RESOLUTION NO. FILE NO. R-2014-04-COE 1 [Revised Reduced-Risk Pesticides List] 2 3 Resolution Adopting a Revised Reduced-Risk Pesticides List For 2014. 4 WHEREAS, Chapter 3, Section 307(d) of the San Francisco Environment 5 Code allows the Commission on the Environment to exempt “reduced-risk” 6 pesticides from the ban imposed by the Ordinance upon a finding that the 7 “reduced-risk” pesticide is commonly used as part of an 1PM strategy; and, 8 WHEREAS, The Department of the Environment has performed an 9 extensive evaluation of pesticide products that qualify as “reduced-risk” in consultation with members of the public, scientists, 10 pesticides 11 departments and agencies of the City and County of San Francisco; and, and 12 WHEREAS, The Department of the Environment has developed and 13 recommends the attached revised Integrated Pest Management Program 14 Reduced-Risk Pesticides List, hereby called the Approved List 2014, for adoption 15 by the Commission for the year 2014; and, WHEREAS, The Approved List 2014 will be reviewed and updated on an 16 17 as-needed basis; now therefore, be it 18 RESOLVED, That the Commission on the Environment finds that the 19 pesticide products on the Approved List 2014 are “reduced-risk” pesticides 20 commonly used as part of an 1PM strategy, and are therefore exempt from the 21 ban imposed by Sections 302 and 303 of the Environment Code. 22 II Commission on the Environment 1 January 28, 2014 FILE NO. R-2014-04-COE RESOLUTION NO. 1 I hereby certify that this Resolution was adopted by the Commission on the 2 Environment at its meeting on January 28, 2014. 3 4 Monica Fish, Commission Secretary 5 Vote: 6 Ayes: 7 Noes: 8 Absent: Coin,nissioiz oiz the Enviromnent 2 January 28, 2014 SF Environment Our home. Our city. Our planet. A Department of he City and County of San Francisco Guide to San Francisco’s Reduced Risk Pesticide List Revised September 1, 20 13 Introduction The City of San Francisco Department of the Environment’s (SFE) Reduced-Risk Pesticide List is the result of a multi-step process that involves both environmental scientists and pest managers. The first step is a hazard assessment of both the active ingredients and the formulated product. The second step is a consideration of the potential human and environmental exposure that may result from use of the product in the particular application proposed by San Francisco City staff. This informal exposure assessment is done by SFE staff in conjunction with the Integrated Pest Management Technical Advisory Committee (IPM-TAC). The third and final step combines the results of the hazard and exposure assessments into a decision by staff and the TAC as to whether a Application to Certified product should be added to the List, and if so, whether it requires an Green Buildings “least restricted, (formerly denoted as “Approved (A)”), “more The U.S. Green Building Council’s restricted” (formerly “Limited Use (L)”), and “most restricted” 2009 LEED for Existing Buildings categorization (formerly “Limited Use-Special Concern (L*). Operations and Maintenance Approval for use in the San Francisco 1PM program is determined on (LEED-EBOM) refers to San the basis of the need for the product, the availability of alternatives, Francisco’s Hazard Tier System in the Hazard Tier, and the exposure potential. its reference manual. For LEED certified buildings, building Step 1: Hazard Assessment managers are not required to San Francisco summarizes the hazards associated with pesticide provide universal notification of products and places the products into Hazard Tiers (Table 1) based pesticide applications if those on the toxicity of the active ingredient(s) and the other ingredients (if pesticides would qualify as Tier Ill they are identified) in the product. The specific hazards assessed are (lowest hazard). LEED users should described in Table 2 and the ingredients in the product are refer to the “Hazard Tier Review evaluated for each category and ranked as high, moderate or low Process” section below for hazard, according to the criteria in Table 3. guidance on how to categorize their products themselves. Lists of Step 2: Exposure Assessment products that San Francisco has The hazard review and tier ranking process is only the first step categorized are posted on the toward placing a pesticide on the Reduced-Risk Pesticide List. A www.sfenvironment.org/ipm critical second step is review by the San Francisco 1PM Technical website, but are neither Advisory Committee (1PM TAC), which is composed of 1PM comprehensive nor necessarily up Coordinators from the largest City departments (SF Public Utilities to date. Commission, SF Dept. of Recreation and Parks, SF Dept. of Public Works, SF Port, SF MUNI, SF International Airport, SF Dept. of Public Health). The Committee discusses each proposed addition/deletion Guide to San Francisco Reduced-Risk Pes,icide List, Lndaied 9 113 to the list and reviews: • The potential for human exposure or environmental release for each proposed product. Products such as containerized baits, for example, use very small amounts of active ingredient encased in a protective covering. These would therefore pose less exposure potential than, say, aerosol spray products. • The effectiveness of each proposed product. Does the product work as intended? • The need for the product. Is this kind of pest management action truly necessary? If so, is this the least-hazardous product available for the task? Step 3: Placement on Reduced-Risk Pesticide List The 1PM TAC makes recommendations for additions/deletions to the list. These recommendations are then reviewed by SFE. If the decision is made to list a product, it is categorized in one of three ways: Least Restricted (formerly “Approved” or “A”). These products are generally the least hazardous pesticides on the list. More Restricted (formerly “Limited Use” or “L”). These products include specific restrictions on allowable situations. Most Restricted (formerly “Limited Use Special Concern” or lL*l). These are pesticide products that pose the greatest health or environmental concerns, but which are nevertheless considered the least-hazardous chemical alternative for a particular purpose. Use of “Most Restricted” products must be justified at an annual public hearing. — The SEE proposes a new Reduced-Risk Pesticide List annually, and holds a public hearing (generally in January) to obtain public comments and suggestions. The list is then submitted for final approval by the SF Commission on the Environment. Exemptions For special, unforeseen, or emergency situations, City Departments must be granted a formal exemption from SFE to use products not found on the Reduced Risk Pesticide List. Most exemptions granted are for pilot testing new, safer products. Guide to San Francisco’s Reduced-Risk Pesticide List, L/pdated 9 1 13 2 Hazard Tier Review Process Pesticide products are assigned a hazard tier ranking after evaluating the hazard indices listed in the following section. The product is assigned a ranking as High, Moderate, or Low for each characteristic based on the ranges or values shown in Table 3 below. If any of the criteria are in the High category, the product is placed in Tier 1 If the chemical does not have any criteria in the High category, but does have at least one criterion in the Moderate category, the product is placed in Tier 2. Products with criteria only in the Low category are placed in Tier 3. See Table 1 for a summary of rankings, and Table 2 for a summary of data sources. . Table 1: Tier Rankings Derived from Hazard Screening Tier Tier 1 Tier 2 Tier 3 Definition Highest concern. At least one criterion in Table 6 placed in highest hazard category. Moderate concern. At least one criterion in Table 6 placed in the moderate hazard category. Lowest concern. No criteria flagged for Tier 1 or Tier 2. Table 2: Hazards Evaluated and Data Sources Used Hazard Acute toxicity Restricted use Cancer Reproductive or Developmental Toxicity Endocrine disruption Water pollution potential Hazard to birds Hazard to aquatic life Hazard to bees Hazard to wildlife Soil mobility Persistent, Bioaccumulative, Toxic substances (PBTs) Source(s) of Information Used Product label: Signal word (Caution, Warning or Danger) Product label: Use restricted to professional applicators Cancer classification of ingredient by US EPA, State of California (Proposition , or the 21 , National Toxicology Program (Report on Carcinogens) 20 65 list) Monographs) International Agency for Research on Cancer (IARC 22 ), US 20 Designation of ingredient by the State of California (Proposition 65 list 1 EPA on the Toxics Release Inventory list 2 or included in the book Designation of ingredient by the European Commission 3 Lawrence H. Keith by Disruptors al Environment Endocrine Ingredient listed under Clean Water Act Section 303 Id) .4 50 Product label or MSDS: Presence and wording of bird hazard statement or LD available). product hf or LCso of 50 Product label or MSDS: Presence and wording of fish hazard statement or LC of product (if available). 