Butvar products ® Uses and physical properties Butvar ® products Uses and physical properties • Metal coatings—Butvar can improve coating uniformity, minimize cratering, improve adhesion, and increase coating toughness and flexibility. Butvar resin is approved by the U.S. Food and Drug Administration for indirect food additive uses, making it an excellent choice for drum and can-lining applications. Butvar resin was pioneered in the 1930s as the key ingredient for automotive safety glass interlayers. It still enjoys widespread use in automotive and architectural applications for laminated safety glass. Polyvinyl butyral resins are employed in a wide array of industrial and commercial applications. These unique resins offer impressive performance, as well as outstanding versatility. Butvar® polyvinyl butyral resins have a combination of properties that make them a key ingredient in a variety of successful formulations. Some of these properties for which Butvar is widely used are outstanding binding efficiency, optical clarity, adhesion to a large number of surfaces, and toughness combined with flexibility. Wood finishes • Protective wash coats and sealers—Butvar helps provide good holdout, intercoat adhesion, moisture resistance, flexibility, toughness, and impact resistance. In addition, the wood substrate is protected against discoloration when Butvar is used in the finish, including color changes caused by light. Some of the applications in which Butvar® is a vital ingredient include: •K not sealers—polyvinyl butyral resins are excellent barriers to bleeding of terpenaceous matter from knots, heartwood, and rosin ducts. Metal coatings • Wash primers—anticorrosive primers that apply easier, adhere better, and dry faster than other materials. •S urface coatings—Butvar enables good wetting of most substrates while providing a reactive site for chemical combination with thermosetting resins. Resulting films may be air dried, baked, or cured at room temperature. •S urface coatings—Butvar enables good wetting of most substrates while providing a reactive site for chemical combination with thermosetting resins. Resulting films may be air dried, baked, or cured at room temperature. Unit Test method B-72 B-74 B-76 B-79 B-90 B-98 °C DSC-Tg 72–78 72–78 62–72 62–72 72–78 72–78 1000X — 170–250 120–150 90–120 50–80 70–100 40–70 Solution visc 10% by wt cP — 1600–2500 800–1300 200–450 75–200 200–400 75–200 Hydroxyl content as % polyvinyl alcohol — — 17.5–20.0 17.5–20.0 11.5–13.5 11.0–13.5 18.5–20.5 18.0–20.0 Acetate content as % polyvinyl acetate — — 0–2.5 0–2.5 0–2.5 0–2.5 0–1.5 0–2.5 Butyral content as % polyvinyl butyral — — 80 80 88 88 80 80 Property Tg MW Water-based dispersions Dipsersion formulation RS-261 RS-3120 FP BR Plasticizer Castor oil Castor oil Butyl ricinoleate Butyl ricinoleate Surfactant Sodium sulfonate Potassium oleate Potassium oleate Potassium oleate Butvar B-72 Butvar B-72 Butvar B-72 Butvar B-72 Brookfield visc at 25°C (cP) 100–5000 100–1500 <150 500–1500 Total solids 40.0–43.0 50.0–53.0 >50.0 50.0–52.0 8.9 8.6 8.7 8.4 PVB polymer Specifications Density @ 25°C (lb/gal) Adhesives Water-based dispersions • Structural adhesives—When combined with phenolic laminating resins, Butvar gives the highest shear strength values at temperatures up to 250°F. Other outstanding properties of the PVB-phenolic system include high peel strength at very low temperatures, excellent dielectric properties, and exceptionally good creep resistance as measured by the ability of the bond to carry sustained loads for extended periods of time. Eastman also offers a line of waterborne Butvar® dispersions, which are used in a wide variety of applications. Some of their key benefits are good adhesion to many surfaces, toughness, and transparent coatings that can be used in dipped, brushed, or spray applications. •H ot-melt adhesives—Butvar® makes an excellent base for hot-melt adhesives even where difficult-to-bond surfaces are involved. The many types of Butvar resins allow the best match to individual applications. Other applications • Textile coatings—PVB resins can be compounded to make fabrics both water and stain resistant without noticeably affecting the appearance, feel, drape, and color of the fabric. Almost any fairly tightly woven fabric with a flat surface can be made both water and stain resistant with a coating based on Butvar. • E poxies and other thermosetting resins—Butvar resins are compatible with many epoxy resins and can confer such improvements on epoxy-based systems as increased impact resistance and peel strength. • E lectronics/ceramic tape casting—Butvar imparts excellent green strength and flexibility to the ceramic tape. The primary advantages of using Butvar resins are their solubility in a wide range of solvents and uniform adhesion to conductive metals. Some of the unique applications in which Butvar® dispersions are used include: •T emporary strippable coatings—Butvar dispersions are easy to apply, noncorrosive, and easily removable. They are excellent choices for paint masking, spray booth coatings, and equipment protection. •P rotective coatings for leather, can, wire, packaging, and paper applications. extiles—PVB dispersions provide a “silk feel” for textiles •T while providing stain resistance. arpet backing—PVB dispersions are replacing PVC in •C carpet backing for commercial applications, reducing odor and off-gassing often associated with “sick buildings.” eat belt restraints •S For additional information, including technical specifications and sample formulas, visit BUTVAR.COM. Eastman Chemical Company Corporate Headquarters P.O. Box 431 Kingsport, TN 37662-5280 U.S.A. Telephone: U.S.A. and Canada, 800-EASTMAN (800-327-8626) Other Locations, (1) 423-229-2000 Fax: (1) 423-229-1193 Eastman Chemical Latin America 9155 South Dadeland Blvd. Suite 1116 Miami, FL 33156 U.S.A. Telephone: (1) 305-671-2800 Fax: (1) 305-671-2805 Eastman Chemical B.V. Fascinatio Boulevard 602-614 2909 VA Capelle aan den IJssel The Netherlands Telephone: (31) 10 2402 111 Fax: (31) 10 2402 100 Eastman (Shanghai) Chemical Commercial Company, Ltd. Building C, No. 399 Shengxia Road, Pudong New District 201210, Shanghai, P.R. China Telephone: (86) 21 6120-8700 Fax: (86) 21 5027-9229 Eastman Chemical Japan Ltd. MetLife Aoyama Building 5F 2-11-16 Minami Aoyama Minato-ku, Tokyo 107-0062 Japan Telephone: (81) 3-3475-9510 Fax: (81) 3-3475-9515 Eastman Chemical Asia Pacific Pte. Ltd. 9 North Buona Vista Drive #05-01 The Metropolis Tower 1 Singapore 138588 Telephone: (65) 6831-3100 Fax: (65) 6732-4930 www.eastman.com Although the information and recommendations set forth herein are presented in good faith, Eastman Chemical Company and its subsidiaries make no representations or warranties as to the completeness or accuracy thereof. You must make your own determination of their suitability and completeness for your own use, for the protection of the environment, and for the health and safety of your employees and purchasers of your products. Nothing contained herein is to be construed as a recommendation to use any product, process, equipment, or formulation in conflict with any patent, and we make no representations or warranties, express or implied, that the use thereof will not infringe any patent. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS AND NOTHING HEREIN WAIVES ANY OF THE SELLER’S CONDITIONS OF SALE. Safety Data Sheets providing safety precautions that should be observed when handling and storing our products are available online or by request. You should obtain and review available material safety information before handling our products. If any materials mentioned are not our products, appropriate industrial hygiene and other safety precautions recommended by their manufacturers should be observed. © 2014 Eastman Chemical Company. Eastman and The results of insight are trademarks of Eastman Chemical Company. Butvar is a trademark of Solutia Inc., a subsidiary of Eastman Chemical Company. As used herein, ® denotes registered trademark status in the U.S. only. BVR-003A 7/14
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