新学術領域研究「高次π空間の創発と機能開発」第４回国際シンポジウム
主
催
新学術領域研究「高次π空間の創発と機能開発」総括班
協
賛
日本化学会、応用物理学会、高分子学会、日本生物物理学会、光化学協会、有機合成化学協会、
フラーレン・ナノチューブ・グラフェン学会、分子科学会、基礎有機化学会、
筑波大学戦略イニシアティブ(A)
会
期
会 場
2012 年 11 月 13 日（火）13：00 〜 11 月 14 日（水）12：30
浜名湖ロイヤルホテル
浜松市西区雄踏町山崎 4396-1（JR 舞阪駅よりタクシー又は無料送迎バスで約 7 分）
http://www.daiwaresort.co.jp/hamanako/
参加費
無料
懇親会
11 月 13 日（火）19:00−21:00 浜名湖ロイヤルホテル「2F オリオン」にて
------------------------------------------------------------------------------------------------------------------------------------------------✱✱✱Program✱✱✱
【November 13 (Tuesday)】
12:00-13:00
Registration
13:00-13:10
Opening Remark: Takeshi Akasaka (University of Tsukuba)
13:10-13:50
I-1
John T.M. Kennis (VU University Amsterdam, The Netherlands)
Photoactivation Mechanisms of Novel Blue and Red Light Photoreceptors
13:50-14:20
R-1
Shunichi Fukuzumi (Osaka University)
-Functions in Artificial Photosynthesis
14:20-14:50
R-2
Jun-ichi Kikuchi, Kazuma Yasuhara, Keishiro Tahara (Nara Institute of Science and
Technology)
Construction of Highly Integrated π-Space on Artificial Cell Membranes and Its
Nano-device Function
14:50-15:30
I-2
Victor A. Lorenz-Fonfria (Free University of Berlin, Germany)
From Bacteriorhopsin to Channelrhodopsin. Or How Retinal Isomerization Drives Both
Proton-Pump and Ion Channeling.
15:30-15:50
Coffee Break
15:50-16:20
R-3
Xiaozhang Zhu, Hayato Tsuji, Eiichi Nakamura (The University of Tokyo, JST)
Carbon-bridged Phenylenevinylene (COPV) for a Linker of Novel and Efficient Sensitizers
for Dye-sensitized Solar Cells
16:20-16:50
R-4
Hiroyuki Furuta (Kyusyu University)
N-Confused Porphyrinoids: From Porphyrin Isomer to Multi-Metal Complexes with
Unique d- Interactions
16:50-17:30
I-3
John Christie (University of Glasgow, UK)
Understanding Photoreceptor Function in Plants
17:30-19:00
Poster Session
19:00-21:00
Banquet
21:00-
Extended Poster Session
【November 14 (Wednesday)】
09:00-09:40
I-4
Gustavo Fernandez, Maria Jose Mayoral, Christina Rest, Vladimir Stepanenko (University
of Wuerzburg, Germany)
Cooperative Self-Assembly and Self-Sorting of Oligophenyleneethynylene Derivatives
09:40-10:10
R-5
Qitao Tan, Shuhei Higashibayashi, Hidehiro Sakurai (Institute for Molecular Science)
Triazasumanene: An Isoelectronic Heteroanalogue of Sumanene
10:10-10:40
R-6
Hitomi Uehara, Keisuke Sato, Tsukasa Nakahodo, Hisashi Fujihara (Kinki University)
Selective Confinement and Release of Molecule in -Conjugated Polythiophene Nanotubes
and Their Chiral Biointerface
10:40-11:00
Coffee Break
11:00-11:30
R-7
Hirotaka Kitoh-Nishioka, Koji Ando (Kyoto University)
Electron Transfer Pathway Analysis in Biomolecules
11:30-12:10
I-5
Marco Garavelli (University of Bologna, Italy)
Photoinduced Events in Retinal Systems: a Computational Perspective
12:10-12:20
Comments by Reviewers
12:20-12:30
Closing Remark
-----------------------------------------------------------------------------------------------------------------------------------------------Poster Presentations
【Members】
P-1
Mitsuaki Suzuki, Xing Lu, Zdenek Slanina, Naomi Mizorogi, Shigeru Nagase, Marilyn M. Olmstead, Alan L.
