Appendices Appendix I: International Abbreviations for Polymers and Polymer Processing AA AAS, ASA ABA ABM ABMA ABR ABS ABSM ABSMA ABS-MA ABVC ACM ACM ACPES ACRYL ACS ACS, ACPES AEM AES AF Acrylic acid (monomer) Copolymer of acrylonitrile, acrylate (ester), and styrene Acrylonitrile-butadiene-acrylate copolymer Copolymer of acrylonitrile-butadiene-methyl acrylate Copolymer of acrylonitrile-butadiene-methacrylic acid Elastomeric copolymer from an acrylate (ester) and butadiene, a rubber Thermoplastic terpolymer, an acrylonitrile-butadiene-styrene copolymer Graft copolymer of acrylonitrile-butadiene-styrene-methyl methacrylate Graft copolymer of acrylonitrile-butadiene-styrene-maleic anhydride Maleated acrylonitrile-butadiene-styrene copolymer Thermoplastic terpolymer, an acrylonitrile-butadiene-vinyl chloride copolymer Acrylate rubber, based on ethyl acrylate with other acrylics Acrylic elastomer, e.g., alkyl acrylate-2-chloroethyl vinyl ether copolymer Acrylonitrile-chlorinated polyethylene-styrene copolymer Poly- or copoly-methyl methacrylate (acrylic) Thermoplastic blend of acrylonitrile-styrene-chlorinated PE terpolymer Acrylonitrile-chlorinated polyethylene-styrene copolymer Elastomeric ethyl (or other) acrylate-ethylene copolymer Terpolymer from acrylonitrile, ethylene-propylene elastomer, and styrene Aniline-formaldehyde molding resins L.A. Utracki, C.A. Wilkie (eds.), Polymer Blends Handbook, DOI 10.1007/978-94-007-6064-6, # Springer Science+Business Media Dordrecht 2014 2155 2156 AFMU AK AMAB AMC AMMA AMS AN ANM AP, APR APET aPP aPP AR ARP AS ASA, AAS ASR AU BA, PBA BAAN BAMM BFE BIIR BMC BMI BMMM BOPP BP, BR BPA bPC BR Bu-ABS Appendix I: International Abbreviations for Polymers and Polymer Processing Terpolymer of tetrafluoroethylene, trifluoro-nitrosomethane, and nitrosoperfluorobutyric acid Alkyd resin Copolymer from acrylonitrile, methyl acrylate, and butadiene rubber Alkyd molding compound Thermoplastic copolymer from acrylonitrile and methyl methacrylate a-Methyl styrene Acrylonitrile Acrylate rubber, based on ethyl acrylate with acrylonitrile Elastomeric ethylene-propylene-diene copolymer, now EPDM Amorphous polyethyleneterephthalate Amorphous polypropylene Atactic PP Elastomeric copolymer from acrylates and olefins Polyarylterephthalate liquid crystal copolymers, also PAT Acrylonitrile-styrene copolymer (see also SAN) Thermoplastic copolymer from acrylonitrile, styrene, and acrylates Alkylene sulfide rubber Elastomeric polyester or polyurethane with polyester segments Polybutylacrylate (incorrectly used for acrylic elastomer, ACM) Butyl acrylate-acrylonitrile copolymer Butyl acrylate-methyl methacrylate copolymer Bromotrifluoroethylene polymers Brominated elastomer from isobutene and isoprene, bromobutyl rubber Bulk molding compound (UP resins) Bismaleimide Butyl methacrylate-methyl methacrylate copolymer Biaxially oriented polypropylene film Polybutadiene or an isobutene-isoprene copolymer, butyl or butadiene rubber Bisphenol-A Branched polycarbonate of bisphenol-A Butadiene rubber Graft copolymer of butylacrylate and triallyl isocyanurate on polybutadiene, in turn emulsion grafted with styrene and acrylonitrile Appendix I: International Abbreviations for Polymers and Polymer Processing CA CAB CAN CAP CB CBR CDB CE CEM CF CFM CHR CIIR CM CMC CMHEC CMPS CN CNR CO COP CO-PAI COPE CO-PI COPO COX CP CP2 CP4 CPE CPET CPI CPVC CR CRM CRP CS 2157 Cellulose acetate Cellulose acetate-butyrate Cellulose acetate-nitrate Cellulose acetate-propionate Cellulose butyrate (also carbon black reinforcing pigment) Chlorinated butadiene rubber Conjugated diene butyl elastomer Cellulose plastics in general Polychlorotrifluoroethylene (also CFM, CTFEP, PCTFE) Cresol-formaldehyde resins (also reinforcing carbon fiber) Polychlorotrifluoroethylene (also CEM, CTFEP, PCTFE) Elastomeric copolymer from epichlorohydrin and ethylene oxide Post chlorinated elastomeric copolymer from isobutene and isoprene Chloro-polyethylene (also compression molding) Carboxymethyl cellulose (or critical micelle concentration) Carboxymethyl hydroxyethyl cellulose Poly(chloromethyl styrene) Cellulose nitrate (celluloid) Elastomeric terpolymer from tetrafluoroethylene, trifluoronitrosomethane, and a small amount of an unsaturated monomer, e.g., nitrosoperfluorobutyric acid and nitroso or carboxy nitroso rubber Polychloromethyl oxirane elastomer, epichlorohydrin rubber Cycloolefin polymers or copolymers Copolyamideimide Copolyester elastomer Copolyimide Poly(carbon monoxide-co- polyolefin), a linear, alternating terpolymer: ethylene-co- propylene-co-carbon monoxide Carboxylic rubber Cellulose propionate, or chlorinated polyethylene, also CPE Alternating copolymer from vinyl ether and maleic acid Copolymer from acrylic acid and maleic acid Chlorinated polyethylene Crystallizable (or chlorinated) polyethyleneterephthalate cis-Polyisoprene, also IR Chlorinated polyvinyl chloride Chloroprene, or neoprene, rubber Chlorosulfonated polyethylene Carbon fiber reinforced plastics Casein 2158 Appendix I: International Abbreviations for Polymers and Polymer Processing CSM, CSPE CSR CT, CTA CTBN CTFE CTFEP CUT CV DAC DAF DAIP DAP DCA DMA DMC DMF DMSO DSC E/B E/P EAA EAM EBA EBA-AA EBA-GMA EBA-MA EBM EC ECA ECB ECO, CO ECPE ECTF, ECTFE EEA EEAAA EEA-GMA EGMA EHEC ELAST EMA EMAc Chlorosulfonated polyethylene, also CSPE or CSR Chlorosulfonated polyethylene (also CSPE or CSM) Cellulose triacetate Carboxy-terminated nitrile rubber Polychlorotrifluoroethylene Polychlorotrifluoroethylene (also CFM, CEM, PCTFE) Continuous use temperature Viscose, also VI Diallylchlorendate Diallylfumarate Diallylisophthalate Diallylphthalate Dichloroacetic acid Dynamic mechanical analysis Dough molding compound N,N-dimethylformamide (solvent, also DMT) Dimethyl sulfoxide (solvent) Differential scanning calorimetry Copolymers of ethylene and 1-butene Ethylene-propylene copolymer EA Ethylene acrylic acid copolymer Elastomeric copolymer of ethylene and vinyl acetate Ethylene-butyl acrylate copolymer Ethylene-butyl acrylate-acrylic acid copolymer Ethylene-butyl acrylate-glycidyl methacrylate copolymer Ethylene (50–90 parts)-co-butyl acrylate (5 to 49 parts)-comaleic anhydride (0.5 to 10 parts) copolymer Extrusion blow molding Ethyl cellulose Ethylene-carbonate copolymer Blends from ethylene copolymers with bitumen Elastomeric copolymer from ethylene oxide and epichlorohydrin (also EO-ECH) Extended chain polyethylene Poly(ethylene-co-chlorotrifluoroethylene) Elastomeric copolymer from ethylene and ethyl acrylate Polyethylene grafted with ethyl acrylate and acrylic acid Ethylene-ethyl acrylate-glycidyl methacrylate copolymer Ethylene-glycidyl methacrylate copolymer Hydroxyethyl cellulose Elastomer Copolymer from ethylene and maleic anhydride or ethylenemethyl acrylate Copolymer from ethylene and methacrylic acid Appendix I: International Abbreviations for Polymers and Polymer Processing EMAC EMI EMM EMP ENR EO-ECH EP EPD EPD, EPDM EPDM-MA EPE EP-G-G EP-K-L EPR, EPM EPR-MA EPS EPT, EPTR E-PVC ES E-SBR ESCR ESD ETE ETFE EtOH EU EVA EVAc EVAc-AA EVAc-CO EVAc-MA EVA-GMA EVAl, EVAL EVAVC EVC EVE EVM EVOH 2159 Ethylene methacrylate copolymer Electromagnetic interference Copolymer from ethylene and methyl methacrylate Ethylene-propylene copolymers (ethylene-modified polypropylene) Epoxidized natural rubber Copolymer of ethylene oxide and epichlorohydrin (also ECO, CO) Epoxy resins Ethylene-propylene-diene copolymer Elastomeric terpolymer from ethylene, propylene, and a non-conjugated diene Maleic anhydride-modified ethylene-propylene-diene terpolymer Ester of an epoxy resin Prepreg from epoxy resin and glass fabric (German literature) Prepreg from epoxy resin and carbon fiber fabric (German literature) Elastomeric copolymer of ethylene and propylene Maleated ethylene-propylene rubber, EPR Polystyrene foam, expanded PS Ethylene, propylene, and a non-conjugated diene terpolymer, also EPDM Emulsion polyvinyl chloride, PVC polymerized in emulsion Ethylene-styrene block copolymer Polymerized in emulsion styrene/butadiene copolymer Environmental stress crack resistance Electrostatic dissipation Engineering thermoplastic elastomer Copolymer from ethylene and tetrafluoroethylene Ethanol Polyether urethane Ethylene-vinyl acetal copolymer Copolymer from ethylene and vinyl acetate Ethylene-vinyl acetate-acrylic acid graft copolymer Ethylene-vinyl acetate-carbon monoxide copolymer Copolymer from ethylene, vinyl acetate, and methacrylic acid Ethylene-vinyl acetate-glycidyl methacrylate copolymer Copolymer of ethylene and vinyl alcohol Ethylene-vinyl acetate-vinyl chloride copolymer Copolymer from ethylene and vinylene carbonate Ethylene-vinyl ether copolymer Ethylene-vinyl acetate copolymer, a thermoplastic elastomer Ethylene-vinyl alcohol copolymer (also EVAl, EVAL) 2160 Appendix I: International Abbreviations for Polymers and Polymer Processing EVP FA FE FEP FF FFKM FK, FRP, GRP FKM FMQ FP FPM FPVC FQ FRE FRP, GRP, FK FTIR FVMQ GC GECO GEP GF GF-PF GF-UP GMA GMT GP GPC GPO GPPS GPSMA GR GR-1 GR-N GR-S Ethylene-vinyl pyrrolidinone copolymer Formic acid Fluorine-containing elastomer Fluorinated EPR, tetrafluoroethylene/hexa-fluoro propylene rubber Resin from furan and formaldehyde Perfluoro rubbers of the polymethylene type, having all substituent fluoro, perfluoroalkyl, or perfluoroalkoxy groups on the polymer chain Fiber reinforced plastic Hexa-fluoro propylene- vinylidene fluoride copolymer Methyl fluoro silicone rubber Fluoroplastic Vinylidene fluoride/hexa-fluoro propylene elastomer, rubbers with fluoro and fluoroalkyl or fluoroalkoxy groups Flexible PVC film Elastomeric silicone with fluorine-containing substituents Fiber reinforced epoxy Glass fiber reinforced polyester Fourier transform infrared spectroscopy Silicone rubber with fluorine, vinyl, and methyl substituents Gas chromatograph Epichlorohydrin-ethylene glycol- glycidyl ether elastomeric copolymer Glass fiber reinforced epoxy resin Glass fiber, or glass fiber reinforced plastic Glass fiber reinforced phenolic resin Glass fiber reinforced unsaturated polyester resin Glycidyl methacrylate (monomer) Glass mat reinforced plastics Gutta-percha Gel permeation chromatograph (now: size exclusion chromatography, SEC) Elastomeric copolymer from propylene oxide and allyl glycidyl ether General-purpose polystyrene (also PS) General-purpose styrene-maleic anhydride copolymer (also SMA) Government rubber from state-owned factories in the USA during the Second World War Butyl rubber Nitrile rubber, now NBR Styrene-butadiene rubber Appendix I: International Abbreviations for Polymers and Polymer Processing GRP GUR HALS HAO HBV HDPE HDT HEC HIPS HISMA HM HMC HMW HMW-PE H-NBR, HNBR HPC HPMC HR HTE ICP IEN IGC IHPN IIR IM IO IPN IPS IR IR, FTIR LCP LDPE LIM LIPN LLDPE LMDPE LPE LRM LRMR L-SBR 2161 Glass reinforced polyester (thermoset) Ultrahigh molecular weight polyethylene (UHMWPE) Hindered amines (antioxidants) Higher alpha-olefins Poly(3-hydroxy butyrate- co-valerate) High-density polyethylene (ca. 960 kg/m3) Heat deflection temperature Hydroxyethyl cellulose High-impact polystyrene High-impact styrene-maleic anhydride copolymer Hot melt adhesive Sheet molding compound with high glass fiber content High molecular weight Polyethylene with high molecular weight Hydrogenated acrylonitrile- butadiene elastomer Hydroxy propyl cellulose Hydroxy propyl-methyl cellulose High resiliency foams Hydroxyl-terminated polyether Intrinsically conductive (or connecting) polymer Interpenetrating elastomeric network Inverse gas chromatograph Interpenetrating homopolymer network Isobutene-isoprene rubber (butyl rubber) Polyisobutene, also PIB Ionomer Interpenetrating polymer network Impact resistant polystyrene Synthetic cis-1,4-polyisoprene, synthetic isoprene rubber Infrared spectroscopy (or Fourier transform infrared spectroscopy) Liquid crystal polymer Low-density polyethylene (ca. 918 kg/m3) Liquid impingement molding (now reactive injection molding, RIM) Latex interpenetrating polymer network Linear low-density polyethylene Linear medium-density polyethylene Linear polyethylene Liquid reaction molding (now reactive injection molding, RIM) Reinforced liquid reaction molding (now reinforced reactive injection molding, RRIM) Solution-polymerized SBR 2162 Appendix I: International Abbreviations for Polymers and Polymer Processing LSR LTG MA or MAH MABS MAN MAS MBA MBS MC MC MDI MDPE MEK MeSAN MF MFI MFK MFQ MFR MI MIPS MMA MMA-MAc-EA MMBA MMBA-TPT MMEA MMMA MMPMI MMS MMVAc MMVAc-AA MMW MPC MPF MPQ MPR Liquid silicone rubber Low-temperature zinc phosphate glasses Maleic anhydride (monomer) Copolymer from methyl methacrylate, acrylonitrile, butadiene, and styrene Copolymer from methyl methacrylate and acrylonitrile Copolymer from methyl methacrylate, acrylonitrile, and styrene Copolymer from methyl methacrylate, butadiene, and acrylonitrile Copolymer from methyl methacrylate, butadiene, and styrene Methyl cellulose Methylene chloride (solvent) Methyl di-isocyanate Medium-density polyethylene (ca. 930 to 940 kg/m3) Methyl ethyl ketone (solvent) Copolymer from a-methyl styrene and acrylonitrile Melamine-formaldehyde resins Melt flow index Metal fiber reinforced plastic Silicone rubbers with methyl and fluorine substituent groups, also FMQ Melt flow rate Melt index Medium-impact-strength polystyrene Methyl methacrylate (monomer) Copolymer of methyl methacrylate, methacrylic acid, and ethyl acrylate Copolymer from methyl methacrylate and butyl acrylate Copolymer from methyl methacrylate, butyl acrylate, diallyl maleate, and trimethylol propane triacrylate Methyl methacrylate-ethyl acrylate copolymer Methyl methacrylate-methyl acrylate copolymer Methyl methacrylate-co-N-phenylmaleimide copolymer Copolymer from methyl methacrylate and a-methyl styrene Methyl methacrylate-vinyl acetate copolymer Copolymer of methyl methacrylate, vinyl acetate, and acrylic acid Medium molecular weight Tetramethyl polycarbonate (also TMPC, TMBPA-PC) Melamine-phenol-formaldehyde resin Silicone rubbers having both methyl and phenyl substituent groups, also PMQ Melt-processable rubber poly(a-methyl styrene) Appendix I: International Abbreviations for Polymers and Polymer Processing M-PVC MPVQ MQ MSABS MSAN MSMA MVQ MWR n-C6 n-C7 n-C10 NBR NC NCR NDPE NIR NK NP NR OEP OPET OPP OPR OPS OPVC OSA P3FE PA 2163 Polymerized in bulk polyvinyl chloride Silicone rubbers with methyl, phenyl, and vinyl groups, also PVMQ Elastomeric silicones with methyl substituents Methylstyrene-styrene-acrylonitrile-grafted polybutadiene Thermoplastic copolymer from a-methyl styrene and acrylonitrile Copolymer of methyl methacrylate, p-methyl-styrene, and maleic anhydride Silicone rubbers having both methyl and vinyl substituent groups, also VMQ Molding with rotation n-Hexane n-Heptane n-Decane Elastomeric copolymer from butadiene and acrylonitrile, nitrile rubber Cellulose nitrate, also CN Elastomeric copolymer from acrylonitrile and chloroprene Low-density polyethylene (see also LDPE) Elastomeric copolymer from acrylonitrile and isoprene Natural rubber, also NR Network polymer Natural rubber, also NK Oil-extended polymer Oriented polyethyleneterephthalate Oriented polypropylene, film, or bottles, also PP Elastomeric polymer from propylene oxide Oriented polystyrene films Oriented polyvinyl chloride Olefin-modified styrene-acrylonitrile copolymer Poly(trifluoroethylene) Polyamide; the abbreviation PA is normally followed by a number, a combination of numbers, a letter, or a combination of letters and numbers. A single number refers to the polyamide from an a,o-amino acid or its lactam. A combination of two numbers is often separated by a comma. The first number following the symbol PA indicates the number of methylene groups of aliphatic diamines and the second number the number of carbon atoms of aliphatic dicarboxylic acids. An I stands for isophthalic acid and a T for terephthalic acid. For example, co-polyamide from caprolactam, hexamethylenediamine condensed with isophthalic and terephthalic acids 2164 PA-6 PA-46 PA-66 PA-6IT6 PAA PAAE PAAM PABM PAC PACE PADC PAE PAEB PAEI PAEK PAES PAI PAK PALL PAMS PA-mXD PA-mXD6 PAN PANI PAPA PAPI PAr, PAR PARA PARS PArSi PAS PAS, PASU PAT PAUR PB Appendix I: International Abbreviations for Polymers and Polymer Processing is abbreviated as PA-6IT6, or that from caprolactam, m-xylylenediamine, and adipic acid as PA-mXD6, etc. Poly-e-caprolactam Poly(tetramethylene adipamide), also PTA Poly(hexamethylenediamine-adipic acid), polyhexamethylene adipamide Poly(caprolactam-co-hexamethylenediamine-isophthalic and terephthalic acids) Polyacrylic acid Polyarylamide-polyether Polyacrylamide Polyaminobismaleimide Polyacrylonitrile fiber (also PAN), polyacrylate Polyacetylene Poly(allyl diglycol carbonate) Polyarylether Poly(p-aminoethyl benzoate) Polyacrylic ester imide Polyaryletherketone Polyarylethersulfone Polyamide-imide Polyester alkyd Polyallomer – a block copolymer of propylene, ethylene (1.5 to 3%), butene (8%), and hexene (5%) Poly-a-methyl styrene Poly(m-xylylene adipamide) Poly(m-xylylenediamine and adipic acid-co-caprolactam) Polyacrylonitrile Polyaniline Polyazelaic polyanhydride Polymethylenepolyphenylene isocyanate, also PMPPI Polyarylate [j-C(CH3)2-j-CO2–j-CO2-]n, amorphous polyester of bisphenol-A with isophthalic and terephthalic acids Polyaryl amide (aromatic, usually amorphous polyamide) Polyaryloxysiloxane Poly(aryloxysiloxane), e.g., poly(dimethylsiloxane biphenylene-oxide) Polyarylsulfide copolymers (esp. in German and Japanese literature) Polyarylsulfone [j-SO2- j-O–]0.875 [j-O–]0.125 Polyaminotriazole, also polyarylterephthalate, aromatic LCP polyester Polyester urethane Poly-1-butene, polybutylene, elastic polydiene fiber Appendix I: International Abbreviations for Polymers and Polymer Processing PBA PBAN PBCD PBD PBE PBG PBI PBMA PBMI PBN PBNDC PBO PBR PBS PB-SMA PBT, PBTP PBT-PBG PBZ PBzMA PBZT PC PCA PCD PCDP PCDT PCE PCF PCHMA PCI PCME PCN PCO PC-Ph PCT, PCTG PCTFE PCU PDAP PDCP PDMDPhS 2165 Polybutylacrylate, also poly(1,4- benzamide) Poly(butadiene-co-acrylonitrile) Poly(butylene cyclohexane dicarboxylate) Polybutadiene Poly(1-butene-co-ethylene) Polybutylene glycol, also known as polytetrahydrofuran, PTHF Polybenzimidazoles Poly-n-butyl methacrylate Polybismaleimide Poly(butylene-2,6-naphthalene dicarboxylate) Poly(butylene-2,5-naphthalene dicarboxylate) Polybutylene oxide Copolymer from butadiene and vinyl pyridine Copolymer from butadiene and styrene (see also GR-S, SBR) Styrene-maleic anhydride-grafted polybutadiene Polybutyleneterephthalate Copolymer of 1,4-butanediol- polybutylene glycolterephthalic acid Polybenzobisoxazole Poly(benzyl methacrylate) Poly(p-phenylenebenzobisthiazole) Polycarbonate of bisphenol-A Polycarbonate-acrylic Polycarbodiimide Polydicyclopentadiene Poly(1,4-cyclohexylene dimethylene terephthalate) Polycycloenes Polychlorotrifluoroethylene fiber Polycyclohexyl methacrylate Poly(1,4-cyclohexylenedimethylene isophthalate) Poly(2,2-dichloro- methyltrimethylene ether) Poly(2-cyano-5-norbornene) Polycycloolefin Co-polycarbonate from phosgene with bisphenol-A and phenolphthalein Poly(cyclohexane terephthalate- glycol), copolymer of cyclohexanedimethanol (66 mol%), ethylene glycol, (34 mol%), and terephthalic acid Polychlorotrifluoroethylene (also CEM, CFM, CTFE) Polyvinyl chloride (old German literature) Polydiallylphthalate (also DAP, FDAP) Polydicyclopentadiene Poly(dimethyl-diphenylsiloxane) 2166 Appendix I: International Abbreviations for Polymers and Polymer Processing PDMS PDPS PE PEA PEAc PEB PEBA PEC PeCe PECO PEE PEEI PEEK PEG PEH PEI PEIE PEIm PEK PEKEKK PEL PEM PENDC, PEN PENi PEO PEOX PEP PEPA PES PEsA PESK PEST PET, PETP PETG PEtI PEUR PF PFA PFEP Polydimethylsiloxane Polydiphenylsiloxane Polyethylene Polyetheramide Polyethylacrylate Polyethylene-p-oxybenzoate Thermoplastic elastomer, polyether block amide Polyestercarbonate or chlorinated polyethylene, usually CPE Chlorinated PVC (also CPVC, PC, PVCC) Polyethylene carbonate Polyester ether fibers (containing diol and p-hydroxy benzoate units, e.g., polyethylene-p-oxybenzoate Polyesteretherimide Polyetheretherketone Polyethyleneglycol High-density polyethylene, also HDPE Polyetherimide Polyetherimide ester copolymer Polyetherimine Polyetherketone Poly(ether-ketone-ether-ketone-ketone) Low-density polyethylene, also LDPE Medium-density polyethylene, also MDPE Poly(ethylene 2,6-naphthalene dicarboxylate) or polyethylenenaphthalate Polyethernitrile Polyethylene glycol, usually PEG Poly(2-ethyl-2-oxazoline) Thermoplastic copolymer from ethylene and propylene Polyether-polyamide copolymer Polyethersulfone [j-SO2-j-O–]n Polyesteramide Polyarylenethioetherketone Thermoplastic polyesters, e.g., PBT, PET, also TPES Polyethyleneterephthalate Polyethyleneterephthalate glycol, copolymer with 66 mol% ethylene glycol and 34 mol% cyclohexylene dimethanol Polyethyleneimine Polyether urethane Phenol-formaldehyde resin Polyfluoroalcoxyalkane, copolymer of tetrafluoroethylene and perfluorinated Copolymer from tetrafluoroethylene and hexa-fluoro propylene, also FEP Appendix I: International Abbreviations for Polymers and Polymer Processing PFF PG PGI PH PHB, POB PHBA PHEMA PHIT PHMT, PHT PHP PhPS PHT, PHMT PHZ PI PIAN PIB PIBI PIBO PIP PIPO PIR PISU PL PLA PMA PMAC PMAN PMB PMCA PMI PMMA- GMA PMMA PMMA-MA PMMI PMP PMPhS PMPPI PMQ PMS PNA PNF PNR 2167 Phenol-furfural resin Poly-a-hydroxy acrylic acid Polyglutarimide Phenolics Poly(p-hydroxybenzoic acid) Poly(b-hydroxybutyric acid) Poly-2-hydroxyethyl methacrylate Poly(hexylene-isophthalate-terephthalate) Polyhexamethylene terephthalate PHP Physiological hydrophilic polymers PhPS Poly(p-phenyl styrene) Physiological hydrophilic polymers Poly(p-phenyl styrene) Polyhexamethylene terephthalate Polyphosphazene Polyimide but also trans-1,4- polyisoprene, gutta-percha (UK) Isoprene – acrylonitrile oil-resistant elastomer Polyisobutene Copolymer from isobutene and isoprene, butyl rubber (also butyl, GR-I, IIR) Polyisobuteneoxide Synthetic cis-1,4-polyisoprene (also CPI, IR) Polyimidazipyrolone Polyisocyanurate (foam) PIS Polyisobutylene Polyimidesulfone Polyethylene (EWG), also PE Polylactic acid Polymethyl acrylate Polymethoxy acetal Polymethyl acrylonitrile Poly-methylenebenzoate Polymethyl-a-chloro acrylate Polymethacrylimide Poly(methyl methacrylate-co-glycidyl methacrylate) Polymethyl methacrylate Poly(methyl methacrylate-co-acrylic acid) Polypyromellitimide Poly-4-methyl-1-pentene (see also TPX) Polymethylphenylsiloxane Polymethylenepolyphenylene isocyanate, also PAPI Silicone rubbers with methyl and phenyl substituents Poly-a-methyl styrene Polynuclear aromatics Polyfluoroalcoxyphosphazene Polynorbornene rubber 2168 Appendix I: International Abbreviations for Polymers and Polymer Processing PO POB, PHB POBA POBI POCA POD PODZ POM POMA POP POR POT PP PPA PPAc PPBA PPC PPC PPCA PPD-T, PPTA PPE PPeA PPE-MA PPG PPhA PPI PP-MA PPMA PPMS, PpMS PPO PPOEA PPOX, PPO PPP PPR PPrA PPS PPSK, PKS PPSS PPS-S Polyolefin but also elastomeric polypropylene oxide and phenoxy resin Poly-p-hydroxy benzoate Polyoxybenzoyl acid, rigid-rod polymer Polyoxadiazobenzimidazole Poly(oxy(cyanoarylene)) or polyoxycyanoarylene Polyoctadecene Poly(p-phenylene 1,3,4-oxadiaxole) Polyoxymethylene, polyformaldehyde, polyacetal, or “acetal resin” Poly(oxetane methacrylate) Polyoxypropylene, usually PPG Elastomeric copolymer from propylene oxide and allyl glycidyl ether Polyoctyl thiophene Polypropylene or oriented polypropylene (see also OPP) Polyphthalamide, also polypropyleneadipate Polypropyl acrylate Polyparabanic acid Chlorinated polypropylene Polyphthalate-carbonate, High heat PC with HDT ¼ 160 C Poly(polycyclic (meth)acrylate) Poly(p-phenylene terephthalamide) Kevlar™ Poly(2,6-dimethyl 1,4-phenylene ether) (see also PPO) Poly(n-pentyl acrylate) Maleic anhydride-modified poly(2,6-dimethyl 1,4-phenylene ether) Polypropylene glycol Polyphthalamide Polymeric polyisocyanate Maleic anhydride-modified polypropylene Poly(phenyl methacrylate) Poly(para-methyl styrene) GE Co., Polymer Products Operation, trade name for poly (2,6-dimethyl 1,4-phenylene ether) (see PPE) Poly(phenoxyethoxyethyl acrylate) Polypropylene glycol, usually PPG Poly-p-phenylene Polypyrrole Poly(n-propyl acrylate) Polyphenylsulfide Polyketonesulfide [j-S-j-CO–]n Polyphenylenesulfidesulfone polythioethersulfone Appendix I: International Abbreviations for Polymers and Polymer Processing PPSU, PSF, PSO PPT, PPTP PPTA, PPD-T PPX PPy PPZ PQ PS P-S, PSA PSAB PSAN PSB PSBR PSF PS-GMA PSI PSL PS-MA PSO PSOX PST PS-TSG PSU PSUL PS-VPh PTA PTF PTFE PTHF PTMA PTMC PTMEG PTMG PTMT PTO PTR PTT PU, PUR PVA PVAc, PVAC 2169 Polyphenylene sulfone, polysulfone Polypropyleneterephthalate; (see also PTT) Poly(1,4-phenylene terephthalamide) Poly(p-xylylene) Polypyrrole Polyorganophosphazene Elastomeric silicone with phenyl substituents Polystyrene Pressure-sensitive adhesive Copolymer from styrene and butadiene (also SB, S/B) Thermoplastic copolymer from styrene and acrylonitrile, also SAN Styrene-butadiene rubber, also GS-R, SBR Elastomeric terpolymer from vinyl pyridine, styrene, and butadiene Polysulfone, also PSUL, PSU, PSO Styrene-glycidyl methacrylate copolymer Polymethylphenylsiloxane Polyspirodilactone Styrene-maleic anhydrite copolymer Polysulfone, also PSUL, PSU, PSF Styrene polymer having reactive (2-oxazoline) groups Polystyrene fiber with at least 85% styrene units Polystyrene foam, processed by injection (German literature) Polysulfone [j-SO2-j-O–j-C(CH3)2-j-O–]n Polysulfone, also PSF, PSU, PSO Poly(styrene-b-vinyl phenol) block copolymer Polytetramethylene adipamide Polytetrafluoroethylene fiber Polytetrafluoroethylene (also TFE) Polytetrahydrofuran [also known as polybutylene glycol, PBG] Polytetramethyleneadipate Poly(trimethylene carbonate) Poly(tetramethylene ether glycol) Polytetramethylene glycol Poly(tetramethylene terephthalate) or polybutyleneterephthalate, PBT Polytransoctanylene Polysulfide rubber Poly(trimethylene terephthalate), also PPT Polyurethane elastomer Polyvinyl acetal Polyvinyl acetate 2170 Appendix I: International Abbreviations for Polymers and Polymer Processing PVAl, PVAL PVBO PVBu PVC PVCA, PVCAc PVCC PVC-DC PVD PVDC PVDF PVE PVF PVFM, PVFO PVI PVID PVIE PVK PVM PVME PVMQ PVOH PVP PVPh PVSI PY Q QA QC QDS QMC RAM RCF REX RF RH RHB RIM RLM RMPS RP, RTP RPBT RPET RPVC Polyvinyl alcohol Polyvinyl butyral Polyvinyl butyrate Polyvinyl chloride Copolymer from vinyl chloride and vinyl acetate Chlorinated PVC, also CPVC, PeCe Poly(vinyl chloride-co-vinylidene chloride) Polyvinylidene chloride fiber with 50 wt% vinylidene chloride Polyvinylidene chloride, also PVC2 Polyvinylidene fluoride, also PVF2 Polyvinylethylene Polyvinyl fluoride Polyvinyl formal Poly(vinyl isobutyl ether) Polyvinylidenecyanide Polyvinyl isobutyl ether Poly-N-vinylcarbazole Copolymer from vinyl chloride and vinyl methyl ether Polyvinyl methyl ether Silicone rubber with methyl, phenyl, and vinyl substituents Polyvinyl alcohol (also PVAL, PVAl) Poly-N-vinylpyrrolidone Poly(4-vinylphenol), poly(p-hydroxy styrene) Polydimethylsiloxane with phenyl and vinyl substituents Unsaturated polyester resins, also UP Silicone elastomer Quality assurance Quality control Quality data statistics Quick molding change Restricted area molding Refractory ceramic fiber Reactive extrusion Resorcinol-formaldehyde resin Relative humidity (in %) Reheat blow molding Reaction injection molding Reactive liquid polymer Rubber-modified polystyrene Reinforced plastics, reinforced thermoplastic, also RP/C Reinforced polybutyleneterephthalate Reinforced polyethyleneterephthalate Rigid PVC film Appendix I: International Abbreviations for Polymers and Polymer Processing RRIM RTD RTM RTP RTPO RTS RTV RUC SAA SAMA SAN SAN SANGMA SANMA SAXS SB, SBR SB/BA SBCL SBMA SBMI SBP SBR SBS SBS SCR SEBS SEM SEP S-EPDM SF, SFM SFK SFP SHIPS SI SIN SIPN SIR SIS SMA SMAA SMA-AA 2171 Reinforced reaction injection molding Residence time distribution Resin transfer molding Reinforced thermoplastic Reactor-blended thermoplastic olefinic elastomer Reinforced thermoset Room temperature vulcanization (of silicone rubber) Chlorinated rubber Styrene-acrylic acid copolymer Styrene-acrylonitrile-methacrylic acid copolymer Styrene-acrylonitrile Thermoplastic copolymer from styrene and acrylonitrile, also AS, PSAN Styrene-acrylonitrile-glycidyl methacrylate copolymer Styrene-acrylonitrile-maleic anhydride copolymer Small-angle X-ray scattering Thermoplastic copolymer from styrene and butadiene, also PASB, S/B Styrene-butadiene-butyl acrylate copolymer Styrene-butadiene-caprolactone copolymer Styrene-butadiene-maleic anhydride copolymer Styrene-butadiene-maleimide Styrene-butadiene polymer Styrene-butadiene elastomer Styrene-butadiene-styrene Styrene-butadiene-styrene triblock polymer Elastomeric copolymer from styrene and chloroprene Styrene-ethylene/butylene-styrene triblock polymer Scanning electron microscopy Styrene-ethylene-propylene block copolymer Sulfonated ethylene- propylene-diene terpolymer Structural foam, structural foam molding Synthetic fiber reinforced plastic (German literature) Scrapless forming process Super-high-impact polystyrene Thermoplastic silicone Simultaneous interpenetrating network or semiinterpenetrating network Sequential interpenetrating polymer network Elastomeric copolymer from styrene and isoprene Styrene-isoprene-styrene triblock polymer Copolymer from styrene and maleic anhydride Copolymer from styrene and methacrylic acid Styrene-maleic anhydride-acrylic acid copolymer 2172 Appendix I: International Abbreviations for Polymers and Polymer Processing SMC SMI SMMA, SMM SMM-GM SMM-MA SMS SP SPC sPP SPPF SPSF S-PVC SR SRIM SRP SSE SVA SVPh SWP TA TC TCE TDI TE TEEE TEO TES TFE TGA TGIC THF TM TMA TMBA-PC TMC TMPC TOR TPA, TPR TPE, TPEL TPE-A TPE-E TPE-S TPES Sheet molding compound Copolymer from styrene and maleimide Styrene-methyl methacrylate copolymer Styrene-methyl methacrylateglycidyl methacrylate copolymer Styrene-methyl methacrylate-maleic anhydride copolymer Copolymer from styrene and a-methyl styrene Saturated polyester plastics Statistical process control Syndiotactic polypropylene Solid-phase pressure forming Solid-phase stretch forming Suspension PVC Synthetic rubber, polysulfide rubber Structural reactive injection molding Styrene-rubber plastics Single-screw extruder Styrene-vinyl-acrylonitrile copolymer Styrene-p-vinyl phenol copolymer Solvent-welded plastics pipe Cellulose triacetate, also CT, CTA Technically classified natural rubber Tetrachloroethane Toluene di-isocyanate Thermoplastic elastomer of any type Thermoplastic elastomer, ether-ester Thermoplastic elastomer, olefinic Thermoplastic elastomer, styrenic Polytetrafluoroethylene (also PTFE) Thermogravimetric analysis Triglycidyl isocyanurate Tetrahydrofuran (solvent) Thioplasts, transfer molding Thermomechanical analyzer Tetramethyl bisphenol-A polycarbonate (or MPC, TMPC) Thick molding compound Tetramethyl bisphenol-A polycarbonate (TMBPA-PC) Trans-polyoctenamer rubber TP Thermoplastic 1,5-trans-polypentenamer Thermoplastic elastomer Thermoplastic elastomer-amide Thermoplastic elastomer-ester Thermoplastic elastomer-polystyrene Thermoplastic polyesters, e.g., PBT, PET (see also PEST) Appendix I: International Abbreviations for Polymers and Polymer Processing TPI TPO TPS TPU, TPUR TPV TPX TR TREF TS TSE TSI TSUR UE UF UFS UHMW-PE ULDPE UP UP-G-G UP-G-M UP-G-R UPVC UR VAc VAc-AN VAcE VC/E, VCE VCE VCEMA VCEV VCM VCMA VCMMA VCOA VCVAc VCVDC VDC VDC/AN VF/HFP VLDPE VMQ VOC 2173 Thermoplastic polyimide Thermoplastic olefinic elastomer Toughened PS (in the UK for HIPS) Thermoplastic urethanes Thermoplastic vulcanizate Poly(4-methyl-1-pentene) (see also PMP) Thermoplastic elastomer or thio rubber (UK) Temperature-rising elution fractionation Thermoset Thermoset elastomer Thermoset polyimide Thermoset polyurethane Polyurethane elastomer Urea-formaldehyde resin Urea-formaldehyde foam Ultrahigh molecular weight polyethylene (over 3 Mg/mol) Ultralow-density polyethylene (ca. 900–915 kg/m3) Unsaturated polyester Prepreg from unsaturated polyesters and textile glass fibers Prepreg from unsaturated polyesters and textile glass mats Prepreg from unsaturated polyesters and textile glass rovings Unplasticized PVC Polyurethane elastomers, also UP Vinyl acetate Copolymer from vinyl acetate and acrylonitrile Vinyl acetate-ethylene copolymer Vinyl chloride-ethylene copolymer Copolymer from ethylene and vinyl chloride Copolymer from vinyl chloride, ethylene, and methyl acrylate (or maleic anhydride) Copolymer from vinyl chloride, ethylene, and vinyl acetate Vinyl chloride (monomer), also VC Copolymer from vinyl chloride and methyl acrylate Copolymer from vinyl chloride and methyl methacrylate Copolymer from vinyl chloride and octyl acrylate Copolymer from vinyl chloride and vinyl acetate Copolymer from vinyl chloride and vinylidene chloride Vinylidene chloride Copolymer from vinylidene chloride and acrylonitrile Copolymer from vinylidene fluoride and hexa-fluoro propylene Very low-density polyethylene (ca. 885 kg/m3) Silicone rubber with methyl and vinyl substituents Volatile organic compound 2174 VPE VQ VSI WAXS WR XABS XLPE XMC XNBR XPS XSBR YBPO YSBR YXSBR Appendix I: International Abbreviations for Polymers and Polymer Processing Vulcanized (cross-linked) polyethylene, also XLPE Elastomeric silicone with vinyl substituents Polydimethylsiloxane with vinyl groups Wide-angle X-ray scattering Woven rovings Acrylonitrile-butadiene-styrene/acidic monomer, an elastomeric copolymer Cross-linked polyethylene Extra-strength molding compound Acrylonitrile-butadiene/acidic monomer, an elastomeric copolymer Expandable or expanded PS Butadiene-styrene/acidic monomer, an elastomeric copolymer Elastomeric polyetherester: [((CH2)4-O)n-CO-j CO-O-]m Thermoplastic, elastomeric block copolymer from styrene and butadiene Block copolymer from styrene and butadiene containing carboxylic groups Note: This list is based on the nomenclature proposed by diverse standardizing organizations, as well as on the acronyms used in technical literature, viz., American Society for Testing Materials, Standard Terminology for Abbreviated Terms Relating to Plastics, ASTM D1418-01a, ASTM D1600-99, and their referenced standards; British Standards, schedule of common names, and abbreviations for plastics and rubbers, BS 3502–1978; Deutsches Institut f€ur Normung, plastics, symbols and codes for polymers and their special characteristics, DIN 7728 Teil 1 01.88; symbols for reinforced plastics, DIN 7728 Teil 2 03.80; plastics molding materials DIN 7742 Teil 1 01.88; molding techniques for molding materials, definitions, DIN 16700 09.67; Association Franc¸aise de Normalisation, plastics, vocabulary, T 50–100 08.90; plastics, symbols, T 50-050-1, T 50-050-2, T 50-050-3 06.89; International Organization for Standardization, plastics, symbols, ISO 1043–1; 1987, ISO 1043–2; 1988, ISO 1043–3; International Union for Pure and Applied Chemistry, Pure Appl. Chem. 18, 583 (1969); Pure Appl. Chem. 40, 473 (1974). Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 1. PS PB(BR) or PE 2. ABS or Elastomer ASA or SMA* Name Hostyren Supplier Hoechst Limera R Polysar Polystyrol Styroblend Styroplus Dainippon Ink and Chemicals Bayer Miles BASF AG BASF AG BASF AG Cadon* Centrex Luran S Magnum Rovel Starflam ABS Terluran Monsanto Chem. Monsanto Chem. BASF AG Dow Chem. Co. Uniroyal Ferro Plastics BASF AG L.A. Utracki, C.A. Wilkie (eds.), Polymer Blends Handbook, DOI 10.1007/978-94-007-6064-6, # Springer Science+Business Media Dordrecht 2014 Comments The blends are formulated for extrusion, injection and blow molding They show excellent processability, low moisture absorption and shrinkage, improved impact strength. Composition-dependent modulus, toughness, ductility, transparency, and gloss Blends of ABS or ASA with either acrylic rubber (800) or PB (900 series) were formulated for extrusion, thermoforming, injection, and blow molding. They show excellent processability, weatherability, impact strength, HDT, scratch resistance, paintability, and plateability (continued) 2175 2176 Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 3. TPU ABS 4. LDPE 5. NBR Name Prevail Techniace TU Supplier Dow Chem. Co. Sumitomo Dow Comments The blends can be injection molded, extruded, blow molded, or thermoformed. Transfer or compression molding, calendering, and solid state may also be used. They show hardness between that of TPU and ABS, superb toughness, chemical resistance, appearance PIB Lupolen O 250 BASF AG The 1:1 blends are flexible Pax-Plus Paxon Polymer Co. and resistant to cracking under stress and show good water-vapor properties. The blends are formulated for extrusion, injection, and blow molding. The weld-line strength, resistance to warpage, and shrinkage depend on processing conditions EPDM or Geolast JSR Monsanto JSR The blends are formulated CPE or PVC NE * for extrusion, calendering, injection, and blow molding. Goodyear Tire & Chemigum They have either Rubber Co. TPE# co-continuous or (less Krynac NV Polysar, Inc. frequently) dispersed # Nipol Nippon Zeon morphology. They show # Paracril OZO Uniroyal Chemical good processability; ozone, oil, and heat resistance; low compression set; low-temperature flexibility; nearly total elastic recovery; and excellent weather resistance. Principal use includes automotive weather stripping, interior moldings, tubings, hoses, seals, gaskets, expansion joints, cable sheathings, conveying belts, roofing, pond liners, geomembranes, floorings, etc. (continued) Appendix II: Examples of Commercial Polymer Blends Polymer No. A B Name 6. PP TPO or EPR BK 891 or EPDM Deflex Dynaflex Ferrolene Ferro Flex HiFax Hostalen PP IPCL JSA1986 Kelburon, Keltan TP Milastomer Modylen Moplen SP Oleflex Optum Polytrope Propathene PU-21713 RPI 507 EP RxLOY Santoprene Sarlink Sumitomo TPE Thermolan 2000 TPO 900 Vestolen EM Supplier Mitsui Chemical A. Schulman JSR Ferro Plastics Ferro Plastics Himont Adv. Mat. Hoechst IPCL DSM Polymer International Mitsui Petrochem. Tiszagi Vergi Kom. Himont Showa Denko Co. Ferro Plastics A. Schulman, Inc. ICI Ferro Plastics Research Polym. Ferro Plastics Monsanto Novacor Sumitomo Chem. Mitsubishi Petrochemicals Reichhold Chem. H€ uls A.-G. 2177 Comments The blends are formulated mainly for injection molding, but they can also be extruded, thermo- or vacuum-formed (e.g., Optum), compression or transfer molded, calendered, and blow molded. Several have dynamic properties, viz., hardness and heat resistance. Some blends are vulcanized, showing toughness, and are composition dependent (30 wt%) (e.g., Kelburon) and reactor made. Reinforced and filled grades (containing glass fiber, talc, CaCO3, or mineral filler) are available. These blends show good processability, low-temperature modulus and impact strength, dimensional stability, low shrinkage, good mechanical properties at temperatures from 40 to 150 C, ozone resistance, dynamic fatigue and abrasion resistance, as well as high good weather ability (especially carbonblack filled grades) tear strength and paintability. Over 200 applications have been found for these materials, e.g., they are used in appliances, hardware and plumbing, automotive industry (arm rests, pillar trim, door panels, radiator grilles, dashboards, children seats, side protectors, bumpers, spoilers), etc. (continued) 2178 Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 7. PVC Acrylics Name Acrylivin Cladux Decoloy Fiberloc HTX Haibulen Kane-ace Kydex Metabulen Polycast Sunloid KD Vinidur 8. PVC NBR Carloy Geon/Hycar Denka LCS JSR NV Krynac NV Nipol Oxyblend Paracril OZO Vynite Supplier General Tire & Rubber R. Daleman GE Plastics The Geon Company Nippon Zeon Kanegafuchi Chem. Rohm and Haas Mitsubishi Rayon Royalite Tsutsunaka BASF AG Comments Suspension PVC modified by 5–15 wt% acrylic elastomer. The blends are are formulated for extrusion, injection, and blow molding, vacuum- or thermoforming, and calendering. They show high impact strength, rigidity, resilience, dimensional stability, flame retardancy, excellent outdoor performance, and good flame, abrasion, electrical, chemical, and solvent resistance. These blends are used in industrial, commercial, consumer (e.g., as wall coverings, corner guards, column covers, shelving, counter laminates, ceiling tiles), medical, food or beverage equipment, aircraft or mass transit interior components, and applications requiring good resistance to weathering Cary Chem. Inc. These blends (containing 30–60 wt% PVC) are B. F. Goodrich Showa Denko Co. formulated mainly for extrusion and calendering, Jap. Synth. Rub. but injection, blow, Miles-Polysar compression, and transfer Nippon Zeon molding can also be used. They show good OxyChem processability, fast Uniroyal Chem. calendering and extrusion, Alpha Chem. Plast. impact and tear strength, and oil, fuel, improved chemical, abrasion, weathering, ozone, antistatic, flame, and moisture resistance. Their applications include cables and hoses, printing plates and rollers, shoe soles, bottles for cosmetics and edible oils, profiles, etc. (continued) Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 9. PVC ABS or ASA* 10. PA-6 PA 11. PA PA Name Abson 042 Cycovin K-29 Denka Taimel. * Geloy XP2003 Kaneka Enplex Kralastic Lustran ABS 860 Nipeon AL Polyman 500 Supplier Abtec Chem. Co. The Geon Co. Denki Kagaku GE Plastics 2179 Comments These blends are formulated for injection molding, extrusion, and thermo-or vacuum forming, but calendering can also be used. The blends show superior Kanegafuchi Corp. processability to component Uniroyal/Sumitomo polymers, impact strength, flame retardance, and cost-toMonsanto Chem. performance ratio. The blends with ASA show superior Zeon Kasei Co. weatherability, while those A. Schulman, containing SMA high Inc. DSM HDT. The main use is for Ronfaloy V DSM business machines, electrical Tufrex VB Mittsubishi and electronic equipment housings, automotive Triax CBE Monsanto Chem. applications, swimming pool (discontinued) fittings, irrigation, etc. Grilon BT EMS-Chemie Miscible blends show improved processability, Wellamid MR Wellman, Inc. solvent resistance, Zytel 3100 E. I. du Pont elongation, low-temperature impact and tensile strength Akuloy RM DSM Eng. Plast. The blends are formulated mainly for injection molding Dexpro, Dexter Corp. and extrusion. Polyamides Dexlon PA-6, PA-66, PA-mXD6, and Eref Solvay PARA. In most blends PA is Flexloy Sumitomo Chem. the matrix phase, but those Gapex Ferro Plastics with PP as a matrix are also LAX 23 Ube, Inc. available (e.g., from Solvay). MCX-Q Mitsui Petrochem. The blends show good processability; reduced water NB Toyobo absorption; dimensional Novamid AC Mitsubishi Chem. stability; low density (i.e., low Orgalloy R-6 Atochem cost per volume); low liquid Poliblend NH Poliresins SA and vapor permeability; Snialoy Nylon Corp. Amer. moderate impact strength; Systemer S Showa Denko Co. good resistance to alcohols, glycols, and gasohol; Thermocomp LNP improved heat aging; primerUbe Alloy CA Ube Inc. less paintability; and Ultramid KR BASF AG resistance to cracking when UTX Unitika exposed to metal halides (e.g., CaCl2). Some grades are reinforced. Principal blend uses include appliances, automotive, tools, building, furniture, and industrial (continued) 2180 Polymer No. A 12. PA-6, P PA-66, PARA, or PA-666 Appendix II: Examples of Commercial Polymer Blends B E, EPR, acrylic elastomers, or ionomers 13. PA-66, Brominated or PA-6 PS Name Albis Bexloy C Brilion BT-40 Capron Durethan Dynyl Fiberfil TN Grilon A Maranyl Minlon Nybex Nycoa Nydur Nylafil Nylon Star X Technyl A and B Ultramid A, B, C, and T Vydyne Wellamid 22 L Zytel ST Zytel 300, 400 Supplier Albis Plastics E. I. du Pont Emser Ind. AlliedSignal Bayer A.