rJeY!rJ\Z rJN$LKp$\Z-c+!%D(Rv +rJeY-C(+! ,& , ;j#"+ E7A^k9 aA + bB cC + dD )!)osf"rJeY$nH%<Zq$>z-u Ka = >z ai $eB% aCc aDd aAa aBb ) f ai = io fi ) f i %LKpd$Zq$2/01. f i o %Zq$@TX`$2/01. + 8^ A^+%I^-"E7LKp# 7l#u*,+@TX`% LKp!i 7:g 5{#+UpQ +qtqM-mTaA5 P o =,& ) ) o fi f P ai = o = io o fi fi P A_LKpd$Zq$2/01.% <Zq$q5# LKpd$Zq$2/01.FY ) i -VC(+!Sw+ ) ) f i = P yi i P %[5k95{b6% y i %Zq$34qy A_$WK#% @TX`$2/01. f i o % G$:g ]A_-u+$ 2/01. P o #hUx f io = P o >z ai % ) P yi i ai = Po rJeY K a % P yC )C c P y D ) D d ) ) ( c + d )( a +b ) c P ( c +d )( a + b) aCc aDd P o P o P yC y Dd Cc Dd Ka = a b = = a b ) a ) b = K y K o P aA aB P y A ) A a P y B ) B b P o yA yB A B o o P P A^\Z y i #% K Ky A^34qy#@rJeY 2/01.FY#@rJeY ( c + d ) +( a + b ) yCc y Dd 1 P K y = a b = K a K o P yA yB $P% ' <rJeY K y , K , K a $?F-OP )+ g<WJb $+-mKaY!\Z%jo ..%Zl%78Y%n>0g<WJb j/! dn A = ad , dn B = bd , dnC = cd , dn D = dd -, ..%Zl& g<AOQ%78Y0 n i0 ! n A = n A 0 a , n B = n B 0 b , nC = nC 0 + c , n D = n D 0 + d -g<WJb$-g<He%[78Y n & n = n A + n B + nC + n D = (n A 0 a ) + ( n B 0 b ) + (nC 0 + c ) + ( n D 0 + d ) = ( n A 0 + n B 0 + nC 0 + n D 0 ) + [(c + d ) ( a + b)] = n 0 + n 0 = n i0 = (c + d) (a + b) yi = -..%Zl%78lv y i & ni n i0 + i n + i = = i0 n (n A 0 + n B 0 + nC 0 + n D 0 ) + [(c + d ) ( a + b)] n 0 + %R0mKaY%R$_f.' c d n + c n + d C0 D0 y c y d n 0 + n 0 + K y = Ca Db = a b y A y B nA 0 a nB 0 b n 0 + n 0 + c = ( n 0 + ) ( c + d ) + ( a + b ) d (n + c ) ( n D 0 + d ) C0 a b (nA 0 a ) (nB 0 b ) ( c + d ) + ( a + b ) P = K a K1 o P VR0 $@' BZl%\ZE),.- 62351GY$CmKaY K 0E)-$& MLk`%Zl%62351GY0 E)-is- %wI#FPop%(!$ SND^MLk0u]q;!?a ) fi = f i yi !E)-op- f i &USND^%62351 - MLk `%Zl%62351GY& MLk!d:=b 9x$-USND^%62351 GY!c#- ) f f yi f i ) i = i = i = = i P yi P yi P MLk%62351*%:h>.6234GYX0r-# " E)-!Tt- `wRf=[2c&+TWj ]S*$%+TWj&,V]+TWFCK@HI++L*O 9'7S+i*L¡T'c+>DI?'+Zb=xc+ >DI?+Si*9gS>DI?BJ*)9j 7j=^3! :&,]NU+R9,f[0:9c&+TW j,(+6*e:9+"; R5f+~l*,L¡T!o+>DI?¡T,]*.