Balch, Takeshi Akasaka (University of Tsukuba, Huazhong University of Science and Technology, Kyoto
University, University of California)
Creation of Novel -Electron Molecules: Three Isomers of Yb@C82
P-2
Michihisa Murata, Satoshi Katsuya, Kei Ohkubo, Shunichi Fukuzumi, Yasujiro Murata (Kyoto University,
Osaka University, JST)
Synthesis and Photophysical Properties of Azafullerenes Directly Connected to an Organic Dye
P-3
Jianming Huang, Makoto Karakawa, Yutaka Ie, Yoshio Aso (Osaka University, JST)
Photovoltaic Performances of Donor-Acceptor Copolymers Having Dioxocycloalkene- annelated Thiophenes
as Acceptor Unit
P-4
Yoshiyuki Mizuhata (Kyoto University)
Synthesis of Phthalocyanine Derivatives Bearing Phosphorus Atoms as Skeletal Elements and Their
Properties
P-5
Taketo Kojima, Chitoshi Kitamura, Takeshi Kawase (University of Hyogo)
Synthesis and Properties of Pyrenofuran and -difuran Derivatives
P-6
Junji Kobayashi, Shunsuke Furukawa, Masanori Shirokawa, Takayuki Kawashima (International Christian
University, The University of Tokyo, Gakushuin University)
Synthesis and Optical Properties of Heavier Group 14 Element Analogues of Sumanene
P-7
Hirotaka Mori, Atsuhiro Osuka (Kyoto University)
Antiaromatic Hexaphyrins and Octaphyrins Stabilized by Hydrogen Bonding Interactions of meso-Imidazolyl
Groups
P-8
Nagao Kobayashi, Yosuke Ogura, Taniyuki Furuyama (Tohoku University)
Synthesis and Properties of Superphthalocyanine Derivatives
P-9
Kentaro Tashiro (National Institute for Materials Science)
3D Sequence Control of π-Electronic Metal Complexes
P-10
Fumito Tani, Hirofumi Nobukuni, Takuya Kamimura, Ken-ichi Sakaguchi, Hidemitsu Uno, Yuichi Shimazaki
(Kyushu University, Ehime University, Ibaraki University)
Creation of π-Space and Functional π-Complexes through the Self-Assembly of Porphyrin Compounds
P-11
Hiroshi Shinokubo (Nagoya University)
Synthesis of Novel Porphyrinoids from Dipyrrin Precursors via Transition Metal Catalysis
P-12
Yoshihiro Matano, Tarou Shibano, Daisuke Fujii, Hiroshi Imahori (Kyoto University)
Peripheral Functionalizations of 5,15-Diazaporphyrins: Synthesis of Tetraaryl Drivatives and -Linked
Dimers
P-13
Hidemitsu Uno, Mitsunori Nakamura, Shigeki Mori, Takahiro Nakae, Tetsuo Okujima (Ehime University)
Precursors of Pyrrolo[3,4-f]isoindole for Preparation of Large Fused π-Systems
P-14
Shuichi Suzuki, Atsuki Nagata, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Keiji
Okada (Osaka City University)
Spin-switching Properties of Electron Donor Molecules Substituted with Stable Neutral Radicals
P-15
Yutaka Majima, Shuhei Takeshita, Victor M. Serdio V., Yasuo Azuma (Tokyo Institute of Technology)
Nanogap Separation Control on Electroless Gold Plated (EGP)
Nanogap Electrodes for Molecular Devices
P-16
Varun Vohra, Gianmichele Arrighetti, Luisa Barba, Koichi Higashimine, Tatsuya Murakami, William Porzio,
Hideyuki Murata (Japan Advanced Institute of Science and Technology, Istituto di Cristallografia del CNR,
Istituto per lo Studio delle Macromolecole)
Enhanced Power Conversion Efficiency by Tuning the Vertical Concentration Gradient in P3HT:PCBM
Bilayer Solar Cells
P-17
Masayuki Kanehara (Okayama University)
Porphyrin and Phthalocyanine Coordinated -Junction Gold Nanoparticles
P-18
Akinori Saeki, Shu Seki (Osaka University, JST)
Fullerene Nanowires as a Versatile Platform for Organic Electronics
P-19
Hitoshi Mizuno, Hisao Yanagi, Fumio Sasaki, Shu Hotta (Nara Institute of Science and Technology, National
Institute of Advanced Industrial Science and Technology, Kyoto Institute of Technology)
Light Amplification by Cooperative Interaction in -Electronic Molecular Crystals