-G Rhoˆne Poulenc DSM Eng. Plast. EMS-Chem. A.-G. ICI E. I. du Pont Ferro Plastics Nylon Corp. Amer. Bayer A.-G Wilson-Fiberfil Int. Celanese Eng. Res. Ferro Plastics Rhoˆne Poulenc Akulon K228 Latamid 66 Starflam PA6 Ultramid A3X Zytel FR DSM Lati Ferro Plastics BASF AG E. I. du Pont BASF AG Monsanto Chem. Wellman Inc. E. I. du Pont E. I. du Pont Comments The blends are formulated for extrusion, co-extrusion, injection, compression, transfer, and blow molding. They can also be thermoformed. Grades containing up to 40 wt% mineral or glass fibers are available. Some may contain PTFE. The blends have good processability, low-temperature impact strength, rigidity, stiffness, high heat resistance, lower service temperature. The molded articles can suppress vibration, even when dry and at sub-zero temperatures. The blends find use in a broad range of applications, viz., automotive (stone and splash guards, under-thehood moldings, seals, hoses, tubes, clips, fasteners, fuel doors, gears), appliances, sport (e.g., ski bindings, roller skates), business equipment, consumer products (office chair seats, housings, casters, wheels, rollers, pulleys, gears), etc. These fire-resistant, unreinforced blends designed for injection molding or extrusion are used in automotive and electrical applications. They show good flame retardance, mechanical properties, and dimensional stability (continued) Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 14. PA-6 or ABS PA-66 Name Alphaloy MPA Elemid Diaaloy N Kane ace MUH Malecca S Maxloy A Monkalloy N N5 Novaloy-A Stapron N SX Techniace TA Toyolac alloy Triax 1000 Ultramid Supplier Kanegafuchi Chem. GE Plastics Mitsubishi Rayon Kanegafuchi Chem. Denki Kagaku K. JSR Monsanto Kasei Thermofil Inc. Daicel Chem. Ind. DSM Polymer Int. Toray Ind., Inc. Sumitomo Dow Toray Ind., Inc. Monsanto BASF AG 15. PA Cyclic - PO Elmit ZF Mitsui Petrochemicals 16. PA PC Dexcarb D & S Int. Iupilon Mitsubishi Gas SC 720 Idemitsu Petrochemicals 17. PC TPU Texin 3000 Texin 4000 Bayer/Miles 18. PC Elastomer Idemitsu SC-150 Makrolon T-78 Novarex AM Idemitsu Petrochemicals Bayer/Miles Mitsubishi Chem. 2181 Comments The compatibilized blends (with either PA as matrix or co-continuity of both phases) are formulated for injection molding, extrusion, and thermoforming, but blow and compression molding also can be used. The blends show good processability and flow; high heat and chemical resistance; high resistance to oil, wear, and abrasion; dimensional stability; low-temperature impact strength; reduced moisture sensitivity; and economy. Main application is in automotive, chemical, electrical, customer, and sport industries. Some grades are glass fiber reinforced. The material has been also used in anti-vibration damping structures Processability, impact strength, moisture insensitivity Processability, HDT > 200 C, impact strength, low mold shrinkage, solvent, and moisture sensitivity PC blends with polyester urethane were designed for extrusion or molding articles used in automotive and consumer goods’ industries The blends for extrusion or injection molding contain < 6 wt% elastomer (e.g., butyl acrylate-comethacrylate) and thus are opaque. They show low temperature toughness, high impact strength, good weldline strength, and HDT (continued) 2182 Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 19. PC ABS (and SAN in some blends) Name Alphaloy Bayblend T Cycoloy Denka HS Dialoy C Exceloy Iupilon MB Lynex B Malecca P Multilon PX Novaloy-S Proloy/Lexan Pulse Ronfalin Royalite R11 Ryulex SC 250 Techniace TC Toplex Terblend B Triax 2000 ABS/PC 7901 20. PC ASA, or AAS* Baitaloy* 21. PC PS Novadol SC 200 Supplier Kanegafuchi Chem. Bayer/Miles GE Plastics Denki Kagaku Mitsubishi Rayon JSR Mitsubishi Gas Asahi Chem. Denka Teijin Chem. Ltd. Daicel Chem. Ind. GE Plastics Dow Chem. Co. DSM Uniroyal Dainippon Idemitsu Petrochem. Sumitomo Dow Multibase, Inc. BASF AG Monsanto Chem. Diamond Polymers Hitachi Chem. highDialoy A Mitsubishi Rayon Geloy XP4001 GE Plastics Terblend S BASF AG Mitsubishi Chem. Idemitsu Petrochemicals Comments The blends are formulated for injection molding, extrusion, and thermo-or vacuum forming, but they can also be compression or transfer molded. They show good processability, excellent plating, HDT and impact strength, high stiffness and strength, dimensional stability, toughness, delamination resistance, low-temperature impact strength, good weld-line strength, and solvent and chemical resistance. These are three-phase blends, with 30–65 wt% PC usually being the matrix. Grades with glass fiber reinforcement are available. The blends are used for housings of computers, business machines and electrical appliances, electrical and electronic parts, connectors, carriages, switches, fans, power and agricul-tural, garden and lawn tools, cameras, optical instruments, exterior automotive components, electronic or telecommunication parts, sporting goods, etc. High impact strength, thermal stability, improved resistance to temperature aging and UV degradation, excellent weatherability, rigidity, and dimensional stability. The blends are formulated mainly for extrusion, injection molding, and thermoforming Impact strength, thermal stability, and weatherability (continued) Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 22. PC SMA 23. PC PBT or PET or PCTG (and 10–20 wt% impact modifier) Name Arloy 1000 Ektar MB R4 9900 Supplier ARCO Chem. Co. Eastman Kodak Thermofil Inc. Azloy BCT 4201 Defsan Dialoy P Ektar MB, Azdel, Inc. Toray Russia Mitsubishi Rayon Eastman Chemical Company Eastalloy DA (PCTG) Idemitsu SC 600 Makroblend MB4300 Novadol Pocan R2-9000 Sabre Stapron E Ultrablend KR Valox Xenoy 1000 Eastman Chemical Company Idemitsu Petrochem. Bayer A.-G. Mitsubishi Gas Mitsubishi Chem. Bayer Thermofil Inc. Dow DSM Polymer Int. BASF GE Plastics GE Plastics 2183 Comments The blends are designed for extrusion, thermoforming, or injection molding. They show excellent processability, toughness, and heat resistance The blends are formulated for injection molding, extrusion, and blow molding, but they can be transfer or compression molded, formed in solid state, or thermoformed. In most blends PC is the matrix phase. The impact modifier can be PE, ABS, or acrylic copolymer, e.g., MBS. The blends show good processability; heat resistance; ductility; HDT; high modulus, impact, tensile, and flexural strength over a wide temperature range; good adhesion; solvent, chemical, and UV resistance. They can be painted, hot stamped, metallized, and plated. Some blends (containing polybutadiene as impact modifier) may have poor weather-ability. The blends are mainly used in automotive industry (continued) 2184 Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 24. PET Elastomer or SMA* 25. PET or PC (and PCTG* 15–20 wt% impact modifier) Name Arloy 2000* Celanex Rynite SC-150 *Ektar MB Hyperlite Impact Makroblend UT MB 3500 Petsar Sabre 1600 SC Xenoy 2000 26. PBT PET 27. PBT Acrylic rubber 28. PBT Elastomer C, CN Celanex EMC Valox BU BX Novadol Vandar Bexloy J Celanex Gafite Macroblend Pibiter HI Starflam PBT Techster T Ultradur KR Supplier ARCO Chem. Co. Celanese Eng. Res. E. I. du Pont Idemitsu Petrochemicals Comments The blends are formulated for extrusion, injection, compression, blow, and transfer molding. The blends contain up to 35 wt% glass fiber. They show good processability, rigidity, impact and tensile strength, as well as excellent weatherability Eastman These blends can be injection Kanegafuchi Chem. molded or extruded. They are partially miscible, with AlliedSignal co-continuous morphology Mobay showing improved processability, solvent Mitsubishi Gas resistance, elongation, Polysar low-temperature impact and tensile strength (possible Dow reduction of crystallinity upon Idemitsu blending) Ektar resins are Petrochemicals based on poly(cyclohexaneGE Plastics terephthalate-glycol) mixed with PC and/or with SMA. They are primarily used in business machines, appliances, consumer goods, garden tools, lightning, automotive, sports equipment, fluid handling, etc. Teijin Good surface properties, HDT, impact strength, Hoechst Celanese dimensional stability, and Toyobo economy GE Plastics Dai Nippon Ink Improved processability and impact resistance Toray Mitsubishi Chem. Hoechst E. I. du Pont These impact-modified PBT blends are formulated for Hoechst Celanese injection molding, but they GAF can also be extruded and Bayer Miles thermoformed. They show Montedipe good processability, Ferro Plastics electrical properties, high stiffness and strength, HDT, Rhoˆne Poulenc dimensional stability, impact BASF AG strength, and solvent and chemical resistance (continued) Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 29. PBT ABS or AAS* 30. PAr PET or PC 31. POM PBT 32. POM TPU Name A, AN Alphaloy MPB BA Baitaloy VL* Cycolin Diaaloy B Lumax Malecca B Maxloy B Novaloy-B Techniace TB Triax 4000 Ultrablend S VX Supplier Teijin Kanegafuchi Chem. Dai Nippon Ink Hitachi Chem. GE Plastics Mitsubishi Rayon Lucky Co., Ltd. Denka Kagaku K. JSR Daicel Chem. Ind. Sumitomo Dow Monsanto BASF AG Toray Ardel D-240 U-8000 Duraloy Lynex T Celcon Delrin Duraloy Formaldafil Fulton KL Hostaform S RTP 800 TC Thermocomp Ultraform Amoco Corp. Unitika Celanese Asahi Chem. Celanese Eng. Res. E. I. du Pont H.-Celanese Wilson-Fiberfil LNP Corp. Hoechst A.-G. RTP Corp. Polyplastics LNP BASF AG 2185 Comments The blends contain 0–30 wt% glass fiber or mineral fillers. They are formulated for injection molding but can be extruded, thermoformed, or solid state formed. They show excellent processability, high gloss, stiffness at high temperature, good electrical properties, thermal stability, mechanical strength, HDT, low shrinkage, good dimensional stability, impact strength, as well as solvent (e.g., to gasoline and motor oils) and chemical resistance. The main consumption includes electronics, automotive and electrical industry, as well as office, sports, and household equipment Processability, high HDT, tough, high impact strength HDT, toughness, softness, high impact strength The blends are formulated for extrusion, injection, compression, blow, and transfer molding. They show excellent processability; rigidity; high impact strength; high fatigue, flexural, and tensile strength; high toughness; low water absorbency; gloss; and resistance to chemicals. In most blends POM is impactmodified with 10–30 wt% TPU. Some grades contain PTFE. Co-continuous morphology gives especially good performance. These blends find use in sports equipment, plumbing, electronic/mechanical parts, automotive, appliances, hinges, etc. (continued) 2186 Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 33. PPE PS (HIPS, SBS, SEBS, ABS, SB,. . .) Name Gepax Luranyl Noryl Prevex Verton Vestoran 1900 and 2000 Xyron 200 34. PPE PA Artley Dimension Lynex A Noryl GTX Remaloy 35. PPE PBT (+ PC + impact modifier) 36. PPE PPS Dialoy X BE Gemax Iupiace DIC PPS Supplier GE Plastics BASF AG GE Plastics GE Plastics H€ uls H€ uls-Nuodex Asahi Chem. Ind. Sumitomo Chem. AlliedSignal Asahi Chem. Ind. GE Plastics Mitsubishi Petrochemicals Ultranyl BASF AG Vestoblend H€ uls A.-G. Xyron A and G Asahi Chem. Ind. Iupiace Noryl APS Mitsubishi Rayon Dai Nippon Ink GE Plastics Mitsubishi Gas Dainippon Ink & Chemicals Mitsubishi Gas GE Plastics Comments These blends, with 25–60 wt% PPE, were designed for injection or blow molding, calendering, thermoforming, and extrusion. Some grades are rein-forced with < 30 wt% glass fibers. They show good processability, heat resistance, HDT ¼ 90–150 C, toughness, good dimensional stability, resistance to hot water, flame retardance, low density, cost/performance ratio, and low moisture absorption The blends are designed for extrusion, thermoforming, or injection molding. They are compatibilized, with 40–60 wt% PA, showing moderate processability and impact strength; good tensile and flexural strength; hightemperature creep, solvent, and chemical resistance; and low moisture absorption. They are dimensionally stable, paintable, and palatable Excellent processability, high solvent and temperature resistance, and dimensional stability The blends are designed for injection molding, but extrusion, compression molding, or thermoforming can also be used. The blends have to be compatibilized and contain up to 40 wt% glass fibers. They show good compatibilized and contain up to 40 wt% glass fibers. They show good processability, reduced flash, toughness, and high heat resistance (continued) Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 37. PVDF PMMA Name Polycast Supplier Royalite 38. PSF ABS Arylon Mindel A Uniroyal Amoco Corp. 39. PSF PET Mindel B Amoco Corp. 40. PSF PA Reo-alloy Riken Vinyl 41. SMI SAN Malecca A Denka 42. SMI ABS Malecca K Denka 43. SMI PA Malecca N Denka 44. PEEK PES Sumiploy SK Sumitomo Chem. 2187 Comments Used for electrets or as outdoor films with good clarity and chemical and UV stability The blends can be either extruded or injection molded. They show good processability, toughness, dimensional stability, high HDT, hot water resistance, plateability, and paintability. The applications include plumbing, food service, and fiber optics controlled system The blends can be either extruded or injection molded. They show improved processability and impact strength, low shrinkage and warpage, high HDT, good stress crack chemical and solvent resistance, and good economy. The blends find applications as molded electrical parts, viz., connectors, relays, switches, motor starters, control housings, etc. Processability, low viscosity, and low water absorption High heat and impact resistanc High heat and impact resistance High heat, solvent, and impact resistance The blends are designed for injection molding, but extrusion, compression molding, or thermoforming can also be used. SK 1660 grade contains glass fibers. The materials show good processability, excellent high temperature, and chemical and hot water resistance (continued) 2188 Appendix II: Examples of Commercial Polymer Blends Polymer No. A B 45. PEEK LCP Name Sumiploy EK Supplier Sumitomo Chem. 46. PEI PC Ultem LTX GE Plastics 47. PI LCP Aurum Mitsui Toatsu 48. HIPS Hydrophilic polymer Toray Comments The blends are designed for injection molding, but extrusion, compression molding, or thermoforming can also be used. They show good process- ability, high strength, modulus, and HDT Designed for injection molding and extrusion. Processability; HDT; flexural, tensile, and impact strength; flame retardancy; long-term hydrolytic stability; stain and chemical resistance; and lower cost than PEI Good processability, low viscosity, HDT, and low water absorption Permanent antistatic properties Appendix III: Dictionary of Terms Used in Polymer Science and Technology A-, B-, and C-stages AB, AABB polymerization Ablation Abrasion Abrasion resistance ABS Accelerated aging Accelerated weathering Expressions used by Baekeland to differentiate polymerization steps of phenolic resins. A-stage, initial; resins are still fusible and soluble. B-stage, advanced degree of condensation; resins are still capable of swelling but no longer soluble. C-stage; complete crosslinking and insolubility. Step-growth polymerization, in which the two types of functional group (A and B) are attached to the same or two different monomers, viz., hydroxy acid (AB) and diol-diacid (AABB). Decomposition of a material caused by heat friction. The wearing away of some surface area by its contact with another material. Ability of material to withstand mechanical action such as rubbing, scraping, or erosion that tends to progressively remove material from its surface; to resist surface wear. A thermoplastic classified as an elastomer-modified styrene-acrylonitrile copolymer. Aging by artificial means to obtain an indication on how a material will behave under normal conditions over long period. Also tests in which conditions are intensified to reduce the time required to obtain deteriorating effects, similar to these resulting from normal service conditions. Duplicating or reproducing weather conditions by machine-made means. Test in which the normal weathering conditions are accelerated by means of a device. L.A. Utracki, C.A. Wilkie (eds.), Polymer Blends Handbook, DOI 10.1007/978-94-007-6064-6, # Springer Science+Business Media Dordrecht 2014 2189 2190 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Accumulator Acetal resins Acrylic elastomer Acrylics Adapter Additive Adhesion Adhesive Advanced composites Aging A device for conserving energy in hydraulic systems of molding equipment, or an auxiliary ram extruder used to provide fast material delivery in a molding machine. Polyoxymethylene – a crystalline thermoplastic material made from formaldehyde, viz., Delrin™ or Celcon™. An elastomer based on polyethylacrylate and/or poly-nbutylacrylate with thermal stability up to T ¼ 200 C, usually cross-linked by heating with peroxides or with alkali. To improve the solvent resistance, 20–50 wt% of ethoxy or methoxyethyl-acrylate may be added. Name given to plastics produced by the polymerization of acrylic acid derivatives, usually including methyl methacrylate. An amorphous thermoplastic material. In technological jargon polymethylmethacrylate (PMMA) or polyacrylonitrile fiber with at least 85 wt% of PAN. A mechanical reducing mechanism between the barrel and either a nozzle or a die. A material added to a polymer during the final synthesis stages or in subsequent processing to improve or alter some characteristics of the polymer. Additives, as a class of materials, are not intended to increase strength properties. Examples of additive include pigments, lubricants, antistatic agents, flame retardants, and plasticizers. The state in which two surfaces are held together at an interface by mechanical or chemical forces, by interlocking action, etc. A substrate capable of holding two materials together by surface attachment. Adhesive can be in film, liquid, or paste form. Composite materials that are reinforced with continuous fibers having a modulus higher than that of glass fibers. The term includes polymeric matrix, metal matrix, and ceramic matrix composites, as well as carbon-carbon composites. The change of a material over time under defined natural or synthetic environmental conditions, leading to improvement or deterioration of properties. Also, changes caused by exposure to physical and chemical factors (viz., light, temperature, chemicals, weather), leading to irreversible deterioration. A process of exposing plastics to natural or artificial environmental Appendix III: Dictionary of Terms Used in Polymer Science and Technology Alkyd resins Alloy Allyl resin Ambient temperature Amino resin Amorphous polymer Amplitude Analysis of variance 2191 conditions for a prolonged time. See also “Accelerated aging,” “Artificial aging,” “Chemical aging,” and “Physical aging.” Name given to synthetic, thermosetting resins processed from polyhydric alcohols and polybasic acid or anhydrides. These unsaturated polyesters are prepared by esterification of a polyfunctional alcohol (e.g., glycerin) with phthalic anhydride in combination with fatty acids or rosin acids (molecular weight about 2,000 to 5,000). These resins are frequently modified by incorporation of, e.g., nitrocellulose, NC, or phenolics. Alkyds are used mainly as lacquers. A material made by blending polymers or copolymers with other polymers or elastomers under selected conditions, e.g., styrene-acrylonitrile copolymer (SAN) blended with butadiene-acrylonitrile elastomer (NBR). A mixture of two chemically different polymers to form a material having properties different from but often comprising those of the original resins. Also see “Polymer alloy.” Low-molecular-weight polymerization product of allyl monomer, CH2 ¼ CHCH2X, where, for example, X ¼ OH, –OOCCH3. Temperature of the medium surrounding an object. Used to denote prevailing room temperature (RT). Collective term for resins that are capable of being cross-linked. Terms, aminoplast and amino plastic, are also used. The materials are based on compounds containing NH2 group and formaldehyde. The representatives are urea-, melamine-, and dicyanodiamide-based resins used for laminating and molding. A noncrystalline polymeric material that has no definite order or crystallinity. A polymer in which the macromolecular chain has a random conformation in solid (glassy or rubbery) state. On the one hand, an amorphous polymer may show a short range order, while on the other, a crystalline polymer may be quenched to the amorphous state (viz., polyethylene terephthalate (PET)). The maximum value of a periodically varying function, e.g., used to describe the energy transmitted from the ultrasonic welding horn to the weld joint. A statistical technique where the total variation of the investigated response is being analyzed or divided into meaningful components, such as a portion due to regression and a portion due to error. 2192 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Anionic polymerization Anisometry Anisotropy Annealing Antioxidant Antiplasticization Chain polymerization in which the active center is an anion, usually carbanion. The method is mostly used to polymerize vinyl monomers carrying electronwithdrawing substituents (e.g., CN, COOR, COR, aryl). The polymerization is frequently initiated by n-butyllithium. The difference in the magnitude of the dimensions of a particle that depend on the direction. Thus, sphere is isometric – it has a minimum of anisometry. It is customary to define anisometry in terms of the aspect ratio, p. For platelets, p is defined as the thickness divided by the longest orthogonal dimension; thus, for platelets, p 1. By contrast, for fiber-like particles, p is the length-to-diameter ratio, i.e., p 1. Macromolecules show high anisometry with a typical value p ¼ 1,000. The material properties being dependent on the direction. Most multiphase polymeric systems show some degree of anisometry. The mechanical performance in the machine direction can be as much as a hundred times higher than those in the transverse direction. In homopolymers, the anisotropy is a reflection of the molecular orientation in either a glassy or a semicrystalline state (see “Birefringence”). To heat a molded plastic article to a predetermined temperature and slowly cool it to relieve stresses. Annealing of molded or machined parts may be done dry, as in an oven, or wet, as in a heated tank of mineral oil. To relieve the stresses without introducing major change of the molecular structure in the formed article, the annealing is frequently carried out at a temperature being few degrees below the glass transition temperature, Tg. The treatment is also used to increase polymer crystallinity. The process requires keeping the polymer at a temperature T < Td (where Td is the thermal degradation temperature). The best results are usually obtained when (Tg + Tm)/2 T < Tm, where Tm is the melting temperature. A substance that, when added in small quantities to the resin during mixing, prevents its oxidative degradation and contributes to the maintenance of its properties. An increase of stiffness, tensile strength, and/or the glass transition temperature and a decrease of the elongation at break caused by addition of small amount of a plasticizer. For example, maximum hardness of Appendix III: Dictionary of Terms Used in Polymer Science and Technology Antistatic agents (antistats) Apparent or bulk density Arc resistance Aromatic Aromatic polymer Artificial aging 2193 polyvinylchloride was observed at 5–10 phr of diethylhexyl phthalate, PVC/DOP, and minimum impact strength at 12 phr. Antiplasticization occurs in many polymers, viz., PVC, polymethylmethacrylate (PMMA), polystyrene (PS), polycarbonate (PC), polyamides (PA), and silk (by water). Substances that, when added to the molding material or applied on the surface of the molded part, make it less able to store static electrical charge. Weight of unit volume of material including voids (air) inherent in the material. The time required for a given electrical current to render the plastic surface of a material conductive because of carbonization by the arc flame. Also ability to resist the action of a high voltage electrical arc, usually in terms of time required to render the material electrically conductive. The total time (in sec) that intermittent arc may play across the plastic surface with rendering the surface conductive. Description used for chemicals that have at least one ring structure derived from benzene in their chemical structure. Benzene rings are made by six carbon atoms forming a hexagonal structure with alternating single and double bonds. The description is general and covers a wide range of chemicals. The word “aromatic” is used because of the strong smell of benzene. Many of the chemicals classified as aromatics have a very different smell or no smell at all. A benzene ring structure with one bonding site is a “phenyl” ring or group. See also “Benzene.” A polymer containing aromatic ring structures, viz., polyamides, polyesters, polyethers, polysulfides, polysulfones, polysiloxanes. The exposure of a plastic to conditions that accelerate the effects of time, such as heating, exposure to cold, flexing, application of electrical field, immersion in water, exposure to chemicals and solvents, ultraviolet, light stability, and resistance to fatigue. The accelerated testing of plastic specimens to determine their changes in properties carried out over a short time. The tests indicate what may be expected of a material under service conditions over extended periods. Typical investigations include those for dimensional stability, mechanical fatigue, chemical resistance, stress cracking resistance, dielectric strength, and so forth, under the 2194 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Ashing Aspect ratio ASTM Atactic polymer Atom Attenuation Autoclave Autoclave molding conditions that reflect the conditions under which the article will be used. Usually, the time the article is exposed to these test conditions is relatively short. See also “Aging.” The reduction of a polymer by high heat to yield any inorganic material, e.g., fillers or reinforcements, used to verify the percentage of nonorganic content in the resin. The relative comparison of one dimension of an object to another. For fibers, the aspect ratio is the length divided by the diameter. For mica, it is the shorter of the length and width of a platelet to its thickness. For complex objects like a particle of clay, it is a relative number approximating the ratio of the longer of two dimensions to the shorter. This ratio is key in how effective a reinforcement is within a matrix of polymer molecules. Given uniform composition and coupling agents, higher aspect ratio reinforcement results in a higher increase in strength. The aspect ratio determines how much stress can be transferred to the fibers or platelets before being transferred back into polymer matrix. Abbreviation for American Society for Testing and Materials. A polymer in which at least one chain atom in a mer can exhibit stereoisomerism (e.g., –CH2C*HX–), but has no preference for one particular configuration, e.g., atactic vinyl polymers (PVC or PS), atactic polypropylene, and PP. The most basic compositional unit of the elements composed of protons, electrons, and neutrons. Elements are any substance composed solely of chemically identical atoms, viz., carbon, hydrogen, oxygen, sulfur, nitrogen, iron, and aluminum. The diminution of vibrations or energy over time or distance. The term is also used to describe a process of making thin and slender articles, e.g., the formation of fiber from molten glass. A closed vessel for conducting either a chemical reaction or other operation (e.g., cooling) under pressure and heat. Autoclaves are widely used for bonding and curing reinforced plastic laminates. A process in which after lay-up, winding, or warping, an entire assembly is placed in a heated autoclave, usually at 340–1,380 kPa (50–200 psi). The pressure results in higher density and improved removal of volatiles. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Automatic mold Auxiliary equipment Average molecular weight Back pressure Back taper or draft Backing plate Ball valve Banbury Barrel Batch Benzene 2195 The lay-ups are usually vacuum bagged with a bleeder and release cloth. A mold or die in injection or compression molding that repeatedly goes through the entire cycle without human assistance. Refers to equipment, other than the principal processing unit (e.g., an extruder or an injection molding machine), required to ensure that the manufactured part would be made correctly. The auxiliary equipment comprises dryers, chillers, material and part conveyors, robots, process monitoring and controlling units, etc. Summation over the distribution of molecular weights of a polymeric substance, e.g., with respect to the number, Mn, weight, Mw, or higher moments. Depending on the method of determination, Mn, Mw, or higher average molecular weight is obtained. A pressure against the free flow of material during extrusion that causes the material to have a high mixing action. Also resistance of a material caused by its viscosity to flow when mold is closing. Reverse draft used in mold to prevent molded articles from drawing freely. In mold construction, a plate used as a support for the cavity blocks, guide pins, bushings, etc. A screw melt seal or valve, similar to a check ring valve, but designed differently. Uses a roundball to seal off the melt so it does not flow back over the screw flights during the injection cycle. An internal mixer for compounding, composed of a pair of counterrotating rotors that masticate the materials. In extrusion, injection molding, or blow molding machine a hollow tube in which the plastic material is gradually heated and melted and from which it is extruded. A quantity of materials formed during the same process or in one continuous process and having identical characteristics throughout. A chemical structure composed of six carbon atoms arranged in a stable cyclic structure. Each carbon atom is single bonded to the next carbon atom on one side and double bonded to the carbon atom on the other side. Each also has a hydrogen atom bonded to it. Phenyl groups are benzene rings where one of the carbon atoms is bonded to another molecule, making the entire cyclic structure a substituent or side group of that molecule. 2196 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Bezel Binder Binomial distribution Bimodal distribution Biopolymer Binodal Birefringence (double refraction) Bleed Bleeding Blending Blends Blister Blister packaging Block copolymers A grooved rim or flange. The resin or a cementing constituent that holds the other components together. The agent applied to mats or preforms to bond the fibers before molding. A discrete probability distribution based on two possible outcomes, which may be labeled success (with probability p) or failure (with probability q ¼ 1 p); the probability function expresses the number of X successes in n independent trials. A probability distribution in which the differential distribution function has two maxima. Polymer produced by biosynthesis in nature, viz., polysaccharides, nucleic acids, proteins, cellulose, lignin, and natural rubber. The line on the temperature vs. composition phase diagram for a mixture of two components, which separates the metastable region from the single-phase regions. Hence, it represents the limits of stability in a two-phase system, viz., a polymer solution or polymer blend. The difference between index of refraction in two directions, measured with polarized light. The birefringence originates in the molecular orientation in either a glassy or crystalline phase. Positive birefringence occurs when the principal optic axis lies along the chain and negative when it is perpendicular. See also “Dichroism.” To give up color when in contact with water or a solvent. Also a “migration,” undesired movement of additives in a plastic (e.g., plasticizers in PVC) to the surface of the finished article or into an adjacent material. The term is also used to describe a passage at the parting line of a mold (such as a vent, but deeper) that makes it possible for the material to escape or bleed. Diffusion of an additive in or out of a plastic part. See “Bleed.” Preparation of polymer blends or alloys, usually involving mixing of two polymeric liquids. see “Polymer blends.” A raised area on the surface of a molded part caused by the pressure of gases inside it. Packaging method based on sealing articles inside thermoformed, transparent cases. Copolymer synthesized from two or more monomers in such a way that monomers of the same kind are arranged in homopolymeric blocks. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Block polymerization Blocking Bloom Blow film extrusion Blow molding Blow pin Blowing agent Blueing off Blush Bonds Boss Bottom plate 2197 An older expression for bulk or mass polymerization. The adhesion between layers of plastic that may develop under pressure during storage or use. A visible exudation or efflorescence on the surface of a plastic – it may be caused by lubricant, plasticizer, etc. Techniques for making film by extruding the plastic through a circular die, followed by expansion (by the pressure of internal air admitted though the center of the mandrel), cooling, and collapsing the bubble. A molding process used to produce hollow objects in which a hollow tube (parison) is forced into a shape of the mold cavity using internal air pressure. The two primary types are injection blow molding and extrusion blow molding. Blow molding is a method of fabrication in which a warm plastic parison is placed between the two halves of a mold and forced to assume the shape of that mold cavity by use of air pressure introduced through the inside of the parison that forces the melt against the surface of the mold. A hollow pin inserted or made to contact the blowing mold so that the blowing media can be introduced into the parison or hollow form and expanded to conform to the mold cavity. Additive capable of producing a cellular structure in a plastic or rubber mass. Checking the accuracy of mold cutoff surfaces by putting a thin coating of Prussian blue on one-half and checking the blue transfer to the other half. The tendency of a plastic to turn white or chalky in areas that are highly stressed (viz., gate blush). Forces between atoms that hold them in relative proximity to each other resulting in larger structures called molecules. Primary bonds result from the sharing of two electrons of two atoms of the same molecule and are strongest. Secondary bonds are between atoms of different molecules or remote sections of the same molecule. They are the result of attractions due to polarity, induced polarity due to displaced electrons, and temporary polarity due to vibration and spinning. These bond forces are weak in comparison to primary bonds. A projection on a plastic part designed to add strength, facilitate alignment during assembly, and provide for fastening. Part of the mold containing the heel radius and push-up. 2198 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Branched chains Branched polymer Breaker plate Breathing or degassing Brittle failure Brittle or brittleness temperature Brittle point Buckling Bulk or apparent density Bulk factor Bulk polymerization Burning Side chains attached to the main, original chain. A nonlinear polymer in which the molecules consist of linear main chain to which there are randomly attached secondary chain branches, viz., low density polyethylene. A fraction of repeat units in a polymer that statistically contain one branch is defined as the branching density: l ¼ ab/n, where a is the branching coefficient (dependent on functionality of the branch point), b is the number of branch points, and n is the number of repeat units. A perforated plate located at the end of an extruder or at the nozzle end of an injection cylinder. It often supports the screens that prevent foreign particles from entering the die. The opening and closing of a mold to allow gases to escape early in the molding cycle. When referring to plastic film, “breathing” indicates permeability. Failure resulting from inability of material to absorb energy, resulting in instant fracture upon mechanical loading. Temperature at which plastics and elastomers exhibit brittle failure under impact conditions – the lowest temperature at which the material withstands given condition without failure. The highest temperature at which a material fractures in a prescribed impact test procedure. Crimping of the fibers in a composite material, often occurring in glass-reinforced thermosets due to resin shrinkage during cure. Average density of material in a loose or powdered form of plastic (granular, nodular, etc.) expressed as a ratio of weight to volume. Ratio of volume of any given quantity of the loose plastic material to the volume of the same quantity of the material after molding or forming. It is a measure of volume change that may be expected in fabrication. Polymerization where only the monomer and initiator (or catalyst) are involved. Owing to heat of polymerization and difficulty of safe dissipation of generated heat, the conversion rarely exceeds 50 %. Older terms: block or mass polymerization. Overheating the resin in the barrel causing discoloration and, if long enough, charring the material. Burning can be caused by trapped gases in poor or nonvented area of the mold. The gases may ignite, due to pressure and Appendix III: Dictionary of Terms Used in Polymer Science and Technology Burst strength Butadiene Butt fusion Buttress thread Calendering Calorimeter Capillary rheometer Carbon black Carbon fiber 2199 temperature (as in a diesel engine) and discolor or char the part. The internal pressure required to break a pressure vessel such as a pipe or fitting. The pressure (and therefore the burst strength) varies with the rate of pressure buildup and the time during which the pressure is held. A common name of a synthetic elastomer, polybutadiene – BR, e.g., used in butadiene-styrene, butadiene-acrylonitrile, and acrylonitrile-butadienestyrene copolymers. A method of joining similar forms of thermoplastic materials using heat. A type of thread used for transmitting power in only one direction. It has the efficiency of the square thread and the strength of the V-thread. The passing of sheet materials between sets of pressure rollers to produce a smooth finish sheet of desired thickness. An instrument capable of making absolute measurements of energy absorbed in a material by measuring changes of temperature. Instrument for measuring the flow properties (viscosity) of polymer melts. Composed of a capillary tube of specified diameter and length, means for applying a pressure to force molten polymer through the capillary, means for maintaining the desired temperature of the apparatus, and means for measuring differential pressures and flow rates. A black pigment or filler produced by the incomplete burning of natural gas or oil. It is widely used in the rubber industry and for wire/cable applications. Since it possesses ultraviolet protective properties, it is also used in formulations intended for outside weathering applications. Fibers produced by the pyrolysis of organic precursor fibers, such as rayon, polyacrylonitrile (PAN), and pitch, in an inert environment. The term is often used interchangeably with the term graphite; however, carbon fibers and graphite fibers differ. The differences lie in the temperature at which the fibers are made and heattreated, as well as in the amount of elemental carbon produced. Carbon fibers typically are carbonized at around 1,315 C and contain 94 1 % carbon, while graphite fibers are graphitized at 1,900–2,480 C and contain 99 % carbon. 