Safety Data Sheet NFPA WHMIS PPE Transport Symbol Not Regulated Preparation Date 27-Jan-2014 Revision Date 30-Jan-2014 Revision Number 1 1. PRODUCT AND COMPANY IDENTIFICATION Product Name CPR Seam Sealer TG Product Code 5306 UN-No 1263 Contact Manufacturer The Garland Company, Inc. 3800 East 91st. Street Cleveland, Ohio 44105-2197 Ph: (800) 762-8225 Fax: (216) 641-0633 Emergency Telephone Number Garland Canada, Inc. 209 Carrier Dr. Toronto, Ontario M9W 5Y8 Ph: (416)747-7995 (800)387-5991 Fax: (416)747-1980 1-800-762-8225 (24 Hrs.) 2. HAZARDS IDENTIFICATION Emergency Overview Combustible Material Appearance: Colored viscous liquid Physical State: Liquid Odor: Solvent Mexico - Grade Potential Health Effects Principle Routes of Exposure Acute Effects Eyes Skin Inhalation Ingestion Skin contact, Inhalation, Ingestion, Eye contact May cause severe irritation of the eye, leading to burns if not immediately treated. Frequent or prolonged contact with the skin may cause temporary irritation or dermatitis. Excessive inhalation of the concentrated vapors from this product may cause headache, coughing, breathing difficulty, convulsions, shock, severe irritation of the mucous membranes and severe lung congestion. Ingestion may cause local irritation of the mucous membranes of the mouth, esophagus and stomach. May act as a laxative. _____________________________________________________________________________________________ Page 1 / 7 CPR Seam Sealer TG - 5306 Revision Date 30-Jan-2014 _____________________________________________________________________________________________ Chronic Effects See Section 11 for additional Toxicological information. Main Symptoms Aggravated Medical Conditions Interactions with Other Chemicals Potential Environmental Effects See Section 12 for additional Ecological information. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Elastomeric Resin Hydrocarbon Resin Stoddard Solvent Inorganic Pigments Aromatic Hydrocarbon Solvent Surfactant CAS-No Mixture Mixture 8052-41-3 Mixture 64742-95-6 Mixture Weight % 10-15 20-30 10-20 30-40 10-20 2-5 4. FIRST AID MEASURES General Advice Eye Contact Flush eyes with copious quantities of water for at least 15 minutes, making sure that the eyelids are held open to allow complete flushing. If irritation persists seek medical attention. Skin Contact Remove contaminated clothing including shoes and wash before reuse. Wash contaminated area thoroughly with soap and water. If redness or irritation occurs seek medical attention. Inhalation This material has a low vapor pressure and is not expected to present an – inhalation exposure problem under ambient conditions. If vapor or mist is generated when the material is heated or handled, remove the victim from the exposure. If breathing has stopped or is irregular, administer artificial respiration and supply oxygen if it is available. If victim is unconscious, remove to fresh air and seek immediate medical attention. Ingestion DO NOT INDUCE VOMITING. Product contains hydrocarbon solvents which may cause serious damage if aspirated into the lungs. Summon immediate medical help. Notes to Physician Protection of First-aiders 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Try to cover liquid spill with foam. Chemical extinguishers may also be used as well as carbon dioxide. Water spray may be used to cool fire exposed containers and surfaces. _____________________________________________________________________________________________ Page 2 / 7 CPR Seam Sealer TG - 5306 Revision Date 30-Jan-2014 _____________________________________________________________________________________________ Unsuitable Extinguishing Media The use of water as the extinguishing medium may only lead to spreading the fire. Hazardous Combustion Products As with any burning organic material smoke, fumes and oxides of carbon, may be produced. Explosion Data Sensitivity to mechanical impact Sensitivity to static discharge No Yes Specific Hazards Arising from the Chemical This product, while it will support combustion, does not ignite easily. When burning under conditions of restricted air there is a possibility of the generation of toxic gases (carbon monoxide, carbon dioxide and oxides of nitrogen). Protective Equipment and Precautions for Firefighters Respiratory and eye protection required for fire fighting personal. Full protective equipment (Bunker Gear) and a self contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. For small outdoor fires, which may be easily extinguished with a portable fire extinguisher, use of an SCBA may not be required. NFPA Health 2 Flammability 2 Instability 0 6. ACCIDENTAL RELEASE MEASURES Methods for Containment Remove all sources of ignition. Add absorbent materials to large spills and scoop into approved disposal containers. Do not use combustible materials such as sawdust. Environmental Precautions Methods for Cleaning Up Wipe up small spills and place wipers in an approved disposal container. Wash or steam clean the area of the spill. Other Information 7. HANDLING AND STORAGE Handling Keep container closed. Loosen closure cautiously before opening. Storage Store in a cool, well ventilated area away from incompatible materials see Section 10 Stability and Reactivity