Dorr-Oliver FluoSolids® Systems

Engineering and technologies
Dorr-Oliver FluoSolids® Systems
The Dorr-Oliver FluoSolids® technology makes Technip
a leading provider of fluid bed systems
Technip profile
Technip is a world leader in project management, engineering and
construction for the energy industry.
With a workforce of 40,000 around the world, we constantly offer the best solutions and
most innovative technologies to our clients to meet the world’s energy challenges.
We operate in three main businesses:
Subsea
Offshore
Onshore
In subsea hydrocarbon development,
Technip’s activities include the design,
manufacture and installation of rigid and
flexible subsea pipelines and umbilicals.
Thanks to its portfolio of technologies
and industrial and operational assets,
Technip offers a unique vertically
integrated model in the industry.
In the Offshore business segment
Technip performs engineering,
procurement, construction,
installation, commissioning and the
refurbishment/upgrading of offshore
facilities for the oil and gas industry.
Technip covers the full range of
onshore facilities for the oil and gas
chain, petrochemicals and other
energy industries (nuclear, renewables
including biofuels and offshore wind).
It holds many proprietary cuttingedge technologies and is the leader in
the design and construction of LNG
and gas treatment plants as well as
ethylene, hydrogen and syngas units.
The Group has 3 flexible pipe
manufacturing plants, 4 umbilical
production units, 9 logistics and pipeline
assembly bases, and 1 construction yard.
Technip’s worldwide leadership is
supported by a modern fleet of vessels
for subsea construction, pipelay
development (rigid and flexible pipes
using S-Lay, J-Lay or Reeled technology)
and heavy lift applications.
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Technip provides these services for
fixed platforms in shallow water with
conventional sub-structures and
self-installing platforms such as the
TPG 500 and for deepwater facilities
including Spar, semi-submersible, TLP,
FPSO and FLNG units. Technip is a
world leader in floatover installation
of topsides and its R&D effort is
focused technology transfer for local
content and new frontier areas such
as ultra-deepwater and the Arctic.
Technip is also one of the key actors
in refining and petrochemical units,
and has developed a leadership
position in the fertilizer industry.
Moreover, the Group is very active in
non-energy activities such as mining
and metals, life sciences, buildings and
infrastructures.
Dorr-Oliver FluoSolids® Systems
Technology
history
50 t/d Arseno-pyrite roaster, Australia
88 t/d Arseno-pyrite roaster, Australia
The Dorr-Oliver FluoSolids® technology makes Technip a leading provider of
fluid bed systems, with nearly 1,000 reference projects.
The technology was developed over a 70-year period with a wide range of
applications in the metallurgical, chemical and waste processing industries.
It started with Dorr-Oliver in 1943 with the first commercial installation in 1947.
Then in 1997, Dorr-Oliver sold its know-how and assets related to fluidized bed
systems and equipment, known by the trademark FluoSolids® to Kinetics Technology
International (KTI).
In 2000, KTI merged with Technip, who has continued to develop the FluoSolids®
technology in order to offer modern fluidized bed systems for roasting, calcining,
incineration, and a host of other applications to customers worldwide. In 2012, Technip
Stone & Webster Process Technology was created and is the exclusive provider of
FluoSolids technology.
More than 310 roaster systems for metallurgical applications, as well as sulfur
dioxide and sulfuric acid manufacture
More than 100 calcining systems
More than 270 drying systems
More than 90 fluid bed solids preheaters and calcine coolers
More than 200 incineration systems, both municipal and industrial
Main features
Chemical and thermal efficiency
Simple start-up and shut-down
Uniform solids temperature in the bed
Variable solids retention time
Vertical, cylindrical design for efficient space utilization
Low operating cost
No internal moving parts
Long refractory life
Low maintenance costs
Simple controls
1,650 t/d Phosphate rock calciner, Morocco
Dorr-Oliver FluoSolids® Systems
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Roasting systems
The world's first commercial fluidized bed roasting system
was a FluoSolids® unit designed to treat gold-bearing
sulfide ore. The technology continued to develop under
Dorr-Oliver and now Technip to include a vast array of
roasting process applications and reactor designs.