2200 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Carborane polymer Carreau-Yasuda equation A polymer containing carborane structures, viz., –C(B10H10)C–, known for their high decomposition temperature Td } 500 C. Owing to the hydrogen presence, the oxidative stability is limited to about 300 C. Relation between viscosity, Z, and the deformation rate, y, was originally derived for monodisperse polymers: h ið1nÞ=2 Z ¼ Z0 1 þ ðtyÞ2 where Zo is the zero-shear viscosity, t is the principal relaxation time, and n is the power-law exponent. For polydispersed systems, the above equation was later modified by other authors to read: m2 Z ¼ Z0 ½1 þ ðtyÞm1 where m1 and m2 are polydispersity parameters: n ¼ 1 m1 m2 Cartridge heaters Catalyst Cationic polymerization Cavity Cavity number Cavity retainer plates Electrical heaters enclosed in a jacket that can be selectively located to heat the surrounding metal. A substrate that changes the rate of a chemical reaction without itself undergoing permanent change in composition or becoming a part of the molecular structure of the product. By contrast, either curing agents or hardeners may not only catalyze the reaction but also participate in it. Also accelerator, curing agent, hardener, inhibitor, and promoter. Chain polymerization in which the active center is a cation, usually carbonium ion, –C+. Generally, the method is used to polymerize vinyl monomers carrying electron-releasing substituents (e.g., alkyl or alkoxy groups). The polymerization is initiated by an initiator and co-initiator, viz., BH3 + H2O. A depression in the mold that usually forms the outer surface of the part. Depending on the number of such depressions, molds are designated as a single cavity, a multicavity, or a family cavity mold. A sequential number engraved in a mold cavity and reproduced on the molded part for later reference in case a problem ever occurs with the part. Plates in a mold that hold the cavities and usually contain the guide pins and bushings. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Ceiling temperature Cellular plastic Cellulose acetate Cellulosic plastics Cementing Center-gated mold Chain member number Chain polymerization 2201 Temperature at which the free polymerization energy is zero. Thus, above this temperature, no further polymerization takes place. A plastic with greatly decreased density because of the presence of numerous cells or bubbles dispersed throughout its mass. Also foamed plastics and synthetic cellular plastics. An acetic acid ester of cellulose, obtained by the action of acetic acid or acetic anhydride on purified cellulose (e.g., from cotton linters). All three hydroxyl groups of each glucose unit can be acetylated. For plastics’ applications, it is usual to acetylate fully and then lower the acetyl value to 54 2 % by partial hydrolysis. Plastics based on cellulose derivatives, such as esters (cellulose acetate) or ethers (ethyl cellulose). A process of joining two similar plastic materials to themselves or to dissimilar materials by means of solvents. An injection or transfer mold in which the cavity is filled with molding material through a sprue or gate directly into the center of the part. Number of atoms involved in building a macromolecule. An addition polymerization in which a monomer is converted to polymer in a chain reaction. Here initiator activates the monomer to which other monomers are added: I þ M ! IM IM þ M ! IMM Chalking Change request Charpy Charpy impact test preserving the active status of the terminal mer. The active center may be a free radical, an anion or a cation. A dry, whitish, powdery chalk-like appearance or deposit on the surface of a plastic caused by material degradation (usually from weather). See also “Haze” and “Bloom.” A request to modify or alter the dimensions, material, tolerances, or manufacture of a part now in or soon to be in production. Used to ensure all interested and involved department personnel are informed and can comment and approve or disapprove of the pending change. A common name of a type of pendulum tests for toughness. A test for shock loading in which a centrally notched sample bar is held at both ends and broken by striking 2202 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Check ring Chemical aging Chemical resistance Chi-square (w2) test Chromatography Chromium plating Clamping area Clamping force or pressure Clamping plate Clarity or transparency Closed loop the back face in the same plane as the notch. A destructive test measuring impact resistance, consisting of placing the specimen in a horizontal position between two supports, then striking the specimen with a pendulum striker swung from a fixed height. The magnitude of the blow is increased until specimen breaks. A material shutoff ring mounted on the front of the screw, behind the screw tip, that allows melt to flow past it when the screw is retracting so that a supply of melt builds up in front of the screw. When the screw moves forward to inject melt into the mold, the check ring moves rearward and seals off the screw flights so that the melt is pushed into the mold. The long-term deleterious effects on a material under defined natural or artificial environmental conditions (viz., light, temperature, humidity), leading to irreversible deterioration of properties. A process of exposing plastics to natural or artificial factors for prolonged time. See also “Aging,” “Accelerated aging,” “Artificial aging,” and “Physical aging.” Ability of a material to retain utility and appearance following contact with chemical agents. Test of normality of distribution or a goodness of fit. The separation, especially of closely related compounds, caused by allowing a solution or mixture to seep through an absorbent, such that each compound becomes adsorbed in a separate layer. An electrolytic process that deposits a hard film of chromium metal onto working surfaces of other metals. Used when resistance to corrosion, abrasion, and/or erosion is needed. The largest rate molding area an injection or transfer press can hold closed under full molding pressure. In injection molding, the pressure applied to the mold to keep it closed despite the fluid pressure of the compressed molding material within the cavity and runner system. A plate used to fasten the mold to a molding machine. Frequently considered as evidence of blends miscibility or at least that of fine domains. This, however, is misleading when the refractive indices of the two polymers approach each other. Also material clearness or lack of haze. A feedback system used with microprocessor for control of a processing unit operation. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Coefficient of expansion or thermal expansion Coefficient of friction Coefficient of linear expansion Coefficient of regression, or coefficient of correlation, R Coefficient of thermal expansion Coining Cold flow Cold shot Cold slug Cold slug well Colloid Colloidal molecules Color concentrate 2203 The fractional change in a specified dimension or volume of a material for a unit change in temperature. Values for plastics range from 10 to 200 ppm per 1 C (ASTM D696). A measure of the resistance to sliding of one surface in contact with another. The value calculated under a known set of conditions, such as pressure, surface, speed, temperature, and material, to develop a number, either static or dynamic, of the resistance of the material to slide – the lower the value, the higher the material’s lubricity. A measure of the change in dimension of an object caused by a change in temperature; specifically measured by the increase in length of an object per one degree. Measure of the degree of relationship between a model obtained by regression (curve fitting) and the independent variables; if reported as 100R2 (%), it can be interpreted as the percentage variation explained by the postulated model. The change in volume per unit volume produced by a one degree rise in temperature. The peening over or compressing of a material to change its original shape or form. A plastic exhibits cold flow when it does not return to its original dimensions after being subjected to stress. See also “Creep.” Incomplete parts formed while cycling a molding machine during heating. The first material to enter an injection mold so called because in passing through sprue orifice, it is cooled below the effective molding temperature. Space provided directly opposite the sprue opening in an injection mold to trap the cold slug. A system in which at least one component exists in state of fine dispersion with particle diameter d ¼ 1 to 1,000 nm. Three types, colloidal dispersions, lyophilic colloids, and colloidal associations, are distinguished. A discrete macromolecule is the colloidal particle. A mixture of a measured amount of dye or pigment and a specific plastic material base. A more precise color can be obtained using concentrates than using neat colors. Note: Care should be taken to verify that the color concentrate base is miscible with the plastic it is to color. Color concentrate may contain up to 60 wt% of 2204 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Color standard Colorfast Colorimeter Commodity resin Compatibility Compatibilization Compatible polymer blend Complex modulus Compliance Composites pigment and it is normally used at 1–4 % of the plastic material to be colored. The exact color a plastic resin or part must match to be acceptable. Resin suppliers often submit color chip samples of the matched resin color to be compared to the molded part. The color chip, or standard, is usually 51 76 mm with one polished surface and various textured surfaces on the opposite side. Suppliers use similar standards to verify the color of each lot of resin shipped to their customer. The ability to resist change in color. Instrument for matching colors with results approximately the same as those of visual inspection but more consistently. The term associated with the high-volume low-price resins having low-to-medium physical properties, used for less critical applications. The principal five resin types are polyethylenes (PE), polypropylenes (PP), styrenics (PS, HIPS, ABS, MBS, etc.), acrylics, and vinyls (PVC, EVAc, etc.). Ill-defined term pertaining to ability of one material to coexist with another without undesirable effects – to be avoided. A process of modification of interfacial properties of an immiscible polymer blend, leading to creation of a polymer alloy. Ill-defined, utilitarian term indicating a commercially attractive polymer mixture, normally homogenous to the eye, frequently with enhanced physical properties over the constituent polymers – to be avoided. The ratio of stress to strain in which each is a vector that may be represented by a complex number. It may be measured in tension or flexure, E*; compression, K*; or shear, G*. Tensile compliance is the reciprocal of Young’s modulus. Shear compliance is the reciprocal of shear modulus. The term is also used in the evaluation of stiffness and deflection. Any solid material that consists of a combination of two or more types retaining their separate identity. In polymer technology, the term is reserved for these polymeric systems in which additions of solid particles result in reinforcing effect. The composites are divided into reinforced filled systems (with a particle size: Appendix III: Dictionary of Terms Used in Polymer Science and Technology Compound Compounding Compression molding Compression ratio Compressive strength Concentricity Condensation polymer Conditioning Conditioning chamber Configuration 2205 d ¼ 50 nm), short fiber composites, long fiber composites, and continuous fiber composites. A mixture of polymer(s) with all materials necessary for the finished product. In reinforced plastics and composites, the intimate admixture of a polymer with other ingredients, such as fillers, softeners, plasticizers, reinforcements, catalysts, pigments, dyes, etc. Preparation of a compound. A molding technique in which the preheated compound is placed in the heated open mold cavity, the mold is closed, pressurized (what causes the material to flow and fill the cavity), and then pressure is held until the material has cured. In an extruder is a ratio of volume available in the first flight (at the feed) to the last flight at the end of the screw (near the die). The ability of a material to resist a compressive force. It is expressed as maximum load sustained by a test specimen in a compressive test divided by original crosssectional area of the specimen or, in other words, a crushing load at the failure divided by the original sectional area of the specimen (ASTM D695). The relationship of all circular surfaces with the same center. Deviation from concentricity is often referred to as a runout. A polymer obtained in step-growth polymerization, often accompanied by elimination of small molecules (e.g., water). Polyesters, polyamides, phenol-, melamine-, and urea-formaldehyde resins are typical condensation polymers. The subjection of a material to standard environmental and/or stress history before testing, so that it will respond in a uniform way to subsequent testing or processing. The term is frequently used to refer to the treatment given before testing. ASTM standard conditions for a plastic testing laboratory are 23 2 C and 50 + 5 % relative humidity. An enclosure used to prepare parts for their next step in the assembly or decorating process. Parts can be stress relieved, humidity or moisture conditioned, or impregnated with another element. Spatial arrangement of atoms in a molecule. The chemical constitution of a polymer chain, which can be changed only by breaking the chemical bonds. 2206 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Conformation Arrangements of the chain elements in space, which may be changed by rotation about bonds. The conformation depends on the internal and external forces, e.g., interactions, pressure, temperature, and stresses. For polymers with the carbon-carbon main chain, two conformations are important: trans or t and gauche or g: CH3 CH3 H H gauche Conjugated polymer Continuous use temperature (CUT) Cooling channels Cooling or shrink fixture Cooling time Copolycondensation Copolymer H H CH3 H H H H CH3 trans The helical conformations are defined by the long sequences of these two, viz., tgtgtgtgtgt and tggtggtggtggt. A polymer with sequence of conjugated double bonds, such as polyacetylene, polyphenylene, and dehydrogenated polyvinyl chloride. Maximum temperature at which material may be subjected to continuous use without fear of premature thermal degradation. Passageways within the body of a mold through which a cooling or heating medium (e.g., chilled water, steam, hot oil, or other fluids) can be circulated to control temperature on the mold surface. A block of steel, wood, or composite material that is similar to the shape of the molded piece. The hot molded part is taken from the mold, placed on it, and allowed to cool, without distorting. The time required after the gate freezes for the part to cool and becomes rigid enough for ejection from the mold cavity. Polycondensation of different monomers having either a different constitution or different functional groups following different reaction mechanisms. A polymer obtained from polymerization of two or more monomers, where the repeating structural units of both are present within each molecule, thus comprising more than one chemical species. In most cases, the term refers Appendix III: Dictionary of Terms Used in Polymer Science and Technology Copolymerization parameter Copolymerization Core Coring Corona treatment Corrosion Corrosion resistance Coupling agent Covalent bond Crack Crazing 2207 to a polymer containing two monomer types, e.g., styrene and butadiene (SBR). When a copolymer contains three or four different mer species terms, terpolymer, tetrapolymer, or multipolymer may be used. Seven types of copolymers are recognized: statistical, random, alternating, periodic, graft, block, and core-shell. The copolymers may be prepared in reactive blending, with properties intermittent between those of polymers of the two composing monomers. Ratio of the velocity constants during copolymerization. Polymerization with more than one species of monomer, which can react with one another, forming a copolymer. Either a male element in die that produces a hole or recess in a part, a part of a complex mold that molds undercut parts (cores are usually withdrawn to one side before the main sections of the mold open), a channel in a mold for circulation of a heat-transfer medium or the central part of a laminate. Removal of excess material from the cross section of a molded part to attain a more uniform wall thickness. Exposing a plastic part to a corona discharge increases receptivity to inks, lacquers, paints, and adhesives. See also “Surface treatment.” Material that is eaten away by chemical reactions at the surface. The ability of a material to withstand contact with ambient natural factors or those of a particular artificially created atmosphere. A material used to improve the interfacial properties between two phases. The term most frequently refers to the material used to improve an adhesion between polymer matrix and filler or reinforcing particles. A bond where electrons are equally shared between two atoms producing a stable electron configuration and a very stable molecule. Covalent bonds are the strongest of the molecular bonds. A fracture, a separation of material, visible on opposite surfaces of the part, and extending through the thickness. A series of or the forming of very fine cracks in the surface of a material, usually a polymeric substance. The cracks may extend in a network on or under the surface or through a layer of plastic material. These are 2208 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Creep Creep modulus (apparent modulus) Creep rupture strength Creep strength Cross-links Cross-linking Cross-linked polymer undesirable defects, characterized by distinct cracks or minute, frost-like internal cracks, resulting from stresses within the article. These stresses result from molding shrinkage, machining, flexing, impact shocks, temperature changes, or action of solvents. Crazing is generally caused by chemical attack or other degrading agents such as ultraviolet radiation. The change in dimension of a plastic under load over a period of time (excluding the initial instantaneous elastic deformation). Owing to viscoelastic nature, a plastic subjected to a load for a period of time tends to deform more than it would from the same load released immediately after application. The degree of this deformation depends on the load duration. Creep is the permanent deformation resulting from prolonged application of stress below the elastic limit. Data obtained in creep test are presented as creep vs. time, with stress and temperature constant. Slope of the curve is the creep rate, and the end point of the curve is the time for rupture. Creep at room temperature is called cold flow (ASTM D674). Ratio of initial applied stress to creep strain. Stress required to cause fracture in a creep test. Maximum stress required to cause specific creep in specific time. Covalent bonds, or a short sequence of chemical bonds, joining two macromolecules to form a cross-linked or network polymer. The chemical reaction between polymeric molecules to form covalently bonded three-dimensional macromolecules. The reaction progresses from a linear chain to branched elastomeric macromolecules, than to hard and brittle resin. When extensive, as in most thermosetting resins, cross-linking engenders a single, infusible supermolecule of all the chains. Cross-linking can be achieved by irradiation with high energy electron beams or by chemical means. A polymer in which initially linear macromolecules are joined by a covalent bond or a short sequence of chemical bonds either during the polymerization [e.g., poly(styrene-co-divinylbenzene)] or in a postpolymerization cross-linking reaction (cross-linking, curing, or vulcanization). The cross-linked materials are insoluble and they do not flow when heated. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Crystalline polymer Crystallinity Cup flow test Cup viscosity test Cure Curing Cushion Curing time Cycle Cyclopolymerization 2209 A material having an internal structure in which the atoms are arranged in an orderly three-dimensional configuration. More accurately a semicrystalline polymer, since only a portion of the macromolecules is in crystalline form. A state of molecular structure attributed to existence of solid crystals with a definite geometric form. Such structures are characterized by uniformity and compactness. A regular arrangement of the atoms of a solid in space. In most polymers, including cellulose, this state is imperfect. The crystalline regions are submicroscopic volumes in which there is a degree of regularity sufficient to obtain X-ray diffraction patterns. High crystallinity causes a polymer to be less transparent or opaque. Test for measuring the flow properties of thermosetting materials. A standard mold is charged with preweighed material, and the mold is closed using sufficient pressure to form a required cup. Minimum pressures required to mold a standard cup and the time required to close the mold fully are determined. Test for making flow comparison under strictly comparable conditions. The cup viscosity test employs a cup-shaped gravity device that permits the timed flow of a known volume of liquid passing through an orifice located at the bottom of the cup. That portion of the molding cycle during which the plastic material in the mold becomes sufficiently rigid to permit ejection. Cross-linking or vulcanizing a polymer to improve such properties as modulus, strength, thermal stability, etc. The 5–10 mm of resin in front of the screw tip that remains at the end of the injection cycle. It is used to maintain packing pressure on the melt until the cavity gate freezes. The time between the end of injection pressure and the opening of the mold. Complete, repetitive sequence of operations in a process or part of a process. In molding, the cycle time is the period, between a certain point in one cycle and the same point in the next. Polymerization leading to ring structures, with usually low molecular weight and low viscosity. These prepolymers or cyclomers can be used at a higher temperature in the subsequent catalyzed reaction to generate a high molecular weight, linear polymers, viz., 2210 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Damping Daylight opening Deboss(ed) Decompression Deflashing Deflection temperature under load (DTUL) Deformation Degating Degradation Degree of polymerization Delaminate Density Depropagation or unzipping Desiccant Design of experiments (DOE) polycarbonates and polyesters. The cyclomer technology facilitates preparation of polymer alloys, composites, or nanocomposites. The loss in energy, as dissipated heat, that results when a material system is subjected to an oscillatory load or displacement. Clearance between two platens of a press in the open position. Mold daylight describes the opening distance of mold halves for part removal. Indent or cut in design, or lettering of a surface. The removal of the melt pressure by an increase in screw flight depth and a positive vent opening in the barrel of a vented barrel extruder or injection molding machine. The term is used for a variety of finishing methods used to remove the flash (excess, unwanted material), viz., filing, sanding, milling, tumbling, and vibrating. The temperature at which a simple beam has deflected a given amount under load (formerly called heat distortion temperature (HDT)). Any change of form or shape in a body, in particular a linear change of dimension of a body in a given direction produced by the action of external forces. The removal of the part from the runner system. A deleterious change in the chemical structure, physical properties, and/or appearance of a plastic, usually caused by exposure to heat. Also any undesirable change of polymer chemical structure leading to deleterious change of properties, viz., thermal, hydrolytic, oxidative, photo, bio, and radiation. The number of mers in a macromolecule, i.e., the number of repeat units in the chain of a molecule, DP. In a condensation polymer, a repeating unit is composed of a monomer group from each reactive species. To split or separate a laminated plastic material along the plane of its layers. The weight per unit volume of a substance, expressed in kilograms per cubic meter. A degradation reaction in which the consecutive mers are gradually removed from one macromolecular chain end to another. Few polymers undergo this reverse kinetics process, viz., PMMA, POM, and PTFE. A substance that can be used for drying purposes because of its affinity to water. Process of planning the experiment so that sufficient data will be collected for the statistical analysis, to Appendix III: Dictionary of Terms Used in Polymer Science and Technology Degree of freedom Design stress Destaticization Destructive test Deterioration Devolatilization Diaphragm gate Diblock copolymer Dichroism Dichroic ratio Die Die adapter Die drips 2211 provide valid and objective conclusions. It includes the choice of the factors, levels, and treatments, as well as the use of certain tools called randomization and replication. The term is frequently used to indicate a problemsolving technique developed by Taguchi, i.e., by using a testing process with an orthogonal array to analyze data and determine the main contributing factors in the solution to the problem. The number of degree of freedom in statistical analysis is the number of independent elements used in the computation of that statistic. The long-term stress, including creep factors and safety factors, that is used in designing structural fabrication. Treating plastic materials to minimize their accumulation of static electricity. Any test performed on a part in an attempt to destroy it; often performed to see how much abuse the part can tolerate without failing. Permanent change in the physical properties of a plastic evidenced by impairment of these properties. The removal of volatile components during processing. The gate used in molding annular or tubular articles that forms a solid web across the opening of the part. A block copolymer made of two blocks, one having a chain of AAAAA mers and the other of BBBBB to form AAAAAA BBBBBBB polymer. The two block copolymers are used as compatibilizers in the poly-A + poly-B mixtures. The dependence of absorbency of polarized radiation on the direction of polarization. For polymers the magnitude of dichroism, expressed as dichroic ratio, depends on the orientation of the radiation absorbing groups, thus the macromolecules. In consequence, the infrared dichroism is a powerful method to measure the molecular orientation. The ratio of absorbencies of polarized radiation, usually the infrared region. The dichroic ratio is used as a measure of molecular orientation in oriented polymers. The dichroic ratio may provide information on the orientation in the glassy and at the same time in the crystalline phase. A metal form in making or punching plastic products. The part of an extrusion die that holds the die block. Carbonized resin drool formed on the face of an extrusion die face during the resin production cycle. If the die 2212 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Dielectric constant or permittivity Dielectric heating (also electronic, or R.F. heating) Dielectric strength Dielectrometry Differential scanning calorimetry (DSC) Differential shrinkage Differential thermal analysis (DTA) Diffusion face is not kept clean, it can solidify, break off, and contaminate the product. Normally the relative dielectric constant, in practice, a ratio of the capacitance of a given configuration of electrodes with a material as dielectric to the capacitance of the same electrodes’ configuration with a vacuum or air as dielectric. A relative measure of nonconductance. Capacitance is the ability of a material to store electrical charge when exposed to electrical current. A low dielectric constant is desired for plastic components used to insulate and isolate electrical components from each other. High dielectric constant materials are desirable for use as the insulator portion of capacitors, so that the electrical energy can be stored in as small a volume of material as possible. The plastic to be heated forms the dielectric of a condenser to which a high frequency (20–80 MHz) voltage is applied. Dielectric loss in the material is the basis of the process (e.g., used for sealing vinyl films). The maximum electrical voltage a material can sustain before it is broken down, or “arced through.” Also an electrical voltage gradient at which an insulating material is broken down or “arced through.” An electrical technique to measure changes in loss factor and capacitance during cure of the resin. Also called dielectric spectroscopy. Thermal analysis technique that measures the quantity of energy absorbed or evolved (given off by a specimen as its temperature is changed). Also measurements of the energy absorbed (endotherm) or produced (exotherm) while undergoing glass transition, melting, crystallizing, curing, evaporating of solvents, and other processes involving energy change. Nonuniform material shrinkage in part caused by nonuniform distribution of stresses, thus orientation. An analytical method in which a specimen and a control are simultaneously heated and the difference in their temperatures is monitored. The difference provides information on the relative heat capacities, presence of solvents, changes in structure, and chemical reactions. See also DSC. The movement of a material, such as a gas or liquid, in the body of a polymer. If the gas or liquid is adsorbed on one side of a test piece and given off on the other, the phenomenon is related to permeability. Diffusion and Appendix III: Dictionary of Terms Used in Polymer Science and Technology Digital device Dimensional stability Discoloration Dished Dispersion Dispersive mixing Dissipation factor Distribution Distribution function Distributive mixing Domain Domed 2213 permeability are controlled by the chemical not physical mechanisms. Numerical output device that must index from the initial to the final output reading. More accurate than a similar analog device, but slower. Ability to retain the precise shape to which it was molded, cast, or otherwise fabricated. Either a change from an initial color possessed by a plastic or lack of uniformity in color over the whole area of an object caused either by overheating, light exposure, irradiation, or chemical attack. Showing a symmetrical distortion of a flat or curved section of a plastic object, so that as normally viewed, it appears concave or more concave than intended. See “Warpage.” Finely divided particles of one material suspended in another. A mixing process in which agglomerates are reduced in size by fracture due to stresses generated during mixing and/or drops of the dispersed phase are deformed and broken. Ratio of the conductance of a capacitor in which the material is dielectric to its substance, or the ratio of its parallel reactivity to its parallel resistance. Most plastics have a low dissipation factor, a desirable property because it minimizes the waste of electrical energy as heat. A method of describing the variation of a stable system, in which individual values are not predictable but in which the outcome as a group forms a pattern that can be described in terms of its location, spread, and shape. A differential or integral description of population. For the polymer molecular weight a mathematical description of the polydispersity. A mixing process in which the dispersed phase domains are uniformly distributed – a reduction of nonuniformity. A morphological term used in noncrystalline systems, such as block copolymers, in which the chemically different sections of the chain separate, generating amorphous phases. Showing a symmetrical distortion of a flat or curved section of a plastic object, so that as normally viewed, it appears convex or more convex than intended. See “Warpage.” 2214 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Double strand polymer Double-shot molding Draft Drool Drop impact test Dry as molded (DAM) Dry blend Dry coloring Dryers Ductility Duromer Durometer hardness Rigid rod “ladder polymer,” consisting of two parallel chains of polymer regularly joined by covalent bonding, viz., pyrrones, polyquinoxalines, and polyphenylsilsesquioxane. A method of producing two-color pieces in thermoplastic materials by successive injection molding operations. A taper or slope in a mold that facilitates removal of the molded piece. The opposite of this is called back draft, q.v. Melt oozing from a nozzle that is not correctly temperature controlled, or presence of drip on the face of extruder die. Impact resistance test in which a predetermined weight is allowed to fall freely onto the specimen from varying heights. Term used to describe a part immediately after it is removed from a mold and allowed cooling down. All physical, chemical, and electrical property tests are performed on nonconditioned test bars and the results recorded on the data sheets. Parts and test bars in this DAM state are felt to be their weakest in some properties as they have not had time to condition or relieve the molded-in stresses. Molding compound containing all necessary ingredients mixed in a way that produces a dry, free flowing, particulate material (commonly used for PVC formulations). A method commonly used to color plastic by tumble blending uncolored particles of the plastic material with selected dyes and pigments. Auxiliary equipment used to dry resins before processing to ensure that surface properties are within manufacturer specifications. There are several styles of dryers, including ovens, microwave, hot-air desiccant bed, and refrigeration types. The amount of plastic strain that a material can withstand without fracturing, the extent to which a solid material can be drawn into a thinner cross section without breaking. Also, the ability of material to deform plastically before fracturing. Old German name for thermosets, i.e., strongly crosslinked, insoluble polymer. Measure of the indentation hardness of plastics, usually understood as hardness measured by the Shore Appendix III: Dictionary of Terms Used in Polymer Science and Technology Dwell Dyes Dynamic mechanical measurement Ebonite Ejection Ejection time Ejector pin (ejector sleeve) Ejector pin retainer Plate Ejector return pins Ejector rod or bar Elastic deformation Elastic limit 2215 Durometer as an extent to which a spring-loaded steel indenter protrudes into the material. A pause in the application of pressure to a mold, just before the mold is completely closed, to allow the escape of gas from the thermoset molding material. Also the time between when the injection ram is fully forward holding pressure on the material within the mold and the time the ram retracts. Intensely colored synthetics or natural chemicals that are soluble in most common solvents and can be dissolved in a resin to impart color. Dyes are characterized by good transparency, high tinctorial strength, and low specific gravity. A technique in which either the modulus or damping of a substance under oscillatory load or displacement is measured as a function of temperature, frequency, time, or their combination. A material consisting of rubber cured with large quantity with sulfur (one sulfur atom per 4–8 main chain carbons). The removal by mechanical means of the finished part from the mold cavity. Time in the cycle when the mold opens, the part is ejected, the mold closes, and clamping pressure is applied. A rod, pin, or sleeve that pushes a molding off a core or out of a cavity. It is attached to an ejector bar or plate that can be activated by the ejector rod(s) or the press or by auxiliary hydraulic or air cylinders. A retainer plate onto which ejector pins are assembled. Projections that push the ejector assembly back as the mold closes. Also called safety pins or position push backs. A bar that activates the ejector assembly when the mold is open. A deformation in which a substance returns to its original dimensions on release of the deforming stress – any portion of the total deformation of a body that occurs immediately when load is applied and disappears immediately and completely when the load is removed. The greatest stress a material is capable of sustaining without permanent strain remaining after the complete release of the stress. A material is said to have passed its 2216 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Elastic recovery Elasticity Elastomers Elastomeric Electric discharge machining (EDM) Electrical strength [dielectric strength] Electroformed molds Electronic data interchange (EDI) Electroplating Elongation at break Elongation elastic limit when the load is sufficient to initiate plastic, or non-recoverable, deformation. The fraction of a given deformation that behaves elastically. A perfectly elastic material has an elastic recovery of one, while a perfectly plastic material has an elastic recovery of zero. That property of plastic materials because of which they tend to recover their original size and shape after removal of a force causing deformation. If the strain is proportional to the applied stress, the material is said to exhibit Hookean or ideal elasticity. A customary name for substances showing the plastic–elastic behavior, characteristic for vulcanized rubberlike synthetic or natural polymers, viz., rubbers and weakly cross-linked polyether and polyester urethanes. The property of a material that at room temperature can be stretched under low stress to at least twice its original length and, upon immediate release of the stress, will return with force to its approximate original length. A metal-working process applicable to mold construction in which controlled sparking is used to erode the workpiece. That property of an insulating material that enables it to withstand electrical stress. The electrical strength is defined as the highest electrical stress that an insulating material can withstand for a specified time without the occurrence of electrical breakdown. A mold made by electroplating metal on the reverse pattern of the cavity. Molten steel may be then sprayed on the back of the mold to increase its strength. Exchange of data by customer and supplier computers, usually through a third neutral company that safeguards the host computers from unwanted entry. Used for order placement, shipment, receiving, billing, and payment. A deposition of metals on certain plastics and mold for finish. Elongation recorded at the moment of rupture of a specimen, often expressed as a fraction or percentage of the original length. Deformation caused by stretching, or fractional increase in length of a material in tension, expressed as a percentage difference between the original length and the length at the moment of the break – higher elongation indicates higher ductility. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Embossing Embrittlement Emulsion Emulsion polymerization Endothermic Endurance or fatigue lifetime End use Engineering polymer alloy Engineering polymer Engineering polymer blend Engineering resin Environmental stress cracking (ESC) 2217 Techniques used to create depressions of a specific pattern in plastics’ films or sheeting. Also development of surface patterns on the molded part by photoengraving or a similar process. Reduction in ductility due to physical or chemical changes. A stable dispersion of one liquid in another created in the presence of an emulsifying agent (that has affinity with both phases). The emulsifying agent, discontinuous phase, and continuous phase produce the third phase, the interphase, which serves as an enveloping protective layer around each dispersed drop. Free radical polymerization of an emulsion, consisting of aqueous phase containing an initiator and emulsified oil phase containing the monomer. An action or reaction that absorbs heat. Maximum fluctuating stress a material can endure for infinite number of cycles – determined from the S-N diagram. Function the part or assembly was originally designed and manufactured to perform. A processable engineering material containing two or more compatibilized polymers, capable of being formed to precise and stable dimensions, exhibiting high performance at the continuous use temperature above 100 C, and having tensile strength exceeding 40 MPa. A processable polymeric material capable of being formed to precise and stable dimensions, exhibiting high performance at high temperature and high tensile strength. Usually to qualify for the term, the material must have the continuous use temperature above 100 C and the strength exceeding 40 MPa. Five types of polymers are customarily qualified as engineering resins: polyamide (PA), polycarbonates (PC), thermoplastic polyesters (EST), polyoxymethylene (POM), and modified polyphenylene ethers (PPE). A polymer blend either containing engineering polymer(s) or having properties of an engineering polymer. Term associated with plastics having medium to high physical properties used for structural and demanding applications. Five types of resins belong to this group: PA, PEST (viz., PBT, PET, PAr), PC, PPE, and POM. The susceptibility of a thermoplastic resin to crack or craze when in the presence of surface-active agents or other environments, e.g., under the influence of certain chemicals or aging, weather, and stress. 2218 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Epoxide Epoxy plastics Epoxy resin A compound containing 1,2-epoxide, CH2(O)CH–R, or its derivative. A thermoset polymer containing one or more epoxide groups and curable by reaction with amines, alcohols, phenols, carboxylic acids, acid anhydrides, and mercaptans. It has been primarily used as a matrix resin in composites and adhesives. An oligomer containing two or more epoxide groups per molecule cross-linked with a hardener, usually diglycidyl ether of bisphenol A or pentaerythritol: RH þ CHðOÞCH ! CðRÞH CðOHÞH Etch Ethylene plastics Ethylene-propylene rubber (EPR) Ethylene-vinyl acetate (EVAc) Exfoliated clay Exfoliation Exothermic Extensibility (or extendibility) Extensometer Extrudate swell (sometimes improperly called die swell) The OH group may further react with the hardener, which leads to highly cross-linked thermoset polymer. To treat with an acid, leaving parts of the surface in relief to form the desired design. Plastics based on polymers of ethylene or copolymers of ethylene with other monomer, the ethylene being in greatest amount by mass. An elastomeric copolymer based on ethylene and propylene prepared in Ziegler-Natta polymerization. When small amount of a diene monomer is added, the resulting polymer becomes ethylene-propylene terpolymer, EPDM. A thermoplastic copolymer made from ethylene and vinyl acetate. This copolymer is similar to polyethylene but has considerably increased flexibility. Individual clay platelets dispersed in a matrix polymer with the interlayer distance d001 > 8.8 nm. The platelets can be randomly dispersed individually or as short stacks or tactoids. Chemical and/or mechanical means of dispersing clay platelets in a polymer matrix. The process usually starts with intercalated clay (q.v.). Pertaining to an action or reaction that gives off heat. The ability of a material to extend or elongate upon application of sufficient force, expressed as a percentage of the original length. Instrument for measuring changes in linear dimensions (also called strain gauge). The ratio of the outer parison diameter to the inner diameter of the die. The swell is influenced by polymer nature, die construction, land length, extrusion speed, additives (viz., external lubricants), and temperature. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Extruder Extrusion blow molding Extrusion Extrusion plastometer or melt indexer Exudation Fabricate Fading Fadometer Family mold 2219 A machine that accepts solid (pellets or powder) or liquid feed, conveys it through a surrounding barrel by means of a rotating screw(s), and pumps it, under pressure, through an orifice called “die.” Most often the process, in which a parison is extruded from a polymeric melt and is then entrapped between the halves of a mold. The parison is expanded by compressed air against the mold cavity, and then it is cooled, removed, and trimmed. Compacting a plastic material (powders or granules) into a uniform melt and forcing it through an orifice in a continuous fashion to yield a desired shape. While held in the desired shape, the melt must be cooled to solidify. The term also describes plasticization of a resin in an extruder (barrel-and-screw or plunger assembly) and forcing of the molten material or extrudate through a die or into a mold. Extrusion is the initial part of the molding process. A primitive viscometer used for determining the melt flow index, MFI. It is composed of a vertical cylinder with two longitudinal bored holes (one for measuring temperature and one for containing the specimen, the latter having an orifice of stipulated diameter at the bottom and a plunger from the top). The cylinder is heated by external bands, and weight is placed on the plunger to force the polymer specimen through the orifice. The result is reported in g/10 min. See also “Melt index.” Formation of liquid plasticizer on the surface of a plasticized (usually PVC) resin. To work a material into a finished form by machining, forming, or other operation. In the broadest sense, it means to manufacture. Any lightning of an initial color possessed by a plastic. Apparatus for determining the resistance of materials to fading by exposing them to ultraviolet rays of approximately the same wavelength as those found in sunlight. A multicavity mold in which each cavity forms a part that often has a direct relationship in usage to the other parts in the mold. Family molds can have more than one cavity making the same part, but they will still always have the same direct relationship to usage. The term is often applied to molds in which parts for different customers are grouped for economy of production. Sometimes called a combination mold. 2220 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Fan gate Fatigue Fatigue ductility Fatigue failure Fatigue limit Fatigue strength Feathered thread Feed throat Feedback Fiber Fiber-reinforced plastic (FRP) Fiberglass Fiberglass reinforcement A shallow gate somewhat wider than the runner from which it originates. Permanent structural changes that occur in a material subjected to fluctuating stress and strain, which cause decay of mechanical properties. See “S-N diagram.” The ability of a material to plastically deform before fracturing in constant strain amplitude and low-cycle fatigue tests. See “S-N diagram.” The failure or rupture of a plastic under repeated cyclic stress, at a point below the normal static breaking strength. See “S-N diagram.” The stress below which a material can be stressed cyclically for an infinite number of times without failure. See “S-N diagram.” Magnitude of fluctuating stress required to cause failure in a fatigue test specimen after specified number of cyclic loading – determined from the S-N diagram. Also the maximum cyclic stress a material can withstand for a given number of cycles before failure. The residual strength after being subjected to fatigue. See “S-N diagram.” A thread that is thin at one end and does not end abruptly. Usually found in screw machine parts. The section of the hopper mounted on the extruder to feed resin into the feed section of the barrel and screw. Information returned to a system or process to maintain the output within specified limits. See also “Closed loop.” Often the term is used synonymously with filament having a finite length, L ¼ 100d, where the diameter is typically d ¼ 100–130 mm. In most cases, it is prepared by drawing from a molten bath, spinning, or depositing on a substrate. Fibers can be continuous, long (10–50 mm) or short (about 3 mm). In the plastics industry almost synonymous with thin strands of glass used to reinforce both thermoplastic and thermosetting materials. A general term for a plastic that is reinforced with cloth, mats, strands, or any other fiber form. Filaments made by drawing molten glass. Continuous filaments have indefinite length. Staple fiber mat is made of glass fibers of the length generally 430 mm, the length depending on the forming or spinning process used. Major material used to reinforce plastic, available as mat, roving, fabric, and so forth. It is incorporated into both thermosets and thermoplastics. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Filament Filler Fillet Fines Finish Finite element analysis First surface Fisheye Fishbone diagram Fissure Fixture Flakes 2221 The smallest unit of a fibrous material. The basic units formed during drawing and spinning, which are gathered into strands of fiber for use as reinforcements. Filaments usually are of great length and small diameter, d < 25 mm. A relatively inert substance added to plastics to improve their physical, mechanical, thermal, electrical, or other properties or to lower cost or density. A compound or substance added to a polymer during the initial synthesis process or in subsequent processing to decrease the volume of resin needed to produce a given product. Fillers are generally much lower in cost than the resins they are used in, thus reducing resin cost per part. Fillers or extenders are generally not used with engineering resins. A rounded inside corner of a plastic piece. The rounded outside corner is called a bevel. Small particles mixed in with larger particles. The secondary work on a part so that it is ready for use: filing, deflashing, buffing, drilling, tapping, and degating are commonly called finishing operations. A stress analysis technique of a part using a computergenerated model that can take finite sections of the part for analysis of the forces and loads the part will experience in service. It generates a part-section analysis that shows the force concentrations in the section and determines if the material selected will be suitable for the part. The front surface of a plastic part, nearest the eye. A small, globular mass that has not completely blended into the surrounding polymeric material. This condition is particularly evident in a transparent or translucent film, fiber, or sheet. A problem analysis technique used to list all the variables and steps in the solution to a problem. All contributing elements are associated with each factor and taken back to their starting point to ensure that all variable elements are considered. A narrow opening crack in a material. Means of holding a part during a machine or other operation. A term used to describe resin residue formed on the inside of pipes during material transfer, created by the friction of the pellets against the surface of the transfer piping. With time, they build up, flake off, and can cause feed problems at the throat of the extruder. 2222 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Flame resistance Flame retardants Flame retarded Flame treatment Flammability Flash Flash gate Flash line Flash mold Flash trap Flex life Flexural modulus Flexural strength Flock Flocking Ability of a material to extinguish flame once the source of heat is removed. Chemicals used to reduce the tendency of a polymer to burn. A resin modified by flame-inhibiting additives so that exposure to a flame will not burn or will self-extinguish. Some resins will not burn and others can be modified to meet flame burning specifications, while others may not be able to be modified. A type of surface treatment that oxidizes a plastic surface for better reception of paint, inks, and adhesives. See also “Surface treatment.” Measure of the extent to which a material will support combustion. Extra plastic attached to a molding along the parting line. Under most conditions, it is objectionable and must be removed before parts are judged acceptable. Usually a long gate extending from a runner parallel to an edge of a molded part along the flash or parting line of the mold. A raised line appearing on the surface of a mold and formed at the junction of mold faces. “See Parting line.” A mold in which the faces are perpendicular to the clamping action of the press. The higher the clamping force, the tighter the mold seam. A molded-in lip or blind recess on a part that is used for trapping excess molten material during an assembly operation. It negates flash trimming secondary operations. The time of heat aging that an insulating material can withstand before failure when bent around a specific radius (used to evaluate thermal endurance). The ratio within the elastic limit of the applied stress to specimen’s strain during flexural deformation mode testing – a measure of relative stiffness. Ability of a material to flex without permanent distortion or breaking. The resistance of a material to being broken by bending stresses. Short fibers of cotton, wood, glass, etc., used as inexpensive filler. A decorating and/or sound-deadening technique where fibers of different materials are attached to the surface of a plastic part. Fibers can be oriented in specific directions and patterns determined by the techniques used, and adhesive patterns lay down on the surface of the part. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Flow Flow chart Flow curve Flow length Flow line Flow marks Flow coating Fluidized bed coating Fluoropolymer Fluoropolymers Foamed plastics or cellular plastics Foil decorating Force 2223 A qualitative description of the fluidity of a plastic material during processing. A quantitative value of fluidity may be expressed by the flow curve, melt index (MI), or melt flow index (MFI). A line chart that traces the whole process. A log-log plot of the isothermal viscosity as a function of the deformation rate. The actual distance a material will flow under a set of molding machine conditions. Influenced by the processing and mold design variables, the composition of the polymer, and any additives in the polymer. A mark on a molded piece made by the meeting of two flow fronts during molding. Also called weld line or weld mark. Wavy surface appearance of an object molded from thermoplastic resins, caused by improper flow of the resin into the mold. Also see “Splay marks.” A painting process in which the article to be painted is drenched under a curtain of lacquer. The part is withdrawn and rotated until the coating dries. Process in which small particles of a thermoplastic resin are suspended in a gas stream (generally air) and behave like a liquid. A heated article is immersed in this fluidized bed of powder. The particles melt and fuse to the heated surface, forming a smooth coating. A polymer whose mers contain fluorine, F. The family of fluorinated polymers that include polytetrafluoroethylene, (PTFE), polychlorotrifluoroethylene (PCTFE), polyvinylidenefluoride (PVDF), and fluorinated ethylene-propylene. These resins are characterized by good thermal and chemical resistance, nonadhesiveness, low dissipation factor, and low dielectric constant. They are available in a variety of forms, such as moldings, extrudates, dispersions, films, or tapes. Plastics with numerous cells disposed throughout its mass. Cells are formed by a blowing agent or by the reaction of the constituents. Resins in sponge form may be flexible or rigid; the cells may be open or closed. Molding paper, textile, or plastic foils printed with compatible inks directly onto a plastic part so that the foil is visible below the surface of the part as an integral decoration. That which changes the state of rest or motion in matter, measured by the rate of change of momentum. 2224 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Forming Fourier transform Fractionation Fracture strength Fracture Free radical polymerization Freeze drying Freeze-off Frequency Friction welding Full IPN Fusion bond The term usually applied to a process in which the shape of plastic pieces such as sheets, rods, or tubes is changed to a desired form. Usually the term does not include extrusion, molding, or casting, in which forms are made from molten polymers or solutions. An analytical method used in advanced forms of spectroscopic analysis such as infrared and nuclear magnetic resonance spectroscopy. Experimental methods for separating and isolating fractions, each with the more uniform molecular weight, and thus of low polydispersity. The process also serves for ascertaining the distribution function. The normal stress at the beginning of fracture. Calculated from the load at the beginning of fracture during a tension test, and the original cross-sectional area of the specimen. The separation of a body, defined both as rupture of the surface without complete separation of the laminate and as complete separation of a body because of external or internal forces. Polymerization in which the active centers of reaction are radicals. The polymerization can be initiated by thermally activated or redox initiator, by irradiation, or through thermal activation of monomer. A method of removing volatiles from solidified material at low temperatures. Refers to the gate area when polymer solidifies, as well as any area in the flow system when the melt becomes too cool to flow and solidifies. The number of times a specified phenomenon occurs within a specified interval, e.g., number of completed energy transmissions imparted to the welding horn in a vibratory motion. A means of assembling thermoplastic parts by melting them along their line of contact through friction. See also “Spin welding.” Any material containing two or more polymers in an intimate network form without induced cross-links between the individual polymers. The joining of two melt fronts that meet and solidify in a mold cavity. A bond formed during the assembly operation where the joint line is melted before assembly. See “Hot-plate welding,” “Induction welding,” and “Ultrasonic sealing.” Appendix III: Dictionary of Terms Used in Polymer Science and Technology Fusion Galling Gas-assisted injection molding (GAM) Gaseous blowing agent Gate Gauges Gaussian (or normal) distribution Gaylord Gel or Trommsdorff effect Gel permeation chromatography (GPC, more recently size exclusion chromatography, SEC) 2225 Heating of a vinyl dispersion to produce a homogeneous material. A surface area that is worn away by another by rubbing against it. An injection molding process that introduces a gas (usually nitrogen) into the plasticized material, to form voids in strategic locations. A compressed gas, such as compressed air or nitrogen, used to create a cellular structure or controlled voids in a rubber or plastic’s mass. In injection and transfer molding, the orifice through which the melt enters the cavity. Measuring devices used to determine if the part meets customer specifications, including micrometers and vernier calipers. A symmetrical, bell-shaped distribution function: o h i n y ¼ 1=sð2pÞ1=2 exp ½ðx xÞ=s2 =2 where x is a variable and s is the standard deviation. A term used to identify a box of resin vs. a bag or drum. Box size and weight of resin can vary depending on the density of the resin and the supplier’s box size. Box size usually conforms to the size of a standard pallet on which it is shipped. Auto-acceleration at the end of chain growth polymerization. With increasing size of the macroradicals, their mobility decreases and terminations are less frequent. However, the diffusion of the monomer remains unhindered and the polymerization proceeds exothermally, resulting in auto-acceleration. A form of liquid chromatography in which the polymers are separated by their ability or inability to penetrate the material in the separation columns. Column chromatography technique employing a series of columns containing closely packed rigid gel particles. The polymer to be analyzed is introduced at the top of the column and then is eluted with a solvent. The polymer molecules diffuse through the gel at rates depending on their molecular size. As they emerge from the columns, they are detected by differential refractometer, viscometer, FTIR device, etc. From the output of these detectors, a molecular weight distribution curve can be obtained. 2226 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Gel point Gel solutions Gel Generic Glass Glass-mat thermoplastics, (GMT) Glass transition temperature, or glass transition point, Tg Gloss Grades The stage at which a liquid begins to exhibit pseudoelastic properties. Also known as “gel time.” Concentrated solutions; intermediate state between gel and sol. That cross-linked part of polymer in liquid state, which having its network character may swell but not dissolve. Descriptive of an entire type or class of plastic resins. The base resin is one of a family of polymers, but there may be hundreds of product combinations. A material that solidifies from the molten state without crystallization, a supercooled liquid whose shear viscosity is Z 1012.5 Pas, a liquid whose rigidity is great enough to be put to use, or a glassy state of matter. A typical glassy material is hard and brittle (tensile modulus E } 70 GPa, tensile strength s } 0.5 GPa). Typical polymeric glasses are atactic polystyrene, atactic polymethylmethacrylate, polycarbonate, etc. A mat consisting of long glass fibers that are impregnated with a thermoplastic resin to produce a flat, homogeneous, semifinished composite blank. The center of the temperature range in which a noncrystalline solid changes from being glass brittle to being viscous or rubbery. The temperature, or a range of temperatures, separating the rigid (glassy) from elastic (rubbery or liquid) state of a polymer. For the transition to occur, 20 to 50 main chain atoms must be able to move in a cooperative manner. For the organic polymers 160 “Tg” 400 C depending on the intrinsic flexibility of the polymeric chain and its molecular weight. Since the transition is kinetic in nature, it depends on the rate or frequency. The measured Tg value depends considerably on the test rate, frequency, or mechanical deformation. Brightness or luster of a plastic resulting from a smooth surface. The shine or luster of the surface of a material (ASTM D 673). See “Specular gloss” and “Surface finish.” Polymers that belong to the same chemical family and are produced by the same manufacturer. They may vary in processing or performance due to differences in molecular weight, additives, or other structural features. For example, a supplier of PC may have flame-resistant grades, glass fiber-reinforced grades, a conductive grade, and easy flowing grades. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Graft copolymers Graining Graphite Graphite fiber Grinder or granulator Grit blasted Guide or leader pins Guideway Gusset Hand molds Hardenable substance Hardeners Hardening, curing Hardness 2227 A copolymer whose macromolecules consist of two or more macromolecular parts of different composition, covalently joined in such a way that one of the parts forms the main chain (polymer A) and the other(s) the side chains (polymer B). In a sense the block copolymers are graft copolymers in which the graft block B is attached to the end of main chain A. Graft copolymers are frequently used as compatibilizers. The term refers to wood graining on plastics. This can be done by hand, roller coating, hot stamping, or printing. A crystalline allotropic form of carbon. A fiber from either pitch or polyacrylonitrile (PAN) precursor by an oxidation, carbonization, and graphitization processes. See also “Carbon fiber.” A machine (in many sizes, styles, and capacities) with a series of knife blades and a sizing screen to chop up plastic materials for reuse. A surface treatment of a mold in which grit or sand materials are blown onto the walls of the cavity to produce a roughened surface. Air escape from mold is improved and special appearance of the molded article is often obtained by this method. Devices that maintain proper alignment of parts. Usually a T-shaped slot in a mold. An angular piece of material used to support or strengthen two adjoining walls. Molds that are removed from the press by the operator, who opens the mold and extracts the part by hand. Thermoset resin that, under the influence of temperature and/or reactive agent, undergoes cross-linking that irreversibly changes the chemical constitution and thereby physical properties. Polyfunctional substances that are able to cause crosslinking in thermosets. A chemical cross-linking of material, initially soft or that can be made so by warming, into a more viscous form or hard solid. The resistance to compression and surface indentation, usually measured by the depth of penetration of a blunt point under a given load using a particular instrument according to a prescribed procedure. Among the most important methods of testing are Barcol hardness, Brinell hardness, Knoop hardness, Mohs hardness, Rockwell hardness, and Shore hardness. 2228 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Haze Head Head-to-head structure Heading Heat resistance Heat sealing Heat stability Heat stabilizer Heat distortion temperature (HDT) Heated manifold mold Heater bands Heating chamber The degree of cloudiness in a plastic material. The cloudy or turbid aspect of appearance of an otherwise transparent specimen caused by light scattered from within the specimen or from its surface. The end section of the molding machine that consists of the core, die, mandrel, mold, and other parts necessary to form the plastic. A structure of the type –CH2CHX—CHXCH2– in polymers where the monomer placement in the growing chain has two isomeric possibilities: head-to-head (as shown) or head-to-tail, viz., –CH2CHX— CH2CHX–. The latter structure predominates. The mechanical, thermal, or ultrasonic deformation of a pin to form a locking attachment. The property or ability of plastics and elastomers to resist the deteriorating effects of elevated temperatures. A process of joining two or more thermoplastic films or sheets by heat. The resistance of a plastic material to chemical deterioration caused by exposure to heat during processing. An ingredient added to a polymer to improve its processing or end-use resistance to elevated temperatures. The term is used in different contexts depending on the benefit to be derived from the additive. For processing, it retards changes of color. For end use, it protects the surface of the part exposed to elevated temperatures. It does not imply that a resin can be used beyond its recommended end-use temperature rating if it is heat stabilized. The temperature at which a standard test bar deflects by an arbitrary value under a stated load. In ASTM D648, it is defined as a total deflection of 250 mm in a rectangular bar supported at both ends under a load of 0.5 or 1.8 MPa. The temperature is increased at a rate 2 C/min. A hot-runner mold that is both heated and insulated; an insulated mold is a hot-runner mold that does not contain heaters. The heat source for the barrel and nozzle. The temperature control is usually divided into rear, middle, front, and nozzle sections. The bands are accurate resistance heaters with high heat output. In injection molding that part of the machine in which the cold feed is reduced to a hot melt. Also called heating cylinder. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Helix Hermetic Heterogeneous Hiding power High-density polyethylene (HDPE) High-impact polystyrene (HIPS) Histogram Hob Hobbing Holding pressure Homologous polymer blend Homologous polymers Homopolymer 2229 A helical conformation of polymeric chain in which all main chain atoms can be placed on a cylindrical surface in such a way that all elements on that surface are cut at constant angle or, in other words, that the conformation is exactly repeated at constant intervals. For example, 31 helix in polypropylene has three repeating units per one helix turn. As in seal, to form a bond that is pressure tight, so that air or gases cannot enter or escape. Materials consisting of identifiable dissimilar constituents separated by internal boundaries. It is noteworthy that not all nonhomogeneous materials are necessarily heterogeneous. The opacity that can be effected with a coating. Linear polyethylene copolymers with low branching, having density r ¼ 940–960 kg/m3. The regular structure engenders material with greater strength, rigidity, chemical resistance, and higher softening temperature than the branched one. A thermoplastic resin from a styrene and elastomer. It has good dimensional stability and low-temperature impact strength, high rigidity, and ease of processing. A bar chart with the height of each bar indicating how many data points were collected within certain interval. The width of the bar provides a measure of the interval. A master model in hardened steel used to sink the shape of a mold cavity into a soft steel block. Forming multiple mold cavities by forcing a hob into soft steel cavity blanks. Also called sinking. The pressure maintained on the melt after the cavity is filled until the gate is filled and freezes. A mixture of two or more homologous polymers, usually narrow molecular weight distribution fractions of the same polymer. Polymers identical in structure and composition and differing only in molecular weight. A polydispersed polymer is a miscible blend of homologous polymers. The product of the polymerization of a single monomer, i.e., a polymer containing one type of repeating units, viz. ½CH2 CHX CH2 CHX n: Hone, honing, honed To impart a precise accuracy to the surface finish by using a fine-grained whetstone. 2230 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Hooke’s solid Hoop stress Hopper Hopper feeder Hot stamping or branding Hot tip Hot-plate welding Hot-runner mold Hot/heated manifold mold Hydrolysis Hydrophilic Hydrophobic Hygroscopic Hysteresis Immiscible polymer blend Impact strength An ideal elastic material where stress is directly proportional to strain. The circumferential stress in a material of cylindrical form subjected to internal or external pressure. A conical reservoir from which the molding powders or pellets are fed into the extruder. Usually part of the resin drying system that also can be an independent unit, to convey material to the machine’s feed hopper using vacuum or pressure. Engraving operation in which roll leaf is stamped with heated metal dies onto the face of the plastics. The precise controller and gating mechanism of a hot-runner mold. The use of a heated tool to cause surface melting of a part at the joint area. It is then removed before the joint surfaces being pressed together to form a fusion bond. A thermoplastic injection mold in which the runners are insulated from the chilled cavities and remain hot so that the center of the runner never cools in normal cycle operation. Runners are not usually ejected with the molded pieces. A thermoplastic injection mold in which the mold that contains the runner system has its own heating elements to keep the molding material in a plastic state ready for injection into the cavities, from which the manifold is insulated. Chemical decomposition of a substance involving the addition of water. Capable of absorbing water. Capable of repelling water. Material capable of absorbing and retaining atmospheric moisture from air. Plastics such as PA, PEST, or ABS are hygroscopic and must be dried before molding. The failure of a property that has been changed to return to its original value when the cause of the change was removed. The cyclic noncoincidence of the elastic loading and the unloading curves under cyclic stressing. The area of the resulting elliptical hysteresis loop is equal to the heat generated in the system. Any polymer blend whose free energy of mixing is positive: DGm > 0. The ability of a material to withstand shock loading, expressed as an amount of energy required to fracture a specimen subjected to impact. The work done in fracturing, under shock loading, using a specified test Appendix III: Dictionary of Terms Used in Polymer Science and Technology Impact test Induction welding Inert pigment Infrared (IR or FTIR) Infrared spectroscopy or spectrometry Inhibitor Initiator Injection blow molding Injection molding 2231 specimen and a specified procedure. Also, the relative susceptibility of plastic articles to fracture under stress applied at high speeds. Often associated with the Gardner (ball or falling dart) test, with a known weight falling at a known distance and hitting a part, thereby subjecting it to an instantaneous high load. ASTM impact tests for material properties are the Izod, Charpy, and tensile impact tests. The test can also be a pendulum type. The use of radio, magnetic, or electrical energy to form a melt through the application of a foreign medium at the joint line to form a fusion bond. A pigment that does not react with any component of paint. Pertaining to that part of the electromagnetic spectrum between the visible light range and the radar range. Radiant heat is in this range, and infrared heaters are frequently used in the thermoforming and curing of plastics and composites. Infrared analysis is used for identification of polymer constituents. The powerful Fourier transform infrared spectroscopy, FTIR, uses a method of splitting a beam into two waves, and the spectral information is obtained from the phase difference between the two waves, recombining them in the Michelson interferometer. The interferogram is obtained by digitizing the detector signal and transforming it from the time domain by means of the Fourier transform operation into a conventional IR spectrum. See “Infrared spectroscopy.” A technique used to observe the wavelengths in the electromagnetic spectrum lying beyond the red, from about 750 nm to a few mm. A substance that reacts with the active polymerization site either to form a totally nonreactive product or to reduce the system reactivity. In radical polymerization, the radical scavengers, viz., diphenylpicrylhydrazyl and quinones, are used as inhibitors. Either an additive mixed in a material to cause a chemical or physical reaction in the melt or a substance able to engender reaction of a monomer, radical or ionic. Blow molding in which the parison is directly formed by injection molding. A method of forming a plastic to the desired shape by forcing the softened plastic into a relative cool cavity 2232 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Injection pressure Injection ram Injection time Inorganic Inorganic pigments Inorganic polymer Insert Intercalated clay Intercalation Interface Interpenetrating polymer network, (IPN) using a screw or ram – used with thermoplastics or thermosets. See “Thermoplastic injection molding” and “Thermoset injection molding.” The pressure in the mold during the injection of plasticized material into the mold cavity. See “Ram.” The time it takes for the screw’s forward motion to fill the mold cavity with melt. A mineral compound not composed of carbon atoms. Natural or synthetic metallic oxides, sulfides, and other salts that impart color, as well as heat and light stability, and weathering resistance. A polymer with high proportions of non-carbon atoms. In principle, most inorganic materials can be considered inorganic polymers, viz., silicates. In polymer science, the inorganic materials containing organic groups are considered inorganic polymers, e.g., polysiloxanes (silicones), phosphonitrilic elastomers, polycarboranes, organometallic polymers, polymetaphosphates, polyphosphazenes, and sulfurnitride polymers. See also “Organic polymers.” An integral part of plastics molding. It consists of metal or other material that may be molded into position or may be pressed into the molding after the molding is completed. Also a removable or interchangeable component of the mold. Clay having organic or inorganic molecules inserted between its platelets, thus increasing the interlayer spacing between them to at least 1.5 nm. Process of inserting organic or inorganic molecules between platelets of a layered material, thus increasing the interlayer spacing. The boundary or surface between two different, physically distinguishable media. With fibers, the contact area between the fibers and sizing or finish. In laminates, the contact area between the reinforcements and the laminating resin. Historically, any material containing two or more polymers, each in network form, without induced cross-links between the individual polymers, usually produced by polymerizing and/or cross-linking at least one component in the immediate presence of the other, thus thermoset in character. Currently, the term IPN encompasses the thermoplastic co-continuous polymer blends, as well as ionomers and block and graft Appendix III: Dictionary of Terms Used in Polymer Science and Technology Interphase Intrinsic viscosity Ion exchange resins Ionic polymers or ionomers Ionomer Ishakawa Isomeric polymers Isotactic polymer Izod impact test Izod impact strength Jetting 2233 copolymers. The later materials are known as thermoplastic IPN. The boundary region between two phases in polymer blends, the matrix polymer and the dispersed phase, or (in case of phase co-continuity) between two polymeric phases. In compatibilized blends, the interphase contains the compatibilizer as well as low-molecularweight additives and fractions. The limiting value (at infinite dilution) of the ratio of specific viscosity of the polymer solution to concentration. Cross-linked polymers that form salts with ions from aqueous solutions. Polymers of linear or network structure with ionic groups which by addition of the appropriate counterions can be ionically cross-linked. A copolymer of ethylene and acrylic acid is used as a compatibilizer in polyamide blends. Converted to ethylene-zinc acrylate copolymer, Surlyn™ is used as packaging film. Other ionic polymers are applied as polyelectrolytes, ion exchange resin, etc. Polyethylene that contains both covalent and ionic bonds. The polymer exhibits strong interchain ionic forces. The anions hang from the hydrocarbon chain, and the cations are metallic, e.g., Na, K, Li, Zn, and Mg. The resins have similar properties as polyethylenes, with high transparency, tenacity, resilience, and increased resistance to oils, greases, and solvents. See Fishbone diagram. Polymers that are basically homogeneous but in which, by secondary alterations or by a small number of different kinds of linking of the primary molecules (e.g., branching), variations are introduced. A polymer in which the constitutional repeating units have the same stereochemical configuration, for example, isotactic polypropylene. A type of pendulum impact test in which a notched sample bar is held at one end and broken by a blow. This is a test for shock loading. Determination of the resistance of a plastic material to a shock loading, in which a notched specimen bar is held at one end and broken by striking, and the energy absorbed is measured. Turbulent flow of plastic from an undersized gate or thin section into a thicker mold section, as opposed to 2234 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Just-in-time (JIT) Kirksite Kneading elements, kneading blocks Knit line Knockout or ejector pin Kurtosis Lack of fill-out Ladder polymer laminar flow of material progressing radially from a gate to the extremities of the cavity. May also result from shooting material into a mold cavity where there is no core or immediate cavity wall to break up the flow of the material coming through the gate. A practice developed to minimize customer inventory. The supplier provides the product, at predetermined intervals, so that it can proceed directly to the customer’s assembly line. This practice demands excellent quality control and production schedules. Customers who use JIT must demand the same care and treatment from their own suppliers. Suppliers and customers are usually located within a few hours shipping time of each other. An alloy of aluminum and zinc used for the construction of prototype molds. It imparts a high degree of heat conductivity to the mold Three types of elements are used to assemble screws in a twin-screw extruder: kneading, mixing, and transporting. The kneading elements are mostly twoor three-lobe self-wiping that mainly provide for the dispersive mixing by pressing, stretching, and folding actions. An assembly of kneading elements is known as a kneading block, characterized by the individual disk length, number of disks, and stagger angle between the disks in the kneading block. See also “Mixing elements.” A line on a part where opposing melt fronts meet. Created by material flow around obstructions or multiple gating. See “Weld line.” A pin that pushes a cured molded article out of a mold. The state or quality of peakedness or flatness of the graphic representation of a statistical distribution expressed as a4 ¼ m4/m22, where m4 and m2 are the fourth and second moment of the distribution function. The excess of kurtosis is given as a4 – 3. The kurtosis is large when on a distribution function there is a relatively high concentration in the middle and out on the tails, with a relatively steep drop in between. An area occurring usually at the edge of a laminated plastic, where the reinforcement has not been wetted with resin. A rigid rod polymer, consisting of two parallel macromolecular chains regularly joined by covalent bonding, forming a sequence of interconnecting rings, e.g., Appendix III: Dictionary of Terms Used in Polymer Science and Technology Lamella Lamellar thickness Laminar flow Land Latex, lattices LCST (lower critical solution temperature) Let-down ratio Level of significance, “a” Light resistance Limit switch Liquid crystal polymer (LCP) Living polymer 2235 pyrrone, polyquinoxalines, polyphenylsilsesquioxane, and poly(bisbenzimid-azobenzo-phenanthroline). The basic morphological unit of a crystalline polymer, usually ribbonlike or platelike in shape. Generally (if ribbonlike), about 10–50 nm thick, 100 nm wide, and 1,000 nm long. A characteristic morphological parameter, usually estimated from X-ray studies or electron microscopy, usually 10–50 nm. Flow of thermoplastic resins accompanied by solidification of the layer in contact with the mold surface that acts as an insulating tube through which material flows to fill the remainder of the cavity. This type of flow is essential to duplication of the mold surface. Either a horizontal bearing surface of a semipositive or flash mold by which excess material escapes, a bearing surface along the top of the flights of a screw in an extruder, or the surface of an extrusion die parallel to the direction of the melt flow. In injection molding, the gate, when entering a part, has always the length of the gate itself that is called the land. Aqueous dispersion of polymeric particles, a polymer emulsion, a product of emulsion polymerization used in paints, adhesives, coatings, etc. The lowest temperature of immiscibility, where binodal and spinodal curves meet. This type of phase separation predominates in polymer blends. The quantity of one ingredient to be mixed with a base material to obtain the desired results. The probability of committing the error of rejecting a given hypothesis when it is true; “a” is usually set to 0.05 for most of the statistical tests. The ability of a plastic material to resist fading after exposure to sunlight or ultraviolet light (ASTM D1501). Light stability is the measure of this resistance. An electromechanical switch positioned to stop or start an action. It is operated by mechanical action on a movable control arm. A thermoplastic polymer (polyamide or polyester) that contains primarily benzene rings in its backbone, is melt processable, and can be highly oriented during processing. Available with or without fiber reinforcement. An ionic polymer in which, in the absence of a monomer, the active centers of polymerization are 2236 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Loading or charging tray London dispersion forces Long chain branching Loss modulus Lubricants Macbeth Macromer Macromolecule Manifold Mass spectrometer Master curve Matched metal, or die, molding Matrix Matte finish Mean or average Mechanical properties preserved. Formation of living polymers in anionic or Ziegler-Natta polymerizations makes it possible to produce block copolymers. A device used to load the charge of material or metal inserts simultaneously into each cavity of a multicavity mold by the withdrawal of a sliding bottom from the tray. Weak intermolecular forces based on dipole-dipole interactions. Branches of comparable length as the main polymer chain as in low-density polyethylene, polyvinylchloride, etc. A quantitative measure of energy dissipation, defined as the ratio of stress 90 out of phase with oscillating strain to the magnitude of strain. The loss modulus may be measured in tension of flexure, E”, compression, K”, or shear, G” (see also “Complex modulus”). Processing aids to assist material flow during extrusion or injection molding. The internal and external lubricants are recognized. Internally lubricated resins use oils, Teflon™, MoS2, or other materials to give the molded part a lower coefficient of friction. The external lubricant can be a solid, such as sodium or zinc stearate, a fluoropolymer, or silicone resin or liquid. A lighting system used for checking color. An oligomeric or telomeric chain capable of entering into a polymerization reaction. A large molecule in which neither the end groups nor the substitution of a group has any significant influence on the material properties. A pipe channel, or mold, with several inlets or outlets. An instrument capable of separating ionized molecules of different mass/charge ratios and measuring the respective ion currents. The acceptable or required curve that all subsequent test curves must match. A method of molding reinforced plastics between two close-fitting metal molds mounted in a press. Either the base resin used for a molded part or the main phase in polymer blends. A type of dull, nonreflective finish. See “Surface finish.” The sum of values divided by their number. The properties related to the relationships between stress and strain, such as compressive and tensile strengths and moduli, associated with elastic and inelastic reaction to the applied force. