WL aI`ckhAm`cMTGER r|ÔÓsÕÕÓ~i `cb_veN`ct34=6159u `cSov , jr]Cv `cjrDtFQu :;4827n?iUB-/0sY ^@XV.^[ `cjrDtfQu #&( $#$ &$&&" '' $#"# '" #)+ #)!& !#(# $"%!*' `c>gd HZ fOtu qJIpHI<\KIl<AP `cd]Cv £|´ÖEJ5=-9(Ln(III))ÆT*³ `( &b ÆTµ') Î ff Vz* Ye K O Ln(III)ÆTd|KbÊ*²) ' ff Vz$.<G1L¢_ɸ*²«)ÆT#ÂR oS^½MÃÌ{'.<G1L¢_&( ff V®*( \' O Ln(III)ÆTTb(III)' Eu(III)ÅqÈ.<G1L¢_c®z* g(«*x PQÍ ÐÅÍbRÖXÑ }ª» È}ª» d · 2007 st 2008 st st st st ¬ · £ZÄÖ`p ¡»Z¡K©Ök`pK`p 0LIL9ÖÆTKEJ5=-9K³ K¿KVz ÓÒ£Çnu[ EJ5=-9(Ln(III))ÆT5s & 5p lËoÀ°)Ç 4f Ëo¦*# WjU¨$ d ?H62Á¢U¨ *f !`dµ')yKZ Vpz¼* 'NMR 3>8¹ ±$0EF7,L@HL?`pZÄ 'VEAG`]$ MRI ¿w] $apZÄ#mv Ln(III)ÆT ¾( )' Ln(III)ÆT' (®*º½%"z$ D/;4C¶¥phk*¤( ôB-J8(N#Ln(III) ÆTVzÉÂRoV+J7 :® ^½.<G1L Ln(III)¢_ ff V*( ') ( ff VLn(III) 4f Ëol ËoÀ°)("V¯§t ÎÏ(y( 'ÂRoV^½.<G1L^½ f M$Ûµ º[/¡ÝMuÒÐ !¾"ç| hæ.&Ln(III)! 57C]"Úºßz!57C] ¤% ç| s( Ln(III)áN"r»r ÝM2.Ø!V æ è2/- ´ QZ®!eF2Ã/ä "ff ´QZ®2 G/¥Tu*¨tTu2ÝMl-a. ã)à R0TuÒÐ Î /(V*c!æ p! "0&!ng!r ¤Öµa. *^áN ²&/! ¯ ¬/-)L¸/ / ¹¼"Í Ln(III)áN ·¶ Í!d» Ln(III)$!d6=A8Eº [ ,/-/} ff ´Q*³/ Ln(III)$!d*×¢&"Ûµ6=A8 Eº[ ,/ ff ´Qff ´Q!rPDr \2¹¼2ÙÉ ðí¹¼!¶µ ¹¼!¶µ" Ø V æ Ln(III)áN2dD³I\Ln(III) áN! ff ´Q rPDr 2yR/© /0&!r! ff ´Q Ln(III) á N " [Eu(phen) 2 (NO 3 ) 3 ] ê phen = 1,10-phenanthrolineë KË0/, )^¿^Ø.´Q¡ â )ÝMu Q2f`!YÔ6=A 8E Ln(III) º[/1+/4 C:<Z ,.´Q2/!'/J Í!d» Ln(III)$!d6=A8Eº [ ,/-/}´Q³» Ln(III)$! d*×¢&"Ûµ6=A8Eº[ ,/´QÄrPDr 2/\v »2WÌ/ ,vʵ s 5C>9;2H/"ÈQ@B E?½! °è§Õ/ Ln(III)áN! ÒÐà )rsÓ / ñí¹¼!¦ I \ Ý M u H 3L ê Tris[4-(2-hydroxy-3-methoxyphenyl)-3-aza-3butenyl]amineë êiïë2°dD³I Ln(III)áN!cD^å2É! iï I\ÝMu HñL !Ø H3L ÝMu"ÇéÜM2/( Q4C:<Z®Å¡Ä/bÄ 2Ã-0/&¤Ö_ª!( x /^ Ln(III)áN â)cD^ å2ÉO°/ Ln(III)"^ áN!oc"/ 0& kSq* ~ ¹ ¼ w n Þ ! / Tb(III) * Eu(III)2°Ñ2É òí¹¼ dI Tb(III), Eu(III)áNêLTb2, LEu2ë *³I Eu(III)/Tb(III)áN(LTbEu) - "¤Ö_ª!(!x /^áN êLTb, LEuë â)cD^å X %!áN!^À ÂÀØÏ Xêiðë^áN"0)óÝM LTb LEu LTb2 LEu2 LTbEu ið ^dD³ I Ln(III)áN êLTb, LEu, LTb2, LEu2, LTbEuë!^À Ø !£3 mono-capped octahedral ØdD ³IáN"ôÝM! dodekahedral Ø ïîÝM!£3 cis-bicapped cube Ø2 / UjN¬ / ´Q« â"ÝMu! -ìÚº m f`{êmax = 350 nm for LTb and LEu, 370 nm for LTb2 and LEu2,ë2QYÔ/ ,.LTb * LTb2 !ocTb(III)! 5D47F6, 5 D47F5,,# 5D47F4 Úº ±/ÁÆ ! ff ´Q 00 490, 550, ,# 585 nm RÓ$LEu / LEu2 %ulEu(III)% 5D07F0, 5 D07F1,0' 5D07F2 ظ$¬3ÏÄ % ff ®_44 580, 595, 0' 620 nm RÓ$ɧ44%ÞW. ff ®_6· !5+Eu(III)ÞW%ul PÞW02.gÞWTb(III)ÞW%ul &gÞW02.PÞW%02 ff ®_6·!1!