Keep away from heat, sparks and flame. Empty containers may retain hazardous properties. Follow all MSDS/label warnings even after container is empty- Protect from freezing. _____________________________________________________________________________________________ Page 3 / 7 CPR Seam Sealer TG - 5306 Revision Date 30-Jan-2014 _____________________________________________________________________________________________ 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name Hydrocarbon Resin ACGIH TLV 100 ppm TWA OSHA PEL 100 ppm TWA Ontario TWAEV 525 mg/m3 TWA Chemical Name Hydrocarbon Solvent Mexico STEL: 200 ppm STEL: 1050 mg/m3 TWA: 523 mg/m3 TWA: 100 ppm NIOSH IDLH 20000 mg/m3 IDLH: Engineering Measures The use of local exhaust ventilation is recommended to control emissions near the source. Provide mechanical ventilation in confined spaces. Personal Protective Equipment Eye/face Protection Skin Protection Gloves Respiratory Protection Hygiene Measures Should be worn for the handling of any chemical materials Should be worn for prolonged or repeated contact None normally needed Protective cream may be useful when repeated skin contact is expected. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Physical State pH Flash Point Autoignition Temperature Boiling Point/Range Freezing Point Flammability Limits in Air Explosion Limits Explosive Properties Oxidizing Properties Evaporation Rate Vapor Pressure Vapor Density Specific Gravity Water Solubility VOC Content Colored viscous liquid Solvent Liquid N.A. 100°-120° F ASTM D-93 Not Determined 300°-390°F N.A. Lower .8% Lower Upper 5% Upper Slower than butyl acetate Less than 10 mm Hg Heavier than air Lighter than water Insoluble < 300 10. STABILITY AND REACTIVITY Stability This product is stable and hazardous polymerization will not occur. Conditions to Avoid Incompatible Materials Strong oxidizing agents Strong acids. _____________________________________________________________________________________________ Page 4 / 7 CPR Seam Sealer TG - 5306 Revision Date 30-Jan-2014 _____________________________________________________________________________________________ Hazardous Decomposition Products None Possibility of Hazardous Reactions None 11. TOXICOLOGICAL INFORMATION Acute Toxicity Component Information Chemical Name Hydrocarbon solvent LD50 Oral 8400 mg/kg Rat LD50 Dermal 2000 mg/kg Rabbit LC50 Inhalation 3400 ppm Rat 4h 5.2 mg/L Rat 4h Chronic Toxicity Carcinogenicity Chemical Name ACGIH IARC NTP OSHA Mexico 12. ECOLOGICAL INFORMATION Ecotoxicity Hydrocarbon Solvent Water Flea Data: Daphnia magna EC50=6.14 mg/L (48 h) Persistence/Degradability Bioaccumulation/ Accumulation Mobility in Environmental Media 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of waste by burning in an approved incinerator, in accordance with federal, state and local regulations. Contaminated Packaging US EPA Waste Number 14. TRANSPORT INFORMATION DOT UN-No Not Regulated UN1269 _____________________________________________________________________________________________ Page 5 / 7 CPR Seam Sealer TG - 5306 Revision Date 30-Jan-2014 _____________________________________________________________________________________________ 14. TRANSPORT INFORMATION Special Provisions Not Regulated for non-bulk packaging of 450 liters (119 gallons) or less (DOT 49 CFR 173.150(f)) Combustible Liquid, n.o.s. Description TDG Description Non-regulated for surface transportation (no hazard label required for surface transportation via motor freight). Not Regulated for non-bulk packaging of 450 liters (119 gallons) or less (DOT 49 CFR 173.150(f)) Combustible liquid, n.o.s. MEX Not Regulated Special Provisions ICAO UN-No Proper Shipping Name Hazard Class Packing Group 1263 Paint 3 III UN-No Proper Shipping Name Hazard Class Packing Group ERG Code 1263 Paint 3 III 128 UN-No Proper Shipping Name Hazard Class Packing Group 1263 Paint 3 III IATA IMD/IMO 15. REGULATORY INFORMATION International Inventories Chemical Name Hydrocarbon Resin Hydrocarbon Solvent TSCA DSL NDSL EINECS ELINCS ENCS CHINA KECL PICCS AICS TSCA X X DSL X X NDSL EINECS ELINCS ENCS X X X X X CHINA X X KECL X X PICCS X X Complies Complies Complies Complies Complies Complies Complies Complies Complies Complies USA _____________________________________________________________________________________________ Page 6 / 7 AICS X X CPR Seam Sealer TG - 5306 Revision Date 30-Jan-2014 _____________________________________________________________________________________________ Federal Regulations SARA 313 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Chemical Name State Regulations California Proposition 65 This product contains no Proposition 65 chemicals. State Right-to-Know Chemical Name Hydrocarbon Resin Massachusetts X New Jersey X Pennsylvania X Illinois Rhode Island X Canada WHMIS Hazard Class B3 Combustible liquid D2B Toxic materials Legend NPRI - National Pollutant Release Inventory 16. OTHER INFORMATION Preparation Date 27-January-2014 Revision Date 30-January-2014 Revision Summary N/A Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS _____________________________________________________________________________________________ Page 7 / 7
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