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Median Melt fracture Melt front Melt index (MI), melt flow index (MFI), or melt flow rate (MFR) Melt strength Melt temperature Melting point Metal plating Metallizing Metallocenes 2237 The middle value when all values are arrayed in order of magnitude. An elastic strain set up in a molten polymer as the polymer flows through the die. It may show up as irregularities on the surface of the plastic. Several stages (and different mechanisms responsible for these) are recognized, viz., shark skin, pressure oscillation (or spurt), and gross distortions. The exposed surface of molten resin as it flows into a mold. The melt front advances as the molten resin is continuously pushed through its center section. The amount in grams of a thermoplastic resin forced through a 2.10 mm (0.0825 in. orifice when subjected to the prescribed force, e.g., 2.16 kg force during 10 min at the prescribed temperature ( C) using an extrusion plastometer (ASTM D1238). It is customary to refer to the flow rate of polyethylene as “melt index.” However, for all other materials, the term “melt flow rate” should be used. The strength of a plastic while in the molten state. The temperature at which a resin melts or softens and begins to flow. The temperature of resin melt taken with a pyrometer melt probe. The temperature at which a resin changes from a solid to a liquid. The process of plating a plastic part by chemically etching the surface to accept a base metal on which the subsequent layers of metal are deposited. Usually a multistep process. Not all plastics can be metallized. A general term used to cover all processes by which plastics are coated with metal. Metallo-organic sandwich compounds in which two cyclopentadienlidene, Cp, rings form a sandwich around a metallic ion of, e.g., Fe, Co, Ni, Cr, Ti, V, and Zr. They have been used to catalyze the coordination polymerization of olefinic or vinylic monomers into highly regular macromolecules, viz., with narrow molecular weight, high regularity of comonomer placement, and/or high tactic purity. For example, ethylene was catalyzed with R’s(Cp)2MeQ [Me is metal from group 4b, 5b, or 6b (preferably Zr); R’ is a C1–C4 alkylene radical, a dialkyl germanium, or silicone; Q is an alkylidene radical having from 1 to about 20 carbon atoms, s ¼ 0–1, p ¼ 0–2, m ¼ 4–5], in combination with alumoxanes. 2238 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Meter Metering equipment Metering screw Micelle colloids Microcracking Micro-morphology Microprocessor Microstructure Migration of plasticizer Migration Mil Miscible polymer blend SI length unit equal to 100 cm molecular dimension, or 39.37 in. A machine or system to accurately meter additives to the machine’s hopper or feed throat. Comes in many sizes and types to suit each particular application, including augers, shuttle plates, photoelectric eyes, and positive or negative weight loss belt feeders. An extrusion or injection molding screw that has constant shallow depth and pitch section, usually over the last three to four flights. Low-molecular-weight, mainly homogeneous molecules, held together by secondary forces to form a colloidal particle. Cracks formed when local stresses exceed the strength of the matrix. In composites, because microcracks do not penetrate the reinforcing fibers, in cross-ply or cloth prepreg tape laminates, they are usually limited to the thickness of a single ply. Structural constitution on a submicron scale as related to crystallinity, viz., crystalline unit cells, lamellae shape and size, and stress-induced shish kebab crystals. Computer system that stores, analyzes, and adjusts the controls of a machine based on the parameters established during the operation of the machine it is controlling. It continuously analyzes output data to adjust and maintain the machine’s cycle within programmed limits. Can also store data and output it as directed by programming. The molecular structural features of a single polymer chain: tacticity, isomerism, chain branching, structural irregularities, etc. Loss of plasticizer from a polymeric compound, with subsequent absorption by an adjacent medium that lowers its concentration and induces brittleness. The transfer of a material from a plastic to other contacting solids. English unit of length equal to 0.001 in. or 25.4 mm. A polymer blend, homogenous down to the molecular level, in which the domain size is comparable to macromolecular dimension, associated with the negative value of the free energy and heat of mixing, DGm and DHm < 0, and @ 2DGm/@j2 > 0. Operationally, it is a blend whose domain size is comparable to the dimension of the macromolecular statistical segment. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Mixing Mixing elements Modified natural products Modifiers Modulus of elasticity Modulus of resilience Moisture absorption Moisture adsorption Moisture vapor transmission rate (MVTR) 2239 General term associated with the physical act of homogenization (e.g., mixing of fractions). Mixing of liquids is usually called blending (e.g., preparation of polymer blends or alloys), while incorporation of solids into molten polymer is usually called compounding (e.g., preparation of a compound). Three types of elements are used to assemble screws in a twin-screw extruder: kneading, mixing, and transporting. The mixing elements of different types are provided by the equipment manufacturers, viz., turbine, gear, notched disk, and blister rings. Depending on the type, these elements are responsible for either or for both the distributive and dispersive actions. Several authors consider kneading and mixing elements as belonging to the same class, alternatively labeled as kneading or as mixing blocks. See also “Kneading elements.” Plastics or fibers that are prepared by chemical transformation of natural substances, e.g., cellulose nitrate or acetate and casein or gelatin hardened by formaldehyde. Any additive that improves the processing or end-use properties of the polymer, e.g., PVC plasticizers added to make it soft and pliable and improve its impact strength. Almost all plastic resins use different modifiers to meet desired product requirements. The ratio of the stress to the strain produced in a material that is elastically deformed (ASTM D790). If a tensile stress of 20 MPa results in an elongation of 1 %, the modulus of elasticity is 2 GPa. The energy that can be absorbed per unit volume without creating a permanent distortion. Calculated by integrating the stress–strain curve from zero to the elastic limit and dividing by the original volume of the specimen. The pickup of water vapor from the atmosphere by bulk of a material. It relates only to vapor withdrawn from the air by a material and must be distinguished from water absorption, which is the gain in weight due to the takeup of water by immersion. Surface retention of moisture from the atmosphere. The rate at which water vapor permeates through a plastic film or wall at a specified temperature and relative humidity (ASTM E96). 2240 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Mold deposits Mold release agent Mold shrinkage Molding Molding cycle Molding compound powder or material Molding pressure Molding shrinkage Molecular weight, or an average molecular weight (MW) Material build up on a cavity’s surface due to plate out of resin, usually in a gaseous state. Can be attributed to additives in a resin adhering to the mold’s surface. A lubricant, liquid, or powder (often silicon oils and waxes) used to coat a mold cavity to prevent the molded piece from sticking to it, thereby facilitating its removal from the mold. Additives put into a material to serve as a mold release. Shrinking a molded part while it is removed from a mold and cooled to room temperature. The difference in dimensions between a piece and the mold cavity. The incremental difference between the dimensions of the molding and the mold from which it was made, expressed as percentage of the mold dimensions. A group of plastics processes used to form polymers or composites into solids with shape and size defined by the mold cavity, by the application of pressure and heat for a given time. The time required to complete a cycle and produce a part. Plastic material, often comprising resin, filler, pigments, plasticizers, and other ingredients, ready for molding operation. The pressure applied directly or indirectly on the compound to allow the complete transformation to a solid dense part. The pressure developed by a ram or screw to push molten plastic into a mold cavity. See “Injection pressure.” See “Mold shrinkage.” The sum of the atomic masses of the elements forming the molecule expressed in units of 1/12 the mass of 12C atom, or a mass of one mole of the substance (kg/mol), indicating the relative size typical chain length of the polymer molecule. Owing to polydispersity the molecular weight of a polymer is expressed as an average: X Ni Mkþ1 i i Mk ¼ X Ni Mki i For k ¼ 1, the number average; for k ¼ 2, the weight average; for k ¼ 3, the z-average; for k ¼ 4 (z + 1), average molecular weight is generated; etc. (viz., Mn, Mw, Mz, Mz + 1, respectively). Appendix III: Dictionary of Terms Used in Polymer Science and Technology Molecularly homogeneous Molecular weight distribution (MWD) Molecule Monomer (monomer ¼ single unit)’ Morphology Mottle Movable platen Multiblock copolymer 2241 A polymer in which all the molecules possess the same chemical structure. A statistical description of the sizes and frequency of occurrence of different molecular chain lengths within a given sample or lot of polymers, i.e., the distribution of molecular sizes in a polydispersed polymer. Several analytical functions f(M) have been proposed. Some of them are general statistical expressions (e.g., log-normal distribution, q.v.) and the others are based on assumed kinetics of polymerization (e.g., Schultz-Flory distribution). MWD is normally determined using a size exclusion chromatography, SEC (an old GPC). Wide and skewed distributions result in significant variation of properties. Narrow distributions are more consistent. A group of atoms bonded together which forms the fundamental structural unit of most organic substances. The number of atoms can range from two to millions. A molecule is the smallest unit of a substance that still retains the properties of that substance. A small molecule of an organic substance capable of entering into a polymerization reaction with itself or with other similar molecules or compounds, viz., vinyl monomers, dienes, a,o-lactams, and diamines. A low-molecular-weight-reactive chemical that polymerizes to form a polymer. Monomers are generally gases or liquids. When bonded together in long chains, they form solid materials or polymers. The study of the physical form and structure of a material. The overall physical form of the physical structure of a material on a submicron and micron scale. Common units are dispersed phase domains, lamellae, spherulites, etc. The term comprises notion of the global structure (e.g., stress-induced skin core), as well as shape, size, orientation, and distribution of the dispersed phase (solid, liquid, or gaseous). The desired or accidental mixture of colors or shades of a color giving approximately distinct or complicated patterns or specks, spots, or streaks of color. The moving platen of an injection or compression molding machine to which half of the mold is secured during operation. The platen is moved either by a hydraulic ram or a toggle mechanism. A block copolymer with more than three blocks, e.g., -[AB]n-. 2242 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Multicavity mold Multichain polymer Multiple-screw extruder Nanocomposite (NC) Necking Network polymer Newtonian fluid Nondestructive evaluation (NDE) or nondestructive inspection (NDI) Nondestructive inspection (NDI) Nonpolar Nonreturn valve Nonrigid plastic Normal distribution Notch sensitive Notch sensitivity A mold having more than one cavity or impression for forming finished items during one machine cycle. A polymer with more than two chains extending from a center, e.g., comb or star polymer. An extruder machine that has two or more screws, as contrasted with conventional single-screw extruders. A matrix material (metallic, ceramic, or polymeric in nature) having dispersed particles, with at least one dimension that does not exceed 10 nm. Polymeric nanocomposites (PNC) of commercial interest comprise 2–5 wt% of exfoliated clay. Localized reduction in cross section that may occur in a material under tensile loading during a tensile test. Necking is disregarded in calculation of the engineering stress, but is taken into account in determining the true stress. A cross-linked polymer forming infinite network, obtained in a step-growth polymerization with multifunctional monomers. An ideal fluid characterized by a constant ration of the shear stress to the rate of shearing in a simple shear deformation and with zero normal stress difference (nonelastic). An analysis to determine whether the material is acceptable for its function. A process or procedure, such as ultrasonic or radiographic inspection, for determining the quality or characteristics of a material, part, or assembly, without permanently altering the subject or its properties. Used to find internal anomalies in a structure without degrading its properties. Incapable of having a significant dielectric loss. Polystyrene and polyethylene are nonpolar. See “Ball or checking valve.” A plastic that has a modulus of elasticity (either in flexure or in tension) of not over 69 MPa (10,000 psi) at 25 C and 50 % relative humidity (ASTM D747). See “Gaussian distribution.” A plastic material is said to be notch sensitive if it will break when it has been scratched, notched, or cracked. Glass is considered to be highly notch sensitive. A measure of reduction in load-carrying ability caused by stress concentration in a specimen. Brittle plastics are more notch sensitive than ductile. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Nozzle Nuclear magnetic resonance (NMR) Nuclear magnetic resonance (NMR) spectroscopy Nucleating agent Nucleation Nylon™ Olefins Oligomer Opalescence Opaque Open-hole insert Optical comparator 2243 A hollow metal nose screwed into the extrusion end of either the heating cylinder of an injection machine or a transfer chamber (where this is a separate structure). Relates to the radio frequency-induced transitions between magnetic energy levels of atomic nuclei. NMR instrument consists essentially of a magnet, radio frequency accelerator, sample holder, and detector, capable of producing an oscilloscope image or line recording of NMR spectrum. See also “Nuclear magnetic resonance spectroscopy.” When an organic molecule containing certain atoms (e.g.,13C, H, D, F) is placed in a strong magnetic field and irradiated with radio frequency, transition between different nuclear spin orientational states takes place, and energy is absorbed at specific frequencies. Several different types of NMR measurements have been developed for characterization of polymer molecules, viz., high-resolution NMR of polymer solutions, wide-line solid-state NMR, magic-angle spinning NMR, and pulse-induced NMR. A foreign substance, often crystalline, usually added to a crystallizable polymer to increase its rate of solidification and reduce size of spherulites. Any additive that assists or acts as a starting site for crystallization of a polymer. These initiators can reduce cycle time by speeding up the crystalline formations, thereby causing the part to solidify faster so its ejection from the mold can occur sooner. A generic term for polyamides (a trademark of E. I. du Pont de Nemours, adduct of New York and London). To be avoided – use polyamide, PA, instead. Plastics produced from olefins, viz., polyethylene or polypropylene. Low-molecular-weight polymeric material with the degree of polymerization, 10 < DP < 50; from Greek oligos ¼ few, little. Limited clarity of vision through a sheet of transparent plastic at any angle, caused by light scattering within or on the surface of the plastic. A material that will not transmit light and is not transparent. An insert having a hole drilled completely through it. An inspection machine using optics to compare the outline of a part to its required dimensions on a graphic screen. 2244 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Optical distortion Orange peel Ordered polymer Organic Organosol Orientation Orifice Out-of-round Overflow Tab Overlay sheet Oxidation Oxygen index Pack time Any apparent alteration of the geometric pattern of an object when observed through a plastic or as reflection from a plastic surface. An unintentional rugged surface that gives an appearance resembling the skin of an orange. A polymer with monomers arranged in regular sequence, viz., alternating or block copolymers. The term refers to a general class of substances whose composition is based on the element carbon. Organic infers some relationship to materials, which at some point in time were alive. Fine PVC suspension in a volatile, organic liquid. At room temperature, the resin is swollen, but not appreciably dissolved. At elevated temperatures, the liquid evaporates, and the residue upon cooling forms homogenous plastics. Plasticizers may be dissolved in the volatile liquid. See also “Plastisols.” The alignment of the molecular structure in polymeric materials to produce anisometric material properties. It can be accomplished by drawing or stretching during fabrication, especially at low temperatures. An opening in a die or other metal piece used to meter the flow of fluid material. Nonuniform radius or diameter. A small, localized extension of a part at a weld-line junction to allow a longer material flow path for the purpose of obtaining a better fusion bond of the meeting melt fronts. See “Foil decorating.” Any chemical reaction in which electrons are transferred. The chemical reaction involving oxygen to form an oxide; the deterioration of an adhesive film due to atmospheric exposure; the breakdown of a hot melt adhesive due to prolonged heating and oxide formation. Degradation of a material through contact with air. A chemical reaction involving a combination with oxygen to form new compounds. The minimum concentration oxygen expressed as a volume percentage in a mixture of oxygen and nitrogen that will just support flaming combustion of a material initially at room temperature under the specified conditions. An indication of flammability. The amount of time that packing pressure is kept on the screw until the gate freezes. It takes time immediately after the injection stroke ends. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Packing pressure Pad Paint line Paint step Parallel to the draw Parallels (risers or support fillers) Pareto analysis Parison Part separator Parting agent Parting line Partitioned mold cooling Pastel Paucimolecular Peak exothermic temperature Permeability pH Phase 2245 The pressure applied just before the part cavity fills, which is about 50 % of the injection pressure required to continue filling the mold without flashing it. Packing pressure is maintained until the gate freezes. See “Cushion.” The point where two colors meet. Break in a smooth surface that allows a mask to rest. The axis of the cored position or insert parallel to the up-and-down movement of the mold as it opens and closes. The support spacers between the mold and press platen or clamping plate. An analytical and statistical technique used to determine part defect type and quantity. Ranks each type of defect as a percentage of the total number of defects found, based on the quantity of each type of defect. Hollow plastic tube from which a part is blow molded. A machine or system used to automatically separate parts from the runner system after molding. Separated parts go to their next station and the runner moves to a granulator for reuse if permitted. The system may use blades, rigid pins, or a degating station with parts placed by a robot for separation. See “Mold release.” The point in the mold where two or more metal surfaces meet creating a shutoff. Mark on a molding or casting where halves of a mold met in closing. See “Bubbler.” A tint, a tone to which white has been added. Polymers that consist of only a few different molecular weight components. Also called the paucidisperse polymers. The maximum temperature reached by reacting thermosetting plastic composition is called peak exothermic temperature. The passage or diffusion of a gas, vapor, liquid, or solid through a barrier without affecting it. The rate of the passage. Negative logarithm of concentration of hydrogen ions, log [H+], a measure of the acidity or alkalinity of a substance. Acid solutions have pH < 7, at neutrality pH ¼ 7, and in alkaline solutions pH > 7. A separate, but not necessarily separable, portion of a system. 2246 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Phenolic resins Photodegradation Photoelasticity Physical aging Physical cross-link Physical cross-linking Piece part price Pigment Pigmented Pinpoint or restricted gate Pit Pitch Cross-linked resins based on phenol and formaldehyde of a complex, not fully known, structure. Degradation caused by long wavelength ultraviolet radiation that is the main cause of outdoor weathering. Experimental technique for the measurement of stresses and strains in material objects by means of the mechanical birefringence. The relaxation process that takes place in plastics after fabrication. Upon cooling a melt, the molecular mobility decreases, and when the relaxation time exceeds the experimental time scale, the melt becomes a glass in nonequilibrium thermodynamic state (density, enthalpy, etc.). Thus, the value of the thermodynamic parameters continues to change toward an equilibrium state. The process may lead to development of cracks and crazes that initiate critical failure. See also “Aging,” “Accelerated aging,” “Artificial aging,” and “Chemical aging.” A physical bond that joins two or more chains together. They may arise from crystalline portions of a semicrystalline polymer, the glassy or crystalline portion of a block copolymer, or the ionic portion of an ionomer. The physical cross-link forces are affected by the temperature. An existence of restraining force between polymer chains other than covalent bonding; viz., entanglements, presence of microcrystallinity, and glassy blocks in block copolymer. Calculated finished part cost based on material, processing, assembly, decorating, and packaging, including productivity and overhead costs. Imparts color to plastic while remaining a dispersion of undissolved particles. A plastic resin comprising pigments to produce a desired color after molding. The pigments can be either organic or inorganic based. A restricted orifice through which molten plastic flows into a mold cavity. Small regular or irregular crater in the surface of a plastic, usually with width approximately of the same order of magnitude as its depth. With respect to extruder or injection molding, the distance from any point on the flight of a screw line to the corresponding point on an adjacent flight, measured parallel to the axis of the screw line or threading. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Plastic Plastic deformation Plastic memory Plasticate Plasticating extruder Plasticity Plasticization Plasticize Plasticizer Plastisols Plate dispersion plug Platens Plunger Poisson distribution 2247 A synthetic or natural organic substance (exclusive of adhesives and rubbers) formable or pliable at some stage during its formation or subsequent manufacturing process, thus a polymeric material that is capable of being shaped through plastic flow under influence of deforming forces, a thermoplastic or thermoset material. It either melts and flows with heat and pressure, as with a thermoplastic, or it chemically “sets,” as with a thermoset material. Many materials, such as glass, become plastic under the right conditions. Any portion of the total deformation of a body that occurs immediately when load is applied but that remains permanently when the load is removed. The deformation of a material under load that is not recoverable after the load is removed. Opposite of elastic deformation. A phenomenon of a plastic to return, in some degree, to its original form upon heating. To soften by heating and/or kneading. An extruder fed with solid polymer that melts and plasticates it while conveying toward the die. A property of plastics that upon the application of a force allows the material to be deformed continuously and permanently without rupture (the opposite of “elasticity”). Softening, enhancement of flexibility engendered by incorporation of low-molecular-weight liquid, a plasticizer, such as 2-ethylhexylphthalate (DOP). To make a material soft and moldable with the addition of heat, pressure, or a plasticizer. A material incorporated in a thermoplastic to reduce its glass transition temperature, thus to increase its flexibility. Mixtures of PVC and plasticizers that can be molded, cast, or converted to continuous films by the application of heat. The mixtures that contain volatile thinners are known as organosols, q.v. See “Breaker plate.” The mounting plates of a press to which the entire mold assembly is bolted. The part of a transfer or injection press that applies pressure to the unmelted plastic material to push it into the chamber. This, in turn, forces the melt out through the nozzle. Discrete probability function, derived by Simeon Poisson in 1837, for the situation when the probability 2248 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Poisson’s ratio, r Polarized light Polarizer Polyacrylonitrile (PAN) Polyaddition Polyallomers Polyamide-imide (PAI) Polyamides (PA) Polyarylates (PAr) Polyarylsulfone (PAS) of a single event is very small, but the number of events approaches infinity. The ratio of lateral strain to the corresponding axial strain in axially loaded specimens, below the proportional limit. It is a material constant that relates the modulus of rigidity, G, to Young’s modulus, E, in the relation: E ¼ 2G(r + 1), viz., ASTM E1321. Polarized electromagnetic radiation whose frequency is in the optical region. A medium or a device used to polarize the incoherent light. Product of free radical polymerization in solution or suspension. Used primarily for production of fibers (it may contain up to 10 % comonomer to improve dyeability). Homopolymer of PAN is a base material in the manufacture of carbon fibers. A step-growth polymerization from two types of bi- or polyfunctional primary molecules, e.g., polyurethane formation. This irreversible, rapid process is caused, usually through heteroatoms, by bond displacement without the splitting off any component. Crystalline thermoplastic polymers made from two or more different monomers, usually ethylene and propylene. A family of polymers based on the combination of trimellitic anhydride with aromatic diamines. In the uncured form (ortho-amic acid), the polymers are soluble in polar organic solvents. The imide linkage is formed by heating, producing an infusible resin with thermal stability up to 290 C. These resins are used for laminates, prepregs, and electrical components. A group of semicrystalline thermoplastics containing the amide group (NHCO–) in the main chain, resulting from polycondensation of either a,o-lactam or a diacid with a diamine. Natural polyamides, polypeptides, and synthetic polyamides belong to this family. Wholly aromatic polyesters from dihydric phenols and dicarboxylic acid chlorides. They are characterized by high melting point (up to 500 C), good thermal stability, and solubility in chlorinated solvents. Commercial polymers are produced by polycondensation of iso- and terephthalic acids with bisphenol A, having glass transition temperatures near 170 C and the continuous use temperature of 140–150 C. Alternative name for aromatic polyethersulfone. See “Polyethersulfone.” Appendix III: Dictionary of Terms Used in Polymer Science and Technology Polybenzimidazole (PBI) Polybutylene terephthalate (PBT) Polybutylenes, BR Polycarbonate (PC) Polycondensation Polyesters Polyether-imide (PEI) Polyethersulfone (PES) 2249 The polycondensation product of tetraaminobiphenyl with terephthalic acid has the highest thermal stability of all commercial organic polymers. Its continuous use temperature is 400 C, and it has good chemical stability. Polycondensation product of dimethylterephthalate and 1,4 butanediol, with melting temperature Tm } 224 C. PBT can be easily blended with number of other thermoplastics. Major uses include automotive parts (interior, under-the-hood, and exterior), electrical connectors, small appliances, and pump housings. A group of polymers consisting of isotactic, stereoregular, highly crystalline polymers based on butene-1. Their properties are similar to those of polypropylene and linear polyethylene, with superior toughness, creep resistance, and flexibility. An amorphous thermoplastic derived from the direct reaction between aromatic and aliphatic dihydroxy compounds with phosgene or by the ester exchange reaction with appropriate phosgene-derived precursors. Highest impact resistance of any transparent plastic. It is transparent and can be injection molded, extruded, thermoformed, or blow molded (esp. branched PC). A polymer synthesis from bi- or multifunctional monomers with liberation of a low-molecular, volatile by-product. Polymers containing the ester group (COO–) in the main chain, products of polycondensation of a,o-lactones or diacid with diols. Both unsaturated (alkyd) polyesters and thermoplastic polyesters (including PC, PET, PBT, and PNT) enjoy wide commercial use. An aromatic polymer containing both ether and imide groups in the polymeric chain. It has a heat distortion temperature of 200 C, continuous use temperature of 170 C, and low flammability. It can be blended with several engineering thermoplastics for a wide range of properties and applications (mainly in automotive and electronic/electrical industries). An aromatic polymer containing benzene rings linked by both ether and sulfone groups in the polymeric chain. Several commercial products of this type have been developed. Their glass transition temperature varies from 190 to 285 C. The materials have high rigidity, low creep, high electrical resistance, transparent, selfextinguishing, and low flammability. They can be 2250 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Polyethylenes (PE) Polyethylene terephthalate (PET) Polyimide (PI) Poly-liner Polymer Polymer alloy blended with several engineering thermoplastics. The applications include printed circuit boards, TV components, and diverse electronic/electrical parts. Thermoplastic materials composed of ethylene units. They are normally translucent, tough, waxy solids that are unaffected by water and by a large range of chemicals. These plastics have >85 % ethylene and >95 % of total olefins. Polycondensation product of dimethylterephthalate and ethylene glycol, with Tm ¼ 260–270 C. Oriented PET has outstanding tensile strength. Its principal use includes bottles, X-ray films, electrical insulation, and food packaging. Polymer produced by reacting an aromatic dianhydride with an aromatic diamine. It is highly heat-resistant (at T ¼ 315 C) resin, similar to a polyamide, differing only in the number of hydrogen atoms per mer. The polymer is suitable for the use a binder or adhesive and may be either a thermoplastic or a thermoset. Initially, it could not be processed by conventional molding methods. The polymer has rings of four carbon atoms tightly bound together. It has excellent resistance to heat. A perforated, longitudinally ribbed sleeve that fits inside the cylinder of an injection molding machine. Used as a replacement for conventional injection cylinder torpedoes/older machines. Also a plastic bag placed inside a carbon or box to prevent material contamination during shipment. Material composed of many (Greek poly) units (Greek meros). A high molecular weight organic compound – natural or synthetic, formed by a chemical reaction in which two or more small organic units join to form large units composed of repeating small units. Its structure can be represented by repeated small units, the mers. Synthetic polymers are formed by addition or condensation polymerization of monomers. Some polymers are elastomeric, and others thermoplastic or thermoset. The term was coined by Berzelius in 1832 to describe hydrocarbons of a general formula (CH2)n with n ¼ 1 to 4 (sic!). Today a substance may be called polymer if it shows high degree of polymerization, DP >50. An immiscible polymer blend having a modified interface and/or morphology. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Polymer blend Polymer conversion Polymerization Polymethylmethacrylate (PMMA) Polymolecularity Polyphenylene ether (PPE) Polypropylenes (PP) Polystyrenes (PS) 2251 A mixture of at least two macromolecular materials: two or more polymers, polymer with copolymers, two or more copolymers, etc. Polymer blends are either miscible or immiscible. See “Miscible polymer blend” and “Immiscible polymer blend.” Preparation of polymer derivatives during which the number of macromolecules or the degree of polymerization is preserved. The process or chemical reaction in which the molecules of a monomer are linked together to form macromolecules whose molecular weight is a multiple of that of the original substance nM ! [M]n, where n is a degree of polymerization, DP. It is said that the polymerization leads to oligomer if 10 < DP < 50 and to polymer if DP > 50. When two or more monomers are involved, the process is called copolymerization. Most polymerization processes are classified as condensation (step) reactions or addition (chain) reactions. Crystal-clear radical polymerization product of methyl methacrylate. PMMA has the glass transition temperature of 105 C, excellent weatherability, and scratch resistance, as well as useful combination of stiffness, density, and toughness. It can be easily modified by co-reacting or blending. Practically all polymers are mixtures of impossible to separate homologues or fractions. Mathematically the polymolecularity is expressed by a molecular weight distribution, MWD, q.v. An amorphous thermoplastic with useful temperature range that depending on composition varies from 135 C to 190 C. A crystalline thermoplastic made by polymerizing propylene gas. It has the lowest density of all plastics, except methylpentene. Tough, lightweight thermoplastics made by the polymerization of propylene in the presence of an organometallic catalyst at relatively low pressures and temperatures. An amorphous thermoplastic made by polymerizing styrene. Thermoplastics produced by the polymerization of styrene, having outstanding electrical properties and good thermal and dimensional stability. Because it is somewhat brittle, it is often copolymerized or blended with other materials to obtain desired properties (see HIPS). 