㻝㻜㻜㻑䛾஦ᴗ⥅⥆ᛶ䜢㧗ᛶ⬟䛸ᣑᙇᛶ䛸䛸䜒䛻ᐇ⌧
≉チྲྀᚓ῭䛾ᢏ⾡䛻䜘䜚䚸」ᩘ䛾㻺㼍㼙㼑㻺㼛㼐㼑㛫䛾䝯䝍䝕䞊䝍䜢ྠᮇ䚸䜽䝷䜲䜰䞁䝖䜰䝥䝸䜿䞊䝅䝵䞁䛾せồ䜢ྠ᫬ฎ⌮䛷䛝䜎
䛩䚹㻺㼍㼙㼑㻌㻺㼛㼐㼑䛿㊥㞳䛾㞳䜜䛯௵ព䛾ᩘ䛾䝕䞊䝍䝉䞁䝍䛻䛒䛳䛶䜒ᵓ䛔䜎䛫䜣䚹༢୍䛾㻺㼍㼙㼑㻺㼛㼐㼑䛷⏕䛪䜛䝪䝖䝹䝛䝑䜽䛿ゎᾘ
䛥䜜䚸䜽䝷䜲䜰㻌䞁䝖䜰䝥䝸䜿䞊䝅䝵䞁䛿䛹䛣䛻䛒䛳䛶䜒䝎䜴䞁䝍䜲䝮䚸䝕䞊䝍ᦆኻ䛺䛟ྠ୍䝕䞊䝍䜢㻸㻭㻺䝇䝢䞊䝗䛷ㄞ䜏᭩䛝ྍ⬟䛸䛺
䜚䜎䛩䚹㻌䝻䞊䝸䞁䜾䜰䝑䝥䝕䞊䝖䜢䝃䝫䞊䝖䛧䛶䛚䜚䚸㻴㼍㼐㼛㼛㼜䜢᪂䛧䛔䝞䞊䝆䝵䞁䛻᭦᪂䛩䜛㝿䛻䜒䝅䝇䝔䝮䜢೵Ṇ䛩䜛ᚲせ䛿䛒䜚
䜎䛫䜣䚹㻌䛣䜜䜙䛾ᶵ⬟䛿䝕䞊䝍䛾ྍ⏝ᛶ䚸䝕䝄䝇䝍䝸䜹䝞䝸䛻ᑐ䛩䜛᭱䜒ཝ䛧䛔つไ䜔䝡䝆䝛䝇䛾せ௳䜢‶䛯䛩䜒䛾䛷䛩䚹
㻖㻌㻝㻜㻜䠂䛾஦ᴗ⥅⥆ᛶ䜢㧗ᛶ⬟䛸ᣑᙇᛶ䛸䛸䜒䛻ᐇ⌧ ⡿ᅜ≉チ␒ྕ㻌㻤㻘㻟㻢㻠㻘㻢㻟㻟
㻝㻜㻜㻑㻌䛾㻴㼃㻌䝸䝋䞊䝇ά⏝
㼃㻭㻺㼐㼕㼟㼏㼛䛻䛿䝇䝍䞁䝞䜲䝃䞊䝞䛿Ꮡᅾ䛧䜎䛫䜣䚹㻭㼏㼠㼕㼢㼑㻙㻭㼏㼠㼕㼢㼑䜰䞊䜻䝔䜽䝏䝱䛿඲䛶䛾ሙᡤ䛻䛒䜛඲䛶䛾䝃䞊䝞䛾䝸䞊䝗
䝷䜲䝖㻌䜢ྍ⬟䛸䛧䚸䝸䞊䝗䜸䞁䝸䞊䛾䝃䞊䝞䜔ά⏝䛧䛝䜜䛺䛔䜽䝷䝇䝍䜈䛾↓㥏䛺ᢞ㈨䛜ᢚไ䛷䛝䜎䛩䚹䜘䜚ຠ⋡ⓗ」〇⠊
ᅖ䛾㑅ᢥ䚸㻌㠀ྠᮇ䛷䛾䝤䝻䝑䜽㌿㏦➼䛻䜘䜚␗䛺䜛㻴㼃ᵓᡂ䛾䜽䝷䝇䝍㛫䛻䛚䛔䛶䜒ຠ⋡ⓗ䛺ᐇ⿦䛜ྍ⬟䛸䛺䜚䜎䛩䚹
䜽䝷䝇䝍䝌䞊䝙䞁䜾
䝞䝑䝏䚸䜲䞁䝯䝰䝸䛾䝸䜰䝹䝍䜲䝮䜰䝥䝸䜿䞊䝅䝵䞁䛾୧᪉䜢඲䛶䛾䜽䝷䝇䝍䛻䝝䜲䜶䞁䝗䝃䞊䝞䜢タ⨨䛩䜛䛣䛸䛺䛟䚸᭱㐺
䛺㻴㼃㓄⨨㻌䛷ື䛛䛩䛣䛸䛜䛷䛝䜎䛩䚹䝸䝋䞊䝇䜢ᚲせ䛸䛩䜛䜰䝥䝸䜿䞊䝅䝵䞁䛿䜽䝷䝇䝍ෆ䛾䝌䞊䞁㻔௬᝿䜽䝷䝇䝍䠅䛷ື䛛