50 Product label or MSDS: Presence and wording of bee hazard statement or LD or LCso of product (if available). Product label or MSDS: Presence and wording of wildlife hazard statement or 50 or LC5O of product (if available). LD Soil mobility score (Groundwater Ubiquity Score or GUS) calculated from physical properties or CA DPR’s assessment of groundwater contamination potential using physical properties. Physical property data available in the OSU 5 CA DPR Pesticide Contamination Prevention Act Pesticide Properties Database, 7 EU Footprint Pesticide Properties database. the or 6 Reports, Status 8 or listed by the European Union US EPA Waste Minimization priority chemical 9 as fulfilling PBT or Persistent Organic Pollutant (POP) criteria. Guide to San Francisco’s Reduced-Risk Pesticide List, Updated 94 13 3 Table 3: Criteria for San Francisco Hazard Tier Ranking Hazard High Moderate Low Signal word Danger Warning Caution or none Restricted use Yes Cancer (see Table 1) Known or Probable Reproductive or Developmental Toxicity Listed Not listed Endocrine disruption EC category I or II EC category Ill or not listed Water pollution 303(d) listed Not listed Hazard to birds “Extremely toxic” or “Highly toxic” according to product label, or high product toxicity based on LC5O or 0 (see above) LDs “Toxic” according to product label, or moderate product toxicity based on 50 or LD LC 50 (see above) No warning on product label, or low product toxicity based on LC 50 or 50 (see above) LD Hazard to aquatic life “Extremely toxic” or “Highly toxic” according to product label, or high product toxicity based on LC5O (see above) “Toxic” according to product label, or moderate product toxicity based on 50 (see above) LC No warning on product label, or low product toxicity based on LC 50 (see above) Hazard to bees “Extremely toxic” or “Highly toxic” according to product label, or high product toxicity based on LDso (see above) “Toxic” according to product label, or moderate product toxicity based on 50 (see above) LD No warning on product label, or low product toxicity based on LDso (see above) Hazard to wildlife “Extremely toxic” or “Highly toxic” according to product label, or high product toxicity based on LC5O or 50 (see above) 1D “Toxic” according to product label, or moderate product toxicity based on 50 or LDs LC 0 (see above) No warning on product label, or law product toxicity based on LC5O or 50 (see above) LD GUS 2 or DPR classifies Al as exceeding SNVs GUS <2 and Not listed by DPR as exceeding SNVs. Soil mobility No Possible PBT Listed Guide to San Francisco ‘s Reduced-Risk Pesticide List, Updated 9 J/]3 Unclassifiable, Not Likely, Not Listed Not listed 4 Below are details on the hazard indices used in the evaluation: •• Acute Toxicity EPA assigns every pesticide product to a hazard category based on the results of acute toxicity testing of the full product including inert ingredients. The testing includes the single dose required to cause death in test animals via ingestion, inhalation, and skin absorption. The testing also considers the degree of skin and eye irritation or damage. Based on the results of these tests, EPA assigns the product to a hazard category and requires a signal word such as Caution, Warning, or Danger to be placed on the label. Danger indicates the highest hazard, Warning indicates moderate hazard, and Caution indicates a lower hazard. + Restricted Use Some pesticides are restricted to use only by certified pesticide applicators and are not available to the general public because of high toxicity, particularly hazardous ingredients, or environmental hazards. Pesticides designed as restricted use are so indicated on the product label. + Cancer (known ingredients only) Various state, federal, and international organizations evaluate or list chemicals for carcinogenicity, their potential to cause cancer 19, 20,21,22 Due to the expense and difficulty of such evaluations, not all agencies have reviewed the same chemicals and not all reach the same conclusions on a given chemical. For this reason, we use the ratings of several agencies whenever possible. These ratings indicate the strength of the scientific evidence that a particular chemical can cause cancer in humans, but they do not consider the potency of the chemical, i.e. the number of cancers that will result from a standard level of exposure to a population. The various agencies use different words to describe the strength of evidence, such as possible, probable, likely, known, etc. In order to simplify the rating, we have assigned the various phrases used by the different agencies to a standard phrase used in the Hazard Tier assessment (see Table 4). The tier rating is based on the highest likelihood assigned by any agency that has evaluated the chemical. Guide to San Francisco ‘s Reduced-Risk Pesticide List, Updated 9 1/13 5 Table 4: Standardized Cancer Rankings Used in Hazard Tier Assessment Organization US EPA 19 22 ARC Organization Rating Group A: Known Human Carcinogen Known/Likely Likely to be Carcinogenic to Humans Group B: Probable Human Carcinogen B]: Sufficient evidence of carcinogenicity from animal studies with limited evidence of carcinogenicity from epidemiologic studies in humans B2: Sufficient evidence of carcinogenicity from animal studies with inadequate or no data from epidemiologic studies in humans Group C: Possible Human Carcinogen Likely to be Carcinogenic to Humans at High Doses, but Not Likely at Low Doses Suggestive Evidence of Corcinogenicily to Humans Group D: Not classifiable as to human carcinogenicity Data are inadequate for an assessment of human carcinogenic potential Group E: Not Likely to be Carcinogenic to Humans Standardized Rating for SF Hazard Tier Known or Probable Known or Probable Known or Probable Known or Probable Possible Possible Possible Unclassifiable Unclassifiable Not Likely Group 1: Carcinogenic to Humans Group 2A: Probably Carcinogenic to Humans Group 2B: Possibly Carcinogenic to Humans Group 3: Unclassifiable as to Carcinogenicity to Humans Group 4: Probably not Carcinogenic to Humans Known or Probable Known or Probable Possible Unclassifiable 21 NIH/NTP Known to be a Human Carcinogen Reasonably Anticipated to be a Human Carcinogen Reviewed but not listed Known or Probable Known or Probable Not Listed Proposition Known to the State of California to Cause Cancer Known or Probable Not Likely 6520 •. Reproductive/Developmental Toxicants (known ingredients only) Known ingredients in the products are screened against the State of California lists of known reproductive and developmental toxicants, 20 the US EPA Toxics Release Inventory (TRI) chemical hazard 23 or the list from the National Toxicology Program’s Health Assessment and Translation (formerly the list, Center for Evaluation of Risks to Human Reproduction). 