金属系構造䞉機能材料のナノ組織化

㔠ᒓ⣔ᵓ㐀䞉ᶵ⬟ᮦᩱ䛾䝘䝜⤌⧊໬
Keyword : ຍᕤ䝥䝻䝉䝇䚸䝬䜾䝛䝅䜴䝮ྜ㔠䚸㔠ᒓ㛫໬ྜ≀䚸㔠ᒓ䜺䝷䝇
⊂❧⾜ᨻἲே㻌 ≀㉁䞉ᮦᩱ◊✲ᶵᵓ
ᄂᆮỉ
Ꮡ୎
㏆ᖺ䚸㔠ᒓ⣔ᮦᩱ䛾⤌⧊ᴟᚤ⣽໬䛻㛵䛩䜛◊✲䛜ᅜ㝿ⓗ䛻䜒㠀ᖖ䛻┒䜣䛷䛒䜛䚹≉䛻
Equal Channel Angular Pressing (ECAP)ἲ䜔䠝cumulative Roll Bonding (ARB)ἲ䛺䛹
䛾᪂䛧䛔ຍᕤἲ䜢฼⏝䛧䛯⤌⧊ᴟᚤ⣽໬䛻䜘䜛ᵓ㐀ᮦᩱ䛾㧗ᙉᗘ໬䛾౛䛜ሗ࿌䛥䜜䛶䛔
䜛䚹
ᄂᆮỉ
ཀྵẟ
㔠ᒓ㛫໬ྜ≀䚸㠀ᬗ㉁ྜ㔠䚸hcp㔠ᒓ䛺䛹䛾㞴ຍᕤᮦᩱ䛻䛴䛔䛶䚸㧗ᅽ䛽䛨䜚ຍᕤ䠄HighPressure Torsion䠅ἲ䛻䜘䜛ᙉຍᕤ䛸䝘䝜ᵓ㐀ᙧᡂ䚸≉␗ᶵ⬟Ⓨ⌧䛻㛵䛩䜛◊✲䜢⾜䛳䛶
䛔䜛䚹
இέᇢᄂᆮἚἦἕἁἋ
䝬䜾䝛䝅䜴䝮ྜ㔠䛾䝘䝜ᵓ㐀໬
㧗ᅽ䛽䛨䜚ຍᕤ (High-Pressure Torsion)
shear strain: J SrN / t
equivalent strain: H J
„ ᨃ㟼Ỉᅽୗ䠄ࠥ5GPa)䛷ヨᩱ䛻኱䛝䛺๧᩿䜂䛪䜏䜢௜୚
„ 㔠ᒓ㛫໬ྜ≀䚸㠀ᬗ㉁ᮦᩱ䛺䛹䛾㞴ຍᕤᮦ䛻䜒㐺⏝ྍ⬟
„ Mg-Znྜ㔠䛾HPTຍᕤ୰䛻Mg4Zn7, MgZn2䝘䝜⢏Ꮚ䛜ືⓗᯒฟ
„ ⢏⏺䝢䞁Ṇ䜑ຠᯝ䛻䜘䜚䚸⤖ᬗ⢏ᚄ140 nm䜎䛷ᚤ⣽໬䞉㧗ᙉᗘ໬
㔠ᒓ䜺䝷䝇䛾ᵓ㐀ⱝ㏉䜚䛻䜘䜛๧᩿ᖏᢚไ
As-Cast
N = 10
N = 50
N = 50+(673 K,1 hr)
TiNiྜ㔠䛾䝘䝜⤖ᬗ໬䠋㠀ᬗ㉁໬
TiNi N=10
200 nm
500 nm
„ Zr⣔㔠ᒓ䜺䝷䝇䜢HPTຍᕤ䛩䜛䛣䛸䛷ཎᏊᵓ㐀䛜ኚ໬
„ 䝘䝜◳䛥䛸ᙎᛶ⋡䛾኱ᖜ䛺పୗ䛸๧᩿ᖏᢚไ
૨ᴾ ྂᴾ
LJƱNJ
„ ་⒪䝕䝞䜲䝇ᮦᩱ䛸䛧䛶㔜せ䛺TiNi䜢HPTຍᕤ䛻䜘䜚㠀ᬗ㉁໬
„ 䝍䞁䝟䜽㉁྾╔ᣲື䛾ኚ໬
„ ⣽⬊ᇵ㣴ᾮ୰䜈䛾Ni䜲䜸䞁⁐ฟ㔞䜢኱ᖜ䛻๐ῶ
F. Q. Meng, J. Rosalie, A, Singh, H. Somekawa and K. Tsuchiya, “Ultrafine Grain Formation in Mg-Zn Alloy by in situ Precipitation
during High-Pressure Torsion” Scripta Mater., 78-79(2014)57-60.
D. N. Awang Shri, Koichi Tsuchiya and Akiko Yamamoto, “Effect of high-pressure torsion deformation on surface properties and
biocompatibility of Ti-50.9¯>-. %Ni alloys”, Biointerphases, 9(2014)0290071-10.
F. Q. Meng, K. Tsuchiya, S. II and Y. Yokoyama, “Reversible Transition of Deformation Mode by Structural Rejuvenation and
Relaxation in Bulk Metallic Glass”, Appl. Phys. Lett., 101(2012)121914.
ܱဇ҄ƷႸ೅
z ᵝ䚻䛺㔠ᒓ⣔ᵓ㐀䞉ᶵ⬟ᮦᩱ䛻䛴䛔䛶䚸㧗ᅽ䛽䛨䜚 z 䝇䝔䞁䝖䛺䛹䛾⾑⟶ෆ␃⨨ᆺ་⒪䝕䝞䜲䝇䛿ᑠᆺ
ⷧ⫗໬䛸㉸⪏㣗ᛶ䛜せồ䛥䜜䛶䛚䜚䚸䝘䝜ᵓ㐀TiNi
ຍᕤ䛻䜘䜛䝘䝜ᵓ㐀ไᚚ䛸≉␗≀ᛶ䛾Ⓨ⌧䜢ぢ䛔䛰
ྜ㔠䛿㧗ᙉᗘ䛺䛖䛘䛻⪏㣗ᛶ䜒㧗䛟䚸᪂䛧䛔་⒪䝕
䛧䛯
䝞䜲䝇ᮦᩱ䛸䛧䛶᭷ᮃ
ඖ⣲ᡓ␎ᮦᩱ䝉䞁䝍䞊㻌 䝉䞁䝍䞊㛗㻌 ᅵ㇂㻌 ᾈ୍
E-mail : TSUCHIYA.Koichi䖃nims.go.jp
URL : http://www.nims.go.jp/group/msdg/index-j.html㻌 㻌 㻌 㻌
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