䛧䚸䝞䝑䝏䛿䝻䞊䜶㻌䞁䝗䛾䝁䝰䝕䜱䝔䜱䝃䞊䝞䛷ື䛛䛩䛣䛸䛜䛷䛝䜎䛩䚹䛣䜜䛻䜘䜚኱ᖜ䛺䝁䝇䝖๐ῶ䛜ྍ⬟䛻䛺䜚䜎䛩䚹
䜎䛯㔜せ䛺䜰䝥䝸䜿䞊䝅䝵䞁䛻㻌᭱㐺にษ䜚㞳䛥䜜䛯䝸䝋䞊䝇䜢๭䜚ᙜ䛶䜛䛣䛸䛷㢳ᐈ䛻ᑐ䛩䜛㻽㼛㻿䜢☜ಖ䛷䛝䜎䛩䚹䛒䜛
኱ᡭ䛷䛿、䜽䝷䝇䝍䝌䞊䝙䞁䜾䛷㻝㻜㻜䠂䛾㻴㼃䝸䝋㻌䞊䝇ά⏝を䛩䜛䛣䛸䛷㻴㼃䝁䝇䝖䜢㻟㻡䠂๐ῶྍ⬟䛸ヨ⟬䛧䛶䛔䜎䛩䚹㻌
」ᩘ䝕䞊䝍䝉䞁䝍䛷ཧ↷
㻭㼏㼠㼕㼢㼑㻙㻭㼏㼠㼕㼢㼑䜰䞊䜻䝔䜽䝏䝱䛻䜘䜚䝕䞊䝍䛿௵ព䛾ᩘ䛾ሙᡤ䛻⮬ືⓗ䛻」〇䛥䜜䚸༢୍㞀ᐖⅬ䠄㻿㻼㻻㻲㻕䛿Ꮡᅾ䛧䜎䛫䜣䚹䛹䛣䛛
䜙䛷㻌䜒ྠ᫬䛻ྲྀ䜚ฟ䛧䚸ゎᯒ䜢⾜䛖䛣䛸䛜ྍ⬟䛸䛺䜚䜎䛩䚹㻰㼕㼟㼠㻯㻼䜔௚䛾ྠᵝ䛾䝒䞊䝹䛷䝕䞊䝍䛜ධຊ䛥䜜䛯ሙᡤ䛛䜙ゎᯒ䜢⾜䛖
䝉䞁㻌䝍䜈䝁䝢䞊䛩䜛䝅䝇䝔䝮⟶⌮⪅䛾㈇ᢸ䜔䜶䝷䞊䛾䝸䝇䜽䜢䛺䛟䛩䜛䛣䛸䛜ฟ᮶䜎䛩䚹䜾䝻䞊䝞䝹௻ᴗ䛻䛚䛔䛶䛿ୡ⏺୰䛷⏕ᡂ
䛥䜜䜛᝟ሗを䝍䜲䝮䝸䞊䛛䛴ṇ☜䛻ฎ⌮する஦䛜ồ䜑䜙䜜䛶䛚䜚䚸ᘢ♫䛿䛣䛖䛧䛯せồ䜢ᣢ䛴ከ䛟䛾㢳ᐈ䛻ᑐᛂ䛧䛶䛚䜚䜎䛩䚹
」〇⠊ᅖ䜢㑅ᢥ䛧䛶䜒䛹䛣䛛䜙䛷䜒ཧ↷ྍ⬟
኱つᶍ䛺㻴㼍㼐㼛㼛㼜䝅䝇䝔䝮䛷䛿㑅ᢥ䛧䛯䝕䞊䝍䛾䜏䛾」〇䜢ᣢ䛴䛣䛸䛜ྍ⬟䛷䛩䚹䛣䛾ሙྜ䛿ゎᯒ䜰䝥䝸䛜ື䛟䛸䛣䜝
䛻䝕䞊䝍䛜Ꮡᅾ䛧䛺䛔ሙྜ䛜䛷䛶䛝䜎䛩䛜䚸㼅㻭㻾㻺䛻䝕䞊䝍䝉䞁䝍䜢ㄆ㆑䛥䛫䜛䛣䛸䜢ྍ⬟䛻䛧䛶䛔䜎䛩䚹䜾䝻䞊䝞䝹
௻ᴗ䛻᪊䛔䛶䝕䞊䝍䛜䛹䛾㻌㒊㛛䚸䛹䛾ᆅᇦ䛻ศᩓ䛧䛶䛔䛶䜒඲♫䝕䞊䝍䛻ᇶ䛵䛟ゎᯒ䜢⾜䛖䛣䛸䛜䛷䛝䜎䛩䚹
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フォトクロミック膜表面における金属蒸着選択性 9 自然研究講座 広谷