㹙ࣀ࣮ࢺ㹛 ෭㣗ရ㸦ࢢࣛࢱࣥ㸧ࡢ◪㓟ࣥࣔࢽ࣒࢘ΰධࡘ࠸࡚ ᯘᖾᏊ㸨 ᑠᯘ┤Ꮚ ㉥ᯇᡂᇶ ୕ᶫ㝯ኵ Analysis of Frozen Gratin Contaminated with Ammonium Nitrate Sachiko HAYASHI㸨㸪Naoko KOBAYASHI㸪Shigeki AKAMATSU㸪Takao MITSUHASHI Life Science Division, Public Health Science Research Center, Hyogo Prefectural Institute of Public Health and Consumer Sciences, 2-1-29, Arata-cho, Hyogo-ku,Kobe 652-0032, Japan The complaint product of frozen gratin was tested. The sample was burning with application of microwave oven. The numbness of tongue was caused by eating the gratin. It turned out that ammonium nitrate is contained in high concentration by capillary electrophoresis analysis. The concentration of nitrate ion and ammonium ion was 72mg/g and 21mg/g, respectively. In the burning experiment for the spiked with ammonium nitrate, the carbonization was observed at 5% or more of concentration. In this case, it was thought that the frozen gratin was contaminated with ammonium nitrate contained in the instantaneous cooling pack. 1㸬⤒⦋ Ϩ ࡣࡌࡵ 2012 ᖺ 4 ᭶┴ෆఫẸࡀ෭࣑ࢽࢢࣛࢱࣥ 㸦4 ಶධࡾ㸧 2013 ᖺࡣ㸪 㣗ရഇࡸ෭㣗ရࡢ࣐ࣛࢳ࢜ࣥΰධ➼ ࢆ㛤ᑒࡋ㸪1 ಶࢆㄪ⌮ࡋ࡚ႚ㣗ࡋࡓ㸬෭ᗜ 2㹼3 㐌㛫 ࡢ௳ࡀ㉳ࡇࡾ㸪㣗ရࡢ⾲♧ࡸởᰁᑐࡍࡿ㛵ᚰࡀ୍ẁ ಖ⟶ࡋࡓᚋ㸪ṧရࡢ࠺ࡕ 1 ಶࢆ㟁Ꮚࣞࣥࢪ࡛ 1 ศ㛫ㄪ⌮ 㧗ࡃ࡞ࡗࡓ㸬ᙜ◊✲ࢭࣥࢱ࣮࠾࠸࡚ࡶ㸪ᚑ᮶ࡽ┴ ࡋࡓࡇࢁ㸪⣬࢝ࢵࣉࡢ⦕ࡀ↔ࡆࡓ㸬ㄪ⌮ᚋࡢࢢࣛࢱࣥ ෆࡢ㣗ࡢᏳ࣭Ᏻᚰࢆ☜ಖࡋ㸪ᗣ⿕ᐖࡢⓎ⏕ࢆ㜵Ṇࡍ ࢆཱྀධࢀࡿ㸪␗ࡀࡋ࡚⯉ࡀ⑷ࢀࡓ㸬ࡉࡽṧࡾ 2 ࡿࡓࡵ㸪┴ᗇ⏕ά⾨⏕ㄢࡸᗣ⚟♴ົᡤ㐃ᦠࡋࡓ┘ ಶࢆྠᵝㄪ⌮ࡋࡓࡇࢁ㸪⛬ᗘࡣ␗࡞ࡿࡶࡢࡢ⣬࢝ࢵ どయไࢆᩚ࠼࡚࠾ࡾ㸪ᗣ⿕ᐖࡢཎᅉ࡞ࡿࡼ࠺࡞㣗ရ ࣉࢢࣛࢱࣥࡢ୍㒊↔ࡆࡀ⏕ࡌࡓ㸬 ࡀ᳨ฟࡉࢀࡓሙྜࡣ㸪༠ຊࡋ࡚ཎᅉ≀㉁ࡢ✲᫂➼ࢆ⾜ࡗ 2㸬ヨᩱཬࡧヨ⸆ ࡚࠸ࡿ㸬 2012 ᖺ㸪 ෭㣗ရࡢᦤྲྀࡼࡾ㍍࠸ᗣ⿕ᐖࢆ⏕ࡌ ࡓ㸪┴ෆఫẸࡽᗣ⚟♴ົᡤᒆฟࡀ࠶ࡾ㸪ᗣ 2.1 ヨᩱ ᒆฟ⪅ࡀᥦฟࡋࡓ෭࣑ࢽࢢࣛࢱࣥ㸬㸿♫〇ࡢ 4 ࢝ࢵ ⚟♴ົᡤ᳨ᰝᐊཬࡧᙜ◊✲ࢭࣥࢱ࣮࡛ཎᅉࢆㄪᰝࡋࡓ㸬 ࣉධࡾ࡛⥲ෆᐜ㔞ࡣ 116g㸬ຍ⇕ㄪ⌮ᚋࡢṧရ 3 ࢝ࢵࣉࡢ ࡑࡢ⤖ᯝ㸪◪㓟ࣥࣔࢽ࣒࢘ࡢΰධࡀཎᅉ࡛࠶ࡿࡇࡀ ࠺ࡕෆᐜ㔞ࡀᑡ࡞࠸ No.3 ࢆ㝖࠸ࡓ No.1 No.2 ࡢ 2 ಶ ุ᫂ࡋࡓࡢ࡛㸪᳨ᰝෆᐜ➼ࡘ࠸࡚ሗ࿌ࡍࡿ㸬 ࢆヨᩱࡋࡓ㸦Fig.1㸧 㸬 ࡞࠾㸪↔ࡆࡢ⛬ᗘࡣ㸪No.2 ẚ࡚ No.1 ࡀ⃭ࡋࡗࡓ㸬 ϩ ᮦᩱ᪉ἲ ᮏ࡛ࡣ㸪ᙜ◊✲ࢭࣥࢱ࣮ࡢᦙධ๓㸪ᡤ㎄ࡢຍ ྂᕝᗣ⚟♴ົᡤ᳨ᰝᐊ࡛ࢫࢡࣜ㸫ࢽࣥࢢ᳨ᰝࡀᐇ ࡉࢀ㸪◪㓟ሷࡢ㡯┠ࡀ㝧ᛶ࡛࠶ࡗࡓ㸬 ᗣ⛉Ꮫ㒊 2.2 ヨ⸆ 