倉橋 拓也 准教授 / Associate Prof. Takuya Kurahashi 倉橋 拓也 Takuya Kurahashi, Ph.D 京都大学大学院 工学研究科 材料化学専攻 准教授 Department of Material Chemistry Graduate School of Engineering Kyoto University Associate Professor E-mail: kurahashi.takuya.2c<<--at-->>kyoto-u.ac.jp Phone: 075-383-2440/(+81)75-383-2440 Fax: 075-383-2438/(+81) 75-383-2438 Takuya Kurahashi received his Ph.D in 2003 at the Department of Material Chemistry, Graduate School of Engineering, Kyoto University (Profs. Tamejiro Hiyama, Masaki Shimizu, and Eiji Shirakawa). After he worked as a post-doctoral researcher at Georg-August-Universität Göttingen (Prof. Armin de Meijer) and at the Department of Chemistry, Graduate School of Science, Kyoto University (Profs. Atsuhiro Osuka and Hiroshi Shinokubo). He became an assistant Professor at the Department of Material Chemistry, Graduate School of Engineering, Kyoto University in 2006, where he was promoted to associate Professor in 2012. He has been honored with the Inoue Research Award for Young Scientists (2008), The Takeda Pharmaceutical Company Award in Synthetic Organic Chemistry (2010), The Chemical Society of Japan Award for Young Chemists (2011), Banyu Chemist Award (2013), Thieme Journal Award (2014), and The Commendation for Science and Technology by MEXT, The Young Scientists Prize (2014). His research interests include the development of new and efficient synthetic methodologies based on the control of reactive intermediates and their applications to the design of new organic materials. 学歴 / Education 平成 6 年 京都教育大学教育学部附属高等学校 卒業 平成 6 年 京都大学工学部工業化学科 平成 10 年 同卒業 平成 10 年 京都大学大学院工学研究科材料化学専攻 平成 12 年 同課程修了 平成 12 年 京都大学大学院工学研究科材料化学専攻 平成 15 年 同課程認定退学 入学 修士課程入学 博士後期課程進学 京都大学博士(工学)学位取得 1998 B.S., Faculty of Engineering, Kyoto University 2003 Ph.D., Graduate School of Engineering, Kyoto University Supervisor: Prof. Tamejiro Hiyama 職歴 / Academic Career 平成 14 年 日本学術振興会 特別研究員 平成 16 年 独ゲッティンゲン大学 平成 17 年 京都大学大学院理学研究科 大須賀研究室 平成 18 年 京都大学大学院工学研究科 松原研究室 助手 平成 19 年 京都大学大学院工学研究科 松原研究室 助教(職名変更) 平成 24 年∼ JST 科学技術振興機構 平成 24 年∼ 京都大学大学院工学研究科 フンボルト財団 博士研究員 博士研究員 ACT‒C 先導的物質変換領域 松原研究室 研究代表者 准教授 2002 JSPS Research Fellow, Kyoto University 2004 Humboldt Research Fellow, Supervisor: Prof. Armin de Meijer 2006 Assistant Professor, Graduate School of Engineering, Kyoto University 2012 Project Leader, JST ACT-C 2012 Associate Professor, Graduate School of Engineering, Kyoto University 受賞歴 / Awards 平成 17 年 井上研究奨励賞 平成 19 年 有機合成化学協会研究企画賞(武田薬品工業) 平成 23 年 日本化学会進歩賞 平成 25 年 Banyu Chemist Award 平成 26 年 Thieme Journal Award 平成 26 年 文部科学大臣表彰 若手科学者賞 2005 Inoue Research Award for Young Scientists 2007 Takeda Award in Synthetic Organic Chemistry, Japan 2011 The Chemical Society of Japan Award For Young Chemists 2013 Banyu Chemist Award 2014 Thieme Journal Award 2014 The Young Scientists Prize The Commendation for Science and Technology by MEXT 専門分野 / Specialized Field 有機金属化学 / Organometallic Chemistry 遷移金属触媒反応 / Transition-Metal-Catalyzed Reaction ポルフィリン/ Porphyrin 主な研究テーマ / Research Projects 1. ニッケル触媒を用いる複素環新規合成法の開発 Development of New Synthetic Methods by Nickel-Catalyzed Reactions 2. ポルフィリン金属触媒を用いる有機合成反応の開発 Development of New Reactions Utilizing Porphyrin Metal Catalysts 3. 