2252 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Polysulfones (PSF or PSU) Polytetrafluoroethylenes (PTFE) Polyurethanes (PU) Polyvinyl chloride (PVC) Polyvinylidene chloride (PVDC) Porosity A family of engineering thermoplastics with excellent high-temperature properties, high strength, high service temperature, low creep, and self-extinguishing properties, produced either by a Friedel-Crafts reaction of sulfonyl chloride groups with aromatic nuclei or by reacting dichlorosulfone with diphenyls. The continuous use temperature is about 160 C. They can be formed by extrusion and molding method, directly competing with metals and more expensive materials for electronic circuitry. A linear polymer obtained by radical polymerization of tetrafluoroethylene. PTFE has a melting point of 327 C and outstanding resistance to chemical attacks or dissolution. Its uses include liners for chemical processing equipment, high-temperature cable insulation, bushings, seals, and nonstick surfaces. Polymers containing urethane groups (NHCOO–) in the main chain. Thermoplastic or thermoset materials made from isocyanates and polyols. The linear polyurethanes (thermoplastic polyurethanes, TPU) are formulated with rigid and soft segments, thus (as block copolymers) showing interesting elastomeric character. However, most polyurethanes are produced as cured rubbers (polyurethane rubber, PUR) by means of combining isocyanate having functionality about 2.7 with diols. The principal use of PUR is in manufacture of rigid and flexible foams. A thermoplastic material composed of polymers of vinyl chloride. It is a colorless solid with outstanding resistance to water, alcohols, and concentrated acids and alkalis. It is obtainable as granules, solutions, lattices, and pastes. Compounded with plasticizers, it yields a flexible material superior to rubber in aging properties. It is widely used for cable and wire coverings, in chemical plants, and in the manufacture of protective garments. The pure polymer is brittle and difficult to process. It yields a flexible material when compounded with plasticizers. A thermoplastic material composed of polymers of vinylidene chloride. Its principal uses are in flexible films and coatings. A condition of trapped pockets of air, gas, or vacuum within a solid material, expressed as percentage of the total nonsolid volume to the total volume. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Post annealing Post mold shrinkage Post-forming Pot life Potentiometer Preplastication Prepolymer Press fit Pressure drop Pressure gradient lines Pressure pads Primary molecule, monomer Printing on plastics Process control procedures Processing aid 2253 Stress relieving of molded parts by external means, hot air or oil, humidity chambers, or submersion in a fluid. The shrinkage occurring after a part has been removed from the mold is influenced by the material properties of the resin and its molding conditions. A process used to impart a shape to a previously molded article. The time span during which a cross-linking resinhardener system can still be processed. An electrical control device that senses changes in voltage or a potential difference by comparison to a standard voltage and can transmit a signal to a control switch. Technique of premelting injection molding powders in a separate chamber and then transferring the melt to the injection cylinder. The device used for preplastication is known as a preplasticizer. A chemical intermediate with a molecular weight between that of the monomer or monomers and the final polymer. An interference assembly between two mating parts, with friction holding the parts together under considerable stress. The decrease in pressure of a fluid related to the number of turns it has to make and the distance it must flow to fill a cavity. A hypothetical set of pressure lines in a part created by the material’s pressure drop as the part is filled. The further the material flows from the gate, the lower the packing pressure. Reinforcements distributed around the dead areas in the faces of a mold to help the land absorb the final pressure of closing. The smallest molecular unit from which the macromolecule is built. The decoration of plastics by means of various printing processes, e.g., offset, silk screen, letterpress, electrostatic, or photographic methods. A separate document, often included as an attachment to the quality control manual that provides detailed description of the methods to be followed in the manufacture of a product. A copy may be attached to the work order for reference and revision as required should changes in the product occur. An additive that improves processing characteristics. 2254 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Product certification Projected surface area Propagation Proportional limit Prototype mold Pseudo-IPN Pultrusion Purging Pyrometer Quality assurance Quality circles Quality control (QC) The certificate or letter stating that the material or product meets or exceeds customer requirements. Values are often listed for the tested or measured results. To be signed by a key representative of the company to verify accuracy. The exposed resin area of a mold on the parting line that transmits the injection pressure on the closed mold halves. It includes part, runner, and sprue surfaces. A series of reaction steps in a chain polymerization in which the monomers are being added to the active polymerization center. The greatest stress that a material is capable of sustaining without deviation from proportionality of stress and strain (Hooke’s law). A simplified mold construction often made from a light metal casting alloy or from an epoxy resin to obtain information for the final mold and/or part design. Simultaneous IPN in which one polymer is in network form and the other linear. A continuous process for manufacturing composites that have a constant cross-sectional shape. The process consists of pulling a fiber-reinforcing material through a resin impregnation bath and then through a shaping die, where the resin is subsequently cured. Cleaning one color or type of material from the processing machine by forcing it out with the new color or material to be used in subsequent production. Special purging materials are also available. An electrical thermometer for measuring high temperatures. The units come with two probes to measure melt and surface temperatures. A separate department established to direct the quality function of the business areas. Major efforts are directed to assisting and auditing the activities of the quality control department in their efforts to ensure that quality products are manufactured. A quality analysis group consisting of employees with specific departmental knowledge used to provide suggestions and ways to solve a procedural or manufacturing quality problem. If found acceptable, the group’s findings and solutions are then passed on to upper management for implementation. A department set up to be technically involved in the control of product quality. Involved in the principal Appendix III: Dictionary of Terms Used in Polymer Science and Technology Quality control manual Quality rated Quenching Radical polymerization Radio frequency, RF, preheating Ram Ram travel Random copolymer Randomness Reactive extrusion Reactive injection molding (RIM) 2255 inspection and testing of a product, with limited systems responsibility. A document that states the company’s quality objectives, and how they will be implemented, documented, and followed in the manufacture of products. See “Approved supplier.” A method of rapidly cooling thermoplastic parts when they are removed from the mold, usually by submerging the parts in water. Polymerization in which the active centers of reaction are radicals. The polymerization can be initiated by thermally activated or redox initiator, irradiation, or through thermal activation of monomer (also known as free radical polymerization). A method of preheating used to mold materials to facilitate the molding operation and/or reduce the molding cycle. The frequencies commonly used are between 10 and 100 MHz/s. The press member that enters the cavity block and exerts pressure on the molding compound designated as the “top force” or “bottom force” by position in the assembly. See “Plunger.” Distance ram moves during a complete molding cycle. A copolymer in which the different monomers are randomly placed in the main chain. A perfectly random copolymer is produced by polymerization of different mers having identical reactivity ratios, rA ¼ rB ¼ rC. A condition in which individual values are not predictable, although they may come from a definable distribution. Execution of chemical reactions during extrusion of polymers and/or polymerizable monomers. The reactants must be in a physical form suitable for extrusion processing. Reactions have been performed on molten polymers, on liquefied or dispersed monomers, or on polymers dissolved or suspended in or plasticized by a solvent (also reactive compounding or reactive processing). A semicontinuous manufacturing process in which two liquid components are metered in the calculated ratio by high pressure piston pumps, mixed by impingement mixing and injected into a mold cavity or cavities, where the reactants are polymerized or cured. The process has been used to polymerize polyamides, elastomeric polyurethanes, and polyurethane foams. 2256 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Reactivity ratio Real time Reciprocating screw Recycled plastics Redox initiator Regrind Reinforced molding compound Reinforced polypropylene Reinforcement Relative viscosity Relaxation time Release agent A ratio of two kinetic constants r ¼ kAA/kAB where kAA represents the self-propagation and kAB the transfer from A* active center to B* active center caused by addition of monomer-B to a growing copolymer chain. The present time or as an activity is occurring. A combination injection and plasticizing unit in which an extrusion device with a reciprocating screw is used to plasticize the material. Injection of material into a mold can take place by direct extrusion into the mold, by reciprocating the screw as an injection plunger, or by a combination of the two. When the screw serves as an injection plunger, this unit acts as a holding, measuring, and injection chamber. A plastic material prepared from previously used or processed plastic materials that have been cleaned and reground. An initiator capable of generating free radicals at low temperature by oxidation-reduction reaction between two components, viz., H2O2 + FeSO4. Waste material from industrial operations that has been reclaimed by shredding or granulating. Regrind is usually incorporated, at a predetermined percentage, with virgin material. A material reinforced with special fillers to meet specific requirements, such as rag or glass. Polypropylene that is reinforced with mineral fillers, such as talc, mica, and calcium carbonate, as well as with glass and carbon fibers. The maximum concentration is about 5 wt%, although concentrates with higher levels of filler or reinforcement are available. A substance or material added to a polymer during the final synthesis stages or in subsequent processing to improve the strength properties of the polymer. Usually, a high strength material bonded into a matrix to improve its mechanical properties. Reinforcements are usually long fibers (glass, carbon or aramid), chopped fibers, whiskers, particulates (glass beads, mica, clay, and organic fibers), and so forth. The term is not synonymous with filler. Ratio of the kinematic viscosity of a polymer solution to the kinematic viscosity of the pure solvent. The time required for a stress under a sustained constant strain to diminish by a stated fraction of its initial value. See “Mold release.” Appendix III: Dictionary of Terms Used in Polymer Science and Technology Release or parting agent Relief angle Repeatability Reprocessed plastic Reproducibility Residence time Residence time distribution Residual stress Resin 2257 A material that is applied in a thin film to the surface of a mold to keep the resin from bonding (also mold release agent). The angle of the cutaway portion of the pinch-off blade from a line parallel to the pinch-off land. In a mold, the angle between the pitch-off land and the cutaway portion adjacent to the pinch-off land. The variation obtained when one person measures the same quantity several times using the same instrument. A thermoplastic material, prepared from melt-processed scrap or reject parts, or from nonstandard or nonuniform virgin material. The term scrap does not necessarily connote feedstock that is less desirable or usable than the virgin material from which it may have been generated. Reprocessed plastic may or may not be reformulated by the addition of fillers, plasticizers, stabilizers, or pigments. The variation in measured averages obtained when several persons measure the quantity using the same instrument or when one person measures the quantity using different instruments. Time a resin spends in a given processing machine (an extruder, injection molding unit, etc.) and is subjected to heat and stress. The distribution of residence time provides information how long different parts of the resin reside in the processing equipment. The spread of the residence times reflects, on the one hand, the uniformity of flow inside the processing unit and, on the other, the quality of the product, the degree of mixing, or the extent of a chemical reaction. The stresses remaining in a plastic part as a result of thermal or mechanical treatment. An organic material, usually of high molecular weight, that tends to flow when subjected to stress. Any of a large class of synthetic substances that have some of the properties of natural resin (or rosin) but differ chemically. “Resin” is often used as a general term for polymers or plastics and denotes a class of material. It usually has a softening or melting range and fractures conchoidally. Most resins are polymers. Also any of a class of solid or semisolid organic products of natural or synthetic origin, generally of high molecular weight with no definite melting point (also see “Polymer”). 2258 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Resin pocket Resin transfer molding (RTM) Restricted gate Retainer plate Retaining pin Rheology Rib Rigid plastics Ring gate Rockwell hardness Rubbers Runner Runner system Rupture In reinforced plastics, the material used to bind together the reinforcement material; the matrix. An apparent accumulation of excess resin in a small localized section that is visible on cut edges of molded surfaces. Also called resin segregation. A fabrication process that involves the transfer of catalyzed resin into an enclosed mold cavity containing a previously positioned reinforcement preform. The process has been used for manufacturing from components consisting of glass fiber mats and polyester resins. Sometimes referred to as pinpoint gate. A small opening between the runner and cavity in an injection or transfer mold. The plate, usually drilled for steam or water, on which demontable pieces, such as mold cavities, ejector pins, guide pins, and bushings, are mounted. A pin on which an insert is placed and located before molding. The study of the deformation and flow of materials of the interrelations between the force and its effects. The science considers deformation of all materials from the elastic deformation of Hookean solids to the flow of Newtonian liquids. An object designed into a plastic part to provide lateral, longitudinal, or horizontal support. A plastic that has a modulus of elasticity either in flexure or in tension greater than 690 MPa at 23 C and 50 % relative humidity, RH. A gate or annular opening that circles around a core pin or molded part. A common method of testing materials for resistance to indentation in which a diamond or steel ball, under pressure, is used to pierce the test specimen. Cross-linked polymers having glass transition temperatures below the room temperature that exhibit highly elastic deformation and have high elongation. In an injection or transfer mold, the channel that connects the sprue with the gate to the cavity. The sprues, runners, and gates that lead the material from the nozzle of an injection machine to the mold cavity. A cleavage or break resulting from physical stress. Work of rupture is the integral under the stress–strain curve between the origin and the point of rupture. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Salt and pepper blends SAN Scanning electron microscopy (SEM) Scanning probe microscopy (SPM) Scanning transmission electron microscopy (STEM) Scrap Screw plasticating injection molding Screw 2259 Resin blends of different concentrate additives, in pellet form, mixed with virgin resin to make a different product. Usually associated with color concentrate blends, that, when melted and mixed by the injection molding machine’s screw, yield a uniform colored melt for a part. An abbreviation for styrene-acrylonitrile copolymers. Electron microscopy that uses the secondary emission of electrons from a surface when bombarded with an electron beam. The main advantage is the depth of field. Technique in which the surface of a specimen is scanned, point by point, with a finely focused electron beam. Image formation is made by detecting the secondary electrons emitted by the specimen’s surface. Even though resolution in modern SEM can be as high as 4 nm, the main advantage of SEM over the other microscopy techniques is its very large depth of field. a microscopy technique in which the surface of a specimen is scanned, point by point, using a very sharp probe (d ¼ 10 nm). Accurate piezoelectric devices are utilized to maintain the separation distance between the lowest atom on the probe tip and the highest atom on the specimen constant and in the range of 1–100 nm. In this range of tip-to-sample spacing, phenomena like tunneling current (scanning tunneling microscopy (STM)) or interatomic repulsion/attraction (atomic force microscopy (AFM)) can be used for determining specimen topography with resolution ranging from a few microns, down to atomic level. a microscopy technique in which an ultrathin specimen is scanned, point by point, with a finely focused electron beam. Image formation is made by detecting the electrons transmitted through the specimen. A product or material that is out of specification to the point of being unusable. See “Injection molding.” The main component of the “reciprocating screw” injection molding machine. It may have various sizes, lengths, and compression ratios. It is used to feed, compress, melt, and meter the resin for injecting into the mold cavity. Basically divided into 3 major sections: feed section, deep screw depths to convey the resin into the next screw’s section; transition section, gradually decreasing screw depths when resin is compressed, forced against the barrel’s surface, and melts; and 2260 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Scuff mark Sealant Sealing diameter Secant modulus Second-surface decorating Semiautomatic molding machine Semi-I IPN Semi-II IPN Semicrystalline Sequential polymerization Sequential IPN (SIPN) Servomotor Shear heat Shear joint metering section, the molten melt that is further compressed in a shallow, uniform screw depth conveying forward as the screw turns. An imperfection on a part’s show surface caused by dragging the part against the mold’s surface during ejection from the mold cavity. A material applied to a joint in paste or liquid form that hardens or cures in place, forming a seal. That portion of a metal insert that is free of knurl and is allowed to enter the mold to prevent the flow of plastic material. The ratio of total stress to corresponding strain at any specific point on the stress–strain curve. A method of decorating a transparent plastic part from the back or reverse side. The decoration is visible through the part, but is not exposed. A molding machine in which only part of the operation is controlled by direct human action. The automatic part of the operation is controlled by the machine according to a predetermined program. An intimate combination of two polymers in network form. Sequential IPN in which polymer-1 is cross-linked and polymer-2 linear. An intimate combination of two polymers in network form. Sequential IPN in which polymer-1 is linear and polymer-2 cross-linked. Polymers that exhibit localized, partial crystallinity (see “Crystalline plastic”). Formation of an alternating or block copolymer through careful control of addition of different monomers at specific stages of the reaction. An intimate combination of two polymers in network form. During preparation of SIPN, the first polymerA is swollen in a mixture of monomer-B, crosslinking agent, and initiator and then polymerizing in situ. An electrical motor or hydraulic piston that supplies power to a feedback system that consists of a sensing element and an amplifier used in the automatic control of a mechanical device. The rise in temperature created by the compression and longitudinal pressure on the resin in the barrel by the screw’s pumping action. An ultrasonic welding joint design where the welding action is parallel to each part surface. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Shear rate Shear strain Shear strength Shear stress Shearing Shelf-life Shore hardness Short or short shot Shot capacity Shot peening Shot 2261 The overall velocity over the cross section of a channel with which molten polymer layers is gliding along each other or along the wall in laminar flow. A change of shear strain within one second. Deformation relative to the reference configuration of length, area, or volume. Tangent of the angular change, caused by a force between two lines originally perpendicular to each other through a point in a body is called angular strain. The maximum shear stress that a material is capable of sustaining. The maximum load required to shear a specimen in such a volume manner that the resulting pieces are completely clear of each other. Shear strength (engineering) is calculated from the maximum load during a shear or torsion test and is based on the original cross-sectional area of the specimen. Stress developed because of the action of the layers in the material attempting to glide against or separate in a parallel direction. In other words, the stress developed in a polymer melt when the layers in a cross section are gliding along each other or along the wall of the channel (in laminar flow). Breaking caused by the action of equal and opposed forces, located in the same plane. The time a material, such as a molding compound, can be stored without loss of its original physical or functional properties. A method of determining the hardness of a plastic material using a scleroscope or sclerometer. The device consists of a small conical hammer fitted with a diamond point and acting in a glass tube. The hammer is made to strike the material under test and the degree of rebound is noted on a graduated scale. Generally, the harder the material, the greater the rebound (ASTM D2240). A molded part produced when the mold has not been filled completely. The maximum volume of material that a machine can produce from one forward motion of the plunger or screw. Impacting the surface of the material with hard, small, round beads of materials to disrupt the surface flatness. Used to stress relieve welds and to improve the release of plastic resins on smooth core surfaces. The yield from one complete molding cycle, including cull, runner, and flash. 2262 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Shrink fixture Shrinkage allowance Shrinkage SI units Side actions (side coring or side draw pins) Sigma (s) See “Cooling fixture.” The additional dimensions that must be added to a mold to compensate for shrinkage of a plastic material on cooling. In a plastic, the reduction in dimensions after cooling. The relative change in dimension from the length measured on the mold when it is cold to the length of the molded object 24 h after it has taken out of the mold. International System of Units. An action built into a mold that operates at an angle to the normal open-and-close action and facilitates the removal of parts that would not clear a cavity or core on the normal press action. Projections used to core a hole in a direction other than the line of closing of a mold and which must be withdrawn before the part is ejected. The Greek letter used to indicate the standard deviation of a population, defined as the square root of the variance, e.g., for the normal (Gaussian) distribution: o h i n y ¼ 1=sð2pÞ1=2 exp ½ðx xÞ=s2 =2 Variance s2 ¼ Sðx xÞ=ðN 1Þ Silicones Silk screen printing Simultaneous IPN (SIN) Sink mark Chemicals derived from silica used in molding as a release agent and general lubricant. A silicon-based thermoset plastic material. Polyorganosiloxanes of different composition (e.g., polydimethylsiloxane, silicone rubber), structures (linear or network), and molecular weight, used as “high-temperature oil,” resin, or elastomer. In its basic form, it involves laying a pattern of an insoluble material, in outline, on a finely woven fabric. When ink is drawn across the material, it passes through the screen only in the designed areas. Also called screen process decorating. IPN is prepared by mixing together the two monomers, their respective cross-linking agents, and initiators and then polymerizing simultaneously by way of noninterfering modes. A depression or dimple on the surface of an injection molded part formed as a result of collapsing of the surface following local internal shrinkage after the gate seals. May also be an incipient short shot. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Size exclusion chromatography, SEC Skewness Skins Slides S-N diagram Snap fit Softening temperature Sol solutions Solid-state polymerization Solvent Solvent welding, cementing, or bonding Solvent casting Specific gravity 2263 Recent name for what has been known as gel permeation chromatography, GPC, q.v. The degree to which a distribution is asymmetrical; negative or positive skewness is observed when the distribution peak is shifted to the upper or lower side. See “Flakes.” Sections of a mold cavity that form complex threedimensional parts that must move before the molding can be ejected. Used to form openings and sections of parts 90 to the part’s release from the mold cavity. Plot of stress, S, vs. number of cycles, N, required to cause failure of similar specimens in fatigue test. Data for each curve on the S-N diagram are obtained by determining fatigue life of a number of specimens subjected to various amounts of fluctuating stress. The stress axis may represent stress amplitude, maximum stress, or minimum stress. A log scale is usually used, especially for the N-axis. An assembly of two mating parts, with one or both parts deflecting under stress, mating the parts together. Temperature at which amorphous polymer (or the amorphous part of crystalline polymer) passes from the hard glass to the soft elastic or liquid state. Solutions of macromolecules so diluted that they do not hinder each other free rotation. The limiting concentration depends on the hydrodynamic volume of the macromolecule, usually expressed by the intrinsic viscosity, [Z]. Polymerization of crystalline monomer, usually vinyl, using high energy radiation. Topochemical, topotactic, and canal polymers belong to this group. Any substance, but usually a liquid, that dissolves other substance. A method of bonding thermoplastic articles of like materials to each other by using a solvent capable of softening the surfaces to be bonded. Thermoplastic materials that can be bonded by this method are ABS, PA, PC, PS, acrylics, cellulosics, and vinyls. A process that consists of mixing and dissolving the ingredients in a suitable carrier that conveys the solution of “dope” through a drier where the solvent is subsequently evaporated; the resulting film is removed from the substrate surfaces and wound into rolls. The ratio of the mass of a given volume of a substance to the mass of an equal volume of a reference substance, 2264 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Specific heat Specific volume Specification Spectrometry Spectrophotometer Spectroscopy Specular gloss Spherocolloids Spider gate Spin welding Spinodal Spinodal decomposition usually water, at a specified temperature (ASTM D792). Also, dimensionless ratio of a substance density to that of a reference material. The quantity of heat required to raise the temperature of a unit mass of a substance by one degree (1 C) at constant pressure or volume. Reciprocal of density. A written statement that dictates the material, dimensions, and workmanship of a manufactured product. A method based on designation of the wavelengths within a particular portion of a range of radiation or absorption, for example, ultraviolet (UV), emission, and absorption spectrometry. An instrument that measures transmission of apparent reflectance of visible light as a function of wavelength, permitting accurate analysis of color or accurate comparison of luminous intensities of two sources of specific wavelengths. The study of spectra using an instrument for dispersing radiation for visual observation of emission or absorption. See also “Infrared,” “Nuclear magnetic resonance,” “NMR,” and “Spectroscopy.” The relative luminous reflectance factor of a specimen at the specular direction. The colloidal particle has a spherical shape, formed either by single macro-molecule or an association of low-molecular weight species. Multi-gating of a part through a system of radial runners from the sprue. The process of fusing two objects by forcing them together while one of the pair is spinning, until frictional heat melts the interface. Spinning is then stopped and pressure held until they are frozen together. The line on the temperature vs. composition phase diagram for a mixture of two components, which separates the region from the two-phase regions. Hence, with binodal, it represents the limits of metastability of a two-phase system, viz., in polymer solutions or polymer blends. See also “Binodal.” The phase separation that occurs when the single-phase system is abruptly brought into the spinodal region of phase diagram, by either a rapid change of temperature, pressure, or flash evaporation of a solvent, viz., in polymer blends. Owing to spontaneous phase separation in Appendix III: Dictionary of Terms Used in Polymer Science and Technology Spiral flow test Splay marks or splay Split cavity Split-ring mold Spot welding Spray drying Spreader/torpedo Sprue bushing Sprue Sprue gate Sprue lock or puller 2265 the system (no nucleation!), the morphology generated is co-continuous. A method for determining the flow properties of a plastic material based on the distance it will flow under controlled conditions, pressure, and temperature along the path of a spiral cavity using a controlled charge. The length of the material that flows into the cavity and its weight gives a relative indication of the flow properties of the resin. Marks or lines found on the surface of the part after molding that may be caused by overheating the material, moisture in the material, or flow paths in the part. Usually white, silver, or gold in color. Also called silver streaking. A cavity of a mold that has been made in sections. A mold in which a split cavity block is assembled in a chase to permit the forming of undercuts in a molded piece. These parts are ejected from the mold and then separated from the molded piece. The localized fusion bonding of two adjacent plastic parts that does not require a molded protrusion or hole in the parts. To be effective, use where two parallel and flat surfaces meet. The transformation of feed from a fluid state into a dried particulate form by spraying the feed into a hot drying medium. It is used for the continuous production of dry solids in powder, granulate, or agglomerate form from liquid feedstocks as solutions, emulsions, pastes, and pumpable suspensions, viz., PVC lattices. A streamlined metal block placed in the path of flow of the plastics material in the heating cylinder of extruders and injection molding machines to spread it into intimate contact with the heating areas. A hardened steel insert in an injection mold that contains the tapered sprue hole and has a suitable seat for the nozzle of the injection cylinder. Sometimes called an adapter. Feed opening provided in the injection or transfer mold. Also, a slug formed at this hole. A passageway through which molten plastic flows from the nozzle to the mold cavity. In injection molding, a portion of the plastic composition held in the cold slug well by an undercut, used to pull the sprue out of the bushing as the mold is opened. 2266 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Stabilizer Staking Standard deviation, or sigma (s) The sprue lock itself is pushed out of the mold by an ejector pin. An ingredient used in the formulation of some plastics to assist in maintaining the physical and chemical properties of the compounded materials at their initial values throughout the processing and service life of the material. A term used in fastening – forming of a head on a protruding stud to hold component parts together. Staking may be done by cold staking, hot staking, or ultrasonic heating. The standard deviation of a population, labeled as the Greek letter sigma, is defined as the square root of the variance: s ðVarianceÞ1=2 ¼ Starve feeding Stationary platen Statistical chain (Kuhn) pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi Sðx xÞ=ðN 1Þ A method of feeding an extruder where the polymer is metered in a rate below the full capability of the machine. Thus, the output is determined by the feeder not the extruder or process variables. The controlled metering of resin into the machine’s feed section to fill the screw flights is not necessarily from the hopper, but from auger, feed belt, or by hand. The plate of an injection or compression molding machine to which the front plate of the mold is secured during operation. This platen does not move during the normal operation. Hypothetical free rotating polymer chain units with length ls, defined to reproduce the chain length; viz., the square end-to-end distance can be expressed as: < r2 >¼ Ns 12s Statistical process control (SPC) Stereolithography Stereoregular polymers The use of statistical methods to monitor and control a process. A three-dimensional printing process that produces copies of solid or surface models in plastic. This process uses a moving laser beam, directed by computer, to print or draw across sections of the model onto the surface of photo-curable liquid plastic. Tactic polymers exhibiting tacticity, i.e., regularity in the stereochemical configuration of its constitutional repeating units: isotactic, syndiotactic, erythro, and threo. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Storage life Storage modulus Strain Strength of material Stress concentration Stress concentration factor (SCF) Stress crack Stress cracking Stress optical sensitivity Stress relaxation Stress 2267 See “Shelf-life.” A quantitative measure of elastic properties, defined as the ratio of the stress inphase with strain, to the magnitude of the strain. The storage modulus may be measured in tension or flexure, E’, compression, K’, or shear, G’. The charge in length per unit of original length, expressed as a fraction of the original length, l ¼ (L Lo)/Lo, in percent, Dl ¼ 100l, or in extensional flow as e ¼ (L Lo)/L. The dimensionless numbers that characterize the change of dimensions of a specimen during controlled deformation. In tensile testing, the elongation divided by the original gage length of the test specimen. Refers to the structural engineering analysis of a part to determine its strength properties. Magnification of the level of applied stress in the region of a notch, crack, void, inclusion, or other stress raisers. Sections or areas in a part where the molded-in or physical forces are high or magnified – all sharp corners have high stresses. Ratio of the maximum stress in the region of a notch, or another stress raiser, to the nominal corresponding stress. SCF is a theoretical indication of the effect of stress concentration on mechanical behavior. Since it does not take into account the stress relief due to plastic deformation, its value is usually larger than the empirical fatigue notch factor or strength reducing ratio. External or internal cracks in a plastic caused by imposed stresses. A process of cracking under induced mechanical stress. Stress cracking generally starts with microscopic surface cracks, caused by chemical attack or other degrading influence such as ultraviolet radiation. Under mechanical stress, the microcracks propagate eventually producing a localized failure. The ability of materials to exhibit double refraction of light when placed under stress. The gradual decrease in stress with time under a constant deformation (strain) and temperature. Stress relaxation is determined in creep test. Data is often presented as stress vs. time plot. The stress relaxation rate is given by the slope of the curve at any point. The force applied to produce a deformation in the material. The ratio of applied load to the original 2268 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Stress-induced crystallization Stress–strain curve Stress–strain diagram Striation Stripper-Plate Structural reaction injection molding (SRIM) Styrene-acrylonitrile copolymers (SAN) Styrenics Submarine gate Substituted macromolecules cross-sectional area of a test specimen, or force per unit area that resists a change in size or shape of a body. The production of crystals in a polymer by the action of stress, usually in the form of an elongation. It occurs in fiber spinning, or during rubber elongation, and is responsible for enhanced mechanical properties. Simultaneous readings of load and deformation, converted to stress and strain, plotted as ordinates and abscissas, respectively, to obtain a stress–strain diagram. Graph of stress as a function of strain constructed from data obtained in any mechanical test in which a load is applied to a material and continuous measurements of stress and strain are made simultaneously. It is constructed for tensile, creep, or torsional loadings. A separation of colors resulting in a linear effect or color variation. In blow molding, the rippling of thick parisons. Also a longitudinal line in a plastic created by a disturbance in the melt path. A plate that strips a molded piece from core pins or cores. A molding process that is similar in practice to resin transfer molding, RTM. SRIM derives its name from the RIM process from which the resin chemistry and injection techniques have added to indicate the reinforced nature of the composite components manufactured by this process. A thermoplastic copolymer of styrene and acrylonitrile. If it comprises either SAN-grafted butadiene or is blended with nitrile rubber, NBR, a terpolymer is known as ABS. A group of plastic materials that are either whole or partially polymerized from styrene monomer. A type of edge gate where the opening from the runner into the mold is located below the parting line or mold surface, as opposed to conventional edge gating where the opening is machined into the surface of the mold. With submarine gates, the item is broken from the runner system on opening of the mold or ejection from the mold. Linear macromolecules with the side chains consisting of definite and usually homogeneous substituents. (In branched macromolecules, the side chains consist of the same primary molecules as in the main chain and are of varied length and irregularly arranged.) Appendix III: Dictionary of Terms Used in Polymer Science and Technology Substrate Suck-back Surface finish Surface treatments Surfactant Surging Suspension polymerization Swaging Sweating Swell Swelling Syndiotactic polymer Tab gated 2269 A material upon the surface of which an adhesivecontaining substance is spread for any purpose, such as bonding or coating. A slight retracting of the screw, usually no more than 5–7 mm as the mold opens to suck-back any resin that might have drooled out of the nozzle after the sprue was pulled. Correct nozzle type and temperature control can eliminate a need for this step, even when using very fluid resins. Finish of a molded product. Refer to the SPI-SPE Mold Finishes Comparison Kit. Any method of treating a material so as to alter the surface and render it receptive to inks, paints, lacquers, and adhesives such as chemical, flame, and electronic treatments. A compound that affects (usually reduces) interfacial tension between two liquids. Unstable pressure buildup in an extruder leading to variable throughput. Chain polymerization of vinyl monomer dispersed in form of large drops in aqueous medium. The polymerization is initiated by monomer-soluble initiator; thus, each drop can be treated as individual bulk polymerizing volume. An assembly technique, similar to heading, where the plastic material is deformed to a specific shape to assemble one or more parts. Exudation of drops of liquid, usually a plasticizer, on the surface of a plastic part. A dimensional increase caused by exposure to liquids and/or vapors. Swelling is the ability of a body to take up liquids. It depends on the size and shape of the macromolecule. Linear or lightly branched polymers immersed in a good solvent first swell without limit and then dissolve. The cross-linked polymers show limited swelling capability. A stereoregular polymer in which at least one monomeric carbon atom exhibits stereochemical configurational isomerism and in which the configurations alternate between the neighboring units, viz., syndiotactic PVC and isotactic or syndiotactic PP. A small removable tab of approximately the same thickness as the mold item, usually located perpendicular to the item. The tab is used as a site for edge gate location, usually on items with large flat areas. 