㸨ูๅㄳồඛ㸸ࠛ652-0032 ⚄ᡞᕷරᗜ༊Ⲩ⏣⏫ 2-1-29 රᗜ┴❧ᗣ⏕ά⛉Ꮫ◊✲ᡤ ᗣ⛉Ꮫ◊✲ࢭࣥࢱ࣮ ᗣ⛉Ꮫ㒊 ᯘ ᖾᏊ ◪㓟࢜ࣥᶆ‽ᾮ㸸◪㓟࣒࢝ࣜ࢘㸦ග⣧⸆ᕤᴗ〇㸪 ≉⣭ရ㸧ࢆ⢭〇Ỉ⁐ࡋ㸪ᶆ‽ཎᾮࢆㄪ〇ࡋࡓ㸬 ࣥࣔࢽ࣒࢘࢜ࣥᶆ‽ᾮ㸸㓑㓟ࣥࣔࢽ࣒࢘㸦ග － 36 － රᗜ┴❧ᗣ⏕ά⛉Ꮫ◊✲ᡤᗣ⛉Ꮫ◊✲ࢭࣥࢱ࣮◊✲ሗ࿌ ➨ ྕ 4.2 CE ヨᩱ 0.50㹥ࢆṇ☜⛗ࡾ㸪⢭〇Ỉ 20mL ࢆຍ࠼࡚ ࠺ࡋࡓᚋ㸪⢭〇Ỉࢆຍ࠼࡚㔞ࢆ 25mL ࡋࡓ㸬ࡇࡢᾮ ࢆ࣓ࣥࣈࣛࣥࣇࣝࢱ࣮㏻ࡋ㸪ᚓࡽࢀࡓࢁᾮࢆヨ㦂⁐ ᾮࡋࡓ. No.1 CE ࡢศᯒࡣࣥࢲࣞࢡࢺἲ࡛ ᐃࡋ㸪྾ගᗘࡢప No.2 No.3 ୗࢆ ᐃࡍࡿࡇࡼࡾྛ࢜ࣥࢆᐃ㔞ࡋࡓ㸦ࢳ࣮ࣕࢺ Fig.1 Samples of cooked gratin The surrounding was burning, and the grade of burn in No.1 was the most intense. ࡛ࡣ྾ගᗘࢆ㌿ࡋ࡚࠸ࡿࡓࡵ㸪ṇࡢࣆ࣮ࢡࡋ࡚⾲ࢃ ࢀࡿ㸧 㸬࡞࠾㸪ヨ㦂⁐ᾮࡢศᯒᑐ㇟㸦◪㓟࢜ࣥࡸࣥࣔ ࢽ࣒࢘࢜ࣥ㸧⃰ᗘࡀ㧗࠸ࡁࡣ㸪⢭〇Ỉࢆ⏝࠸࡚㐺ᗘ ᕼ㔘ࡋࡓ㸬 ⣧⸆ᕤᴗ〇㸪≉⣭ရ㸧ࢆ⢭〇Ỉ⁐ࡋ㸪ᶆ‽ཎᾮࢆㄪ 〇ࡋࡓ㸬 Ϫ ⤖ ᯝ ࢭࢺࢽࢺࣜࣝ㸪࣊࢟ࢧࣥཬࡧࢭࢺࣥࡣṧ␃㎰⸆ศ ᯒ⏝ࢆ㸪ࡑࡢࡢヨ⸆ࡣ≉⣭ရࢆ⏝࠸ࡓ㸬⢭〇Ỉࡣ࣑ࣜ 1㸬GC/MS ࡼࡿ㎰⸆ศᯒ ࣏Ỉࢆ⏝࠸ࡓ㸬 ᙜ◊✲ࢭࣥࢱ࣮࡛ࡣ㸪ᗣ⿕ᐖࡀㄆࡵࡽࢀࡓࡁ㸪࠶ ࣓ࣥࣈࣛࣥࣇࣝࢱ࣮ࡣ᪥ᮏ࣏࣮ࣝ♫〇࢜ࣥࢡ࣐ࣟ ࡿ࠸ࡣ࠾ࡑࢀࡢ࠶ࡿࡁࡣ㸪᭷ᐖ≀㉁ࡢࢫࢡ࣮ࣜࢽࣥ ࢺࢢࣛࣇ⏝ࢆ⏝࠸ࡓ㸬 ࢢࡋ࡚㎰⸆ศᯒࢆᐇࡋ࡚࠸ࡿ㸬ᅇࡶ㸪⯉ࡢࡋࡧࢀ 3㸬⨨ ࡀㄆࡵࡽࢀࡓࡓࡵ㸪㎰⸆ศᯒࢆ⾜ࡗࡓ㸬GC/MS ࢆ⏝࠸ 3.1 ࢞ࢡࢫ࣐ࣟࢺࢢࣛࣇ㉁㔞ศᯒィ㸦GC/MS㸧 ࡚㸪 ㎰⸆ཬࡧࡑࡢ௦ㅰ≀࡛࠶ࡿ 267 ≀㉁ࢆ ᐃࡋࡓ⤖ᯝ㸪 Agilent ♫〇 GC6890N-MS5973inert ᆺࢆ⏝࠸㸪 ᐃ ࡍ᳨࡚ฟ㝈⏺್௨ୗ࡛࠶ࡾ㸪㎰⸆㢮ࡢΰධࡣㄆࡵࡽࢀ ᮲௳ࡣᙜ◊✲ࢭࣥࢱ࣮࡛ࡢṧ␃㎰⸆ヨ㦂 1)ྠᵝ࡛࠶ࡗ ࡞ࡗࡓ㸬 ࡓ㸬 2㸬CE ࡼࡿ↓ᶵ࢜ࣥศᯒ 3.2 ࢟ࣕࣆ࣮ࣛࣜ㟁ẼὋື⨨ 㸦Capillary Electrophoresis : ௨ୗ CE ␎ࡍ㸧 ᙜ◊✲ࢭࣥࢱ࣮࡛ࡢⱞ᳨ᰝ➼࠾࠸࡚㸪࢜ࣥᛶ≀ ሯ㟁Ꮚ♫〇 CAPϨ-3300 ࢆ⏝࠸࡚㸪㝜࢜ࣥཬࡧ㝧 ㉁ࡢศᯒࡣ㸪CE ࢆ⏝ࡋ࡚࠸ࡿ㸬ຍྂᕝᗣ⚟♴ ࢜ࣥࢆ ᐃࡋࡓ㸬୧⪅࡛ࡣ㸪 ᐃ᮲௳ࡀ␗࡞ࡾ㸪ࡑࢀ ົᡤ࡛ࡢணഛ᳨ᰝ㸦⡆᫆㸧࡛◪㓟ሷࡀ㝧ᛶ࡛࠶ࡗࡓࡇ ࡒࢀࢆ Table 1 ♧ࡋࡓ㸬 ࡽ㸪◪㓟࢜ࣥࢆ CE ࡛ᐃ㔞ࡋࡓ㸬ヨ㦂⁐ᾮࢆ CE ࡛ ᐃࡋࡓࡇࢁ㸪◪㓟࢜ࣥࡢὋື㛫୍⮴ࡍࡿࡁ 4㸬ヨ㦂⁐ᾮࡢㄪ〇ཬࡧᶵჾศᯒ ࡞ࣆ࣮ࢡࡀㄆࡵࡽࢀ㸪◪㓟࢜ࣥࡀ㧗⃰ᗘྵࡲࢀ࡚࠸ 4.1 GC/MS ࡿࡇࡀศࡗࡓ㸦Fig.2㸧 㸬ᶆ‽⁐ᾮࡢࣆ࣮ࢡ㠃✚ࢆᇶ ヨᩱ 1.0g ࢆṇ☜⛗ࡾ㸪ࢭࢺࢽࢺࣜࣝࢆຍ࠼ࡓᚋ㸪 ⟬ฟࡋࡓヨ㦂⁐ᾮཬࡧヨᩱࡢ◪㓟࢜ࣥ⃰ᗘࢆ ᙜ◊✲ࢭࣥࢱ࣮ࡢṧ␃㎰⸆ヨ㦂ࡢ᧯స 1)ࡼࡾヨ㦂⁐ᾮ Table.2 ♧ࡋࡓ㸬ヨᩱ No.1 ཬࡧ No.2 ࡢ࠸ࡎࢀࡶ㧗⃰ ࢆㄪ〇ࡋࡓ㸬ヨ㦂⁐ᾮࢆ GC/MS ὀධࡋ㸪㎰⸆㢮ࢆศ ᗘ࡛࠶ࡗࡓࡀ㸪⃰ᗘẚ࡛⣙ 17 ಸ㐪࠸ࡀぢࡽࢀࡓ㸬 ᯒࡋࡓ㸬 Table 1 CE operation parameters a) Anion mode Cation mode Buffer Inorganic anion buffer Capillary ID : 75Ǎm, TL : 80.0cm, EL : 67.5cm ID : 75Ǎm, TL : 72.5cm, EL : 60cm Voltage 㸫20kV 25kV Detection 230nm, IndirectUV(200㹼300nm) 215nm, IndirectUV(200㹼300nm) Cation buffer c) b) ID : Internal