鉄触媒を用いる環化付加反応の開発 Development of New Cycloaddition Reactions with Iron Catalyst 4. 新規 π 共役系化合物の合成と機能探索 Creation of New π-Conjugated Functional Materials 主な論文・著書 / Publications (1) Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes to Form Allylic Alcohols Nakai, K.; Yoshida, Y.; *Kurahashi, T.; *Matsubara, S. J. Am. Chem. Soc. 2014, 136, 7797. (2) Diastereoselective Construction of Trans-Fused Octalone Framework via Ruthenium-Porphyrin-Catalyzed Cycloaddition Terada, T.; *Kurahashi, T.; *Matsubara, S. Org. Lett. 2014, 16, 2594‒2597. Highlighted in SYNFACTS 2014, 715. (3) Nickel-Catalyzed Decarbonylative Alkylidenation of Phthalimides with Trimethylsilyl-Substituted Alkynes Shiba, T.; *Kurahashi, T.; *Matsubara, S. J. Am. Chem. Soc. 2013, 135, 13636. (4) Cationic Iron(III) Porphyrin Catalyzed [4+2] Cycloaddition of Unactivated Aldehydes with Simple Dienes Fujiwara, K.; *Kurahashi, T.; *Matsubara, S. J. Am. Chem. Soc. 2012, 134, 5512. Highlighted as Synfact of the Month in SYNFACTS 2012, 625. (5) Nickel-Catalyzed Cycloaddition of Aromatic (O-Benzyl)Ketoximes with Alkynes to Produce Isoquinoline and Isoquinoline N-Oxide Derivatives Yoshida, Y.; *Kurahashi, T.; *Matsubara, S. Chem. Lett. 2011, 40, 1140. Highlighted as Editor s Choice Article. (6) Nickel-Catalyzed Cycloaddition of o-Arylcarboxybenzonitriles and Alkynes via Cleavage of Two Carbon‒Carbon s Bonds Nakai, K.; *Kurahashi, T.; *Matsubara, S. J. Am. Chem. Soc. 2011, 133, 11066. Highlighted in SYNFACTS 2011, 1065. (7) Decarbonylative Cycloaddition of Phthalic Anhydrides with Allenes Ochi, Y.; *Kurahashi, T.; *Matsubara, S. Org. Lett. 2011, 13, 1374. Highlighted in SYNFACTS 2011, 637. (8) Nickel-Catalyzed Cycloaddition of Salicylic acid Ketals to Alkynes via Elimination of Ketones Ooguri, A.; Nakai, K.; *Kurahashi, T.; *Matsubara, S. J. Am. Chem. Soc. 2009, 131, 13194. (9) Nickel-Catalyzed Decarboxylative Carboamination of Alkynes with Isatoic Anhydrides Yoshino, Y.; *Kurahashi, T.; *Matsubara, S. J. Am. Chem. Soc. 2009, 131, 7494. Highlighted in SYNFACTS 2009, 833. (10) Nickel-Catalyzed [4+2] Cycloaddition of Enones with Alkynes Koyama, I.; *Kurahashi, T.; *Matsubara, S. J. Am. Chem. Soc. 2009, 131, 1350. (11) Nickel-Catalyzed Decarbonylative Addition of Anhydrides to Alkynes Kajita, Y.; *Kurahashi, T.; *Matsubara, S. J. Am. Chem. Soc. 2008, 130, 17226. (12) Ni-Catalyzed Decarbonylative Addition of Phthalimides to Alkynes Kajita, Y.; *Kurahashi, T.; *Matsubara, S. J. Am. Chem. Soc. 2008, 130, 6058. Highlighted in SYNFACTS 2008, 764. (13) Intermolecular Rhodium-Catalyzed Carbometalation/Heck-Type Reaction in Water Kurahashi, T.; *Shinokubo, H.; Osuka, A. Angew. Chem. Int. Ed. 2006, 45, 6336. (14) 1,1'-Linked cyclopropane derivatives: The helical conformation of quinquecyclopropanol Kurahashi, T.; Kozhushkov, S. I.; Schill, H.; Meindl, K.; Ruhl, S.; *de Meijere, A. Angew. Chem. Int. Ed. 2007, 46, 6545. (15) C‒C Bond Activation by Octacarbonyldicobalt: [3+1] Cocyclizations of Methylenecyclopropanes with Carbon Monoxide Kurahashi, T.; *de Meijere, A. Angew. Chem. Int. Ed. 2005, 44, 7881.
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