32 Guide to San Francisco s Reduced-Risk Pesticide List. Lvdated 9 113 6 •:• Endocrine Disruptors (known ingredients only) Under the Food Quality Protection Act, the EPA is required to screen pesticide ingredients for endocrine system effects. Until that screening is done, a comprehensive list of endocrine disruptors will not be available. For purposes of this screening, we used the list of endocrine disruptors compiled by the 24 and in the book Environmental Endocrine Disruptors by Lawrence Keith. 25 European Commission Chemicals on the EU list are classified for both humans and wildlife as Category I: evidence for endocrine disruption in living organisms, Category II: evidence of potential to cause endocrine disruption, or Category Ill: low exposure concern, no scientific basis for inclusion, or insufficient information. The list of endocrine disruptors will likely be expanded at a later date, when US EPA publicizes the results of the Endocrine Disruptor Screening Program. •:• Water Pollution (known ingredients only) Section 303(d) of the federal Clean Water Act requires states to compile a list of water bodies with excessive contamination. The list of impaired water bodies in the area where the product will be used ) is searched for pesticide active ingredients. Based on a 33 (available from the US EPA 303(d) web site site-specific analysis of the water bodies, products are assessed as to whether they contain priority 303(d) pollutants for that area. •:• Hazards to Birds, Aquatic Life, Bees, and Other Wildlife The US EPA requires particular hazard warning statements on pesticide product labels depending on the toxicity of the active ingredients and the formulated product to particular off-target species, evidence that adverse effects hove occurred, and the use for which the product is intended. The hazard assessment is based on whether such warnings appear on the specific product label or the acute toxicity 50 (or LD ) that is the lethal 50 of the product as described in the MSDS. This toxicity is expressed as an LC concentration (or dose) to 50% of the test organisms in a laboratory test. The criteria for defining toxicity for different species are shown in Table 5 below. Table 5: Toxicity Reference Values for Terrestrial and Aquatic Wildlife Category High Toxicity Moderate Toxicity Low Toxicity Mammal and Bird 50 1D 34 (mg/kg) <50 50—500 >500 Mammal and Bird LC 50 (mg/kg of 35 food) <500 500—1,000 >1,000 Aquatic LCso Bee LD 50 35 (mgIL) 36 (glbee) < 1 1—10 >10 <2 2—11 >11 •• Mobility in Soil (known ingredients only) The potential for ground-water or surface-water pollution by pesticides is dependent on many factors, including persistence of the ingredients, water solubility, soil binding, amount of rainfall or irrigation, soil properties, amount and frequency of applications, soil slope, vegetation present, proximity to ground- or surface-water, etc. The hazard assessment only considers the properties that relate strictly to the pesticide itself. The potential for a pesticide moving to surface water or groundwater is thus assessed in one of three ways: Guide to San Francisco’s Reduced-Risk Pesticide List, Updated 9 113 7 1) The Ground-water Ubiquity Score (GUS) is an empirically derived index that relates pesticide persistence and soil binding to mobility. The GUS index is defined mathematically as: GUS = logio(half-life) x [4 log 10 (K )] 0 - where K 0 is the soil sorption coefficient and half-life is the soil half-life in days. Information on pesticide K 0 values can be found in the OSU Pesticide Properties database, 27 the California Department of Pesticide Regulation groundwater Status Reports, 28 or in the EU Footprint Pesticide Properties database. 29 A pesticide movement rating ranging from “extremely low” to “very high” has been assigned to the numerical values by the researchers in the OSU Extension Pesticide Properties Database. 27 The values are shown in Table 6. Table 6: Pesticide Mobility in Soil as a Function of Groundwater Ubiquity Score GUS Value <2 >2.0—3.0 >3.0 Pesticide Movement Rating Low Moderate High 2) The California Department of Pesticide Regulation (DPR) lists pesticide active ingredients as potential groundwater contaminants when physical properties exceed Specific Numeric Values (SNVs). In order for a chemical to be listed, one of the following must be true: Water solubility: > 3 ppm (mg/L), or Soil adsorption coefficient (Koc): < 1 ,900 cm /g 3 AND one of the following must be true Hydrolysis half-life: > 14 days, or Aerobic soil metabolism half-life: >610 days, or Anaerobic soil metabolism half-life: > 9 days The list of pesticides that exceed SNVs is available from DPR’s annual Groundwater Status 28 Reports. 3) In addition to the GUS index and DPR’s assessment, information on pesticide water contamination potential is noted from product label warnings. EPA requires two levels of warnings for products with characteristics that have been determined to result in likely contamination of groundwater from use as labeled, A lower level of warning is required if no actual detections have occurred or no field studies have been done. A higher level of warning is required if detections have occurred or field studies have shown that the chemical leaches. For purposes of the initial screening, the presence of either warning is considered an indication that the chemical has high mobility. In rare cases where a label ground-water advisory occurs but the GUS index or DPR assessment did not indicate high mobility, the label advisory is given priority. Guide to San Francisco s Reduced-Risk Pesticide List, Lpdated 9 113 8 Pesticides that have high soil mobility according to the criteria above, but are not otherwise toxic or bioaccumulative are classified as Tier 2. • Persistent, Bioaccumulative, Toxic Chemicals (PBTs) In recent years much attention has been paid to toxic chemicals that persist in the environment and bioaccumulate. PBTs pose a serious threat because they can build up in ecosystems, wildlife, and humans even when deposited slowly. Many organizations including the United Nations, International Joint Commission on the Great Lakes, U.S. EPA, and Washington State Department of Ecology have proposed strategies to reduce or eliminate them. The list used for this evaluation is EPA’s Waste Minimization Priority Chemicals list or listed by the European Union as fulfilling PBT or Persistent Organic Pollutant (POP) criteria. New lists will be added as more information becomes available. Guide to San Francisco’s Reduced-Risk Pesticide List, Updated 91’13 9 References US EPA. 2012. TRI-Listed Chemicals. http://www.epa.gov/tri/trichemicals/ 2 EC. 2000. Towards the establishment ofa priority list of substances for further evaluation of their role in endocrine disruption, Annex 13 (List of 146 substances with endocrine disruption classifications prepared in the Expert meeting). European Commission. Final Report, November 2000. http://ec.europa.eu!environment/docum/01262en.htm#bkh. Keith LH. 1997. Enviromnenial Endocrine Disruplors: .1 Handbook of Proper 1997) i’ Data. Wiley Interscience (New York, US EPA. National Suirimary of Impaired Waters and TMDL Information. http://iaspub.epa.gov/waters 10/attains nation cy.control?p report type=T. OSU. OSU Extension Pesticide Properties Database. http://npic.orst.edu/ingred/ppdmove.htm. 6 CA DPR, Status Report Pesticide Contamination Prevention Act (issued annually). Environmental Monitoring Reports. California Department of Pesticide Regulation. http://www.cdpr.ca.gov/docs/emon/pubs/ehapreps.htm. EU Footprint Database. 2011. http://www.eu-footprint.org. 8 US EPA. Waste Minimization Priority Chemicals List. National Waste Minimization Partnership Program. http ://www.epa.gov/epawaste/hazard/wastern in/priority .htm. q EU. 2012. Persistent Bioaccumulative Toxins. European Commissiont Joint Research Centre. Institute for Health and Consumer Protection (IHCP). http://esis.jrc.ec.europa.eu/index.php?PGM=pbt. I’3 US EPA, List of Chemicals Evaluated for Carcinogenic Potential. US Environmental Protection Agency. http ://www.epa.gov/opp0000 I /carlist/. 