diameter, TL : Total length, EL : Effective length a) Injection parameters were same : Temperature ; 25Υ, Pressurization ; 5kPa, Time ;3sec. b),c) Original buffer manufactured by Otsuka Denshi. － 37 － Absorbance 0.025 NO３－ 0.015 A 0.005 -0.005 0 2 4 Time(min) 6 8 NO３－ 0.015 B 0.005 -0.005 0 2 4 Time(min) 6 8 Fig.3 Electropherograms of ammonium standard solution and sample solution A : 50 ਹ/mL ammonium ion standard solution NO３－ A of No.1 by 500 times diluting B : Sample solution (2mg sample/mL) Table.2 The contents of nitrate ion and ammonium ion -0.005 0 2 in samples 4 Time(min) Absorbance Fig.2 Electropherograms 0.025 of nitrate standard solution and sample solution A : 150 ਹ/mL nitrate ion standard solution 0.015 B : Sample solution of No.1 by 500 times diluting (2mg sample/mL) 0.005 6 8 0.025 Sample No.1 No.2 Absorbance Absorbance 0.025 Content 㸦mg/g㸧 0.015 NO΄ 㸫 NO３－ NH΅ 0.005 72 -0.005 4.3 0 B 㸩 21 Fig.4 2 1.2 Influence of ammonium nitrate concentration on 4 burning. Time(min) ୍᪉㸪㝧࢜ࣥࢆศᯒࡋࡓࡇࢁ㸪ࣥࣔࢽ࣒࢘࢜ 6 8 The samples were applied to the microwave oven for 1 min. ࣥࡢὋື㛫୍⮴ࡍࡿࡁ࡞ࣆ࣮ࢡࡀㄆࡵࡽࢀ㸪㝜 ࡿ 2)㸬ࡑࡇ࡛㸪◪㓟ࣥࣔࢽ࣒࢘ࡢ⃰ᗘࢆኚ࠼࡚Ⅳࡢ ࢜ࣥࡢ◪㓟࢜ࣥ࣌ࢆᡂࡍ㝧࢜ࣥࡣࣥࣔࢽ࣒࢘ ⌧ᐇ㦂ࢆ⾜ࡗࡓ㸬ࢁ⣬ 1㹼40㸣㸦w/v㸧ࡢ 6 ẁ㝵⃰ ࡛࢜ࣥ࠶ࡿ᥎ᐃࡉࢀࡓ㸦Fig.3㸧 㸬ᶆ‽⁐ᾮࡢࣆ࣮ࢡ ᗘࡢ◪㓟ࣥࣔࢽ࣒࢘Ỉ⁐ᾮࢆୗࡋ㸪㟁Ꮚࣞࣥࢪ㸦ฟ 㠃✚ࢆᇶ⟬ฟࡋࡓヨ㦂⁐ᾮཬࡧヨᩱ୰ࡢࣥࣔࢽ࣒࢘ ࢜ࣥ⃰ᗘࢆ Table.2 ♧ࡋࡓ㸬 ຊ 600W㸧࡛ 1 ศ㛫ຍ⇕ࡋࡓ⤖ᯝ㸪5%௨ୖࡢ⃰ᗘ࡛〓Ⰽ ࡢ↔ࡆࡀ⏕ࡌࡓ㸦Fig.4㸧 㸬ࡇࡢࡇࡽ㸪ⱞရࡢ↔ࡆ ࡢཎᅉࡀ◪㓟ࣥࣔࢽ࣒࡛࢘࠶ࡿࡇࡀ☜ㄆࡉࢀࡓ㸬 3㸬◪㓟ࣥࣔࢽ࣒࢘ΰධ㔞 ヨᩱ No.1 ࡢ◪㓟࢜ࣥ⃰ᗘࡣ 72mg/g㸪ࣥࣔࢽ࣒࢘ ࢜ࣥࡣ 21mg/g ࡛࠶ࡾ㸪ࣔࣝ⃰ᗘ࡛⾲ࡍ୧⪅ࡣඹ ⣙ 1.16 ୍⮴ࡋࡓ್࡛࠶ࡗࡓ㸬ࡲࡓ㸪ヨᩱ No.2 ࠾࠸ ࡚ࡶࣔࣝ⃰ᗘࡣ୧⪅ࡀ⣙ 0.07 ୍⮴ࡋࡓ㸬ࡇࡢࡇࡽ㸪 5㸬◪㓟ࣥࣔࢽ࣒࢘ࡢΰධཎᅉ ᅇࡢࢣ࣮ࢫ࡛ࡣ㸪㛤ᑒႚ㣗ࡋࡓ 1 ಶ┠ࡣ␗ᖖࡀ ㄆࡵࡽࢀ࡞ࡗࡓࡓࡵ㸪㛤ᑒᚋ◪㓟ࣥࣔࢽ࣒࢘ࡀΰ ධࡋࡓ⪃࠼ࡽࢀࡿ㸬ࡲࡓ㸪ⱞရࡢ◪㓟ࣥࣔࢽ࣒࢘ ◪㓟࢜ࣥࣥࣔࢽ࣒࢘࢜ࣥࡢሷ࡛࠶ࡿ◪㓟ࣥࣔ ⃰ᗘࡀ 10%⛬ᗘ㧗࠸ࡇࡽ㸪ཎᮎཬࡧ㧗⃰ᗘ⁐ᾮ ࢽ࣒࢘ࡀΰධࡋ࡚࠸ࡿࡇࡀ☜ㄆࡉࢀࡓ㸬 ࡼࡿởᰁ࡛࠶ࡿ᥎ᐃࡉࢀࡿ㸬 ࢢࣛࢱࣥࡢ◪㓟ࣥࣔࢽ࣒࢘ΰධ㔞ࢆ⟬ฟࡍࡿ㸪 ◪㓟ࣥࣔࢽ࣒࢘ࢆྵ᭷ࡍࡿ〇ရࡋ࡚ࡣ㸪ᩘᖺ๓ No.1 ࡛ࡣ 93mg/g㸪No.2 ࡛ࡣ 5.5mg/g ࡛࠶ࡗࡓ㸬๓⪅ ࡢሙྜ㸪ヨᩱ୰ࡢ⃰ᗘࡣ 10㸣㏆ࡃ࡛࠶ࡾ㸪࡞ࡾ㧗್࡛ ࠶ࡗࡓ㸬 ࡽᦠᖏ⏝ࡢ▐㛫෭༷ࣃࢵࢡࡀ⦾⏝ࡉࢀ࡚࠸ࡿࡀ㸪ࡇࡢ〇 ရࡣෆ㒊◪㓟ࣥࣔࢽ࣒࢘ᮎỈࡀධࢀ࡚࠶ࡿ㸬⏝ 㸪྇࠸࡚ෆ⿄ࢆ◚ࡉࡏ㸪୧⪅ࢆΰྜࡍࡿࡇ࡛྾ ⇕ࡍࡿᵝ࡞ࡗ࡚࠸ࡿ㸬ࡇࡢࡓࡵ㸪⏝ᚋࡢࣃࢵࢡෆ 4㸬Ⅳࡢ⌧ᐇ㦂 CE ศᯒࡼࡾ㧗⃰ᗘࡢΰධࡀ☜ㄆࡉࢀࡓ◪㓟ࣥࣔ ࢽ࣒࢘ࡣ㸪ⅆ⸆➼ࡢཎᩱࡶ࡞ࡿ⇿Ⓨᛶࡢ࠶ࡿ≀㉁࡛࠶ － 38 － 㒊ࡣ㧗⃰ᗘࡢ◪㓟ࣥࣔࢽ࣒࢘Ỉ⁐ᾮࡀධࡗ࡚࠾ࡾ㸪 ࡇࡢ⁐ᾮࡀ෭ᗜෆ࡛₃ࢀฟࡋ㸪ⱞရΰධࡋࡓྍ⬟ ᛶࡶ࠶ࡿ⪃࠼ࡽࢀࡿ㸬 රᗜ┴❧ᗣ⏕ά⛉Ꮫ◊✲ᡤᗣ⛉Ꮫ◊✲ࢭࣥࢱ࣮◊✲ሗ࿌ ➨ ྕ ϫ せ ᪨ ㅰ ㎡ ෭㣗ရࡢႚ㣗ࡼࡾ㸪ᗣ⿕ᐖࡀⓎ⏕ࡋࡓ࠾ ᮏヨ㦂ရࡢ᳨ᰝࢆᐇࡍࡿᙜࡓࡾ,ࡈ༠ຊ࠸ࡓࡔ࠸ ࠸࡚㸪ཎᅉࢆ✲᫂ࡋࡓ⤖ᯝ㸪㧗⃰ᗘࡢ◪㓟ࣥࣔࢽ࣒࢘ ࡓ᫂▼ᗣ⚟♴ົᡤ㸪ຍྂᕝᗣ⚟♴ົᡤཬࡧ┴ᗇ ΰධ࡛࠶ࡿࡇࡀุ᫂ࡋࡓ㸬CE ศᯒࡢ⤖ᯝ㸪ⱞရࡢ ⏕ά⾨⏕ㄢࡢ㛵ಀྛ῝ㅰ⮴ࡋࡲࡍ. ࠺ࡕ 1 ಶࡣ◪㓟ࣥࣔࢽ࣒࢘⃰ᗘࡀ⣙ 10㸣࡛࠶ࡾ㸪ࡇࡢ ᩥ ⊩ ⃰ᗘ࡛ࡣ㟁Ꮚࣞࣥࢪࡼࡿㄪ⌮࡛↔ࡆࡀⓎ⏕ࡍࡿࡇࡶ ☜ㄆࡋࡓ㸬 〇ရᏳࢹ࣮ࢱࢩ࣮ࢺ 3)ࡼࡿ㸪◪㓟ࣥࣔࢽ࣒࢘ 1) ⛅ᒣ⏤⨾㸸GC/MS㸪LC/MS ࢆ⏝࠸ࡓ㎰⏘≀୰ࡢṧ ࡣ⓶ࡢ่⃭ᛶࢆ᭷ࡍࡿࡇࡽ㸪ᅇࡢႚ㣗ࡼࡿ⯉ ␃㎰⸆ࡢ୍ᩧศᯒἲ㸬᭶ࡢ㎰ᴗ㸪1㸪50-55 (2007)㸬 ࡢ⑷ࢀࡣ㸪ΰධࡀཎᅉ⪃࠼ࡽࢀࡿ㸬࡞࠾㸪෭㣗ရ 2) ᮌ㐨๎,ἑ,⏣୰ඖ,༓ཎ⚽㸸 ᰴᘧ♫ᮾ ிᏛྠே㸪Ꮫ㸪674 (1994)㸬 ࡢΰධ⤒㊰ࡣ᫂ࡽ࡛ࡣ࡞࠸ࡀ㸪▐㛫෭༷ࣃࢵࢡࡢ₃ฟ ᾮࡢΰධࡶྍ⬟ᛶࡀ࠶ࡿ⪃࠼ࡽࢀࡿ㸬 3) 〇ရᏳࢹ࣮ࢱࢩ࣮ࢺ㸸◪㓟ࣥࣔࢽ࣒࢘㸪ࢼ࢝ࣛ ࢸࢫࢡᰴᘧ♫㸪GHS-02523-2㸪ᨵゞ 2012/02/15㸬 [ᖹᡂ 26 ᖺ 3 ᭶ 28 ᪥ཷ⌮] － 39 －
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