Highly efficient hydrogen and power production from gas without CO2 emissions Dr. Arnstein Norheim Senior Engineer [email protected] The main challenge; the global climate - energy situation ZEG Power more energy – less emission! The ZEG – technology (ZEG®) Innovative, high efficient co-production of electricity and hydrogen from hydrocarbon gases with integrated CO2- capture ZEG Power - more energy and less emissions • Sustainable use of carbon based fuels – Increased life span of fossil energy reserves • No release of greenhouse gases – CO2 capture an integrated part of the technology – No additional costs • Sustainable solutions for an increasing energy demand – Positive, varied market possibilities – Phased technology deployment ZEG Power AS, the company • Established in 2008 2013 – JV between the two Norwegian research institutes Institute for Energy Technology & Christian Michelsen Research • Business objective – Design, build and verify the patented ZEG® for commercial power plants of increasing size and complexity • Main deliverables – Concepts and detailed design of ZEG® plants for selected applications in varying sizes – Complete small scale plants. Manufacturing will be outsourced through agreements with key partners for detailed design, component manufacturing, and construction R&D from 2001; key to ZEG Power development Unique patented technology • • System integration Technology applications Results • Very positive conclusions with respect to efficiency and cost – • • System design and modelling Core technology elements verified: SESMR and SOFC – Reactor technology – Solid high temperature CO2 sorbents – Stack development 1kW el + 1kW H2 demo plant tested ZEG Process Evaluation ZEG Power HYSYS simulations Efficiency (LHV) CO2 Capture 700 MW H2 + 400 MW el 50 MW H2 + 400 MW el 400 MW el 78.5 % 81.3 % 77.0 % ~ 100 % ~ 100 % ~ 100 % Statoil Aspen Plus simulations – 400 MW el power plant: – ZEG: 75 % energy efficiency (LHV) for stand alone power production including ~ 100 % CO2 capture and compression of CO2 to 110 bar. – Traditional amine based CO2 capture: 48-50% energy efficiency (LHV) Power Market potential Superior cost efficiency at 400 MWel Results from a techno-economical feasibility study. Comparison to conventional pre-combustion technology (auto-thermal reforming, water-gasshift, amines, combined cycle) Comparison of NPV- values, 400 MWel with CO2-capture ZEG Power ATR + amines J. Meyer et al. Energy Procedia 4, 1949-56 (2011) • Efficiency ~ 77% • 100% CO2 capture • No NOx ZEG Power highlights 2013 • Commissioning of a 50kW ZEG® Demo plant based on upgraded landfill gas; BioZEG • Third party assessment of the ZEG® technology • Pre-engineering of a 400kW ZEG® plant; ZEG400 • New patent applications filed 50kW ZEG demonstration plant The BioZEG-project Cost-effective stand alone green production of hydrogen and electricity • Objective: – Demonstration of close thermal integration of SOFC (el) & Reformer ( H2 - SESMR) • Input: – Biomethane (upgraded landfill gas) • Output: 70% total efficiency – Hydrogen (30 kWH2) – Electricity (20 kWel) – CO2 BioZEG 3D assembly HyNor Lillestrøm H2-refuelling station 30kW SE-SMR system, 10Nm3 H2/hour (~ 20kg/day) SOFC Module (20 kWel) Stacks from PLANSEE / Fraunhofer IKTS Will produce 100 MWh electricity in 2014 The integrated 50kW BioZEG plant Test campaign of 50 kW BioZEG plant • First major up-scaling towards industrial ZEG - plants – – – – • Establish operational knowledge on industrially relevant ZEG-plant Maximise system efficiency by optimised heat integration Study ZEG-plant operational flexibility Study long-term ZEG-plant operational stability and performance Outcome: – Optimised operational data forming basis for development of commercial, small-scale standalone ZEG-plants – Basis for further development of core ZEG-technologies and ZEGplants Third Party Assessment The ZEG-technology and upscaling from 50kW to 400kW are evaluated by the German research institute ZSW • The concept and potential is confirmed – “Compared with commercial available combinations of technology, the ZEG400 concept shows high potential to become cost effective even when engineering costs for the first plant are considered. This due to the high system efficiency and the included carbon capture technology, which leads for alternatives to high investment and operation costs” • No clear showstoppers are identified – Risks and concerns indicated in different technology elements • Recommended areas for development are focused in the on-going projects and in planned work www.zsw-bw.de Next step……. ZEG 400kW plant Mongstad Test Center - TCMDA 2013-2016 The possibility of technology tests at TCMDA is discussed Foto TCMDA ZEG400 - “proof of concept” in industrial scale Main objectives: •Heat integration with heat transfer loop •H2 – cycling for efficiency optimisation •SOFC-technology •Operation for improved lifetime Pre-engineering phase supported by Market and industrial opportunities The main strengths of ZEG® for energy production: • High overall efficiency with integrated CO2 capture • Flexibility – All types of carbon based fuels can be used – Product composition can be varied within design limits dependent on market demand of electricity and hydrogen (and heat) – Applications and scale from small scale distributed plants based on biogas to industrial scale power plants Scale and complexity 400 ZEG® - a modular technology applicable at increasing scale 50/700 7.5 7.5 ZEG Large Scale Power MW 200 ZEG Industry 200 20 30 • • BioZEG • • kW • • MW-scale power production • Production of ammonia, methanol • Unconventional hydrocarbons and heavy oil processing Integrated processes (metallurgical, mineral dressing) ZEG Offshore • Standalone power to offshore oil & gas Distributed energy from without CO2-emission biomass Hybrid solutions for transportation Greenhouses, district heating, bio-refineries Time Market and Partner Strategy • The ZEG Power market is an immature market, allowing the technology development to mature together with the market and strategic partners. • Identification of areas and potential industrial actors where ZEG® will give a high potential added value. • Case / feasibility studies together with industrial partners will be important to identify areas of special interest for ZEG® – Standalone distributed ZEG® plants based on biomass resources (the BioZEG-concept) • Hydrogen refuelling stations – Integrated industrial solutions where power, heat, hydrogen and/or CO2 is required – Integrated solutions for exploitation of heavy oil – Power production • Offshore ZEG Power by 2017 • BioZEG200 - a commercial product • Developed and sold (Bio)ZEG400 concepts for demonstration projects • Successful 400kW plant – «proof of (industrial) scale» • Ensured demonstration of all critical technology elements • Ongoing concept design and pre-engineering of MW scale plants – Process optimisation – Cost reductions ZEG Power – possible collaboration with Industrial Partner • Project collaboration – General project support • Existing projects • New projects – Specific feasibility studies • • • • • • • CO2-capture Small scale distributed energy production Biomass applications - gasification Integrated industrial applications Offshore electricity production ……. ….. • Direct investment ZEG Power as Superior technology for high - efficiency energy production For more information contact Arnstein Norheim, Senior Engineer [email protected] www.zegpower.com
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