2270 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Tacticity Taguchi method Tapered block copolymer Tear resistance Telechelic polymer Telomer Telomerization Temperature gradient Tensile impact energy Tensile impact test Tensile strength Tensile strength or stress A regularity of configurational isomeric unit placement in the polymeric chain. See “Isotactic, stereoregular, and syndiotactic polymer.” Problem-solving technique developed by Taguchi, which employs a testing process with an orthogonal array to analyze data and determine the main contributing factors in the solution of the problem. Gradient block copolymer in which there is a gradual change of composition at the junction between the two blocks from pure AAAAAAAA type to pure BBBBBBBB type. The tapered block copolymers are reported to be more efficient than pure AB block copolymers as compatibilizers of polymer blends. Tapping cutting threads in the walls of a circular hole. The force required to tear completely across a notched specimen tested according to prescribed procedures, expressed in pounds per inch of specimen thickness. A polymer with purposely introduced chain end groups of a specific type, e.g., ionic, hydroxyl, acidic, etc. Low-molecular-weight radical polymerization product obtained in a reaction in which extensive chain transfer to a solvent (or specifically introduced chain transfer agent) has occurred, so that the telomer contains fragments of these reactants as end groups. Primarily, a radical solution polymerization with high transfer constant, leading to products of relatively low molecular weight (telomers, with MW } 10,000) containing built-in fragments of the solvent. The slope of a temperature curve. An increasing or decreasing temperature profile on the barrel of the molding machine is an example. The energy required to break a plastic specimen in tension by a single swing of a calibrated pendulum. A test whereby the sample is clamped in a fixture attached to a swinging pendulum. The swinging pendulum strikes a stationary anvil causing the test sample to rupture. This is similar to the Izod test. The pulling stress at any given point on the stress vs. strain curve, usually just before the material tears or breaks. Area used in computing the engineering strength is the original, rather than the neckeddown area. The maximum tensile load per unit area of original cross section, within the gage boundaries, sustained by the Appendix III: Dictionary of Terms Used in Polymer Science and Technology Terpolymers Tetrapolymers Texturizing Thermal conductivity Thermal degradation Thermal expansion Thermal polymerization Thermal stress cracking (TSC) Thermocouple Thermoelasticity Thermoforming 2271 specimen during a tension test. Ultimate strength of a material subjected to tensile loading. A copolymer composed of three different repeat units or monomers, where the repeating structural units of all three are present within each molecule. The influence of all three types of monomer is evident in the property profile of the polymer. Common terpolymers include ABS and ASA. Copolymers that contain four different monomers. The etching or cutting of a pattern on a mold surface to be reproduced on the molded part. Ability of a material to conduct heat. The coefficient of thermal conductivity is expressed as the quantity of heat that passes through a unit cube of the substance in a given unit of time when the difference in temperature of the two faces is 1 C. Degradation caused by exposure to an elevated temperature. In the absence of oxygen, the term pyrolysis, while in its presence, the term thermo-oxidative are frequently used. The linear rate at which a material expands or contracts due to a rise or fall in temperature. Each material is unique and has its own rate of expansion and contraction. Free radical polymerization initiated either by thermal homolysis of an initiator (e.g., azo compound) or caused by action of heat on the monomer itself. Crazing and cracking of some thermoplastic resins that results from overexposure to elevated temperatures. A thermoelectric heat-sensing element mounted in or on machinery and the mold to transmit accurate temperature signals to a control and readout unit. Rubberlike elasticity exhibited by a rigid plastic and resulting from an increase of temperature. The process of forming a thermoplastic sheet into a three-dimensional shape after heating it to the point at which it is soft and flowable and then applying differential pressure to make the sheet conform to the shape of a mold or die positioned below the frame. Thermoforming variations include vacuum forming, air-assist vacuum forming, plug-assist forming, drape forming, plug-and-ring forming, ridge forming, slip forming, bubble forming, matched-mold forming, and scrapless thermoforming. 2272 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Thermogravimetric analysis (TGA) Thermomechanical analysis (TMA) Thermoplastics (TP) Thermoplastic elastomer (TPR) Thermoplastic injection molding Thermoplastic (IPN) Thermoplasticity Thermosets (TS) The study of the change in mass of a material, either in oxygen, air, or an inert atmosphere. The test can be conducted under various conditions of time, temperature, and pressure. A testing procedure in which changes in the weight of a specimen are recorded as the specimen is progressively heated. An analytical technique consisting of measuring physical dimensions of a material or changes in its moduli as a function of temperature and/or frequency. A class of plastic materials that is capable of being repeatedly softened by heating and hardened by cooling, viz., ABS, PVC, PS, and PE. Generally, a polymer that, upon heating softens, changing from a solid into elastic or liquid moldable state without having undergone chemical changes. The process is reversible and can be repeated many times. An elastomer which upon heating turns into regularly behaving linear polymer. Polystyrene-polybutadiene block copolymers, polypropylene blends with ethylenepropylene-diene terpolymer provide examples. A process in which melted plastic is injected into a mold cavity, where it cools and takes the shape of the cavity. Bosses, screw threads, ribs, and other details can be integrated, which allows the molding operation to be accomplished in one step. The finished part usually does not require additional work before assembling. Any IPN in which the individual polymers are thermoplastic. The polymers may contain physical cross-links as in ionomers where ionic clusters join two or more chains together. Nowadays, phaseseparated polymeric systems, e.g., block and graft copolymers or thermoplastic polyurethanes, are frequently considered thermoplastic IPNs. The ability of material to be deformed without breaking with a relatively fast flow, when (at a suitable temperature) this material is properly stressed. Materials that undergo a chemical reaction by the action of heat and pressure, catalysts, ultraviolet light, etc., leading to a relatively infusible state. Typical of the plastics in the thermosetting family are the amines (melamine and urea), unsaturated polyesters, alkyds, epoxies, and phenolics. A common thermoset goes through three stages. A-stage An early stage when the material is soluble in certain liquids and fusible and will flow. Appendix III: Dictionary of Terms Used in Polymer Science and Technology 2273 B-stage Thermoset injection molding Thermosetting plastics Thinner Thixotropy Thread plug, ring, or core Tie bars Toggle or toggle action Tolerance Topochemical polymerization Torsion pendulum Torsion Torsional Toughness An intermediate stage at which the material softens when heated and swells in contact with certain liquids, but does not dissolve or fuse. Molding compound resins are in this stage. C-stage The final stage is the TS reaction when the material is insoluble, infusible, and cured. A process in which thermoset material that has been heated to a liquid state is caused to flow into a cavity or several cavities and held at an elevated temperature for a specific time. After cross-linking is complete, the hardened part is removed from the open mold. See “Thermosets.” A liquid that can extend a solution, but not reduce the power of the solvent. A decrease of apparent viscosity under shear stress, followed by a gradual recovery when the stress is removed. The effect is time dependent. Its antonym is rheopexy. A part of the mold that shapes a thread. Bars that provide structural rigidity to the clamping mechanism of an injection molding press and usually guide platen movement. A mechanism that exerts pressure developed by the application of force on a knee joint. It is used as a method of closing presses and serves to apply pressure at the same time. A specified allowance for deviation in weighing and measuring or for deviations from the standard dimensions of weight. Solid-state polymerization of crystalline monomer without any intermediate loss of order. The topotactic oligomers have been produced, but the order is lost as the polymerization progresses beyond a low degree of polymerization. Test equipment used for determining the dynamic mechanical properties of plastics. Stress caused by twisting a material. The twisting or turning motion of a part. Torsional stress is created when one end of a part is twisted in one direction while the other is held rigid or twisted in the other direction. The extent to which a material absorbs energy without fracture. A measure of the ability of a material to absorb energy. The actual work per unit volume or unit mass of 2274 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Transesterification Transfer molding Translucent Transmission electron microscopy (TEM) Transparent Triblock polymer Tristimulus colorimeter Tumbling Tunneling UCST (upper critical solution temperature) Ultimate strength Ultimate tensile strength material that is required to rupture it. Toughness is proportional to the area under the load-elongation curve from the origin to the breaking point. An ester interchange reaction occurring when ester is heated in the presence of hydroxy compound (alcoholysis) or acid compound (acidolysis). Since esterification is reversible, the transesterification occurs between mixed esters in the presence of (thermally activated) low concentration of volatile reaction by-products. Ester-amide exchange can also be accomplished by similar (catalyzed) process. A method of molding thermosetting materials in which the plastic is first softened by heat and pressure in a transfer chamber and then forced by high pressure through suitable spruces, runners, and gates into a closed mold for final shaping and curing. The quality of transmitting light without being transparent. a microscopy technique in which an ultrathin specimen is illuminated by an electron beam. Image formation is made by detecting the electrons transmitted through the specimen. The short wavelength of electrons allows a much higher resolution in TEM (0.2 nm) than in its visible light analogous: the optical microscopy A material with a high degree of light transmission that can be easily seen through. A block copolymer consisting of three AnBmAn blocks. The instrument for color measurement based on spectral tristimulus values. The color is expressed in terms of three primary colors: red, green, and blue. Finishing operation for small plastic article by which gates, flash, and fins are removed and/or surfaces are polished by rotating them in a barrel together with wooden pegs, sawdust, and polishing compounds. Adding color to a material through tumble blending. Release of longitudinal portions of the substrate in incompletely bonded laminates and deformation of these portions to form tunnellike structures. The highest temperature of immiscibility, where binodal and spinodal curves meet. This type of phase separation predominates in solutions. Strength at the break point in tensile test. The highest stress sustained by a specimen in a tension test. Rupture and ultimate stress may not be the same. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Ultrasonic insertion Ultrasonic sealing, bonding, or welding Ultrasonic testing Ultrasonics Ultraviolet, UV Unbalanced mold Undercut Unimodal distribution Unit mold Universal testing machine Unsaturated polyester 2275 The inserting of metal into a thermoplastic part by the application of vibratory mechanical pressure at ultrasonic frequencies. A method in which sealing is accomplished through the application of vibratory mechanical pressure at ultrasonic frequencies (16–4,000 kHz). Electrical energy is converted to ultrasonic vibrations through the use of a piezoelectric transducer. The vibratory pressures at the interface in the sealing area develop localized heat losses that melt the plastic surfaces effecting the seal. Measurement of ultrasonic velocity and absorption (dissipation of sonic energy as a result of conversion to heat) to determine such structure-related factors as glass transition temperature, cross-link density, branching, morphology, composition, etc. Also a nondestructive test applied to materials to locate internal flaws or structural discontinuities by high-frequency reflection or attenuation ultrasonic beam. Branch of acoustics dealing with periodic waves with frequencies above the audible range, i.e., greater than 16 kHz. The region of the electromagnetic spectrum between the violet end of visible light and the X-ray region, including wavelengths from 10 to 390 nm. Because UV wavelengths are shorter than visible wavelengths, their photons have more energy, which initiates some chemical reactions and degrades most plastics, particularly aramids and polypropylenes. A nonuniform layout of mold cavities and runner system, fill rate, packing pressure, and part quality will vary from cavity to cavity. Used only for noncritical, standalone parts. Having a protuberance or indentation that impedes withdrawal from a mold in its normal open/closed movement. Flexible materials can be ejected intact even with slight undercuts. Distribution with a single peak. Mold designed for quick-changing interchangeable cavity parts. A mold that comprises only a single cavity, frequently a pilot for the production set of molds. A machine used to determine tensile, flexural, or compressive properties. A low-molecular-weight polyester with unsaturated, double bonds able to enter into cross-linking reaction 2276 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Unzipping UV stabilizer Vacuum metallizing Variance Vent Vertical flash ring Vicat softening point Vinyl Vinyl chloride plastics Virgin plastics or virgin material Viscoelasticity with added unsaturated monomer by the radical mechanism. The latter reaction is usually initiated by solution of methyl ethyl ketone peroxide. Also a family of polyesters characterized by vinyl unsaturation in the polyester backbone, which enables subsequent hardening or curing by copolymerization with a reactive monomer in which the polyester constituent has been dissolved. Depropagation – a degradation reaction in which the consecutive mers are gradually removed from one macromolecular chain end to another. Few polymers undergo such a reverse propagation reaction, viz., PMMA, POM, and PTFE. Any chemical compound that, when added to thermoplastic material, selectively absorbs ultraviolet rays. Process in which surfaces are thinly coated with metal by exposing them to the vapor of metal that has been evaporated under vacuum (one millionth of normal atmospheric pressure). See “Standard deviation.” In a mold, a shallow channel or minute hole cut in the cavity to allow air to escape as the melt enters. The clearance between the force plug and the vertical wall of the cavity in a positive or semipositive mold. Also the ring of excess material that escapes from the cavity into this clearance space. The temperature at which a flat-ended needle of 1 mm, circular or square cross section, will penetrate a thermoplastic specimen to a depth of 1 mm under a specified load using a uniform rate of temperature rise. The temperature at which a plastic is penetrated to 1 mm depth by a flat-ended circular metal pin, while in a controlled temperature silicone fluid bath. Usually polyvinyl chloride, PVC, but may be used to identify other polyvinyl plastics. Plastics based on polyvinyl chloride, PVC, or copolymers of vinyl chloride with other monomers, the vinyl chloride being the major component. A material not previously used or processed and meeting manufacturer’s specifications. A property involving a combination of elastic and viscous behavior. A material having this property is considered to combine the features of an elastic solid and Newtonian liquid. Appendix III: Dictionary of Terms Used in Polymer Science and Technology Viscosity Viscometer Viscous deformation Void Volume resistivity Vulcanization Warpage Water absorption Weathering Weatherometer Weibull distribution function: 2277 The property of resistance to flow exhibited within the body of a material, expressed in terms of relationship between applied shearing stress and resulting rate of strain in shear. A measurement of resistance of flow due to internal friction when one layer of fluid is caused to move in relationship to another layer. Viscosity is quantitatively defined as a ratio of shear stress to shear rate. An instrument used for measuring the viscosity and flow properties of fluids. Any portion of the total deformation of a body that remains permanently when the load is removed, also referred to as nonelastic deformation. A void or bubble occurring in the center of a heavy thermoplastic part, usually caused by excessive shrinkage. The electrical resistance between opposite faces of a 1 cm cube of insulating material. It is measured under prescribed conditions using a direct current potential after a specified time of electrification. Also called specific insulation resistance (ASTM D257). Process of converting of raw rubber compounds into lightly cross-linked network elastomer. Vulcanization of diene rubbers involves compounding it with sulfur or sulfur compounds and then heating at about 140 C for sometimes several hours. The process can be sped up by addition of catalyst, viz., ZnO. Dimensional distortion in a plastic object after molding. The amount of water absorbed by a polymer when immersed in water for stipulated periods of time. A term encompassing exposure of polymers to solar or ultraviolet light, temperature, oxygen, humidity, snow, wind, pollutants (e.g., ozone, NO2, CO2), cyclical changes of temperature and moisture, etc. Outdoor degradation of material, exposed to adverse weather factors. An instrument used for studying the accelerated effects of weather on plastics, using artificial light sources and simulated weather conditions. n o y ¼ ðb=aÞðx yÞb1 exp ðx gÞb=a for : x g; y ¼ 0 for : x g where x is a variable and a, b, and g are the distribution parameters. 2278 Appendix III: Dictionary of Terms Used in Polymer Science and Technology Welding Welding horn Wetting agent Wheel abrading Witness lines WLF equation Joining thermoplastic pieces by one of several heatsoftening processes. Butt fusion, spin welding, ultrasonic, and hot gas are examples of such methods. The sonic-energy transmission and pressuretransmitting tool used for ultrasonic welding. Each welding horn is tuned to specific amplitudes to efficiently perform the welding operation. An ingredient or solution used to lower the surface tension between two materials, so that good coverage and bonding occur. Deflashing molded parts by abrasion with small particles at high velocity. Lines left on a molded part by poor mating and fit of side action cores. Williams-Landel-Ferry equation that relates the value of the shift factor, aT (associated with time-temperature superposition of viscoelastic data), required to bring log-modulus (or log-compliance) vs. time or frequency curves measured at different temperatures onto a master curve at a particular reference temperature, T0, usually taken at 50 C above the glass transition temperature (T0 ¼ Tg + 50 C): aT ¼ Yellowness index Yield point elongation Yield point Yield strength C 1 ð T T0 Þ ½C2 þ ðT T0 Þ where the constants, C1 and C2, are approximately identical for all polymers: 8.86 and 101.6 K, respectively. Later, the WLF equation has been interpreted in terms of the Doolittle’s free volume theory. Measure of the tendency of plastics to turn yellow upon long-term exposure to light. In materials that exhibit a yield point, the difference between the elongation at the completion and the start of discontinuous yielding. The point at which permanent deformation of a stressed specimen begins to take place. Stress at which strain increases without accompanying increase in stress. Only materials that exhibit yielding have a yield point. The stress at the yield point – stress at which a material exhibits a specified limiting deviation from the proportionality of stress to strain or the lowest stress at which a material undergoes plastic deformation. When the material is elastic at lower stresses and viscoelastic at higher, unless otherwise specified, the stress at the Appendix III: Dictionary of Terms Used in Polymer Science and Technology Young’s modulus Zero defects Ziegler-Natta polymerization 2279 border of this change is the yield stress. Yield stress is often defined as the stress needed to produce a specified amount of plastic deformation, usually a 0.2 % change in length. In tensile testing, the yield stress is taken as that at which there is no increase in stress with a corresponding increase in strain – usually the first peak on the curve. It may also be defined as a specific limiting deviation from the proportional stress–strain curve. The ratio of normal stress to corresponding strain under tensile or compressive loading at stresses below the linearity limit of the material (also modulus of elasticity). A quality control method where anyone in the production cycle who discovers a quality problem can stop the assembly line or manufacturing process until it is corrected. The problem associated with this method is that upper management is often never made aware that a problem occurred. This lack of knowledge may prevent a complete repair from being initiated and the problem continues to occur. Chain polymerization on a Ziegler-Natta catalyst, Z-N. The Z-N catalysts are based either on TiCl4, VCl5, or CoCl3 mixed with either Al(C2H5)3 or Al(C2H5)2Cl, e.g., reacting AlR3 (R is an alkyl group) with crystalline TICl3 in an inert solvent. For example, three catalytic systems led to polymerization of high-density polyethylene, HDPE, (1) molybdena-alumina, (2) hexavalent CrO3 on silica, and (3) aluminum trialkyl (e.g., AlEt3) with TiCl4. The polymerization occurs at relatively mild conditions. Z-N polymerization is frequently used to obtain stereoregular polymers, viz., either to an isotactic or a syndiotactic polypropylene. References M.S.M. Alger, Polymer Science Dictionary (Elsevier Applied Science, London, 1989) H. Batzer, F. Lohse, Einf€ uhrung in die makromoleculare (Chemie H€ utingt & Wepf Verlag, Basel, 1976) J. Brandrup, E.H. Immergut, Polymer Handbook (Intersc Pub, New York, 1966) P.J. Flory, Statistical Mechanics of Chain Molecules (Intersc Pub, New York, 1969) J. Frado (ed.), Plastics Engineering Handbook, 4th edn. (Reinhold Pub Corp, New York, 1976) C.A. Harper (ed.), Handbook of Plastics and Elastomers (McGraw-Hill, New York, 1975) H.E. Pebly, Glossary of terms in composites, in Engineering Materials Handbook, vol. 1 (ASM International, Ohio, 1987) 2280 Appendix III: Dictionary of Terms Used in Polymer Science and Technology T.A. Richardson, Industrial Plastics: Theory and Application (Cincinnati, South-Western, 1983) Standard Abbreviation of Terms Relating to Plastics, D1600, Annual Book of ASTM Standards, American Society for Testing and Materials Standard Definitions and Descriptions of Terms Relating to Conditioning, E41, Annual book of ASTM Standards, American Society for Testing and Materials Standard Definitions and Descriptions of Terms Relating to Dynamic Mechanical Measurements on plastics, D4092, Annual book of ASTM Standards, American Society for Testing and Materials Standard Definitions and Descriptions of Terms Relating to Methods of Mechanical Testing, E6, Annual book of ASTM Standards, American Society for Testing and Materials Standard Definitions and Descriptions of Terms Relating to Plastics, D883, Annual book of ASTM Standards, American Society for Testing and Materials Standard Definitions and Descriptions of Terms Relating to Reinforced Plastic Pultruded Products, D3918, Annual book of ASTM Standards, American Society for Testing and Materials Standard Definitions and Descriptions of Terms Relating to Resinography, E375-75 (reproved in 1986), Annual book of ASTM Standards, American Society for Testing and Materials Standard Guide for Identification of Plastic Materials, D4000, Annual book of ASTM Standards, American Society for Testing and Materials Standard Terminology Relating to Radiation Measurements and Dosimetry, E170, Annual book of ASTM Standards, American Society for Testing and Materials J. Thewlis, R.C. Glass, A.R. Meetham (eds.), Encyclopaedic Dictionary of Physics (Pergamon Press, Oxford, 1967) L.A. Utracki, Commercial Polymer Blends (Chapman & Hall, London, 1998) L.A. Utracki, Encyclopaedic Dictionary of Commercial Polymer Blends (ChemTec Pub, Toronto, 1994) L.A. Utracki, Polymer Alloys and Blends – Thermodynamics and Rheology (Hanser Pub, Munich, 1989) Van Nostrand’s Scientific Encyclopaedia. (D. Van Nostrand Co. Inc., Princeton, 1958) L.R. Whittington, Whittington’s Dictionary of Plastics, 2nd edn. (Technomic, Lancaster, 1978) Appendix IV: Trade Names of Polymers and Their Blends A A-C A-FAX A-fax A-Tell Abbey #100 Abbey #400 Absafil Abson Abstrene Accpro Acctuf Acculloy Accutech Acetabel Acetron GP Acetal Acetron NS Acetal Achieve Acihr Aclar, Aclon Aclyn Acme Acpol Acraldon Low molecular weight polyethylene, PE Amorphous polypropylene, PP Polypropylene, PP Polyethylene-p-oxybenzoate for fibers Poly(vinyl chloride) compound, PVC Polypropylene, PP Acrylonitrile-butadiene-styrene terpolymer, ABS ABS/PVC blends Acrylonitrile-butadiene-styrene terpolymer, ABS Polypropylene blends High-impact ethylene-propylene copolymers Polymer alloys Reinforced resins Cellulose acetate, CA POM reinforced or not (rods or sheets) POM. lubricated (rods or sheets) Metallocene-grade isotactic polypropylene, PP Fluoropolymer film Fluorocarbon PCTFE film Low molecular weight EVAc ionomers Epoxy resins and molding compounds Acrylic or thermoset polyesters; acrylic/urethane/ styrene IPN Ethylene-vinyl acetate copolymer, EVAc Allied-Signal Inc. Himont Himont ICI Abbey Plastic Corp. Abbey Plastic Corp. Fiberfil/Akzo/DSM Abtec/BF Goodrich Distillers Amoco Chemical Amoco Chemical Aclo Compounders Aclo Compounders Ponceblanc Polymer Corp. Polymer Corp. Exxon Allied-Signal Inc. Allied-Signal Inc. Allied-Signal Inc. Allied Products Corp. Freeman Chem Co. Bayer AG (continued) L.A. Utracki, C.A. Wilkie (eds.), Polymer Blends Handbook, DOI 10.1007/978-94-007-6064-6, # Springer Science+Business Media Dordrecht 2014 2281 2282 Acralen Acrifix Acrilan Acronal Acrylafil Acrylan Acrylan-Rubber Acrylite Acrylite FF Acrylite GP Acrylite SDP Acrylivin Acryloid Acrylyn Acrypanel Acrypoly Acryrex ACS ACS Resin NS Acsium ACter ACumist ACX Addylene Addylon Adell A, B Adell F Adell H Adell K Adflex Adion A Adion H Adiprene Admer Adpro AP Adpro Adstif Aerolam, Aerolite Aeroweb, Aracast Afcole`ne Appendix IV: Trade Names of Polymers and Their Blends Elastomers PMMA, poly(methyl methacrylate) Polyacrylonitrile, PAN Acrylic esters; homo- and copolymers Glass fiber-reinforced SAN Acrylic fiber Butyl acrylate-acrylonitrile copolymer Acrylic (PMMA) Poly(methyl methacrylate) powder, sheets, PMMA Cast acrylic sheet, PMMA Bayer AG Ro¨hm AG Chemstrand Corp. BASF Plastics Akzo/DSM Monsanto Monomer Corp. Cyro Industries Cyro Industries Chemacryl Plastics, Ltd. Double-skinned acrylic sheet, PMMA Chemacryl Plastics, Ltd. Poly(vinyl chloride)/Acrylic alloy Gen. Tire & Rubber Poly(methyl methacrylate)-butadiene-styrene Rohm and Haas Melt-processable rubber E. I. du Pont de Nemours PMMA, poly(methyl methacrylate) Mitsubishi Rayon Co. Acrylic extruded sheet, PMMA Chi Mei Ind. Co. Ltd. Acrylic resin, PMMA Chi Mei Ind. Co. Ltd. Chlorinated polyolefins, e.g., PE, cross-linked or not Showa Denko K. K. Styrene-acrylonitrile copolymer, SAN Biddle Sawyer Corp. Alkylated chlorosulfonated polyethylene, CSR DuPont/Safic-Alcan Low molecular weight terpolymers Allied-Signal Inc. Micronized polyolefins, PO Allied-Signal Inc. Polyoxymethylene, POM United Composites Polypropylene, PP Addiplast Polyamides, PA Addiplast Polyamide-6 or polyamide-66; reinforced or not, Adell Plastics, Inc. PA-6 Polypropylene; reinforced or not, PP Adell Plastics, Inc. Poly(butylene terephthalate); reinforced or not, PBT Adell Plastics, Inc. Polyethylene; reinforced or not, PE Adell Plastics, Inc. Reactor PP alloy; soft PP/EP copolymer Himont Inc. ABS/hydrophilic-PA; antistatic, for medical uses Asahi Chemical Ind. HIPS/hydrophilic-PA; antistatic, for cassettes Asahi Chemical Ind. Diisocyanates, polyurethanes, PU E. I. du Pont de Nemours Polyolefins, PO Mitsui Petrochem. Reactor olefinic thermoplastic elastomers, RTPO Genesis Polymers Polypropylene, PP Novacor/Genesis Polymers Rigid polypropylene made in Catalloy process Himont Inc. Epoxy resin and molding compounds Ciba-Geigy Ltd. Honeycomb materials Styrene-acrylonitrile copolymer, SAN Rhoˆne Poulenc (continued) Appendix IV: Trade Names of Polymers and Their Blends Afcoryl Affinity Aflas FA Aflas Aflon Ahane Aim Airflex Akulon Akuloy J Akuloy RM Akuloy XT Alathon Alathon Albertol Albidur Albis Alcotex Alcryn Alcudia Alcupol Alfon Cop. Alftalat Algoflon Algoflon Alkapols Alkathene Alkox Alkydal Alkyde Alkynol Allied CM-X Allobec Alloprene Alpha-PVC Alphaseal 2283 Acrylonitrile-butadiene-styrene terpolymer, ABS Pechiney-SaintGobain Polyolefin plastomer, containing 0–20 wt% Dow Chem. Co. comonomer based on Insite™ metallocene technology, with long chain branching Fluoropolymers 3M Ind. Chem. PTFE + PP + cure site monomer terpolymer Asahi Glass Poly(tetrafluoroethylene-co-ethylene) Asahi Glass Ultra low-density polyethylene, ULDPE Dow Chem. Co. – Dow Plastics Ethylene-vinyl acetate copolymer, EVAc AP&C PA-6, PA-66, blends with PO, reinforced or not Akzo/DSM Plastics Polyamide-66 with PP and 30 % glass fiber DSM Plastics Int. Polyamide-6 or polyamide-66 blend with DSM Plastics Int. functionalized-PP; glass fiber or mineral filled or not Polyamide-6/thermoset elastomer alloy DSM Plastics Int. Polyethylene resins, PE Occidental Polyethylenes, PE Cain Chem. Inc. Phenol-formaldehyde resins, PF Chem. Werke Albert Thermosetting resins; PU, epoxides, polyesters OFACI Polyamide-6/Polyolefin (10 %) blend Albis Plastics Poly(vinyl alcohol), PVAl Revertex Chlorinated olefin/EVAl/acrylate ester blends; E. I. du Pont de PVC/ethylene-carbon monoxide-vinyl chloride Nemours copolymer; TP elastomers Polyethylene, PE Repsol Quimica SA Polyols, polyurethanes, PU Repsol Quimica SA Modified ethylenetetrafluoroethylene copolymer Asahi Glass Alkyd resins Chem. Werke Albert Fluorinated resins Enimont Polytetrafluoroethylene, PTFE Montecatini/Ausimont Polyfunctional PPO polyols Rhoˆne-Poulenc High-density polyethylene, HDPE ICI Adv. Mater. Polyethylene oxide Meisei Chemical Works Alkyd, polyester resins, UP Bayer AG/Miles Polyester polyurethanes, TPU Synres-Almoco Polyester resins for paints and varnishes, UP Bayer Polytetrafluoroethylene, PTFE Allied-Signal Corp. Polyesterimide, PEI Dr. Beck & Co. Chlorinated rubber ICI Adv. Mater. Flexible PVC – CPD Alpha Chem. & Plastics TPO elastomer for packaging Alpha Chem. & Plastics (continued) 2284 Alphatec Alphon Alton Altuchoc Altuglas Altuglas Altulite Alulon Amberlite Ameripol CB Ameripol Ameripol Ameripol SM Amidel Amidel Amilan Amilon Amoco 10 Amoco 20 Amoco A-I Amoco G Amodel AAmodel ADAmodel ETAmoron Ampal Ampec Ampol Antron Apec Apex Apiax Apiflex Apilon Aplical APP Applied Comp 8000 Appendix IV: Trade Names of Polymers and Their Blends TPE for medical products Alpha Chem. & Plastics Fluoroelastomer, PTFE/elastomer blends Custom M.P. Poly(phenylene sulfide)/polytetrafluoroethylene Intl. Polym. Corp. Polycarbonate, PC Societe Altulor SA Acrylic, poly(methyl methacrylate), PMMA; Societe Altulor SA/ sheets Elf Atochem PUR/PMMA interpenetrating polymer networks Elf Atochem Poly(methyl methacrylate); powder, PMMA Societe Altulor SA Polyamide-66, PA-66 Akzo/DSM Synthetic ion exchanger Rohm and Haas Polybutadiene, PB BF Goodrich Polyisoprene, CPI Firestone Polyisoprene, CPI Firestone cis-1,4-Polyisoprene, CPI Firestone Polyamide, amorphous, transparent Union Carbide Polyamide-6, PA-6 Toray Industries Glass fiber- or mineral-reinforced polyamide-6 Toray Industries Polyamide-6 or polyamide-66, PA-6 or PA-66 Toray Industries Polypropylenes, PP Amoco Chem. Corp. Polyethylenes, PE Amoco Chem. Corp. Polyimide; insulative and conductive coatings Amoco Chem. Corp. Polystyrene, PS Amoco Chem. Corp. Polyphthalamide, reinforced Amoco Performance Products Polyphthalamide, PPA, semicrystalline-PA Amoco Performance Products Polyphthalamide, impact modified Amoco Performance Products Polythioethersulfone, block copolymer with 53 % Dainippon Ink & PPS and poly(phenylene sulfide)sulfone, PPSS, Chem. filled with 0, 30, and 40 wt% glass and PTFE Polyester, unsaturated, UP Ciba-Geigy Ltd. Ethyl cellulose, EC American Polymers Cellulose propionate, CP, or cellulose acetateAmerican Polymers butyrate, CAB Polyamide fiber E. I. du Pont de Nemours Aromatic, “high heat,” polyester carbonate, PEC Bayer AG/Miles Poly(vinyl chloride) compounds; PVC Teknor Apex Polyether compound Polymix Poly(vinyl chloride), semirigid, plastified; PVC Polymix Polyurethanes, PU, or poly(vinyl chloride), PVC Polymix Polyimide film, PI Allied Signal Inc. Polypropylenes, PP Reichhold Chem., Inc. Thermoset polyester-based composites, UP Applied Composites (continued) Appendix IV: Trade Names of Polymers and Their Blends Appryl Apscom Aqua Keep Aqualoy 100 Aqualoy 600 Aquathene Arakote Araldite Arcel Arcol Ardel D-100 Ardel Areca Ariloks Arimax Aristech Arlon Arloy 1000 Arloy 2000 Arloy Arnel Arnite PBTP Arnite Arnitel Aropol Aroset Arpak/Arpro Arpro/Arpak Arradur Arum Polypropylene, PP Speciality thermoplastics (ABS, Acrylics, SAN, Akzo/DSM POM, PC, PEI, PP, PPE, PPS, etc.) Superabsorbent polymers Polypropylenes, PP Polyamide-66 Polyethylene Thermoset polyesters, UP Epoxy resins, EP Polyethylene copolymers Polyols Polyarylate, bisphenol-A iso-/terephthalate PAr/PET blends Reinforced polypropylene, PP Poly(phenylene ether)/HIPS; PPE/HIPS blends Polyurethanes, PU Polypropylene, PP Polyetheretherketone; reinforced or not, PEEK Polycarbonate, PC/SMA blend Styrene maleic anhydride, SMA/PET alloys PC/SMA/HIPS blends Cellulose triacetate Poly(butylene terephthalate), reinforced or not Poly(ethylene terephthalate), reinforced or not Thermoplastic ether-ester elastomer, TPE Unsaturated polyesters, UP Acrylic copolymers (P-sensitive adhesives) Polyethylene-expanded beads Polypropylene-expanded beads Acrylonitrile-butadiene-styrene terpolymer, ABS Polyimide for injection molding Arylef Arylon Polyarylate Polyarylate, PAr, PET blends Asahi PPS RE Ashlene Poly(phenylene sulfide), PPS alloy Polyamide-6, polyamide-612, or polyamide-66; reinforced or not Thermoplastic polyester; PET-based blends Phenol-formaldehyde resins, PF Fiber-grade polyethylene resins, PE Acrylic dispersion Polyarylethersulfone, PAES, [f–O–f–SO2–f–f–SO2–] Filled polypropylene, PP Aspect Asplit Aspun Asterite Astrel Astryn 2285 Elf Atochem Elf Atochem CoAlloy Intl. Corp. CoAlloy Intl. Corp. Quantum Ciba-Geigy Corp. Ciba-Geigy Ltd. ARCO Chemical ARCO Chemical Amoco Chem. Co. Amoco Chem. Co. SPCI USSR Ashland Chem. Co Aristech Chem Corp. Du Pont/Green, Tweed Arco Chem. Co. Arco Chem. Co. Amoco Celanese Akzo/DSM Akzo/DSM Akzo/DSM Ashland Chem. Ashland Chem. ARCO Chemical/JSP ARCO Chemical/JSP Elf Atochem Mitsui Toatsu Chem., Inc. Solvay E. I. du Pont de Nemours Asahi Glass Ashley Polymers Inc Phillips 66 Co. Hoechst Dow Chem. Co. ICI Chem. Polym. Ltd. Carborundum Himont (continued) 2286 Astyr Atlac Atlantic Polybead Atlas Attane Aurum Avimid AVP AVP Resin Avron Avtel AX-500 Azdel Azloy Azmet B Bakelite DFD Bakelite DHDA Bakelite DPD Bakelite DQDA Bakelite ERL, ERR Bakelite HFD Bapolan 1000 Bapolan 4000, 5000 Bapolan 6000 Bapolan 7000 Bapolan 8445 Bapolene Barex Basopor Basotect Bayblend DP2 Bayblend Baycoll/Baymer Baycomp Baydur Bayer LCP Appendix IV: Trade Names of Polymers and Their Blends Butadiene rubber, BR Unsaturated polyester resin, UP Montecatini DSM/Koppers Co., Inc. Expanded polystyrene, PS Atlantic Gypsum Acrylate and methacrylate resins Degussa Ultra low-density linear polyethylene copolymers Dow Chem. Co. Polyimide; for injection molding, recyclable Mitsui Toatsu Thermoplastic polyimide E.I. du Pont de Nemours Engineering thermoplastic resins and blends Polymerland, Inc. Recycled thermoplastic resins Polymerland, Inc. Acrylic dispersion ICI Chem. Polym. Ltd. Advanced composites Phillips 66 Co. Amorphous polyarylate/PA-6 alloy + 40 % glass Unitika Continuous glass fiber-filled PP Azdel Inc. Continuous glass fiber-reinforced PC/PBT blends Azdel Inc. Crystalline polyester-based composite Azdel Inc. Polyethylenes, PE Bakelite/Union Carbide Ethylene-vinyl acetate copolymers, EVAc Bakelite/Union Carbide Acrylic resins Bakelite/Union Carbide Ethylene-vinyl acetate copolymers, EVAc Bakelite/Union Carbide Epoxy resins, EP Bakelite/Union Carbide Polyethylenes, PE Bakelite/Union Carbide Polyethylenes; reinforced or not, PE Bamberg Polymers Polypropylenes, PP Bamberg Polymers Polystyrenes, PS Bamberg Polymers Styrene-acrylonitrile copolymer, SAN Bamberg Polymers Acrylonitrile-butadiene-styrene terpolymer, ABS Bamberg Polymers Polyethylene Bamberger Polyacrylonitrile and acrylonitrile copolymers BP Chemicals, Intl. transparent for bottles, films, etc. Urea-formaldehyde resin, UF BASF Plastics Elastic melamine foam, MPF BASF Plastics PC/ABS alloy; molding, structural foam, etc. Bayer AG/Miles PC/ABS alloys, reinforced, flame retard or not Bayer AG/Miles Polyurethanes, PU Bayer AG/Miles Fiber-reinforced plastic Bay Mills Polyurethanes, PU Bayer AG/Miles Liquid crystal polymers, LCP Bayer AG/Miles (continued) Appendix IV: Trade Names of Polymers and Their Blends Bayer Silicone Bayfill/Bayfit Bayflex Bayfol CR Bayfol Baygal/Baymidur Baylon Baylon Baylon Baymer/Baysport Baymoflex Baynat/Baytec Baypren Baypren Latex Baypren/Bystal Baysilone Baytac Baytec 800 Beckacite Beckopox Beetle Beetle Beetle Beetle Beetle Beetle Beetle Beetle Benvic Bergacell Bergadur Bergamid Bergaprop Beta Bexel Bexloy Silicones Polyurethanes, PU Polyurea for reactive injection molding, RIM PC/PBT blends Films made of PC blends Polyurethane casting resins, PU Ethylene-vinyl acetate copolymer, EVAc Polycarbonate PC Polyamide-66 Polyurethanes, PU Acrylonitrile-styrene-acrylic rubber blend Polyurethane, PU Chloroprene rubber, CR; for molding Anionic lattices of chloroprene rubber, CR Polychloroprene elastomers Silicones Laminating adhesives (hot melt) Polyurethanes, PU Phenol-formaldehyde resins, PF Epoxy resins, EP a-cellulose-reinforced urea-formaldehyde, UF PBT, PET compounds Polyamide-6, polyamide-66 compounds, PA-6 Polycarbonate compounds, PC Polyester compounds (PMC) Polyoxymethylene, POM Unsaturated polyester resins, UP Urea-formaldehyde molding powders UF PVC blends with ABS, NBR, MBS, CPE, etc. with glass fiber or not Cellulose acetates, CA Thermoplastic polyesters Polyamides reinforced or not, PA Reinforced polypropylene, PP – SAN/acrylic alloys Automotive engineering resins (an ionomer) Bexloy C Amorphous polyamide blend, PA Bexloy J Poly(butylenes terephthalate), PBT, blend Bexloy K Reinforced PET blend Bexloy M Aromatic polyester blend 2287 Bayer AG/Miles Bayer AG/Miles Bayer AG/Miles Bayer AG/Miles Bayer AG/Miles Bayer AG/Miles Bayer AG/Miles Bayer AG/Miles Bay Resins Bayer AG/Miles Bayer AG/Miles Bayer AG/Miles Polysar/Bayer AG Polysar/Bayer AG Bayer AG/Miles Bayer AG/Miles IGI Baychem, Inc. Bayer AG/Miles Reichhold Ltd. Reichhold Ltd. BIP Chemicals Ltd. BIP Chemicals Ltd. BIP Chemicals Ltd. BIP Chemicals Ltd. BIP Chemicals Ltd. BIP Chemicals Ltd. BIP Chemicals Ltd. BIP Chemicals Ltd. Solvay & Cie SA Th. Bergmann Th. Bergmann Th. Bergmann Th. Bergmann Beta Polymers Bakelite Xylonite E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours (continued) 2288 Appendix IV: Trade Names of Polymers and Their Blends Bexloy Polyarylate, PAr, PET blends Bexloy V Thermoplastic copolyester elastomer blend Bexloy W Ionomer engineering blend Bexoid Bexone F Bextrene Bioform Biopol Biresin Blane Blendex Cellulose acetate, CA Poly(vinyl formal), PVFM Polystyrene, PS Acrylic-based IPN for artificial teeth Poly(b-hydroxybutyric acid), PHBA Thermoset resins, UP Poly(vinyl chloride), PVC; with clay or not ABS modifier/processing aid for rigid PVC Blendur Blendur-E Blueboard BMC Boltaron PU-based thermoset blend Epoxides, EP Plastic foam insulation Unsaturated polyester; reinforced or not, UP Poly(vinyl chloride)/acrylic alloy sheets Bond 811B Bonoplex Bonvic Bovidur/Bovil BP D, H BP Polystyrene BR Brilion BT 40 Bristrend