Roaster with slurry feed
Roasting applications
2 x 3850 MTPD nickel ore roasters, Koniambo,
New Caledonia
Commercial FluoSolids® roasters have been designed and supplied to implement the
following processes:
Two-stage roasting of refractory gold ore using pure oxygen (Freeport process)
CFB roasting of refractory gold ore
Two-stage roasting of gold-bearing arseno-pyrite concentrates for arsenic and
sulfur removal
Partial roasting of copper and nickel sulfides for sulfur control in smelting
Dead roasting of pyrite, pyrrhotite, zinc, nickel and other sulfides
Sulfation roasting of Cu and Cu/Co sulfides (RLE processes)
Reduction roasting of iron ores and nickel laterite ores
Chlorination roasting of copper ores (TORCO process)
Operating Advantages
Ease of operation
High reliability
Low operating and maintenance costs
Flexible designs for various roasting applications
Features of a FluoSolids® roaster system
Nearly
1,000 units installed
worldwide
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Dorr-Oliver FluoSolids® Systems
FluoSolids® roaster systems incorporate the right combination of design features,
specific to the application. Each roaster system is tailored to the specific process
requirements and solids handling characteristics. FluoSolids® systems have incorporated
the following design features:
Cyclone, bag filter and hot ESP dust collection
Direct quench and fluid bed calcine coolers with heat recovery
Fluidized feed distributors for bone dry feed
Slinger-belt feeders for filter cake feed
Slurry distributors and in-bed slurry injection
Direct in-bed injection of liquid, gas and solid fuels
In-bed steam coils for temperature control and heat recovery
Exhaust gas waste heat boilers
Calcining systems
The multi-compartment FluoSolids®
reactor usually consists of a reaction bed
and one or more heat exchange beds for
heat recovery.
Multi-compartment calciner
In a typical 3-stage unit as illustrated here, hot gases from the main calcining
compartment are used to dry and preheat calciner feed. Fuel is directly injected into
the reaction compartment, where temperature and atmosphere are closely controlled.
Finally, heat is recovered from hot product solids and used to preheat the fluidizing
air. Auxiliary vessels, such as fluid bed spray coolers or indirect coolers may be used
to further cool product solids for ease of handling.
Applications
Multi-compartment FluoSolids® reactors have been successfully employed in the
following applications:
Limestone calcining
Calcium and magnesium sulfite decomposition
Foundry sand calcining
Ilmenite roasting
Phosphate rock calcining
Fireclay calcining
Lime mud calcining and pelletization
Alumina and bauxite calcination
Iron ore preheating
Iron ore reduction (hematite to magnetite)
Manganese oxide reduction
4 x 1,500 t/d Phosphate rock calciner, USA
Dorr-Oliver FluoSolids® Systems
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Combustion systems
Technip is a world leader in FluoSolids® combustion technology with more than
200 installations worldwide, spanning the municipal, refining, petrochemical,
food, pharmaceutical and pulp/paper industry sectors.
Combustion system
Combuster, USA
Features
The fluid bed with its homogeneous
temperature, high turbulence and long
residence time performs exceptionally
well for the combustion of sludges,
waste oils, waste chemicals, solid wastes
and other hazardous wastes. Total
systems are available from feed to stack
including ash dewatering and heat
recovery.
All combustion systems are designed to specific application and process requirements
and solids handling characteristics. FluoSolids® systems for the municipal and industrial
waste sectors have these integrated features designed into each plant:
Efficient combustion with low excess air
Lower temperature operations for equivalent combustion results
Reduced air emissions
Flexibility of operation
Simplicity of control
Lower staffing requirements
Lower maintenance and operating costs
Lower total system capital costs
Applications
Technip is the world's most qualified supplier of fluidized bed waste combustion
systems. Installation capacity ranges from 2 to 200 million BTU per hour feed input.