20 CA OEHHA. Proposition 65 List of Chemicals Known to Cause Cancer, Developmental or Reproductive Toxicity. California Office of Environmental Health Hazard Assessment. http://oehha.ca.gov/prop65/prop65_list/Newlist.html. 21 NTP, 2011. 12th Report on Carcinogens. National ToxicoLogy Program. http://ntp.niehs.nih.gov/?objectid=03C9AF75El BF-FF4O-DBA9ECO928DF8B 15 22 IARC, IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. http://monographs.iarc.fr/ 32 NTP. 2012. Health Assessment and Translation (Formerly CERHR). http://ntp.niehs.nih.gov/?objectid=497C419D-E8346B35-8AF I 5D389859AF07. US EPA. How’s i’.ly J1’aterii’ay? http://watersgeo.epa.gov/mywaterway/. l US EPA. Series 870 Health Effects Test Guidelines. Acute Toxicity Testing Background, US EPA Office of Pollution Prevention and Toxic Substances Harmonized Test Guidelines, US EPA, http://www.regulations.gov/#!documentDetail;D=EPA-HQ-OPPT-2009-0 156-0002. Kamrin, MA. 1997. Pesticide Profiles: Toxicity, Environmental Impact, and Fate. Lewis Publishers. Boca Raton, FL. 36 US EPA 2012. Label Review tlanual, Chapter 8: Environ,nental Hazards, http://www.epa.gov/oppfead I /labeling/lrm/. Guide to San Francisco ‘s Reduced-Risk Pesticide List, Updated 9/] /J 3 10 MMF-G Avenger Aquamaster Fungicide Gel Herbicide Agri-Fos Systemic Agnique Bait (Dupont) Advion Cockroach Advion Cockroach Bait Arena (Dupont) (Dupont) Advion Ant Gel (Dupont) Advion Ant Bait Arena 0.1% Limited: Least limited 524-343 82052-1 Herbicide 71962-1 Herbicide Fungicide (Tier II) 53.8% (Tier_II) hazardous More Limited More Limited Least Limited with Sudden Note prohibition on use use near water, Burndown herbicide to replace Greenmatch. Not for bodies in red-legged frog habitat. within buffer zone (generally 60 feet( around water within watershed areas. lake5, drainage canals, and areas around water or Aquatic uses: Use for emergent plants in ponds, measures. hardscape, decomposed granite and edging. OK for rennovations but must put in place weed prevention utility access, or fire prevention. Limit to 2% for or too dangerous for hand methods, right of ways, Terrestrial uses: Spot application of areas inaccessible sycamores. experimental basis for Anthracnose control on Oak Death control. When labelling permits, use on an to Sudden Oak Death, or in experiments For use on high-value oaks (Quercus spp.) susceptible USE UP REMAINING STOCK Presented at Commission on the Environment hearing, 1/28/14 d-Limoriene 60% hazardous isopropylamine salt More More (Tier III( hazardous Least Glyphosate, phosphite 45.8% Potassium . - public hearing (Tier II) sodecyl-omegahydroxy-phosphate control DISCONTINUING Use for late instar mosquito larvae and pupae, in combination with microbial products. (Tier lll( Least Limited ADDED CHANGED NONE CHANGED NONE Greenmatch Page 1 of 9 Requested as replacement for removed superfluous language. Added 2% limit on hardscapes, to Tier II (was Tier l( available. Updated tier ranking preferred alternatives Product being discontinued; toxicity( (was Tier I based on aquatic Updated tier ranking to Tier Ill hazardous Least (was Tier I based on aquatic tosicity( (Tier lll( Most Limited: 32% NONE Updated tier ranking to Tier III hazardous Least (was Tier I based on aquatic toxicity( justify use at - (was Tier I based on aquatic Updated tier ranking to Tier III Changed to flowable formulation. (Tier III( hazardous More other Substitute for wettable formulation of same product Updated tier ranking to Tier Ill NONE NONE NONE REMOVED ADDED Least For use on golf courses only. HIGH PRIORITY TO FIND ALTERNATIVE FIND ALTERNATIVE toxicity( Least limited Least Limited Least Limited Most limited: justify use at public hearing public hearing For use on Harding Park/Fleming golf courses only in preparation for tournament play. HIGH PRIORITY TO (Tier III( hazardous Least (Tier_liii hazardous hazardous (Tier I) Least Most (Tier I( ....t justify use at hazardous PoIy(oxy-1,2- Indoxacarb 0.6% Indoxacarb 0.5% lndoxacarb 0.05% lndoxacarb Most hazardous ethanediyl),alpha53263-30 352-652 352-668 352-746 352-664 /ydicusWVEC 108 Streptomyces Thiophanate-methyl 50% 42.5% Thiophanate-methyl (applicable to City-owned properties only( 2014 San Francisco Reduced-Risk Pesticide List Mosquito Insecticide Insecticide Insecticide Insecticide 73314-1 Fungicide Actinovate 1001-69 1001-63 Fungicide Fungicide 1 I 3336 WP Turf & Ornamental Fungicide (Cleary’s) (Clearys) 3336 F Fungicide ATTACHMENT A Various Insecticide Azatrol EC Insecticide insecticides (excluding 2935-50173 Adjuvant Insecticide Competitor Conserve SC Turf and Ornamental 62719-291 50025 [INACTIVE] Adjuvant 1D5077S- 70589-1 CMR Silicone Surfactant - Mosquito control BVA2 Mosquito other 65 626-8 [INACTIVE], 82074-1 [ACTIVE] Insecticide BotaniGard ES Larvicide 34704-50033 Adjuvant Bond Spreader-Sticker 009 Insecticide control) BestYet Cedarcide mosquito exemptprod- 2217-836 Insecticide Azatin XL Bacillus thuringiensis 7005 1-27 Insecticide ATEACHMENT A 3% I) - (Tier I) (mineral oil( Spinosad 11.6% Ethyl oleate Least Limited NONE NONE Least Limited CHANGED NONE NONE For use as a last resort in greenhouses. If feasible, alternate with other products to avoid the development of resistance. Use on high value ornamentals only. District( For use only at San Francisco International Airport properties (within San Mateo Mosquito Abatement Control of thrips on landscaped plants. Do not apply on flowering plants when bees are active. USE UP EXISTING STOCKS NONE CHANGED More Limited More Limited Least Limited Least Limited Least Limited Presented at Commission on the Environment hearing, 1/28/14 . More hazardous (Tier II) hazardous (Tier Ill) Least hazardous (Tier_III) Least Most hazardous Highly refined petroleum distillate Polymethyl siloxane, nonionic Least hazardous (Tier Ill) hazardous (Tier III) Least Beauveria bassiana strain GHA 11.3% aliphatic oxyalkylated alcohol 1D% 50%, primary carboxylated latex Synthetic (Tier III) hazardous - - 1GB” to other.” Page 2 of 9 “Mosquito control “Mosquito_control Added use limitations. Corrected Type from challenging product claims.” limitations, but FTC is to wide variety of products Removed language: “No Added generic B.t. listing due Least amorphous silica Cedarwood oil, . nurseries to greenhouses Corrected - Corrected “nurseries” to “greenhouses”. Added “Use up existing stocks Azatrol is safer alternative” available. ADDED CHANGED CHANGED (Tier III) when bees are active. interiorscapes. Do not apply on flowering plants For greenhouses and established plants for Azatrol is safer alternative. when bees are active. USE UP EXISTING STOCKS interiorscapes. Do not apply on flowering plants For greenhouses and estaL.ished plants for (various subspp.) Least Limited More Limited More Limited hazardous Least (Tier I) hazardous Most (Tier hazardous Most Bacillus thuringiensis 1.2% Azadirachtin (2328) Azadirachtin (applicable to City-owned properties only) 2014 San Francisco Reduced-Risk Pesticide List Potassium phoshate 68573-2 Fungicide Fosphite Fungicide NONE Only for use on golf courses. More Limited hazardous (Tier_III) Least CHANGED For use on golf greens for spot treatment. NONE CHANGED More Limited Least Limited USE UP EXISTING STOCKS. For use only in nurseries and on roses. CHANGED CHANGED NONE CHANGED NONE CHANGED hazardous (Tier I) Most Least hazardous (Tier Ill) More Limited Preferred alternative to Wasp Freeze but may not act quickly enough during late summer, when yellowjackets are most aggressive. Consider digging up nest and baiting with honey in evening to attract raccoons. Only for use on rat mites, bedbugs, lice, and yellowjackets in walls when nonchemical techniques prove ineffective. Presented at Commission on the Environment hearing, 1/28/14 Iron HEDTA 26.52% 67702-26 Herbicide oleate Fiesta Rosemary oil 10%, geraniol 5%, peppermint oil 2%, wtntergreeri oil, white mineral oil, vanillin, polyglyceryl 5-kinoprene 64.1% exemptprod 013 2724-476 More hazardous (Tier II) More hazardous (Tier II) Pyrethrins 0.4%, 2Phenethyl Propionate 1% 67425-16 More Limited Least Limited exem 007 Insecticide _______________ Insecticide Insecticide Insecticide - Least hazardous (Tier Ill) 2-phenethyl proprionate 2%, rosemary oil 3% Essentria lC3 Enstar II Insect Growth Regulator (Enstar SE) Insecticide EC0PCO DX Dust Killer Eco Exempt/Essentria Jet Wasp and Hornet d Least Limited Least hazardous (Tier Ill) White pepper 3%, white mineral oil 87%, silica 10% exemptprod 015 Mammal repellant Detour Least Limited More hazardous (Tier II) Fats & glyceridic oils margosa 65.8%, azadirachtin 0.7% 70310-5 Nematicide Debug Turbo Least Limited Least hazardous (Tier_Ill) Oil of black pepper 048% 50932-10 Mammal repellant Critter Ridder public hearing (Tier I) 0,005% Most Limited: justify use at Bromadiolone UP EXISTING HIGH r STOCKS. For use only inSan Francisco International Airport Terminal Areas, or for commercial lessees on city properties that are not adjacent to natural areas. In commercial establishments, use of product shall be a last resort after other, less-toxic measures have been implemented, including sanitation and trapping, and only where a significant public health hazard is recognized. In all cases, monitoring shall be used whenever feasible to minimize rodenticide use. (applicable to City-owned properties only) 2014 San Francisco Reduced-Risk Pesticide List Most hazardous 12455-79 Rodenticide Contrac All-Weather Blox AHACHMENT A - Page 3 of 9 Tier III) impurity in chelated iron. Added limitation. Corrected Tier ranking (was toxicity. Added “Use up existing stocks.” Updated tier ranking to Tier II (was Tier I) based on acute Added yellowjackets to limitations Brand name change from Eco Exempt to Essentria Updated tier ranking to Tier II (was Tier Ill) based on aquatic toxicity) Removed language: “City owned sewer lines’ No longer used in sewers. 73079-7 Fungicide Insecticide Heritage Fungicide Intice Thiquid Ant Bait iT Eaton Bait Block Rodenticide with Peanut Butter Flavorizer Organic Stylet Oil JMS Stylet Oil or JMS Insecticide Rodenticide Insecticide Insecticide 100-1093 Herbicide Habitat Javelin WG Biological 241-426 Herbicide Greenmatch EX 56-42 65564-1 70051-66 exemptprod- 2724-469 Insecticide Gentrol Point Source Roach Control Device 62719-527 Herbicide Garlon 4 Ultra ATTACHMENT A Most Limited: Most Least Limited Least hazardous More hazardous (Tier II) Most hazardous (Tier I) (Tier III) Least hazardous More Limited Least Limited Least Limited public hearing (Tier I) (Tier III) justify use at hazardous - REMOVED NONE See Site-Specific Limitations. For rat control only in situations with high public health concerns, where trapping is infeasible. In all cases, monitoring shall be used whenever feasible to minimize rodenticide use. HIGH_PRIORITY TO_FIND ALTERNATIVE. REMOVED ADDED CHANGED NONE REMOVED NONE NONE USE UP EXISTING STOCK. Consider soy or cariola oils instead. To be used only on high profile sports greens. WITH POLARIS Preferred alternative to triclopyr for use on invasive weeds in natural areas, such as broom, Cotoneaster, orArundograss. USE UP EXISTING STOCK REPLACE Not for use in enclosed areas. Observe label precautions on PPE. Use oni for targeted treatments of high prose or highly invasive exotics via dabbing or injection. May use for targeted spraying only when dabbing or injection are not feasible. Follow label requirements regarding exposure to mist. HIGH PRIORITYTO FIND ALTERNATIVE Presented at Commission on the Environment hearing, 1/28/14 Diphacinone 0.005% kurstaki. strain sa11 7.5% Petroleum distillates, refined 97.1% BociIlus thurinqiensis (berliner), subsp. Borax, 5% Azoxystrobin 50% More Limited More hazardous (Tier Ill Imazapyr, isopropylamine salt, 28% More Limited More hazardous (Tier II) l.emongrass oil 50%, other ingredients (corn oil, glycerol esters, potassium oleate, lecithin) Least Limited Most Limited: justify use at public hearing Least hazardous (Tier III) Most hazardous (Tier I) Hydroprene 96% Triclopyr, butoxyethyl ester 6045% (applicable to City-owned properties only) 2014 San Francisco Reduced-Risk Pesticide List Page 4 of 9 thuring,ensis products See genenc lIsting for Bacillus Liquid Ant Bait discontinued Need liquid ant bait; Advance Removed redundant language: “Consider/emphasize use of compost tea for preventative; Improve aeration and monitoring programs. “ and “spot treatment.” Spot treatment inadequately defined. Discontinued Mosquito control microbial Milestone - Control Roach Bait Stations Maxforce FC Professional Insect Control Roach Killer Bait Gel Professional Insect Maxforce FC Control Ant Bait Stations Professional Insect Maxforce FC Maxforce FC Magnum Roach Killer Bait Gel & Nursery Insecticide Marathon 1% Granular Greenhouse Bacillus thuringiensis 62719-519 Herbicide - microbial control Various Least Aminopyralid, triisopropanolamine salt (5928) 40.6% Mosquito More hazardous (Tier II) Fipronil 0.01% 432-1259 )Tier Ill) Israelensis) or Least Limited Most Limited: justify use at public hearing More Limited More Limited More Limited More Limited public hearing Most Limited: justify use at More Limited Least limited. Any microbial mosquito larvicide with active ingredients Bacillus thuringiensis (Berliner or Israelensis( or Bacillus sphaericus is categorized as For invasive species in natural areas where other alternatives are ineffective, especially for invasive legumes and composites such as yellow star thistle and purple star thistle. exposure Not for use in outdoor areas with potential rain exposure Not for use in outdoor areas with potential rain exposure Not for use In outdoor areas with potential rain exposure Not for use in outdoor areas with potential rain plants. HIGH PRIORITY TO FIND ALTERNATIVE Nursery use for control of white fly, not for use in propagation beds, Only effective on quick-growing Bees. Nursery, specialty gardens, and Africanized Honey Presented at Commission on the Environment hearing, 1/28/14 Bacillus sphaericus hazardous (Berliner or (Tier II) hazardous More (Tier II) Insecticide hazardous More hazardous (Tier II) More (Tier II) More hazardous Most hazardous (Tier I) Least hazardous (Tier Ill( Fipronil 0.05% Fipronil 0.01% Fipronil 0.05% Imidacloprid 1% Potash soap 49% preparation for tournament play For use on Harding Park/Fleming golf courses only in More Limited More Clopyralid, 409% hazardous (Tier II) Watch for phytotosicity. Least Limited Least hazardous (Tier Ill) Potassium bicarbonate 82% 432-1257 432-1256 432- 1460 (ACTIVE( 432-1329 3125-452-AA (INACTIVE) 62719-515 62719-305 11581-2 (AcTIVE)4 (INACTIVE) (applicable to City-owned properties only) 2014 San Francisco Reduced-Risk Pesticide List Insecticide Insecticide Insecticide Insecticide Insecticide Herbicide Lontrel Turf and Ornamental Herbicide M-pede Insecticide/Fungicide Fungicide Kaligreen ATTACHMENT A NONE CHANGED CHANGED CHANGED CHANGED ADDED NONE NONE ADDED REMOVED PageS of 9 Corrected language; “Listed as Tier I due to persistence but toxicity & potential exposure are very low,” Limited.” hearing; changed to “More Added limitation per public Limited.” Added limitation per public hearing; changed to ‘More Added limitation per public hearing; changed to “More Limited.’ Limited.” extreme roach infestations. Added limitation per public hearing; changed to “More Need extra bait option for Turflon Ester Added as safer alternative to Not being used - lGRs Perma-Dust Prescription More hazardous (Tier II) hazardous (Tier Ill) Least - Least hazardous (Tier III) Least hazardous (Tier_Ill) More hazardous (Tier II) More Limited Least Limited More Limited Most Limited: justify use at public hearing Least Limited Use in situations where adhesion of dust is important and non-aerosol boric acid products are ineffective. For use with Agrifos only For use only on airport operational areas subject to FAA requirements. HIGH PRIORITY TO FIND ALTERNATIVE - Soap spray is preferred for removing ant trails. Minimize use in enclosed areas due to scent. Wear protective equipment. Potential aquatic hazard do not apply directly to water. Presented at Commission on the Environment hearing, 1/28/14 499-384 Insecticide Treatment Brand Boric acid 35%, petroleum distillateshydrotreated light 10%, HFC-134A, 1,1 difluoroethane 499-491 Prescription Treatment Brand 381B Advance Liquid Ant Bait Insecticide Pentrabark Polyalkyleneoxide modified heptamethyltrisilox ane methyl 753’s Sodium Tetraborate Decahydrate 1.3% 83416-50001 Adjuvant (Dupont) 352-601 Herbicide Oust XP Herbicide Sulfometuron Sesame oil 5% exemptprod 010 Insecticide Organocide More Limited D-limonene 5.8% 61887-1 Insecticide More hazardous (Tier II) Orange Guard Least Limited Least hazardous (Tier_llI( Sodium lauryl sulfate exemptprod002 Insecticide More Limited More hazardous (Tier II) OhYeah? Herbicide Nufarm Polaris Preferred alternative to triclopyr for use on invasive weeds in natural areas, such as broom, Cotoneaster, or Arundograss. Outdoor restricted to planted areas, prefer containers; indoor must be in containers or inaccessible to humans. USE UP EXISTING STOCKS Least Limited Least hazardous (Tier Ill) Boric acid 5% Imazapyr, isopropylamine salt, 28% 64405-2-AA Use or tanks with limited access, or other areas where frequent treatments are infeasible. For City catchment basins, microbial products are preferred. Not for use in estuarine environments except under control of San Mateo Mosquito Abatement District. Least hazardous (Tier III) S-Methoprene (5026 228-534 Insecticide control (applicable to City-owned properties only) 2014 San Francisco Reduced-Risk Pesticide List Herbicide Bait) Multipurpose Insect (equivalent to Terro Niban Granular Bait - ..__,jito control products lGRs AUACHMENT A NONE REMOVED NONE NONE NONE NONE NONE CHANGED NONE Discontinued - Page 6 of 9 Corrected language by removing: “USE UP EXISTING STOCK REPLACE WITH POLARIS’ - any very similar mosquito control products with same active ingredient condensed to one entry. More Limited Least Limited More hazardous (Tier II) More hazardous (Tier_II) Least hazardous (Tier Ill) Glyphosate, isopropylamine salt 48.7% Penoxsutam Coyote urine 5%, limestone 95% Least Limited More Limited More hazardous (Tier II) More hazardous (Tier II) Soybean oil Imazapyr, isopropylamine salt 28% 65328-50001 241-398 Molluscicide Insecticide Herbicide Sluggo Slug and Snail Bait Spraytech Oil Stalker herbicide For invasive species in natural areas where other alternatives are ineffective, especially for invasive legumes and composites such as yellow star thistle and purple star thistle. Only use on City-owned golf courses in preparation for major golf tournaments. decomposed granite and edging only as last resort. OK for rennovations but must put in place weed prevention measures. Note prohibition on use within buffer zone (generally 60 feet) around water bodies in red-legged_frog_habitat. last resort. OK for renovations but must put in place weed prevention measures. Note prohibition on use within buffer zone (generally 60 feet) around water bodies in red-legged frog habitat. Use of Aquamaster + Competitor is preferred except in situations where rainfastness is needed. Spot application of areas inaccessible or too dangerous for hand methods, right of ways, utility access, or fire prevention, Use 2% dilution for cracks in hardscape, - USE UP EXISTING STOCK FOR REMOVAL IN 2013. Spot application of areas inaccessible or too dangerous for hand methods, right of ways, utility access, or fire prevention. Use for cracks in hardscape, decompOsed granite and edging only as Use Only when a concern for public safety, and in situations where use of Ecotsempt product is inadequate or unsafe. Presented at Commission on the Environment hearing, 1/28/14 Least Limited Least hazardous (Tier lll( Phosphoric acid, iron(3+( salt (1:1) 1% 67702-3 Mammal repellant Shake-Away Coyote Urine Repellant Granules esemptprod014 62719-547 Herbicide Herbicide More Limited (Tier II) 41% More Limited More Limited More hazardous - Most hazardous (Tier 1) Glyphosate, isopropylamine salt ‘ Phenothrin 12%, dtrans allethrin .129%, C02 Sapphire 524-475 499-362 524-579 Herbicide Insecticide (applicable to City-owned properties only) 2014 San Francisco Reduced-Risk Pesticide List Herbicide Roundup Promax Herbicide Roundup Pro Prescription Treatment Brand Wasp-Freeze Wasp and Hornet Killer Formula 1 ATtACHMENT A NONE CHANGED NONE NDNE NONE CHANGED REMOVED NONE Page 7 of 9 Removed language: “Consider using this instead of JMS Stylet Oil for aphids and other insects.” Updated tier ranking (was Tier lll( due to signal word. hardscape5 Added 2% limitation for use in products Replaced by other glyphosate Mosquito control lGRs Zoecon Altosid Pellets, Zoecon Altosid Pellets WSP - - 2724-448 5-Methoprene (5026) 4.25% Not for use in estuarine environments except under control of San Mateo Mosquito Abatement District. Presented at Commission on the Environment hearing, 1/28/14 (Tier Ill) Page 8 of 9 growth regulators) mosquito control IGRs (insect Replaced by generic listing for catchment basins, microbial products are preferred. REMOVED where frequent treatments are infeasible. For City More Limited Least hazardous Replaced by generic listing for mosquito control IGR5 (insect Replaced by generic listing for mosquito control IGR5 (insect growth regulators) Need safer alternatives to 3336 fungicide for resistance management Removed: “broadcast application requires exemption.” Definition of broadcast is unclear, and exemptions always required for variances. growth regulators( REMOVED REMOVED CHANGED ADDED NONE NONE Not for use in estuarine environments except under control of San Mateo Mosquito Abatement District. Use for tanks with limited access, or other areas Use for tanks with limited access, or other areas where frequent treatments are infeasible. For City catchment basins, microbial products are preferred. Not for use in estuarine environments except under control of San Mateo Mosquito Abatement District. Use for tanks with limited access, or other areas where frequent treatments are infeasible, For City catchment basins, microbial products are preferred. - Targeted treatment of turf. HIGH PRIORITY TO FIND ALTERNATIVE. Note prohibition on use within buffer zone (generally 60 feet) around water bodies in redlegged frog habitat Lake Merced, Golden Gate Park. For use on Harding Park/Fleming golf courses only in preparation for tournament play For use only on golf courses in preparation for tournament play. For use only in City-owned sewer lines, San Francisco International Airport Terminal Areas, or for commercial lessees on city properties that are not adjacent to natural areas. In commercial establishments, use of product shall be a last resort after other, less-toxic measures have been implemented, including sanitation and trapping, and only where a significant public health hazard is recognized. In all cases, monitoring shall be used whenever feasible to minimize rodenticide use. NONE (Tier Ill) More Limited Mosquito control IGRs Zoecon Altosid Uquid Larvicide Mosquito Growth Regulator Least hazardous 5-Methoprene (5026) 8.62% 2724-375 Mosquito control IGRs Zoecon Altosid Briquets 5-Methoprene (5026)5% More Limited Least hazardous (Tier Ill) Turflon Ester 2724-392 Most Limited: justify use at public hearing Most hazardous (Tier I) Triclopyr, butoxyethyl ester 61.6% 62719-258 Herbicide - More Limited More hazardous (Tier II( Triticonazole, 30.1% 432-1487 Fungicide - hazardous (Tier II) More Limited public hearing (Tier I) More Most Limited: justify use at Least Limited Most hazardous Least hazardous (Tier III) Paclobutrazol 22.3% Bromethalin 0.01% ‘‘° Sodium tetraborate decahydrate 100-1014 67517-66 149-8 Growth regulator Rodenticide Insecticide (applicable to City-owned properties only( 2014 San Francisco Reduced-Risk Pesticide List Growth Regulator for Turfgrass Triton Flo (Chipco) Trimmit 2SC Plant Top Gun All Weather Bait Block Rodenticide PCO Liquid Ant Bait Terro Ant Killer Terro Ant Killer U Liquid Ant Baits, Terro A1TACHMENT A - Mosquito contro) IGRs Zoecon Altosid XR-G, Zoecon Altosid Pro-G Insect Growth Regulator - Mosquito control lGRs Zoecon Altosid