#%¿ &g!PÞW$3»WÕ%× $ÐpÚVy%ây©$« 3-$dШV8BH:Jvf Eu(III)0' Tb(III)%dШV!%à[$v f«- 3!Á14j} =C;@H$02gÞW02.PÞW % Ú V y % - é Ø ¸ 20 nm * " blue-shift 3¿!´²# PÞW 3 LTbEu %®_e$ à&Dieke %?7F<GD02Tb(III) 1 Eu(III)(%8BH:J¸eÐ2w Û ff ®_ 3 77 K $ ®_=C;@H6§{¿çqëè që LTbEu %®_=C;@H qì LTbEu %{®_E9A>D Tb(III)! Eu(III)$¬3 ff ®_N!. ɧ41$LTbEu $3 Tb(III) % ff ®_|o&mP Tb(III)ÞW(LTb2) %.%02.¾ì\µ!1qì$· 0$Tb(III)1 Eu(III)(%Üß8 BH:J¸e%kà 6·¿6 TL%0$¶º$4+ $¤"tnY%#mI P Ln(III) ÞW$³±È%m¹ Ln(III)(%m8 BH:J¸e$031#3 ff ®_ / ¹ Ln(III)(%m/Ô¢+&Ù¯8B H:J¸e$03 ff ®_Ã#"gÞW0 2.w^Iw 63®_ fz¹%b Ç$cZ] 3x#K£6Ñ,` !3Q%0#¶º6s °!1$xåÒI®~3) 1#3w^Iw 63 Ln(III)ÞW% Pf1$&â¥fz¯¦6æX hyZf/hyZf$³ #Èlär¯zÅs°%½&s02ã ¯#_¡Ã %ËÊÝ(.wx# Ϊ 3 íêO#®Æͼ 綺SƶºaÂi'Ö¶ºÂ$ &MÀè áÌÍçÊîUè Hideki Ohtsu, Tomoya Suzuki, Hajime Ohtsuka, Ayumi Ishii, Miki Hasegawa, The Unprecendented Role of a CuII Cryptand in the Luminescence Properties of a EuIII Cryptate Complex, Monatsh. Chem., 140, 2009, in press, Miki Hasegawa, Shunsuke Kunisaki, Hideki Ohtsu, Franz Werner, Ultra-Thin Emissive Molecular Devices: Polarized Emission of Ln(III) Complex Films, Monatsh. Chem., 140, 2009, in press, Miki Hasegawa, Ayumi Ishii, Koichiro Furukawa, Hideki Ohtsu, Polarized ff-Emission of Terbium(III) by using the Stretched Polymer Film Technique, J. Photopolym. Sci. Technol., 21, 2008, 333-338, Tatsuzo Miyagoe, Shoichi Tao, Atsushi Maeda, Hiroyuki Matsuzaki, Hideki Ohtsu, Miki Hasegawa, Shinya Takaishi, Masahiro Yamashita, Hiroshi Okamoto, Ultrafast Optical Responses in a One-Dimensional Mott Insulator of a Br-Bridged Ni Compound, J. Phys. Soc. Jpn., 77, 2008, 023711-1-023711-4, Hideki Ohtsu, Shinya Takaishi, Keita Imamura, Ayumi Ishii, Koji Tanaka, Miki Hasegawa, Masahiro Yamashita, Remarkable Functions of Long-Chain Alkyl Groups in Halogen-Bridged Nickel(III) Nanowire Complexes, Eur. J. Inorg. Chem., 2007, 4425-4428, Ayumi Ishii, Koji Habu, Shinobu Kishi, Hideki Ohtsu, Tamikuni Komatsu, Keiichi Osaka, Kenichi Kato, Masaki Takata, Miki Hasegawa, Yuzo Shigesato, Novel Emission Properties of Melem Caused by the Heavy Metal Effect of Lanthanides(III) in a LB Film, Photochem. Photobiol. Sci., 6, 2007, 804-809, Ayumi Ishii, Shinobu Kishi, Hideki Ohtsu, Toshifumi Iimori, Takakazu Nakabayashi, Nobuhiro Ohta, Naoto Tamai, Milan Melnik, Miki Hasegawa, Yuzo