Municipal sludges - primary, secondary
Petroleum wastes
Pharmaceutical sludge
Pulp and paper deinking sludge
Automobile manufacturing waste
Food wastes
Livestock waste
Chemical process waste
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Dorr-Oliver FluoSolids® Systems
Circulating fluid bed
(CFB) systems
As gas velocities increase, more fluidized solids are carried
upward in the reactor and the boundary between the bed and
freeboard zones becomes less distinct.
Circulating fluid bed
A dense phase of coarse solids is created in the lower zone of the reactor followed
by a dilute phase of upwardly moving particles in the upper zone. A majority of the
solids exit the reactor with the exhaust gases and are collected and re-circulated via
a cyclone.
Advantages
Improved reaction kinetics
Greater range of gas turndown capability
Higher throughput per unit area
Additional
capabilities
Fluid bed dryers
Technip can design and supply fluid bed
dryers for a multitude of applications.
Dryer systems can be configured for
direct heating, indirect heating with bed
coils, or as a dryer-cooler combination.
Applications have included:
Limestone and Dolomite
Phosphate Rock
Potash
Sulfide concentrates
Sand and Flux
Slag
Alumina
Coal and Coke
Uranium Ore
Plastics and Chemicals
Catalyst
4,500 t/d CFB gold ore roaster in
Mali, West Africa
Heat recovery & gas cleaning
High temperature exhaust gases provide the possibility of heat recovery. Technip
has provided heat recovery systems of flue gas to air, flue gas to water and flue gas
to steam via water tube or fire tube waste heat boilers. Every fluid bed produces a
carry-over of solids and gaseous products in the gas stream. Technip designs proprietary
cyclones and venturi scrubbers for solids recovery and emission control. Dorr-Oliver
has also provided multiple component custom-designed emission trains to meet
the most stringent environmental air regulations. A plumeless stack appearance can
also be obtained using flue gas heat recovery. Special exothermic applications have
coils in the fluid bed for steam generation.
Pilot scale testing
Technip routinely conducts pilot plant
testing of fluid bed processes to support
equipment design, scale-up, and process
guarantees. This testing offers the following advantages:
Determine process feasibility
Optimize product quality
Define gaseous emissions
Prove destruction and removal
efficiency
Establish design parameters
for commercial design
120 t/h sand dryer system,
Sweden
Refinery waste incinerator,
USA
Dorr-Oliver FluoSolids® Systems
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HEADQUARTERS
Technip
89 avenue de la Grande Armée
75773 Paris Cedex 16
France
Phone: +33 (0)1 47 78 24 00
CONTACTS
USA
Brent SCHIER
Technip Stone & Webster Process Technology
1430 Enclave Parkway
Houston, Texas 77077
USA
Phone: +1 281 848 5234
Fax: +1 281 575 6653
e-mail: [email protected]
Kevin O’MALLEY / Eric ECCLESTON
Technip Stone & Webster Process Technology
555 West Arrow Highway
Claremont, California 91711
USA
Phone: + 909 447 3600
Fax: + 909 447 3704
e-mail: [email protected]
e-mail: eeccleston@technip,com
BRAZIL
Valfredo SANTOS / Lorena DIDIER
Technip
Rua da Glória, 178
20241-180 Glória
Rio de Janeiro - RJ – Brazil
Tel:. +55 (21) 2139 7000
Fax: +55 (21) 2139 8452
e-mail: [email protected]
e-mail: [email protected]
www.technip.com
This document is the property of Technip and is not intended to be a binding contractual document.
Any information contained herein shall not result in any binding obligation on the part of Technip, or
any of its affiliates, and is provided for information purposes only.
Technip - Group Communications - November 2014 - Photo credits: Technip - Page 2: Harry Gruyaert &
Jean Gaumy / Magnum Photos.

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