XR Extended Residual Briquets AUACHMENT A 2724-451 2724-421 S-Methoprene (5026) 1.5% S-Methoprene (5026) 2.1% More limited More Limited Use for tanks wih limited access, or other areas where frequent treatments are infeasible. For City catchment basins, microbial products are preferred. Not for use in estuarine environments except under control of San Mateo Mosquito Abatement District. lice for tanks with limited access, or other areas where frequent treatments are infeasible. For City catchment basins, microbial products are preferred. Not for use in estuarine environments except under control of San Mateo Mosquito Abatement District. Presented at Commission on the Environment hearing, 1/28/14 Least hazardous (Tier Ill) Least hazardous (Tier Ill) (applicable to City-owned properties only) 2014 San Francisco Reduced-Risk Pesticide List REMOVED REMOVED Page 9 of 9 Replaced by generic listing for mosquito control lGRs (insect growth regulators) Replaced by generic listing for mosquito control lGRs (insect growth regulators) ATTACHMENT B Summary of 2014 Reduced Risk Pesticide List Table 1. Summary of changes to the 2014 Reduced Risk Pesticide List # Products: ADDED REMOVED CHANGED NO CHANGE Total Least hazardous More hazardous 3 8 2 24 37 Most hazardous 4 2 12 9 27 Total 1 2 7 4 14 8 12 21 37 78 Table 2. Types of Products on the 2014 Reduced Risk Pesticide List Least More Most hazardous hazardous hazardous (Tier Ill) (Tier II) (Tier I) GENERAL GOLF VECTOR CONTROL Total 26 1 2 37 20 3 3 27 7 3 3 14 Total 53 7 8 78 Table 3. Categories of Products on the 2014 Reduced Risk Pesticide List Least hazardous (Tier Ill) Adjuvant Fungicide Growth regulator Herbicide Insecticide Mammal repellant Molluscicide Mosquito control lGRs Mosquito control microbial Mosquito control other Nematicide Rodenticide Total - - 4 4 18 3 1 1 1 - 32 More hazardous (Tier II) 1 1 12 10 1 1 1 27 Most hazardous (Tier I) Total 3 3 5 1 2 14 4 8 1 15 33 3 1 1 1 2 1 3 73 ATTACHMENT C Summary of Pesticide Use Trends, 1996 — 2012 All amounts are pounds of active ingredient, combined solid and liquid measures. Fig. 1 Citywide pesticide use, total pounds of active ingredient. Herbicides z LU 3000 Health Insecticides Total Pesticides -no public health (active ingredients) U LU 2000 LU > IC) < 1000 (1) -J 0 I I (0 0) 0) N0) 0) - - I CO CT) 0) I 0) 0) 0) I C C C (N I . C C (N I (N C C (‘sJ I C) C C (N I C C (N I Lf) C C C’] I (0 C C C’] I NC C (N I I CO C C C’] 0) C C C’] C’] C ‘ C C’] C C’] C c.i Figure 2. Citywide pesticide use, total pounds of active ingredient, by hazard tier. Excludes public health treatments. 3000 Tier I Pesticides z LU 2500 2000 1500 1000 I— 500 (I) -J 0 —Tier II Pesticides Tier III PesIicides ATTACHMENT C Table 1. Ranked use of Tier! (highest hazard) pesticides, 2010-12 Product 3336 F 3336 WP TURF PROSTAR 70 WDG FUNGICIDE TURFLON ESTER HERBICIDE RIVERDALE VANQUISH HERBICIDE GARLON 4ULTRA VANQUISH HERBICIDE HERITAGE FUNGICIDE TURFLON ESTER ULTRA PRIMO MAXX ANDERSONS GOLF PRODUCTS K-O-G WEED CONTROL CORETECT TREE AND SHRUB TABLETS INSECTICIDE CONCERN FROM THE EARTH, FOR THE EARTH DIATOMACEOUS EARTH CRAV CONSERVE SC TURF AND ORNAMENTAL MARATHON 1% GRANULAR GREENHOUSE AND NURSERY INSECTICIDE GREEN LIGHT ROSE DEFENSE QUICKSILVER T&O HERBICIDE AVID 0.15EC MITICIDE/INSECTICIDE MAXFORCE PROFESSIONAL INSECT CONTROL GRANULAR INSECT BAIT MAXFORCE PROFESSIONAL INSECT CONTROL ANT KILLER BAIT STATIONS MAXFORCE PROFESSIONAL INSECT CONTROL ANT KILLER GRANULAR BAIT MAXFORCE FC PROFESSIONAL INSECT CONTROL ROACH BAIT STATIONS MAXFORCE FC PROFESSIONAL INSECT CONTROL ROACH KILLER BAIT GEL SAPPHIRE Total 2010 141.61 104.50 66.71 34.71 11.76 29.81 4.86 0.50 0.48 0.28 0.06 0.01 0.02 0.00 0.00 0.00 2011 387.76 4.06 58.80 13.12 8.37 0.08 7.88 0.75 0.11 0.07 0.02 0.01 395.29 r 481.02’ 2012 Total 38.42 567.78 108.56 11.76 70.56 66.71 47.83 23.03 43.16 29.89 1.40 14.14 1.89 1.14 0.50 0.48 0.39 0.33 0.27 0.01 0.09 0.00 0.04 0.03 0.03 0.02 0.02 0.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 76.08’ 952.40 Use GOLF GOLF GOLF GOLF GOLF GENERAL GOLF GOLF GOLF GOLF GOLF GENERAL GENERAL GENERAL GENERAL GENERAL GOLF GENERAL GENERAL GENERAL GENERAL GENERAL GENERAL GENERAL Figure 3. Dept. of Recreation & Parks usage of all pesticides, 2010-2012 (not including public health treatments) GG PARK GOLF NATURAL AREAS J PARKS, FACILITIES GG PARK GOLF NATURAL AREAS PARKS, FACILITIES Total 2010 9.49% 80.70% 3.16% 6.64% 2011 25.03% 52.02% 9.53% 13.42% 100.00% 2012 9.64% 78.06% 4.0 1% 8.28% 100.00% Total 6.37% 80.61 % 3.84% 9.18% 100.00% ATTACHMENT C Figure 4. Natural Areas Program (Dept. of Recreation & Parks) use trends of four herbicides 16 12 AMINOPYRALIU 8 GLYPHOSATE MAZAPYR 4. +TRICLOPYR 2002 -4 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 73079-7 1245500079 62719-537 lntice Thiquid Contrac Bloc_____ Milestone VM Tronsline SFGH Port PUC-WST PIJC-WST Ants Cloth moths Major ant infestation. Advance Liquid Ant Bait is no longer available for purchase/use. The museum has priceless collections that are at lsk to damage from the clothes moths. Least hazardous (Tier Ill) Least hazardous (Tier Ill) - Page 1 015 * Rodenticide to be used as a last resort in exterior anchored bait stations (Bell Protecto Sidekick bait boxes(. Trapping stations have not been effective for controlling the population. A restaurant facility is located on the pier with zero tolerance to pests. City staff has been monitoring the situation since As noted on exemption request. Not to August 2012. As of January 2013, nightly sightings Most Behind Pier 3 hazardous be used on other properties without are being reported. DPH has declared this an Buildings and at exempiion. (Tier I) “imminent health hazard.” the Rear of Pier rats I Target new infestations or periphery of existing infestations to prevent spread. Limit treatment area to —5 acres. Note Purple Star thistle is a Class B rated weed. Both the label restrictions on grazing sprayed size of infested areas and its spread is having an area pesticide may make the impact on the established grasslands and the poisonous weeds more palatable. ability to provide healthy forage. Good land Note that this product may kill any stewardship requires us to maintain our watershed broadleaf species, and should not be in a sustainable fashion and the control of this used in areas with valuable or endemic invasive weed is needed to maintain the quality Purple Rolling species. ecosystem. and lands of our foraged Starthistle Rangeland Approximately 100 acres of yellow starthistle and at this point the need to treat and gain control is emminant. Once control of weed stands and number of data paints is controld other methods Yellow Starthistle/ of 1PM may be employed...336 data points as of More Arctichoke 2008 To be used as an aid in the control of hazardous Limit to high priority treatment areas to data Thistle class Arctichoke thistle...Rated Class B weed Rolling hills of (Tierll( limit spread of infestations. watershed b weed points as of 2008 Avon Building under exfbits. In voids spaces Hazard Tier Llmltatiofl4?o”EE) 1/6/14 For lull details in real time, see: https://sfetoxicsreduction.wufoo.com/reports/pesticide-exemptions-approved-/ 1627 19-259 Exempt Essentria D Asian Art Museum Justification for Use (from applicant) Exemptions granted to the 2013 Reduced-Risk Pesticide List Detailed Location EPA Req # for Pesticide Use Pest Product Name SF City Dept. ATTACHMENT D Fungus Gnats Ground squirrels causing damage to stockponds lending to possible failure, activity in and around corrals possible injury to cattle, dam face intgrity control and limited roadside undermining. All instances need to be addressed to prevent ongoing damage and protect resources. Fungus gnats are common occurrence in office settings. The best long term approach is soil management/repotting. and water management, i.e. letting the soil dry before re watering. This product is new to us and may provide a biological control option that can provide faster results meanwhile education and repotting can