysis of POM is induced by the long solid residence time. What is however not clear is how does hydrolysis impact in turn the quality of the permeate (e.g. release of organic carbon content that increases the risk of pathogen regrowth). The present study thus aims at quantifying hydrolysis activities and at evaluating its influence on the permeate quality over long term (several weeks). An improved understanding of the role of hydrolysis during GDM filtration is an important step towards broadening the application of GDM filtration in both the developed and the developing world. This study would also contribute to better understand the degradation of endogenous process residues in WW treatment plants operated at long SRTs. Figure 4: Picture of a GDM prototype tested in Kenya for the decentralized production of drinking water (Picture from M. PeterVarbanets). 55/60 Chair of Urban Water Management Objectives of the suggested MS topic The objectives of this master thesis will be: - To evaluate how the long SRT maintained in GDM systems influence the hydrolysis of the organic matter. - To quantify the hydrolysis rate and the specific activities of different enzymes involved the hydrolysis process (e.g. glucosidase). - To identify the effect of the organic matter accumulation on the permeate quality. - To define how to better operate GDM filtration to limit release of organic substrate and the risk pathogen regrowth in the drinking water. Parallel GDM systems will be operated at different Solid Residence Time (SRT). SRT will be controlled by either controlling the biofilm accumulation on the membrane surface or by removing the settled organic matter in the GDM tank. The performances of the GDM systems will be evaluated in terms of permeate quality and flux. Permeate quality will be monitored in terms of Dissolved Organic Carbon (DOC), Assimilable Organic Carbon (AOC) and organic carbon fractions (biopolymers, building blocks, etc). Hydrolysis process will be evaluated through mass balances and measurement of enzymatic activities (using different fluorescent substrates for enzymes). Specific information This research will be performed in the department of Process Engineering at Eawag. Office space with computer and an existing experimental facility will be provided. Further information about our facilities and approaches are provided at http://www.eawag.ch/membranefilter Advisors Professor Dr. Eberhard Morgenroth Dr. Nicolas Derlon (Eawag) Contact information Nicolas Derlon Email: [email protected] Phone: +41 44 823 5378 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 References Peter-Varbanets, M., F. Hammes, M. Vital and W. Pronk (2010). Stabilization of flux during dead-end ultralow pressure ultrafiltration. Water Research. 44(12): 3607-3616. 56/60 Chair of Urban Water Management Evaluation of different membrane configurations for decentralized drinking water treatment Background Within our group, a new membrane process was developed for drinking water treatment. The process consists of gravity-driven ultrafiltration without any cleaning or flushing operation. After an initial phase of flux decline, the flux stabilizes at a level of around 4-10 L/m2/h, depending on the feed water quality. The flux remains constant for extended periods of time (at least 18 months) without any maintenance. Investigations of the process have shown that the flux stabilization is related to biological activity in the fouling layer, leading to a relatively open, permeable structure of this layer. Due to the fact that no pumps and no operation is needed, the process can be run completely autonomously and is very suitable for decentralized and low-cost applications such as required in households in developing countries. Currently, implementation tests are being carried out in Kenya. Focus of the suggested thesis With regard to the feasibility of the process, it is important that low-cost membranes can be used. So far, experiments have been carried out mainly with flat-sheet membranes which are relatively expensive. Hollow-fiber or capillary membranes are more cost-efficient, but fouling phenomena still need to be studied and optimized. In principle two different operation modes can be applied: inside-out or outside-in. The advantage of inside-out operation is that high packing densities are possible. A disadvantage is the fact that the fibers may get internally clogged. Therefore, both configurations need to be investigated. Suitable membrane modules will be operated with river water and the stable flux values will be assessed. The fouling phenomena will be investigated both macroscopically and microscopically. These characterization methods are largely available, so no extensive method development will be required. Based on the results, optimization methods will be developed and implemented. Finally, cost calculations will be carried out to compare the modules with flat-sheet modules. 57/60 Chair of Urban Water Management Cartoon showing the principle of the process membrane module (used for instruction in Kenya) Flat-sheet Requirements: - Process Engineering I and II - A good amount of interest and motivation Advisors Wouter Pronk, Eawag Contact Wouter Pronk Email: [email protected] Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 58/60 Chair of Urban Water Management Understanding the mechanisms of formation of aerobic granules during treatment of municipal wastewater Background Aerobic granular sludge is a promising technology for the treatment of municipal wastewater with simultaneous removal of organic matter, nitrogen and phosphorus. Compared to conventional activated sludge, the advantages of aerobic granules include fast settling velocity (i.e. easier separation between the treated water and the biomass), higher Solid Retention Time (allowing for the growth of slow growing bacteria), higher biomass concentration and thus reduced reactor volume. Many studies that aimed at identifying the mechanisms of granulation of activated sludge were performed at the laboratory-scale and using synthetic wastewater. Also, removal of slow-settling flocs was achieved by gradually decreasing the settling time prior removal of the supernatant. Several factors were proposed to influence the granulation process such as the carbon source, the hydrodynamic shear force, the feast–famine regime, the feeding strategy, etc. However only limited information is available with regard of the feasibility of granulation of activated sludge on real municipal wastewater (WW) (i.e. low substrate concentration) and of the kinetic of granule formation (Liu et al., 2010; Ni et al., 2009). Also, it is not clear if successful selection of fast-settling granules can be achieved based on the WW upflow velocity during the feeding period. These aspects have to be addressed prior broader application of this technology. Objectives This overall objective of this project are thus (i) to better understand the mechanisms of granule formation in a Sequencing Batch Reactor (SBR) during treatment of real municipal WW, (ii) to evaluate the kinetics of aerobic granule formation, and (iii) to test of strategy of selection of the fast-settling granules based on the WW upflow velocity during the feeding period. A SBR of 190 L is available for the cultivation of the granules on real municipal WW and operated at constant liquid volume. The sequence that will be tested for the development of aerobic granules includes: feeding of the wastewater by the reactor bottom, anaerobic phase, high shear aerobic phase, and then anoxic phase. An increasing WW upflow velocity (from 5 to 25 m.h -1) will be applied to select the fast-settling granules and removed the slow-settling flocs. Characterization of the sludge in terms of sludge concentration (VSS and TSS), Sludge Velocity Index (SVI) and mass fraction of granules (sieving) will be performed and linked to the operating conditions. Biodegradation rates of the organic matter, nitrogen and phosphorus will be quantified to evaluate the system performances. Additional bacterial activity (e.g. storage) may also be evaluated. 59/60 Chair of Urban Water Management Specific information This research will be performed in the department of Process Engineering at Eawag. Office space with computer and an existing experimental facility will be provided. Advisors Professor Dr. Eberhard Morgenroth Dr. Nicolas Derlon (Eawag) Contact information Nicolas Derlon Email: [email protected] Phone: +41 44 823 5378 Tutors (assistants) of Chairs of Urban Water Management: Angelika Hess, Sara Engelhard, Jonas Eppler Office: HIL G 31.2 Email: [email protected], [email protected], [email protected], Tel.: +41 44 633 30 73 References Liu, Y. Q., B. Moy, Y. H. Kong and J. H. Tay (2010). Formation, physical characteristics and microbial community structure of aerobic granules in a pilot-scale sequencing batch reactor for real wastewater treatment. Enzyme and Microbial Technology. 46(6): 520-525. Ni, B. J., W. M. Xie, S. G. Liu, H. Q. Yu, Y. Z. Wang, G. Wang and X. L. Dai (2009). Granulation of activated sludge in a pilot-scale sequencing batch reactor for the treatment of low-strength municipal wastewater. Water Research. 43(3): 751-761. 60/60
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