P-20
Kazuhiro Yanagi, Kai Hasegawa, Hideki Kawai, Ryo Nakatsu (Tokyo Metropolitan University, Kyoto
University)
Alignment Control of Single Wall Carbon Nanotubes during Aggregation
P-21
Chitoshi Kitamura, Kouji Higashine, Takeshi Kawase, Takashi Kobayashi, Hiroyoshi Naito, Akinori Saeki, Shu
Seki (University of Hyogo, Osaka Prefecture University, Osaka University)
Synthesis, Crystal Structures, and Solid-State Optical Properties of Alkyl-Substituted
5,8,13,16-Tetraphenyldibenzo[b,k]chrysenes
P-22
Taku Hasobe, Hayato Sakai, Takeshi Yasuda (Keio University, NIMS)
Structural and Photophysical Properties of Porphyrin Hexagonal Nanocylinders for Solar Energy Conversion
P-23
Hideki Kandori (Nagoya Institute of Technology)
Bio--space in Photoreceptive Proteins: Spectroscopic Investigation and Creation of New Functions
P-24
Tomoko Fujino, Kenta Endo, Naomi Yamazaki, Hiroyuki Isobe (Tohoku University)
Synthesis of Triazole-linked Analogues of RNA (TLRNA)
P-25
Kanako Terakado, Toru Nakatsu (Kyoto University)
Mechanism of Bioluminescence Color Determination of Firefly Luciferase
P-26
Yasuhiko Yamamoto, Hulin Tai (University of Tsukuba)
π-Electron System of a Heme-DNA Complex
P-27
Kazuhiro J. Fujimoto (Kobe University)
Transition-Density-Fragment Interaction Combined with Transfer Integral Approach for Excitation-Energy
Transfer via Charge-Transfer States
P-28
Yasuko Osakada, Kiyohiko Kawai, Tetsuro Majima (Osaka University, Stanford University)
Dynamics of Hole Transfer through DNA across Guanine-Cytosine Repeats
【Others】
P-29
Hiroshi Ikeda, Atsushi Sakai, Mirai Tanaka, Eisuke Ohta, Yuuichi Yoshimoto, Kazuhiko Mizuno (Osaka
Prefecture University)
Alkyl and Heteroatom Substituent Effects on Emission Property of Diaroylmethanatoboron Difluoride
P-30
Koji Naoda, Hirotaka Mori, Naoki Aratani, Atsuhiro Osuka (Kyoto University, JST)
Synthesis and Characterization of a Doubly Anthracene-Fused Hexaphyrin
P-31
Tsuneaki Sakurai, Akinori Saeki, Shu Seki (Osaka University)
Use of Phthalocyaninato-polysiloxanes with Defined Hole-transporting Pathways for Long-range Molecular
p-n Heterojunctions
P-32
Yuta Takano, Tatsuya Murakami, Tomohiro Numata, Nobuhiro Morone, John E. Heuser, Kei Ohkubo,
Shunichi Fukuzumi, Yasuo Mori, Hiroshi Imahori (Kyoto University, Osaka University)
Photo-control of Cell Membrane Potential and Ion Transport by Electron Donor-acceptor- linked Molecules
P-33
Alejandro M. Facaroli, Omar M. Yaghi, Kentaro Tashiro (National Institute for Materials Science, University
of California)
Sequential Isomers in Metal-Organic Complex Arrays (MOCAs)
P-34
Tomoki Yoneda, Naoki Aratani, Atsuhiro Osuka (Kyoto University, JST)
Reactivity of Hexaphyrin Palladium(II) Complexes
P-35
Victor M. Serdio V., Shuhei Takeshita, Daniel E. Hurtado S., Yasuo Azuma, Yutaka Majima (Tokyo Institute
of Technology)
Nanogap Electrodes Towards Molecular Devices by Molecular Ruler Electroless Gold Plating (MoREP)
P-36
Miki Hasegawa, Shoya Sakurai, Daisuke Kodama, Isao Takahashi (Aoyama Gakuin University)
Luminescence and Molecular Structure of a Series of Europium Complexes with Hexadentate-π-electronic
Ligands
P-37
Kenichi Kawamoto, Keiichi Inoue, Jin Yagasaki, Yuki Sudo, Michio Homma, Hideki Kandori (Nagoya
Institute of Technology, Nagoya University)
Conformational Change in the Photo Reactions of Acidic- and Alkaline Sensory Rhodopsin I
P-38
Yoshitaka Kato, Akira Kawanabe, Kwang-Hwan Jung, Hideki Kandori (Nagoya Institute of Technology,
Osaka University, Sogang University)
Position 206 of Anabaena Sensory Rhodopsin is Responsible for the Isomeric Composition of Retinal and
Photochromism
