Page 1 of 6 Material Safety Data Sheet SPAR 1% SG Registration No. SINNEAI-MicGR/016/0094 Updated 05 January 2012 Replaces all previous editions 1. Identification of the substance / preparation and company Common Name IUPAC Chemical Name Empirical Formula Molecular Mass CAS Number Chemical Family Product Type Company Name and Address Contact Number Emergency Contact Person : Temephos : O,O,O′,O′-tetramethyl O,O′-thiodi-p-phenylene bis(phosphorothioate) : C16H20O6P2S3 : 466.5 : 3383-96-8 : Organophosphorus : Larvicide : Asiatic Agricultural Industries Pte Ltd 150 Gul Circle, Singapore 629607. : Telephone 65 6572 4000 Telefax 65 6862 2268 E-mail [email protected] : Telephone 65 6572 4042 (office hour) Telephone 65 6572 4056 (off-office hour) : Mr Lawrence Chan / Mr Chan Chek Chee 2. Composition / Information on ingredients Formulation : Granule Components Temephos Inert ingredient Content, w/w 1 % 99 % CAS number 3383-96-8 - 3. Hazards Identifications Human health hazards Environmental hazards : Harmful if swallowed. : Toxic to aquatic organisms. 4. First Aid Measures Symptoms and effects First aid - Inhalation First aid - Skin First aid - Eye First aid - Ingestion Advice to physician : Over-exposed may cause local irritation of the skin and irritation of the respiratory tract. : Not harmful under normal conditions. : Remove contaminated clothing. Wash skin with water using soap if available. If persistent irritation occurs, obtain medical attention. : Flush eyes with plenty of water. If persistent irritation occurs, obtain medical attention. : Do not induce vomiting, never give anything by mouth to an unconscious person. Seek medical advice immediately and show container label or this data sheet if possible. : Treat symptomatically. Ingestion posses the major hazard. Asiatic Agricultural Industries Pte Ltd 150 Gul Circle Singapore 629607 Page 2 of 6 Material Safety Data Sheet SPAR 1% SG Registration No. SINNEAI-MicGR/016/0094 Updated 05 January 2012 Antidote Replaces all previous editions : Treat symptomatically. In moderately severe poisoning administer atropine sulphate 0.4 - 2.0 mg repeated every 15 minutes until atropinization is achieve. In case of severe poisoning (expressed by respiratory desperation, muscle weakness and twitching) give parliboxime (protopam-ayerst, 2-PAM) 1.0 g intravenously at no more than 0.5 g/min. 5. Fire Fighting Measures Flash point (close cup) Fire and explosion hazard Suitable extinguishing media : Not applicable, granule : Non-flammable. : Use alcohol foam, carbon dioxide, dry chemical, soft stream water fog only if necessary. Contain all run-offs. Unsuitable extinguishing : Do not scatter spilled material with highmedia pressure water stream. Special exposure hazards : Avoid breathing hazardous vapors, keep upwind. in a fire Fire-fighting : Evacuate area and fight fire from a safe instruction distance. Approach from upwind to avoid hazardous vapors and decomposition products. Fire exposed containers can build up pressure and should be kept cool with water spray if possible. Explosive vapor could form from ruptured containers. Foam fire extinguishing systems is preferred to prevent environmental damage from excessive water run-off. If water is used, avoid heavy hose streams. If possible, dike and collect water used to fight fire to minimize run-off. Special protective : Wear a self-contained respiratory apparatus, wear full fire-fighting turn-out gear. equip. for fire-fighting 6. Accidental Release Measures Personal precautions Environmental precautions Method for cleaning up : Avoid contact with skin and eyes. No smoking, flames or fires in hazard area. Keep unnecessary people away. Isolate hazard area and deny entry. Wear protective clothing and personal protective equipment as prescribed in section 8. : Do not release to the environment in large amount. : Collect scattered material and add to the drums of waste already collected. Repeat if necessary. Dispose off drummed waste according to the method outlined in Section 13 "Disposal Considerations". Asiatic Agricultural Industries Pte Ltd 150 Gul Circle Singapore 629607 Page 3 of 6 Material Safety Data Sheet SPAR 1% SG Registration No. SINNEAI-MicGR/016/0094 Updated 05 January 2012 Replaces all previous editions 7. Handling and Storage Handling - Special protection measures Storage - Sensitivity to humidity, light & oxidation Special storage requirements Storage conditions Polymerization Shelf-life : When handling chemical do not eat, drink or smoke. Wash hands and exposed skin before meals and after work. : Stable under normal atmospheric conditions when stored in close containers. : All chemical must be kept out of reach of children, pets, live stock and people. Pesticide should be stored in a locked, secure place, such as a separate building or storage room. : Maintain a well-ventilated storage area which is relatively free from temperature fluctuations. : Hazardous polymerization has not been reported to occur under normal temperature and pressure. : Will keep their physical & biological properties for minimum 2 years when stored in their original packing in a dry place at an annual average temperature not exceeding 30 deg C. : PE bags. Recommended packaging material Packaging material to be : None avoided 8. Exposure Control / Personal Protection Engineering controls : Local exhaust ventilation may be necessary to control any air contamination to within their TLVs during the use of this product. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Personal protective equipment :Respiratory protection : When handling in a non-ventilated area, use a respirator with an organic vapor removing cartridge with a prefilter approval for pesticides. Hand protection : Wear chemical resistant gloves such as nitrile, butyl rubber, barrier laminate or viton. Eye protection : Wear safety glasses or goggles. Skin protection : Wear long-sleeved coveralls worn over a minimum of short-sleeved shirt and short pants. Wear chemical resistant footwear plus socks. Personal hygiene : Clean water should be available for washing in case of eye or skin contamination. Wash skin prior to eating, drinking, using tobacco or using the toilet. Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product. Shower at the end of the workday. Asiatic Agricultural Industries Pte Ltd 150 Gul Circle Singapore 629607 Page 4 of 6 Material Safety Data Sheet SPAR 1% SG Registration No. SINNEAI-MicGR/016/0094 Updated 05 January 2012 Replaces all previous editions 9. Physical and Chemical Properties Physical state Color Odor Boiling point Melting point Specific gravity pH Vapor pressure : : : : : : : : Solid Gray None Not applicable, granule. 30 deg C (technical) Not applicable, granule. Not applicable, granule. 2.5 x 10-6 pa at 25 deg C (technical) 10. Stability and Reactivity Chemical stability Conditions to avoid Incompatibility with other material Hazardous decomposition products : Stable under normal conditions. : None. : Strong alkalis, amines and oxidizers. : Decomposition products may be hazardous. 11. Toxicological Information Acute toxicity :Oral LD50 - rat Dermal LD50 - rat Eye irritation - rabbit Skin irritation - rabbit Sensitization-guinea pig Medical conditions aggravated by exposure Carcinogen status :OSHA NTP IARC Additional data : : : : : : > 5,000 mg/kg > 5,000 mg/kg Non-irritant Non-irritant Non-sensitizer. Pre-existing cholinesterase depression. : : : : Not listed. Not listed. Not listed. Repeated or prolonged low level exposures may cause sensitization to subsequent exposures that mimic acute exposures. 12. Ecological Information Environmental summary Fish toxicity Bee toxicity : This pesticide is toxic to fish, birds, bees and other wildlife. : 24 hour LD50, trout - 1.9 mg/L (technical). : Highly toxic by direct contact (technical). Asiatic Agricultural Industries Pte Ltd 150 Gul Circle Singapore 629607 Page 5 of 6 Material Safety Data Sheet SPAR 1% SG Registration No. SINNEAI-MicGR/016/0094 Updated 05 January 2012 Replaces all previous editions 13. Disposal Considerations Waste Container : Pesticide waste are toxic and hazardous. Dispose of in accordance with local regulations. Do not discharge or pour into soil, drainage system or bodies of water. : Dispose of according to local regulations. 14. Transport Information Road/Rail transport :Class UN number Proper shipping name Maritime transport :Class UN number Proper shipping name Packing group Marine pollutant Air transport :Class UN number Proper shipping name Packing group : 6.1 : 2783 : Organophosphorus pesticide, solid, toxic (Temephos) : 6.1 : 2783 : Organophosphorus pesticide, solid, toxic (Temephos) : III : No : 6.1 : 2783 : Organophosphorus pesticide, solid, toxic (Temephos) : III 15. Regulatory Information Risk phrases R22 R52 Safety phrases S2 S28 S36/37 S45 S61 : Harmful if swallowed. : Harmful to aquatic organisms. : Keep out of the reach of children. : After contact with skin, wash immediately with plenty of water. : Wear suitable protective clothing and gloves. : In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). : Avoid release to the environment. Refer to special instructions/safety data sheets. Asiatic Agricultural Industries Pte Ltd 150 Gul Circle Singapore 629607 Page 6 of 6 Material Safety Data Sheet SPAR 1% SG Registration No. SINNEAI-MicGR/016/0094 Updated 05 January 2012 Replaces all previous editions 16. Other Information Disclaimer : The information and data contained herein are believed to be correct. The recommendations and suggestions for the use of this product are based upon tests believed to be reliable. The use of this product being beyond the control of the manufacturer, no guarantee, express or implied, is made as to the results to be obtained if not used in accordance with directions or established safe practice. The buyer must assume all responsibility, including injury or damage, resulting from its misuse as such, or in combination with other materials. No statement is to be construed as violating any copyright or patent. Asiatic Agricultural Industries Pte Ltd 150 Gul Circle Singapore 629607
© Copyright 2024 ExpyDoc