occur. Justification for Use (from applicant) — ‘ , - Page 2 of 5 Least hazardous (Tier lll( Only for use in bait station trials at specified locations as described. Must collect data on effectiveness open burrows, timed sitings, or other metric, More for consideration in future efforts. Follow hazardous endangered species restrictions (Tier II) carefully. I Hazard Tier UmItatiofls’(fröm:SFE) 1/6/14 For full details in real time, see: https://sfetoxicsreductian.wufaa.com/reports/pesticide-exemptions-approved-/ 73049-56 6th floor, indoor potted plants PUC-WST Gnatral Real Estate WDG San Antonio Watershed Un named stock pond dam face on the north side of the Stone Cabin Road, Parcel SA-1 Livestock confinement\pr ocessing facility at the McDonald Cabin, Parcel SA‘ 1 Calaveras Watershed Rodent Bait Binder Pond Diphacinon dam face and e treated Grain SLN NO. Ispillway on Oak Ground squirrels (005%) Ca 890020 Ridge R Detailed Location EPA Req # for Pesticide Use Pest Product Name Dept Exemptions granted to the 2013 Reduced-Risk Pesticide List SF City ATTACHMENT D 100-937 Primo Maxx RPD Harding Park Golf Course Putting Greens Harding Park Golf Course Putting Greens The existing moss population on the putting green surfaces has resulted in undesirable playing conditions. Hand removal is not a practical or an Silvery effective solution. The moss has persisted even though the growing conditions have been altered Thread to discourage its growth. Moss The Primo Maxx would be used in conjunction with Trimmit 2SC to suppress Poa annua growth and minimize seed head production. It will also help promote the vigor and health of the desired bentgrass to achieve a smoother putting green surface in preparation for the Charles Schwab Poo annua Tournament. Page 3 of 5 Most hazardous (Tier l( - Follow label directions on PPE although the active ingredient is fairly benign, the inerts’ are quite hazardous. Most To be used only as a last resort in cases hazardous where plugging and fertilization (Tier l( regimes_have proven ineffective. For use only in Soliva infested areas of Harding Park where hand weeding or other nonchemical techniques are not possible. This exemption is intended as a special clean up’ of weed populations that have built up over the More hazardous years, and will not be granted on an annuc basis. (Tier ll( More hazardous Experimental use by UCR personnel as (Tier II) described. HazardTiöi tiitiomSFE) 1/6/14 For full details in real time, see: https://sfetoxicsreduction.wufoo.com/reports/pesticide-exemptions-approved-/ 279-3265 Quicksilver RPD 627 19-3O5Roughs Lontrel - Golf Course Fairways and RPD Fleming Golf Greens #6 and #8 N/A i Methiozolin will be used on an experimental basis only. This product is currently in the process of becoming registered for California use. Currently, ongoing trials are being conducted at golf courses throughout the State and the putting greens on the Fleming Golf Course are ideal for these trials due there make up of 1 :1 Poa annua / Agrostis palustris ratio. It is anticipated that this will eliminate the Poa annua infestations product completely on the putting greens. Thus the desired level of tournament playability would be more practically achieved by leaving only the ‘desired Creeping Bentgrass on the putting Poa annua surface. The playable conditions in various sections of the golf course (fairways and roughs) are at unacceptable levels due to high populations of Soliva spp. The current approved broadleaf herbicides are only partially effective on the control of Saliva spp. Handpicking in conjunction Broadleaf :with the approved herbicides cannot keep up with the encroachment of the Soliva spp. WeedsSoh’vaspp. population. Justification for Use (from applicant) Exemptions granted to the 2013 Reduced-Risk Pesticide List Detailed Location EPA Req # for Pesticide Use RPD Product Methiozalin e SF City Dept. ATTACHMENT D Frog (Xenopus 4Iaevis) Clawed Frog and invasive More hazardous Only as described for tournament (Tier II) hazardous since dollar spot is something that takes (Tier ii) ‘off fast. 1/6/14 For full details in real time, see: https://sfetoxicsreduction .wufoo.com/reporls/pesticide-exemptions-approved-/ 100-937 Primo RPD Harding Park Golf Course Fairways pink snow mold. Normal mowing rates cannot keep up with the current growth rate of the fairway turf grass. This is ‘due to excess nitrogen coming from the recycled water irrigation. Consequently, an overabundance of grass clippings is generated. The clumps of grass clippings are suffocating the healthy turf underneafh. Also, tournament playability is significantly impacted when comparing morning/afternoon ball travel distances. (USGA/PGA tournament rules don’t allow for any kind of maintenance while players Poa annua are on the course competing) Diseases i 41-398 Stalker RPD ‘ The trails are in natural areas I More where public hazardous Only for use on poison oak as described access is also The poison oak presents a public health threat, in areas of high public contact, 4oison Oak The goal is to give public access to these areas,jierNL present 432-1487 various fungal diseases, such as dollar spot and TrOonFLO Fungal RPD More On 7/11/13, Chris approved this exemption by email on the condition that additional outbreaks are observed, Harding Park Golf Course final phase of the integrated plan for the :eradicahon of the frog. Significantly reducing the possibility of disease resistance isa high priority. This product is in a separate family of fungicides than Cleary’s 3336. It would be alternated with Cleary’s 3336 to treat Recommendation by Fish and Game for eradication of the African Clawed Frog. This is the African Clawed Most hazardous See supporting documents I) Hazard Tier Llmltatkns (from SFE) spedes 655-899 Habitat restoration project of lake by Presidio Trust. invasive arp Restoration of Mt. Lake Disinfection of Lilly Pond for control of African Justification for Use (from applicant) 10897-4 HASA Sani- CFT Legumine Presidio Trust Detailed Location EPA Req # for Pesticide Use Pest Page 4 of 5 jClor , Product Name Exemptions granted to the 2013 Reduced-Risk Pesticide List RPD RPD SF City Dept. A1TACHMENT D 100-1448 Medallion SC Fiesta RPD RPD Page 5015 hazardous (Tier_Ill) Least Most Only for use at Harding Park golf course hazardous in preparation for tournament play as (Tier I) described. Most hazardous As described above: Only for Marina (Tier I) Green rennovation Hazard Tier: LimitationS (from SFEf 1/6/14 For full details in realtime, see: https://sfetoxicsreduction.wufoo.com/reports/pesticide-exemptions-approved-/ 67702-2687865 627 19-258 Due to mowing and the way that Arctotheca propagates vegetativly it will spread into the newly planted areas of turf. This is a $500k turf Arctotheca restoration project that will most likely be rapidly calendula, be reinfested with broadleaf weeds if this The western 1/3 and other application is not done. There is not an effective of the Marina broadleaf alternative product to remove Arctotheca from weeds Greens turf. There is active pink snow mold disease present on : the putting greens and the environmental conditions are ideal for its growth right now. We have a PGA golf tournament starting this week and this disease could cause further damage to IHarding Park Pink Snow Golf Course the putting surfaces which would negatively Mold_____ impact playability. Greens New turf was installed on 2/3 of the Marina Green I the remaining 1/3 has braodleaf weeds that will spread to new turf if not treated. Fiesta is a less Targeted area environmentally impactful product than Turflon treatment for the and will be used as a follow up of the initial broadleaf weeds broadleaf treatment at the request of the Golf and Turf Mgr. weeds Steve_Castile. in_turf Justification for Use (from applicant) Exemptions granted to the 2013 Reduced-Risk Pesticide List Detailed Location EPA Req # for Pesticide use Pest Turflon I I Product Name RPD SF City Dept. ATTACHMENT D
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