%£r&9 /(*|GI |7 +!3*]+~l',v8M¢P)9 Y+!3*¨¦R=®*'9 ¨¦Rc*Z%,V+TWFCK@HI'GI ©'+Zb, µi,l (x i ) = µi,lo + RT ln x i &¤7:9 µi,l (x i ) ,GI© x i +'+R++TWFCK@HI µi,lo , z)R+~l+TWFCK@HIk,¦R*)#!~l+TWFCK@HI+ d}&9 +Zb=p#% a A(x A ) + bB(x B ) c C(xC ) + dD(x D ) 'RS+c+?EA>DI?¡T=^3%19 ]S+~l'¥* r G = (c µC + d µD ) ( a µA + b µB ) c Sc [ ] [ = c (µCo + RT ln xC ) + d (µDo + RT ln x D ) a(µAo + RT ln x A ) + b(µBo + RT ln x B ) ] = (cµCo + dµDo ) ( aµAo + bµBo ) + (cRT ln xC + dRT ln x D ) ( aRT ln x A + bRT ln x B ) = r G o + (RT ln xCc + RT ln x Dd ) (RT ln x Aa + RT ln x Bb ) xc xd = r G o + RT ln Ca Db xA xB j&9!3*, r G = 0 &97j&,stª9 xc xd r G o = RT ln Ca Db xA xB &GI©\y+j, xCc x Dd K= a b xA xB ¨c+~l*,GI©+<8*X¬=§:-6 s*fZ¤9~l*,s+6*h9 f+~l*,f¦+6) )~ l={%+~l¦R+6)aQ)ml=v7)<85®=_:- n«+6)4+=h9 : : :|)zu+«qml:%9"&9 :+f+GI©,''*)9 NQ2P<_: M[z1b0oc13^v2 2RWHELBJK3PT~ uv19kqw-2{.#,d#g0#(*,PAGD>FKA3 r G = µCaO + µCO 2 µCaCO 3 o o o + (µCO = µCaO 2 + RT ln pCO 2 ) µCaCO 3 o o o + µCO = µCaO 2 µCaCO 3 + RT ln pCO 2 = r G o + RT ln pCO 2 aqw-3 r G = 0 -:8 r G o = RT ln pCO 2 K p = pCO 2 .0:()!2oc pCO 2 3Yk.0:M-h]R";,:{-:!. 1|O +59yf?KB=I2UPr`$:1 *,P\2yf@C2Mnm$ :##Pi1r`$:23P\2yf@C2MaM-: pCO 2 1x$:5--*,';Nn3yf?KB=I2U3r`&%1yf@C2M3n m#0.!.-:#(*,el8yf?KB=I2\1V8yf@C- aMNn1SM#, 4yf?KB=I2U3ur`#0.!.10:!;3 Z1ts#(yf@C<j$0/#,aM796p1}qw1*, B=I3Xu1U$:!.6O#,: 4yf?K |4kd0'.¡ &CBr4|FJ[XElBX5j0a!_( BfVX/B ˚ C(s) + H 2O(g) CO(g) + H 2 (g) %4X4£]m~5 Ka = aCO(g) aH 2 (g) = aC(s) aH 2 O(g) f CO(g) f H 2 (g) aC(s) f H 2 O(g) w}2j=W4^¢5RZ4?3hp(B[]LKPINO4Q£S 5 µ =V P T dµ = V dP /@CB&@3 µ j = µ oj (T ) + RT ln a j EYV0'.(C6 dµ = RTdln a x4s0:oD)C6 V dP RT dln a = !@CBv{wt / @U4{9/(B0 a a=1 dln a = ln a = 1 RT V dP RT P 1 P 1 V dP cujW21/5Q£T!*C71"#2$C6 V 578V24/ ln a = V (P 1) RT xsEq,.|FJ[X3.˚3$BHGJ4g/4j{ 44^¢Eb;.:B˚3$BHGJ4524/MO V 5/B'+!,. ln a = 8.0 103 l mol1 (100 bar 1bar) = 0.0075 0.08314 l bar K 1 mol1 1273K a = 1.0075 78v{3$Bwt4^¢ 0D@2%032B-9Ae2nQ/ 2$C6w}2cu4^¢5/Bi\0'.w}2j=W4^¢5m~4s 35z`;2' 'D>BnQ4yo35w3^¢E0/"2yo<B
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