Shigesato, Molecular Distortion Effect on ff-Emission in a Pr(III) Complex with 4,7-Diphenyl-1,10-Phenanthroline, ChemPhysChem., 8, 2007, 1345-1351, Shoichi Tao, Tatsuzo Miyagoe, Atsushi Maeda, Hiroyuki Matsuzaki, Hideki Ohtsu, Miki Hasegawa, Shinya Takaishi, Masahiro Yamashita, Hiroshi Okamoto, Ultrafast Optical Switching by Using Nanocrystals of a Halogen-Bridged Nickel-Chain Compound Dispersed in an Optical Polymer, Adv. Mater., 19, 2007, 2707-2710, sV¢±Í¶ÐÑUΠƺy¬»uf \p ¯3E/Jl<130CÅY(¢] 4A28IbsVª r{V { ps f \up¯Æºy ¬»3E/JlF0J@0CÅY(¢ ]bsVª r{V { ps p¯ÄR¤S +)ƺ y¬»½§Ãv/1L.g*GL5; 9¡PÅY(e&¢]ª iÅYbs·¹V { Ãps f \´ u¤S +)p¯Æºy¬»3E/J lF0J@0CÅY(¢]4A28I ª iÅYbs·¹V { Ãps ƺy¬»¤S +)p¯Å Y^q(¼`~',-GL5;9 ¢]([]¢ª iÅYbs·¹ V { Ãps Hideki Ohtsu Akina Watanabe Ayumi IshiiMiki Hasegawa, Luminescence and Electrochemical Properties of Homo- and Hetero-dinuclear Lanthanide Complexes, Third International Minisymposium on Coordination Chemistry for Advanced Materials, { Êws Èps Shunsuke KunisakiKoichiro Furukawa Hideki OhtsuMiki Hasegawa, Emission Spectra of Stretched PVA Film coated with Eu(III)-Tb(III)-phen, Third International Minisymposium on Coordination Chemistry for Advanced Materials, { ÊwsÈps Yu Yoshimura Takeshi Kasai Sae Enomoto Ayumi Ishii Hideki Ohtsu Miki Hasegawa, Emission Spectra of a Eu(III) Complex with a Hexadentate Ligand, Third International Minisymposium on Coordination Chemistry for Advanced Materials, { ÊwsÈps ƺy¬»¤S +)p¯G L5;9ÅY. !%[]¢] ( ¼ {]bs·¹V { pÇ|©ps ƺy¬»p¯´ f \ul?@H3L.ÀX q&$%FNJ@0CÅY(¢]4A 28I {]bs·¹V { pÇ|©ps f \´ u¤S +)p¯Æºy¬»3E/J lF0J@0CÅY(e&Éq4A 28Iª iÀXbe(]bs· ¹V { cÁps jxZTdy«O¾p¯Æº y¬» ²µ Q(³ eY(¢]4A28Iª iÀXb e(]bs·¹V { cÁps p¯ÄR¤S +)ƺ y¬»¢]GL5;9¡PÅY '"#-½§Ãv/1L(aª iÀXbe(]bs·¹V { cÁps ƺy¬»¤S +)p¯ ',-FNJ@0CÅY( ¢] []o¸ª izkË·¹V { 5KNBNI®m ƺy¬»¤S +)p¯° b',-¢]ÅY^q([]o¸ &¼¿¦s£:=72=J3NM <68KN2ÏÂ:=:=72=J 3N t]_ ¥¨nhV { DI>I2pÇ Æºy¬»¤S +)dy«O¾ p¯}WÌ^qQ(¢]F0 J@0CÅY([]&¼bsV ª r{V { © ps n¶Âo¦O*); x±¿eG¤CF7:9ÌU'¥ YA2:6@%ÉaÄX`ar R¬ q|R | «nr ¦O*)ËÊJ¸¡Lw º]¡Óin¶Í¾x±¿ ¥YB0E=0@ ´'Ã%WY arR¬ q|R | «nr ¦O*)¸¡Lwº]¡ Óin¶Í¾x±¿ËÊJ ©vl·´Z&!",B0E=0 @'WY¥YarR¬ jÎ ÆnR | ÒÇn rP n¶Âo¦O*); x±¿¥YeG¤NCF7: 9ÌU'd%ÁarR¬ jÎ ÆnR | Ò ÇnrP ;x±¿bxIŦO*) n¶s¢ÀhÓ¡~S Ó[p´K'{kÑÌU¥Y%ì jÌUar¼½R | fbuznr ¦O*)¡ÓiLwº]n ¶Í¾x±¿ËÊJ 'WY ¥Y&t#,»[p´>. 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