P-39
Kota Katayama, Hiroo Imai, Akimori Wada, Hideki Kandori (Nagoya Institute of Technology, Kyoto
University, Kobe Pharmaceutical University)
Vibrational Modes of the Retinal Schiff Base in Primate Color Visual Pigments
P-40
Hirotaka Kitoh-Nishioka, Koji Ando (Kyoto University)
Electron Tunneling Mechanism of Electron Transfer Reaction from Heme to Photo-oxidized Special Pair in
Bacterial Photosynthetic Reaction Center
P-41
Kouhei Matsuzaki, Tomoya Ishizuka, Kei Ohkubo, Shunichi Fukuzumi, Takahiko Kojima (University of
Tsukuba, Osaka University)
Synthesis and Characterization of a Novel Ruthenium Complex Bearing a Saddle-Distorted Porphyrin
Dication as a Photosensitizer
P-42
Daiki Kawata, Kota Katayama, Hiroo Imai, Hideki Kandori (Nagoya Institute of Technology, Kyoto
University)
Mechanism of Thermal Activation of Visual Pigments in the Dark
P-43
Lakshminarayanan Piramuthu, Omar M. Yaghi, Kentaro Tashiro (National Institute for Materials Science,
University of California)
Metal-Organic Complex Array Helicates
P-44
Kumiko Nagata, Keiichi Inoue, Hideki Kandori (Nagoya Institute of Technology)
Photo-reaction Dynamics of Gloeobacter Rhodopsin (GR) Studied by Transient Grating Method
P-45
Yutaka Matsuo, Hiroshi Okada, Masashi Maruyama, Hiroyasu Sato, Hiromi Tobita, Yoshihiro Ono, Kenji
Omote, Kazuhiko Kawachi, Yasuhiko Kasama (The University of Tokyo, Tohoku University, Rigaku
Corporation, Ideal Star Inc., Idea International Corporation)
Covalently Chemical Modification of Lithium Ion-Encapsulated Fullerene: Synthesis and Characterization of
[Li+@PCBM]PF6–
文部科学省科学研究費補助金 新学術領域研究
（研究領域提案型） 領域略称
「π空間」
領域番号2007
（平成２０∼２４年度）
Grant-in-Aid for Scientific Research on Innovative Areas ("pi-Space") from the Ministry of Education, Culture, Sports, Science and Technology, Japan
4th International Symposium
on Emergence of Highly Elaborated S-Space and Its Function
高次π空間の
創発と機能開発
第４回 国際シンポジウム
主 催 新学術領域研究
「高次π空間の創発と機能開発」
総括班
協 賛 日本化学会 応用物理学会 高分子学会 日本生物物理学会 分子科学会
光化学協会 有機合成化学協会 フラーレン・ナノチューブ・グラフェン学会
基礎有機化学会 筑波大学戦略イニシアティブ
（A)
2012
11/1３
（Tue）
13:00
‒
11/1４
（Wed）
12:30
浜名湖ロイヤルホテル (浜松市西区雄踏町山崎4396-1）
http://www.daiwaresort.co.jp/hamanako/
Invited Lectures・Regular Talks
John Christie (University of Glasgow, UK)
Gustavo Fernandez (University of Wuerzburg, Germany)
Marco Garavelli (University of Bologna, Italy)
John Kennis (VU University Amsterdam, The Netherlands)
Victor Lorenz-Fonfria (Free University of Berlin, Germany)
Hidehiro Sakurai (IMS)・ Hisashi Fujihara (Kinki Univ.)
Hayato Tsuji (Univ. Tokyo)・ Hiroyuki Furuta (Kyushu Univ.)
Shunichi Fukuzumi (Osaka Univ.)・ Jun-ichi Kikuchi (NAIST)
Koji Ando (Kyoto Univ.)
Poster Presentations (Members)
T. Akasaka (Univ. Tsukuba)・ Y. Murata (Kyoto Univ.)・ Y. Aso（Osaka Univ.）
Y. Mizuhata (Kyoto Univ.)・ T. Kawase (Univ. Hyogo)・ J. Kobayashi (ICU)
A. Osuka（Kyoto Univ.）
・ N. Kobayashi（Tohoku Univ.）• K. Tashiro (NIMS)
F. Tani (Kyushu Univ.)・ H. Shinokubo (Nagoya Univ.)・ Y. Matano (Kyoto Univ.)
H. Uno (Ehime Univ.)・ S. Suzuki (Osaka City Univ.)
Y. Majima (TITECH)・ H. Murata (JAIST)・ M. Kanehara (Okayama Univ.)
A. Saeki (Osaka Univ.)・ H. Yanagi (NAIST)・ K. Yanagi (Tokyo Metro. Univ.)
C. Kitamura (Univ. Hyogo)・ T. Hasobe (Keio Univ.)
H. Kandori（Nagoya Inst. Tech.）
・ H. Isobe（Tohoku Univ.）• T. Nakatsu (Kyoto Univ.)
Y. Yamamoto (Univ. Tsukuba)・ K. J. Fujimoto (Kobe Univ.)・ K. Kawai (Osaka Univ.)
参加費: 無料（懇親会費：一般6,000円, 学生4,000円）
懇親会 11/13 19:00-21:00
□お申し込み：領域ホームページから案内（http://www.pi-space.jp)
□お問い合わせ：領域事務担当 大阪大学産業科学研究所 安蘇 芳雄
Yoshio Aso, Osaka Univ., [email protected]
Tel: 06-6879-8475 Fax: 06-6879-8479
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