Bromo XP-50 Epoxy resins, EP Poly(methyl methacrylate), PMMA Rigid PVC formulation based on emulsion resin Poly(vinyl chloride) compounds, PVC Polyethylenes, PE Polystyrene, PS Poly(phenylene sulfide), PPS/PTFE blend Polyamide alloys, PA Poly(vinyl chloride)/Poly(vinyl acetate) Brominated poly(isobutylene-co-pmethylstyrene) Elastomers Thermosetting polyimide Polyamide-6, PA-6 cis-1,4-Polybutadiene, PB Thermoplastic elastomers: EPR or EPDM Styrene-butadiene block copolymer, for impact modification of PS, leading to HIPS Butadiene rubber, BR; polymerized with Ti-, Nd-, or Li-based catalyst Expandable SBR, E-SBR Butadiene-acrylonitrile copolymer, MBR Poly(butadiene-co-acrylonitrile), MBR Polybutadiene, PB Butadiene-styrene copolymer, SB Bromobutyl BT resin Budd Cast Budene Buna AP Buna BL Buna CB Buna EM Buna H€uls butacryl Buna N Buna Buna S E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours British Xylonite British Xylonite British Xylonite Dentsply International SPCI BP Performance GE Speciality Chemicals Bayer AG/Miles Bayer AG/Miles Dow Chem. Co. BMC Inc. GenCorp Polymer Prod. Furane Products AB Bofors, Sweden Solvay & Cie SA Maprac BP Chemicals Ltd. BP Chemicals Ltd. Phillips 66 Co. EMS Polymers Inc. Exxon Chem. Exxon Chem. Mitsubishi Gas Chem. Budd Co. Goodyear, USA Bunawerke H€ uls Polysar/Bayer AG Polysar/Bayer AG Bunawerke H€ uls Plastugil, France Chem. Werke H€ uls Buna AG Chem. Werke H€ uls (continued) Appendix IV: Trade Names of Polymers and Their Blends Bur-A-Loy Butacite Butaclor Butacon Butaprene Buton Butvar PVC/nitrile rubber blends Poly(vinyl butyral) sheeting; safety glass sheeting E. I. du Pont de Nemours Polychloroprene, CR Butadiene copolymers Styrene-butadiene copolymers Cross-linked butadiene-styrene copolymer Poly(vinyl butyral) Butylkautschuk BVC BXL Polyisobutylene with 5 % isoprene, PIB Poly(vinyl chloride), PVC Polysulfone, PSU Bynel (CXA) Coextrudable adhesive resins C C-020 C-Flex Cadon Calatrava Caleprene Calibre Calibre CR Calibre IM Calprene Capran Caprolan Capron Capron Capron AB Caradate Caradol Carapor Carbopol Carboset Carbowax Carbres Cardura Cariflex I Cariflex Caril Carilon Polypropylene, PP Thermoplastic elastomers; SEBS/PDMS blends SMA and SMA/ABS elastomeric blends with glass fibers or not High-density polyethylene, HDPE Elastomers Polycarbonate, PC, and its blends PC blended with PBT and PET PC blended with an elastomer Synthetic rubber Polyamide-6; resins, films, fibers, laminates, PA Thermoplastic elastomers Polyamide-6 and blends; reinforced or not, PA Polyamide/PO or elastomer blend Polyamide-6/elastomer; food grade barrier resin Polyurethanes, isocyanates, PU Polyols for PU Additive for polyurethane Acrylic acid polymers, PAA Acrylic polymers Poly(ethylene glycol), PEO 2289 Mach-1 Compounding Distugil ICI Firestone Exxon, GB Shawinigan Chemicals Bayer AG/Miles Bayshore Vinyl Union Carbide Co., Inc. E. I. du Pont de Nemours Aristech Chem. Concept Polymer Monsanto Chem. Co. Repsol Quimica Repsol Quimica Dow Chem. Co. Sumitomo Dow Ltd. Sumitomo Dow Ltd. Repsol Quimica SA Allied-Signal Inc. Elastogran Allied-Signal Inc. Allied-Signal Inc. Allied-Signal Inc. Shell Chem. Co. Shell Chem. Co. Shell Chem. Co. BF Goodrich BF Goodrich Union Carbide Co., Inc. Reinforced polypropylene, PP SIC Plastic Chemical intermediates Shell Chem. Co. cis-1,4-Polyisoprene Shell Chem. Co. Styrene-butadiene block copolymer, SB Shell Chem. Co. Poly(phenylene ether), PPE blend Shell Chem. Co. Linear, alternating olefin/CO copolymer, COPO, Shell Chem. Co. engineering resin with good barrier properties [based on Pd catalyst; introduced in 1995] (continued) 2290 Carina Carinex Caristar Carloy Cast Nylon Castethane Catalloy Cefor Celanese Nylon 6 Appendix IV: Trade Names of Polymers and Their Blends Poly(vinyl chloride), PVC Polystyrene, PS Plastic packaging material Poly(vinyl chloride), PVC/elastomer blend Polyamide, PA Elastomer systems Polypropylene copolymer alloy Polypropylene Polyamide-6, PA-6 impact modified Shell Chem. Co. Shell Chem. Co. Shell Chem. Co. Cary Chem. Inc. Commercial Plastic Dow Chem. Co. Himont Shell Chem. Co. Hoechst Celanese Corp. Celanese Nylon 6/6 Polyamide-66 and polyamide-66/TPU alloys Hoechst Celanese glass fiber reinforced or not Corp. Celanese Polyamide-6, polyamide-66, PA-6 or PA-66 Hoechst Celanese Corp. Celanex PBT/elastomer; blends reinforced or not Hoechst Celanese Corp. Celanex PBT/PET/elastomer; blends reinforced or not Hoechst Celanese Corp. Celazole Thermoplastic polyimides, reinforced or not Hoechst Celanese Corp. Celcon Copolyoxymethylene, POM, glass-reinforced, Hoechst Celanese impact-modified elastomer blends Corp. Celion Carbon fibers BASF Plastics Cellasto Cellular PUR elastomers BASF Plastics Cellatherm Polyesterimide, PEI Reichhold Chemie Cellidor B Cellulose acetate-butyrate, CAB Bayer AG/Miles Cellidor CP Cellulose propionate, CP Bayer AG/Miles Cellit Cellulose acetate or cellulose propionate Bayer AG/Miles Cellon Cellulose acetate, CA Dynamit Nobel Cellophan Cellulose hydrate from pulp Kalle Cellosize Hydroxyethyl cellulose Union Carbide Celltrek 3000 Polyol for PU foam without CFC Dow Europe Celluloid Cellulose nitrate plasticized with camphor, CN Hoechst Celanese Celstran Long glass fiber-reinforced thermoplastics, viz., Hoechst Celanese POM, PBT, PET, PA, etc. Corp. Centrex 800 ASA-based, weatherable polymers Monsanto Chem. Co. Centrex Acrylonitrile-styrene-acrylate copolymers, ASA/ Monsanto Chem. Co. AES rubber modified blends Cevian ABS Hoechst Celanese Co. Chem-AD Epoxy and polyurethane industrial adhesive Chemque Chem-POT Encapsulating resins of epoxy and polyurethane Chemque Chemfluor Polytetrafluoroethylene compounds, PTFE Norton Performance Chemigum Nitrile rubber, NBR; TP elastomers Goodyear Chem. Chemigum TPE NBR blend with PVC, CPE, TPU, and/or PA Goodyear Chem. Chemorset Epoxy adhesives, EP Chemor Inc Chemplex 1000, 3000 Polyethylenes, PE Norchem, Inc. (continued) Appendix IV: Trade Names of Polymers and Their Blends Chemplex 5000, 6000 Chemplex EVA Chemplex PE Chen-Lon Chevron Chlorkautschuk Chlorobutyl Cibamin Cibanoid CIL 100 CIL 1000 Cis-4 Cladlux Claradex Clarene Clariflex TR Clear 01 Cleartuf 7000 Clysar Cobex Codabs Codica Codimel Codix Comalloy 110 Comalloy 210 Comalloy 220 Comalloy 240 Comalloy 260 Comalloy 310 Comalloy 410 Comalloy 510 Comalloy 610 Comalloy 620 Comalloy 640 Comalloy 710 Comalloy 740 Comalloy 832 Comalloy 862 Comalloy 940 Comalloy Comco Nylon 6 Comco Nylon 6 Polyethylenes, PE EVAc for extrusion coating, laminating EVAc for tough film applications Polyimide, PI, adhesive Polypropylene, PP Chlorinated natural rubber Elastomers UF, MF-lacquer resins Urea-formaldehyde, UF, molding material Low-density polyethylenes and copolymers Ethylene-vinyl acetate copolymers, EVAc cis-1,4-Polyisoprene Acrylic/PVC alloy ABS Poly(ethylene-co-vinyl alcohol); EVAl or EVOH Styrene-butadiene-styrene copolymer, SBS PVC alloy with glutarimide acrylic copolymer for hot-fill bottles Poly(ethylene terephthalate), PET PO shrink films 2291 Norchem, Inc. Norchem, Inc. Norchem, Inc. Chemtronics Chevron Bayer AG/Miles Exxon Chem. Ciba-Geigy Ltd. Ciba-Geigy Ltd. CIL Inc. CIL Inc. Phillips Richard Daleman Shin-A Solvay & Cie SA Shell Chem. Co. Georgia Gulf Goodyear E. I. du Pont de Nemours Poly(vinyl chloride) Bakelite Xylonite ABS reinforced or not Codiplast Reinforced polypropylene, PP Codiplast Reinforced poly(vinyl chloride), PVC Codiplast Polypropylene, PP Codiplast Polypropylenes; reinforced or not, PP Comalloy Intl. Corp. Polystyrenes; reinforced or not, PS Comalloy Intl. Corp. ABS; reinforced Comalloy Intl. Corp. SAN; glass fiber reinforced Comalloy Intl. Corp. Polystyrene; glass fiber reinforced, PS Comalloy Intl. Corp. Poly(vinyl chloride); glass fiber reinforced, PVC Comalloy Intl. Corp. Poly(butylene terephthalate); glass fiber reinforced Comalloy Intl. Corp. Polycarbonate; mineral/glass fiber reinforced Comalloy Intl. Corp. Polyamide-6; glass fiber reinforced, PA-6 Comalloy Intl. Corp. Polyamide-66; glass fiber reinforced, PA-66 Comalloy Intl. Corp. Polyamide-612; glass fiber reinforced, PA-612 Comalloy Intl. Corp. Poly(phenylene sulfide); mineral/GF reinforced Comalloy Intl. Corp. Polysulfone; glass fiber reinforced, PSU Comalloy Intl. Corp. ABS/PVC alloy Comalloy Intl. Corp. Polyamide-66; glass fiber reinforced, PA-66 Comalloy Intl. Corp. Polypropylene; 50 % copper filled, PP Comalloy Intl. Corp. Polycarbonates, PC Comalloy Intl. Corp. Polyamide-6, PA-6 Commercial Plastic Polyamide-6, PA-6 Commercial Plastic (continued) 2292 Appendix IV: Trade Names of Polymers and Their Blends Comco Nylon 6/6 Comco PVC Comco UHMW-PE Comp Armor Polyamide-66, PA-66 Poly(vinyl chloride), PVC Ultrahigh molecular weight PE, UHMWPE Unsaturated polyester, UP Compodic Compound No. 1000 Comshield Comtuf 100 Comtuf 400 Comtuf 600 Conap CE-1132 Conap CE-1170 Conap UC-21 Conapoxy Conathane Condux 8000A Conex Conoptic Contrex Coral rubber Cordura Corezyn Corovin Corton Corvic Cosmic DAP Courlene Courlene PY Courtelle CP 41 CP D33 CP CPP30GF Crastin Crastin Crastin XMB Crastone Crealan Creslan CRI Crystalor PMP Crystic CTE CTI AN Polyamides, PA Unsaturated polyester, UP Filled polypropylene, PP Reinforced polypropylene, PP Reinforced polyesters, PBT, PET Reinforced polyamides-6, PA-612, or PA-66 Unsaturated polyesters, UP Acrylic resins Polyurethanes, PU Epoxy resins, reinforced or not, EP Polyurethanes (TS) Poly(vinyl chloride)/ABS alloy, PVC/ABS Aramid Polyurethanes (TS) Acrylonitrile-styrene-acrylate terpolymer, ASA cis-1,4-Polyisoprene Polyamide fiber Unsaturated vinyl esters or polyesters, UP Polypropylene, PP Mineral-filled resins Poly(vinyl chloride) polymers, PVC Diallyl phthalate (TS), DAP Polyethylene, PE fiber Polypropylene, PP-fiber Polyacrylonitrile, PAN Acrylates Diallyl phthalate (TS); reinforced or not, DAP PMMA/elastomer blend Mineral-reinforced polypropylene, PP Poly(butylene terephthalate), PBT Poly(ethylene terephthalate), PET Poly(butylene terephthalate)/ABS blends Poly(ethylene sulfide), PES Thermoset resins Acrylic fiber Polyamide-6, PA-6 Poly(4-methylpentene-1), PMP Unsaturated polyesters, UP Acrylics Glass fiber-reinforced polyamide, PA Commercial Plastic Commercial Plastic Commercial Plastic Haysite Reinforced Plastics DIC Trading Resinoid Engr. Corp. Comalloy Intl. Corp. Comalloy Intl. Corp. Comalloy Intl. Corp. Comalloy Intl. Corp. Conap, Inc. Conap, Inc. Conap, Inc. Conap, Inc. Conap, Inc. Advanced Dynamics Teijin/Hoechst Conap, Inc. Monsanto Europe SA BF Goodrich DuPont de Nemours Interplastic Corp. J. H. Benecke PolyPacific European Vinyls Corp. Cosmic Plastics Courtaulds Fibers Ltd. Courtaulds Fibers Ltd. Courtaulds Fibers Ltd. Continental Poly. Cosmic Plastics Continental Ferro Corp. Ciba-Geigy Ltd. Ciba-Geigy Ltd. DuPont Ciba-Geigy/Phillips Bayer Cyanamid Custom Resins Phillips 66 Co. Ashland Chem Richardson Polymer CTI (continued) Appendix IV: Trade Names of Polymers and Their Blends CTI AS CTI AT CTI ES CTI NH CTI NI CTI NJ CTI NL CTI NN CTI NY CTI PC CTI PF CTI PI CTI PK CTI PS CTI SF CTI SN Cyanacryl Cyanaprene Cycogel Cycolac Cycolac EHA Cycolac G Cycolac GCT/M Cycolac SDB Cycolac SDM Cycolin Cycoloy Cycoloy EHA Cycoloy LG9000 Cycopac Cycovin Cycovin K25 Cycovin KAB Cyglas Cymel Cyrex 200 Cyrex Cyrolite D D-007 D-10FG D.E.R. D7 2293 Glass fiber-reinforced ABS Glass fiber-reinforced polyoxymethylene, POM Glass fiber-reinforced polyethersulfone, PES Glass fiber-reinforced polyamide-11, PA-11 Glass fiber-reinforced polyamide-610, PA-610 Glass fiber-reinforced polyamide-12, PA-12 Glass fiber-reinforced polyamide-612, PA-612 Glass fiber-reinforced polyamide-66, PA-66 Glass fiber-reinforced polyamide-6, PA-6 Fiber-reinforced polycarbonate, PC Fiber-reinforced polysulfone, PSU Fiber-reinforced polyetherimide, PEI Fiber-reinforced polyetheretherketone, PEEK Glass fiber-reinforced poly(butylenes terephthalate) Glass fiber-reinforced poly(phenylene sulfide), PPS Glass fiber-reinforced SAN Alkyl-co-alkoxyalkyl acrylates, elastomers Castable urethane, PU ABS Acrylonitrile-butadiene-styrene terpolymers, ABS ABS/PC alloys ABS/PBT ABS/PBT automotive blends ABS/engineering polymer blends ABS/electrostatic dissipation polymer blends ABS/PBT alloy ABS/PC; ABS/PVC; or ABS/TPU blends PC/ABS alloys with varying PC content PC/ABS low-gloss alloy Acrylonitrile-butadiene-styrene terpolymers, ABS Acrylonitrile-butadiene-styrene terpolymer, ABS Poly(vinyl chloride)/ABS high impact alloy ABS/PVC alloys Unsaturated polyesters; reinforced or not Alpha cellulose-reinforced melamineformaldehyde PMMA/PC opaque, high-impact-strength alloys SAN/PC opaque blends Acrylic-based, impact-modified highly transparent multipolymer CTI CTI CTI CTI CTI CTI CTI CTI CTI CTI CTI CTI CTI CTI CTI CTI Akzo/DSM Cyanamid Co. Nova Polymers GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics BF Goodrich BF Goodrich BF Goodrich American Cyanamid American Cyanamid Polypropylene, PP Glass fiber-reinforced ABS Epoxy resins, EP Acrylonitrile-butadiene-styrene terpolymer, ABS Aristech Chem. Thermofil, Inc. Dow Chem. Co. Thermofil, Inc. (continued) Cyro Industries Cyro Industries Cyro Industries 2294 Appendix IV: Trade Names of Polymers and Their Blends D8 Dacron Styrene-acrylonitrile copolymer, SAN Poly(ethylene terephthalate), PET fibers Dai El Daki Polistyren Dalpen Daltoflex I Dalvor Dapex RX Daplen Dapon Daramelt Dararay Daraseal Darawave Daron 40 PTFE/PHFP/PVDF or PVDF/PHFP elastomers Styrene-butadiene copolymer, SBR Polyolefins: PE or PP Polyurethane rubber Fluorinated EPR rubber, FEP Diallyl phthalate, DAP LDPE, HDPE, PP, GMT, PCD Diallyl phthalate resin Hot melt adhesives/sealants Microwave fluxed plastisols Poly(vinyl chloride) plastisols, PVC Microwave curable plastisols, PVC Unsaturated polyester/polyurethane thermosetting blends for fiber-filled systems Hybrid polyester resin; HT resistance Polystyrene, PS Poly(vinyl chloride) Polyamide-6, -10, PA-610 Extruded polycarbonate sheet, PC Acrylic/PVC alloy Polyamides Polycarbonate, PC/PET alloy Acrylates and methacrylates, PMMA powder Extruded acrylic sheet, PMMA Polyoxymethylene (acetal) resins, POM, some grades contain PTFE POM toughened by addition of TPU elastomer Daron Dart PS-100 Darvic Decaplast Decargias Decoloy Deerlon Defsan Degalan Deglas Delrin Delrin T, ST Demospan DEN Denka HS Denka LCS Denka Taimelan DER Derakane Desmodur Desmopan Desmopan Desmophen A Dexcarb Dexter RPI Thermofil, Inc. E. I. du Pont de Nemours Daikin/Chevassus INA Kingsley & Keith/PCD ICI Dow Chem. Co. Rogers Corp. Polymere Gesellschaft FMC Corp. W R Grace W R Grace W R Grace W R Grace DSM DSM Dart Polymers, Inc. ICI Montefibre Degussa AG Borg-Warner/Ube Deer Polymer USSR Degussa AG Degussa AG E. I. du Pont de Nemours E. I. du Pont de Nemours Polyurethanes Bayer Epoxy resins, EP Dow Chem. Acrylonitrile-butadiene-styrene terpolymer/PC Denki Kagaku Poly(vinyl chloride)/NBR blends Denki Kagaku/ Chevassus Acrylonitrile-butadiene-styrene terpolymer/PVC Denki Kagaku Epoxy resins, EP Dow Chem. Co. Thermoset vinyl ester epoxy resins Dow Chem. Co. Polyurethanes, isocyanates Bayer AG/Miles Polycarbonate, PC, with TPU blends Bayer AG/Miles Thermoplastic polyurethanes, TPU, isocyanates Bayer AG/Miles TPU ether or ester elastomers Bayer AG/Miles Polycarbonate/polyamide, PC/PA alloys Dexter Corp. Polycarbonate/ABS alloys Dexter Corp. (continued) Appendix IV: Trade Names of Polymers and Their Blends Dexel Dexflex Dexlon Dexloy Dexpro Dexter RPI 101EP Dexter RPI 101EP Dexter RPI 201EP Dexter RPI 207EP Dexter RPI 310 Dexter RPI 424, 600 Dexter RPI 500EP Dexter RPI BEE-15 Dexter RPI BEE-18 Dexter RPI BEE-23 Dia Alloy Diacon Diamond Diarex Diathon DIC-PPS SE-730 Dielectrite Diene Difan Dimension Diolen Dion Dispercoll Distifoam/Distitron Distugil DK DKE 450 Dolan Dorlastan Dow ABS Dow CG Dow Corning 1 Dow D.E.H./D.E.R. Dow HDPE Dow LDPE Dow SAN Cellulose acetate PO alloys Polyamide/polypropylene, PA/PP alloy Customized alloys Polypropylene/polyamide, PP/PA alloy Polypropylene/polyolefins, PP/PO alloy Polypropylene/polyolefins; reinforced or not Acrylonitrile-butadiene-styrene terpolymer, ABS ABS/polycarbonate alloys Poly(butylene terephthalate); reinforced or not, PBT Glass fiber-reinforced polyamide-6 or polyamide-66, PA Polycarbonates; reinforced or not, PC Polyesters Polyamides, PA Polyesters ABS/PC alloys PMMA, acrylic/elastomer blends (powder) – Styrene-butadiene copolymer, SBR Acrylic coatings Poly(phenylene sulfide), PPS, alloys with PPE for high HDT and low flash Unsaturated polyesters, UP Polybutadiene Poly(vinylidene chloride), PVDC PA-6 blends with PPE; reinforced or not with up to 30 wt% GF Poly(ethylene terephthalate), PET Unsaturated vinyl esters, UP Polyurethanes, water dispersions Polyester resins, UP Polyurethane elastomers, PUR Epoxy resins, EP Poly(methyl methacrylate)/PVC alloy 2295 Courtaulds Fibers Ltd. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Dexter Corp. Mitsubishi Rayon ICI Adv. Mater. Diamond Polymers Mitsubishi Monsanto ICI Polyurethanes Dainippon Ink &Chem. Industrial Dielect. Firestone BASF A.-G. AlliedSignal ENKA-Glanzstoff Koppers Co., Inc. Bayer Maprac Arnaud Promecome Dexter Corp. E. I. du Pont de Nemours Polyacrylonitrile, PAN S€ udd. Zellwolle Spandex fiber Bayer Acrylonitrile-butadiene-styrene terpolymer, ABS Dow Chem. Co. Polyethylenes, PE Dow Chem. Co. Silicones Dow Corning Epoxy resins, EP Dow Chem. Co. High-density polyethylene, HDPE Dow Chem. Co. Low-density polyethylene, LDPE Dow Chem. Co. Styrene-acrylonitrile copolymer, SAN Dow Chem. Co. (continued) 2296 Appendix IV: Trade Names of Polymers and Their Blends Dow Tyrin Dowex Dowlex IP-2580 Dowlex IP-90 Dowlex Dowlex NG Dralon Drexflex Driscopipe pipe DS6CO1K Dualite Duct 2.5 Duethan BC Duocel Duoclad Duodeck Duolite Chlorinated polyethylene, CPE Ion-exchange resin Linear low-density polyethylene, LLDPE High-density polyethylene, HDPE Linear low-density polyethylene, LLDPE Poly(ethylene-co-octene) LLDPEs Polyacrylonitrile, PAN, fiber TP elastomer Polyethylene pipe, PE Polypropylene, PP Poly(vinylidene chloride), PVDC, microspheres Epoxy resins, EP Elastomer modified PA-6 blends Epoxy coating, EP Epoxy flooring systems, EP Polyurethane membrane, PU Ion-exchange resin DuPont LCP Liquid crystal polymers, LCP Duracon Duracryn Polyoxymethylene, POM TPE: ethylene interpolymers/PP or PE Duraflex Duraflex 8000 Dural Polyisobutylene, PIB Polyethylenes, PE Reinforced rigid poly(vinyl chloride), CPD Dural 776/X6 Poly(vinyl chloride)/ABS high impact alloy Duralex Poly(vinyl chloride)/PU/NBR alloy Duralon Duraloy 1000 Polyamide-11, PA-11 Polyoxymethylene, POM, with elastomer Duraloy 2000 Duraloy Poly(butylene terephthalate), PBT, with elastomer PBT blended with elastomers or POM Duraloy/Vandar POM/TPU or PBT/elastomer blends Durastrength Acrylic impact modifier for outdoor PVC siding and window profiles Industrial coatings Poly(vinyl chloride), PVC Polyarylate, PAr, and PAr/PBT blends, glass fiber reinforced or not Duratop Duravin Durel Dow Chem. Co. Dow Chem. Co. Dow Chem. Co. Dow Chem. Co. Dow Chem. Co. Dow Chem. Co. Bayer AG/Miles D&S Plastics Phillips 66 Co. Shell Chem. Co. Pierce & Stevens Furane Products Bayer AG/Miles Duochem Inc. Duochem Inc. Duochem Inc. Chemical Processing Co. E. I. du Pont de Nemours Daicel-Polyplastics E. I. du Pont de Nemours Shell Chem. Shell Chem. Dexter Corp./Alpha Chemical Alpha Chem. & Plastics Alpha Chem. & Plastics Thermoclad Co. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Elf Atochem Thermoclad Co. Thermoclad Co. Hoechst Celanese Corp. (continued) Appendix IV: Trade Names of Polymers and Their Blends Durethan Dycryl Dyflor 2000 DYGL Dylark Dylene Dylite Dylite EPS Dym PA-6, PA-66, blended with PO or elastomer, modified and/or reinforced PA-6 blended with ethylene-butyl acrylateacrylic acid PA-6 blended with methacrylate-butyl acrylatebisphenol-A copolymer, with glass fiber or not Polyurethane, thermoplastic, TPU Thermoset phenolic compounds; filled or not Thermoset diallyl phthalate compounds, DAP GRP application and SMC GRP syntactical foam Polycarbonate, PC EPR copolymers Thermoplastic elastomer, TPO Polypropylene, PP, graft for high-temperature steel pipes Photopolymer system Poly(vinylidene fluoride), PVDF Styrene maleic anhydride copolymer, SMA SMA and its blends (with, e.g., PBT, HIPS) Polystyrene, PS; styrene-butadiene rubber, SBR Polystyrene – expandable, EPS Polystyrene – expandable, EPS (25 % recycles) Polyester elastomer Dymetrol Elastomeric type Dynacoll Dynaflex Dynalit Dynamar Dynapol Dynapor Dynaset Dyneema Dynel Dynyl Dyphene Polyesters PP/EPDM/NBR blends Poly(butylene terephthalate), PBT Fluoroelastomer processing aid for LLDPE film Polyester resins Phenolic resin foams, PF Phenolic compounds, PF UHMWPE gel-spun fibers Vinyl chloride-acrylonitrile copolymer Polyblockamides: PA-66-mb-PA-636 Phenolic resins, PF Dytherm Dytherm Dytron XL E E-08, 9900 E-260H, 2748 E1- Expandable copolymer for rigid foam Expandable copolymers Polyolefins/elastomer blends Durethan BC Durethan RM Durethan U Durez 111 Durez SI-75 Durodet Durolito Durolon Dutral Dutralene Duval Reinforced poly(butylene terephthalate), PBT Epoxy; reinforced or not, EP Glass fiber-filled PET/PBT polyesters 2297 Bayer AG/Miles Inc. Bayer AG/Miles Inc. Bayer AG/Miles Inc. Bayer AG/Miles Inc. Cain Chem. Inc. Cain Chem. Inc. Mitras Kunstoffe Mitras Kunstoffe Polymix Himont/Enimont Himont/Montedison E. I. du Pont de Nemours DuPont de Nemours Dynamit Nobel Polymer Composites Arco Chem. Co. Arco Chem. Co. Arco Chem. Co. Arco Chem. Co. E. I. du Pont de Nemours E. I. du Pont de Nemours H€ uls AG Dynamit Nobel 3M Canada Inc H€ uls AG Dynamit Nobel Reichhold Ltd. DSM Union Carbide Co., Inc. Rhoˆne Poulenc PMC Specialties Group Arco Chem. Co. Arco Chem. Co. Monsanto Chem. Co. Thermofil, Inc. ICI/Fiberite Thermofil, Inc. (continued) 2298 E484 EA 3000 Eagle Picher EP EB 6000 Eastalloy DA003 Ebaco Ebecryl EC 6000 Ecavyl Eccogel Eccoseal Eccothane Econit SHF-MR Econol Ecothene Edistir Editer EE4000 EFK Ekkcel Ekonol Ektar Ektar DN Ektar FB Ektar FB CG Ektar FB DG Ektar FB PG Ektar MB DA003 Elastalloy Elastocell Elastocoat Elastoflex Elastofoam Elastogran Elastolan Elastolit Elastopal Elastopor Elastopreg Elastorob Appendix IV: Trade Names of Polymers and Their Blends Glass-filled epoxy, EP Polystyrene, PS Unsaturated polyesters with glass fibers, UP Polystyrene, PS Transparent copolyester/PC alloy Ethylene-vinyl acetate copolymers, EVAc Acrylates and methacrylates Polystyrene, PS Poly(vinyl chloride), PVC Epoxy resins, EP Epoxy resins, EP Polyurethane, PU Polypropylene/nitrile rubber Cosmic Plastics Chevron Chem. Eagle Picher Plas. Chevron Chem. Eastman Neste Chim. UCB Soc. Chevron Chem. Kuhlmann/Fr. Emerson & Cuming Emerson & Cuming Emerson & Cuming Resine Sintet. Adamoli Poly(p-hydroxybenzoic acid ester) Sumitomo Chem. HDPE containing 28 % postconsumer resin Quantum Chem. Corp. High-impact polystyrene, HIPS, PS ECP Enimont Polymeri Glass fiber-reinforced ABS ECP Enimont Polymeri Mineral-filled epoxy, EP Dexter Corp. Aromatic polyester Sumitomo Chemical Aromatic polyester Carborundum Poly(p-hydroxybenzoic acid), Tm ¼ 550 C Carborundum Thermoplastic polyesters and copolyesters: PET, Eastman Chem. Prod. PBT, PCT, PCTG polyesters Thermoplastic polyesters Eastman Chem. Prod. TP elastomers Eastman Chem. Prod. Glass fiber-filled polyarylate Eastman Chem. Prod. Glass fiber-filled poly(ethylene terephthalate), Eastman Chem. Prod. PET Glass fiber-filled polypropylene, PP Eastman Chem. Prod. PCTG/PC or SMA transparent alloys Eastman Chem. Prod TP elastomers GLS Corporation Polyurethane foam compounds, PU BASF Plastics Polyurethane casting systems, PU BASF Plastics Soft PUR foam system BASF Plastics Soft integral-skin PUR foam BASF Plastics Family of polyurethanes, PU BASF Plastics Thermoplastic polyurethane, TPE BASF Plastics Hard integral-skin PUR foam BASF Plastics Polyurethane elastomers, PUR BASF Plastics Hard PUR foam systems BASF Plastics Semifinished product glass-mat BASF Plastics Polyurethane elastomers, PUR Robbe (continued) Appendix IV: Trade Names of Polymers and Their Blends Elastosil Elastotec Elastron Elastuff Electrafil 55-EC Electrafil ABS Electrafil CF Electrafil Electrafil G-1100 Electrafil G-50 Electrafil J-1 Electrafil J-1105 Electrafil J-1106 Electrafil J-1200 Electrafil J-1300 Electrafil J-1400 Electrafil J-1500 Electrafil J-3 Electrafil J-30 Electrafil J-50 Electrafil J-60 Electrafil SMA Elemid Elexar Elix Eltex P Eltex Elvacet Elvacite Elvamide Elvanol Elvax Elvic EM-7302 Emac EMI-X Emiclear EMPEE PE EMPEE PP EMPEE PP Silicone rubbers Polyester thermoplastic elastomers PU vapor barriers Urethane coatings, PU Carbon black-filled EVAc ABS, aluminum filled Polyamide-66, carbon fiber filled; PA-66 Electrically conductive plastics 2299 Wacker Chemie BASF Plastics ICI Polyurethanes ICI Polyurethanes Akzo/DSM Akzo/DSM Akzo/DSM Wilson-Fiberfil Inc./ DSM Polyethersulfone, stainless steel filled, PES Akzo/DSM Polycarbonate, carbon fiber filled, PC Akzo/DSM Polyamide-66, carbon fiber filled, PA-66 Akzo/DSM Polyetheretherketone, carbon fiber filled, PEEK Akzo/DSM Polyetherimide, carbon fiber filled, PEI Akzo/DSM ABS, carbon fiber filled Akzo/DSM Poly(phenylene sulfide), carbon fiber filled, PPS Akzo/DSM FTFE, carbon fiber filled Akzo/DSM Polysulfone, carbon fiber filled, PSU Akzo/DSM Polyamide-6, carbon fiber filled, PA-6 Akzo/DSM Polystyrene, carbon fiber filled, PS Akzo/DSM Polycarbonate, carbon fiber filled, PC Akzo/DSM Polypropylene, carbon fiber filled, PP Akzo/DSM SMA plastics, aluminum filled Akzo/DSM ABS/polyamide alloys; PA/ABS GE Plastics Triblock SEBS or SBS thermoplastic elastomers Shell Chem. Polymer modifiers: elastomer with either PB, Monsanto Chem. Co. SAN, SMA, ASA, or MSAN Polypropylenes, PP; also highly isotactic PP Solvay & Cie SA Polyethylenes, PE Solvay & Cie SA Poly(vinyl acetate), PVAc E. I. du Pont de Nemours Acrylic resins E. I. du Pont de Nemours Polyamide resins, PA E. I. du Pont de Nemours PVAl, ethylene-vinyl alcohol copolymers, EVAl E. I. du Pont de Nemours Ethylene-vinyl acetate copolymers, EVAc Du Pont/Safic-Alcan Poly(vinyl chloride), PVC Solvay & Cie SA Epoxy resins, EP Industrial Dielect. EMA copolymer Chevron PA-6 or PA-66 with Al flakes for EMI control LNP Eng. Plastics – Toshiba Polyethylenes, PE Monmouth Plastics Glass fiber-reinforced polypropylene, PP Monmouth Plastics Polypropylenes, PP Monmouth Plastics (continued) 2300 EMPEE PS Empee Enathene Encron Enduran Engage Appendix IV: Trade Names of Polymers and Their Blends Enjay Butyl Envex EP Total EP Total SL 180 EP Epalex EPDM XG 006 Epi-Rez Epi-Rez Epiall Epic Epikote Epilox EPM XF 004 Epo-Tek Epocast Epodite Epolan Epolene Polystyrenes, PS Polyethylene, polypropylene Ethylene butyl acrylate Polyester fiber High-density PBT resin Poly(ethylene-co-octene) a polyolefin elastomer, POE, based on Insite™ metallocene technology Isobutylene-isoprene copolymer, IIR PI, PI lubricated by PTFE, MoS2, or graphite EPDM, thermoplastic polyolefins Silicones Unsaturated polyesters, UP – Ethylene-propylene oil extended rubber Epoxy resins, EP Ethylene-propylene elastomer, EPR Epoxy resins, EP Epoxy/unsaturated polyesters, UP Epoxy resins, EP Ethylene-propylene elastomer, EPR Ethylene-propylene impact modifier for TPO Epoxy resins, EP Ethylene-propylene elastomer, EPR Epoxy resin Acrylonitrile-butadiene-styrene terpolymer, ABS Oxidized polyolefin, PO Epolite Epon Eponite Eposir Epoxilrub Epoxylite Eraclear Epoxy; filled or not, EP Epoxy resins, EP Epoxy resin-based materials, EP Epoxy resins, EP Epoxy resins, EP Epoxy resins, EP LLDPE and VLLDPE Eraclene High-density polyethylene, HDPE Eref LS Eref PP modified, with 40 % or 50 % glass fiber PA-66 or PA-mXD6 blends with 40–60 % PP; 50 % glass fiber Polyoxymethylene (acetal), POM PA-6, internally lubricated, cast in rods and plates PET rods or plates Epoxy resins, EP Polypropylene, PP Ertacetal Ertalon Ertalyte PET-P ES0002 Esall Monmouth Plastics Monmouth Quantum Akzo/DSM GE Plastics Dow Chem. Co. Enjay Rogers Corp. Total Elastomers Total Elastomers Eagle Picher Plas. PolyPacific Polysar-Miles Celanese Devoe-Raynolds Rogers Corp Epic Resins Shell Chem. Soprochim Polysar-Miles Epoxy Technology Elastomer Chem./USA Showa Highpolymer Industrial Resistol Van Waters & Rogers Ltd. Hexcel Corp. Shell Chem. Co. Shell Chem. Co. Kingsley & Keith/SIR Furane Products Epoxylite Corp. ECP EniChem Polymeri ECP EniChem Polymeri Solvay SA Solvay SA Polymer Corp. Polymer Corp. Polymer Corp. Dexter Corp. Sumitomo Chem. Co. (continued) Appendix IV: Trade Names of Polymers and Their Blends Esbrid Esbrite Escalloy Escor Escorene Micro Escorene Escorene Ultra Esso-PVC Estalloy DA Estane Estar Esthane ET-Polymer ET-Semicon ETA-Polymer Ethavin Ethocel Ethofil Ethron ETP Euredur/Eurelon Euremelt Eurepox Europrene SOL T Evaclene Evaco Evaflex EVAL Evalca Evatane Evatate Evathane Ever-Flex Evoprene Exac CTFE Exac ECTFE Exac ETFE Exac FEP Exac PFA Exac PTFE Polyamide-6 with 50 % ceramic and glass reinforced Polystyrene, PS Polypropylene, PP Ethylene-acrylic acid, EAA, copolymers Ethylene-vinyl acetate copolymers, EVAc 2301 Thermofil, Inc. Sumitomo Chem. Co. Comalloy Intl. Corp. Exxon Chem Exxon Chem/Esso Chem Polyolefins (PO): LDPE, LLDPE, MDPE, PP Exxon Chem/Esso Chem. Ethylene-vinyl acetate copolymers, EVAc Exxon Chem/Esso Chem Poly(vinyl chloride), PVC Esso Chemical Polyester/polycarbonate blends Eastman Kodak Thermoplastic polyurethanes, TPU, and BF Goodrich/ TPU/SAN or TPU/ABS blends Polyplastic Polyester film Eastman Kodak Polyurethane TPE BF Goodrich Butyl-grafted polyethylene, PE ABB Polymer Comp. Conductive butyl-grafted PE ABB Polymer Comp. PP/EPDM, TPO alloys, thermoplastic elastomers Republic Plastics Olefinic/poly(vinyl chloride) alloy Vi-Chem Corp. Cellulose ethers: ethyl and methyl Dow Chem. Co. Polyethylenes; glass fiber filled, PE Akzo/DSM Polyethylenes, PE Dow Chem. Co. Polyamide/acrylic thermoplastic elastomer blend E. I. du Pont de Nemours Polyamide resins, PA Schering AG Polyamide and polyester resins Schering AG Epoxy resins, EP Schering AG Triblock SBS or SIS thermoplastic elastomers EniChem Ethylene-vinyl acetate copolymer, EVAc Anic Ethylene-vinyl acetate copolymers, EVAc Neste Chim. Ethylene-vinyl acetate copolymer, EVAc Mitsui Ethylene-vinyl alcohol copolymers, EVAc EVAL Co. of America EVA copolymer EVAL Co. of America Ethylene-vinyl acetate copolymers, EVAc ICI Ethylene-vinyl alcohol copolymers, EVAl Sumitomo Chem. Co. Ethylene-vinyl acetate copolymers, EVAc Elf Atochem Thermoplastic elastomers, TPO formulations Quality Service Technology Thermoplastic elastomers, TPE Evode Plastics Ltd. CTFE fluorocarbon Norton Performance ECTFE fluorocarbon Norton Performance ETFE fluorocarbon Norton Performance FEP fluorocarbon Norton Performance PFA fluorocarbon Norton Performance PTFE fluorocarbon Norton Performance (continued) 2302 Exac PVDF Exact PE Exprima Extir Extron Exxelor Exxon Butyl 077 Exxtral F F-007 F-40MF F-9900 F6 Fascat Faskene Fastool Fenilin Fenochem Ferrene Ferrex Ferro Flex Ferrocon Ferroflo Ferrolene Ferrolene TPE Ferropak Fertene FF-020 Fibercore Fiberfil Fiberfil G-1 Fiberfil G-1500 Fiberfil G-40 Fiberfil G-50 Fiberfil G-60 Fiberfil J-1106 Fiberfil J-1300 Fiberfil J-1850 Fiberfil J-7 Fiberfil NY-12 Fiberfil NY-7 Appendix IV: Trade Names of Polymers and Their Blends PVDF fluorocarbon Norton Performance Polyethylene (medical grade) prepared using the Exxon Chem. Co. metallocene catalyst, Exxpol Rigid poly(vinyl chloride) compounds, PVC European Vinyls Corp. Expandable polystyrene, EPS ECP Enimont Polymeri Glass-filled resins PolyPacific Polymeric modifiers Exxon Chem. IIR, also chlorobutyl and bromobutyl rubbers Exxon Chem. Reactor olefinic thermoplastic elastomers, RTPO Exxon Chem. Polypropylene; glass filled or not, PP Polyethylene; glass filled or not, PE Polyethylenes, PE Glass fiber-filled polyethylenes, PE Alkydes, polyesters, silicones Poly(vinyl chloride) compounds, PVC Filled epoxy resins, EP Poly(m-phenyleneisophthalamide), PPA Phenol-formaldehyde resins, PF Filled polyolefins, PO Mineral-filled polypropylenes, PP Polypropylene, PP, PP/EPDM or EPM blends Polypropylenes, PP Polyolefins, PO, polystyrene, PS PP, rubber modified, containing 20 % mineral IPN-type PP/EPDM blends PP/PE alloy Low-density polyethylene, LDPE Polypropylene, PP Glass-filled unsaturated polyesters, UP Fiber-reinforced material Polyamide-66 with glass fiber, PA-66 Fiber-filled polysulfone, PSU Fiber-filled SAN Fiber-filled polycarbonate, PC Fiber-filled polypropylene, PP Glass fiber-filled polyetherimide, PEI Glass fiber-filled poly(phenylene sulfide), PPS Glass fiber-filled poly(butylene terephthalate), PBT Fiber-filled polyamide, PA Glass fiber-filled polyamide-612, PA-6,12 Glass fiber-filled polyamide, PA Aristech Chem. Aristech Chem. Thermofil, Inc. Thermofil, Inc. Ceca Technicompound REN Plastics USSR C.P.R.I. Ferro Corp. Ferro Corp. Ferro Corp. Ferro Corp. Ferro Corp. Ferro-Eurostar Ferro Corp. Ferro Corp. Montecatini Aristech Chem. American Cyanamid DSM Akzo/DSM Akzo/DSM Akzo/DSM Akzo/DSM Akzo/DSM Akzo/DSM Akzo/DSM Akzo/DSM Akzo/DSM Akzo/DSM Akzo/DSM (continued) Appendix IV: Trade Names of Polymers and Their Blends Fiberfil TN Fiberstran Fiberstran Fibredux Fibrela Filabond Filmex Polyamide-6, 12 impact modified blends containing PO; GF reinforced or not Flame-retarded plastics Phenolic compounds, PF Graphite-filled polyimide, PI Filled thermoset silica compounds Poly(vinyl chloride) rigid formulation, PVC fiber reinforced Long glass-reinforced thermoplastics Long fiber-reinforced material Epoxy prepregs, EP Honeycomb sandwich panels Unsaturated polyester, UP Cast film extrusion Filmon Cast polyamide, PA, films Fina Finaclear Finaprene Finaprop Finathene Firestone Flemion Flex-Line Polystyrenes, PS SBS, linear Poly(styrene-b-butadiene-b-styrene) with 75 wt% styrene (lamellar structure) Elastomers, TPE Polypropylene, PP Polyethylenes: LDPE, MDPE, HDPE Polyamide-6, PA-6 Carboxylated fluoropolymer Polyamide monofilaments, PA Flexel Flexomer Flexomer DFDA Flexorob/Flexothane Flexthane Flo-Well Flovic Fluon Fluorel Fluorocomp Fluorofil Fluorogold Fluoromelt Fluoromelt FP-CC Fluoromelt FP-EC Fluoromelt FP-FC Fluoromelt FP-PC Fluoromelt FP-VC Fluorosint PTFE Thermoplastic elastomers, TPE Ultra low-density linear polyethylene ULDPE ULDPE high flow processing aid for injection Polyurethane, PU Urethane-acrylate water-based coatings PP/PVC copolymer blends Poly(vinyl acetate), PVAc Polytetrafluoroethylene, PTFE Thermoset fluoropolymers; PVDF/PHFP blend 60 % bronze-filled PTFE Carbon/glass-filled PVDF Polytetrafluoroethylene filled or not, PTFE Fluoropolymers, melt processable ECTFE, glass or carbon fiber filled FTFE, glass or carbon fiber filled FEP, glass or carbon fiber filled PFA, glass or carbon fiber filled PVDF, glass or carbon fiber filled PTFE + mica composites (rods or plates) Fiberfil VO Fiberite FM Fiberite PI Fiberite SI Fiberloc 2303 Akzo/DSM Wilson-Fiberfil Intl. Fiberite/ICI Fiberite/ICI Fiberite/ICI BF Goodrich/Geon Akzo/DSM DSM Ciba-Geigy Ltd. Ciba-Geigy Ltd. Reichhold Ltd. Windmoeller/ Hoelscher SNIA Tecnopolimeri SpA Fina Oil & Chem. Fina Oil & Chem. Fina Chem. Fina Chem. Fina Chem. Firestone Canada Inc. Asahi Glass Elf Atochem Deutschland BF Goodrich Union Carbide Co., Inc. Union Carbide Co., Inc. Robbe Air Products & Chem. Air Products & Chem. ICI Adv. Mater. ICI Adv. Mater. 3M Ind. Chem. LNP Engineering Akzo/DSM Fluorocarbon ICI Adv. Mater. LNP Engineering LNP Engineering LNP Engineering LNP Engineering LNP Engineering Polymer Corp. (continued) 2304 Fluorotemp 103 Fluorothene Fomrez/Formrez Foraflon 51 Foraflon 1000 Foraflon Formacast Formaldafil Formaldafil Formica Formion Formion Forprene Forticel Fortiflex Fortiflex Fortilene Fortilene Fortron Fosta Tuf-Flex FP-200 FPC 18MI FPC 30 FPC 40 FPC 75 FPC 500, 600 FPC Freshtuff FT-015 Fulton 404 FurCarb FyRid G G-2G-Resin G1 Gabrite Gafite Gaflex Gaflon Gaftuf Galalith Appendix IV: Trade Names of Polymers and Their Blends Polyetheretherketone, PEEK, filled Polychlorotrifluoroethylene, PCTFE Polyurethane, PU Fluorocarbon PTFE Fluorocarbon PVDF Poly(vinylidene fluoride), PVDF Epoxy/polyurethane casting blends Polyoxymethylene; filled or not, POM Polyoxymethylene, POM/PTFE blend Melamine-formaldehyde resin Ionomer Ionomer compounds; PO/ionomer blends Olefinic thermoplastic elastomers, TPO Propyl cellulose, CP Fluorocarbon DuPont de Nemours Witco Elf Atochem Elf Atochem Elf Atochem Formulated Resins Akzo/DSM Fiberfil Cyanamid A. Schulman, Inc. A. Schulman, Inc. Ferro Corp. Hoechst Celanese Corp. Polyethylenes, PE Soltex Polymer Co. Polyethylenes, PE Solvay & Cie SA Polypropylene, PP Soltex Polymer Co. Polypropylene, PP Solvay & Cie SA Poly(phenylene sulfide), linear PPS, glass and Kureha Chem./ mineral reinforced or not Hoechst Celanese Styrene-butadiene copolymer, SBR Hoechst AG Polypropylene, PP Aristech Chem. Styrene-acrylonitrile copolymer, SAN Federal Plastics Polypropylene, PP Federal Plastics Polyethylene, PE Federal Plastics Acrylonitrile-butadiene-styrene terpolymer, ABS Federal Plastics Polyethylenes, PE Federal Plastics Polystyrene, PS Federal Plastics Ionomer/polyamide alloys American Can Co. Polypropylene, PP Aristech Chem. POM lubricated with PTFE LNP Eng. Plastics Furan-based TS resins; reinforced or not QC Chem., Inc. Flame-retardant polystyrene, PS GE Plastics Polyoxymethylene, filled: glass bead, graphite, etc. Thermofil, Inc. Polyethylenes, PE Union Carbide Co., Inc. Glass fiber-filled polyoxymethylene, POM Thermofil, Inc. Phenol-formaldehyde, PF, molding material Montecatini PBT/elastomer alloys, reinforced or not GAF Corp. TPU, ester/ether thermoplastic elastomer GAF Corp. Polytetrafluoroethylene, PTFE Gachot, France High-impact PBT/elastomer alloys GAF Corp. Plastics from milk protein, CS Int. Galalith-Ges. (continued) Appendix IV: Trade Names of Polymers and Their Blends Gantrez Gapex Geon Geon HTX Georgia-Gulf Gepax Getem Glaskyd Glastic Glendion/Tercarol Poly(methyl vinyl ether-co-maleic anhydride) PP/PA-6 or PA-66 compatibilized alloy, reinforced or not Poly(vinyl chloride), PVC Thermoplastic elastomers TPO for wire and cable applications Thermoplastic alloy compounds Thermoplastic elastomer PVC compounds for cables Polyurethanes, PU PPE/PS foams Unsaturated polyester, UP Phenol-formaldehyde resins, PF Polystyrene, PS Expanded polystyrene, PS Epoxy resins, EP Amorphous polyamide, PA Acrylic acid-styrene-acrylonitrile terpolymer, ASA ASA/PVC alloys in pellet form ASA/Poly(methyl methacrylate), PMMA blends ASA/Poly(vinyl chloride), PVC alloy ASA/polycarbonate, PC blends for automobile ASA/PC blends Poly(vinyl alcohol) Poly(phenylene ether)/PBT, PPE/PBT blends Maleimide Thermoplastic elastomer blends; NBR/EPDM or PP/NBR blends Poly(vinyl chloride) and blends, viz., PVC/NBR Poly(vinyl chloride)-based high performance alloy Poly(vinyl chloride) resins and alloys, PVC PPE/crystalline PS alloys Amorphous cyclomer-type polymers Thermoset alkyd resins; filled or not, UP Unsaturated polyesters; filled or not, UP Polyether and polyester polyols Glyptal Goodrite Latex Goodrite GPC DELTA GR7 Grafoil Granular Compound Alkyd resin, UP SB and vinyl pyridine Polyacrylic acid, PAA Styrene-acrylonitrile copolymer, SAN Glass-reinforced Zytel polyamides, PA Foils of pure graphite Urea-formaldehyde resin; cellulose filled, UF Garamed Garaprene E Garaprene O Garaprene Garaprene Gary PVC GC 480 GECET Gedamine Gedelite Gedex Gedexcel Gel 151 Gelon Geloy GY1020 Geloy GY1220 Geloy SCC 1320 Geloy XP 2003 Geloy XP 4001 Geloy XP 4025 Gelvatol Gemax Gemon Geolast 2305 GAF Corp Ferro-Eurostar Ferro Corp. Ferro Corp. Ferro Corp. Evode Plastics Ltd. Ferro Corp. Evode Plastics Ltd. Gallagher Corp. GE Plastics Norsolor, France Norsolor, France Elf Atochem Elf Atochem Furane Products GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics Shawinigan Chemicals GE Plastics GE Plastics Advanced Elastom. Syst. BF Goodrich/Geon BF Goodrich/Geon Georgia-Gulf GE Plastics GE Plastics American Cyanamid Glastic Co. ECP EniChem Polymeri GE Plastics BF Goodrich BF Goodrich Grand Pacific Du Pont Canada Union Carbide Co., Inc. Plastics Mfg. Co. (continued) 2306 Appendix IV: Trade Names of Polymers and Their Blends Granular Liquid crystal polyester, LCP Granulation Comp. Grilamid Filled melamine-formaldehyde resin, MF Polyamide-12, reinforced or not, PA-12; also blends with aromatic-aliphatic polyamides Polyetheramide, PEA Polyamide, transparent, amorphous Powder coating resins PBT-extrusion and PET-molding resins PA-6 or PA-612 blended with PB or EPR Polyamide-6, PA-6, with PB or EPR; filled or not PA-6/aromatic-aliphatic polyamide, PA alloys Polyamide-66, PA-66 Polyamide-66/610 copolymer Polyamide-polyethylene blend Ethylene-propylene copolymers, EPR PET, PBT; reinforced or not Copolyamides, copolyesters Amorphous engineering resin, reinforced or not Amorphous polyamide, PA Amorphous polyamide, PA Copolyester resin for powder coating Poly(vinyl chloride) compounds, PVC ASA/polycarbonate, PC, alloys Grilamid ELY-60 Grilamid TR Grilesta Grilet Grilon Grilon A Grilon BT Grilon T Grilon XE Grilon XE3404 Grilonit Grilpet Griltex Grivory Grivory G Grilamid TR Grilesta Gumiplast GX-200 H H-Film Halar Halon Halon 1000R Halon 2000R Halon 3000R Halon 4000R Halon ET Hanalac Hannam ABS Haysite BMC HC-3 HCPP HDPEX Heatlok Herclor Hercocel PI (pyromellitic anhydride/ diaminodiphenylether) ECTFE fluoropolymers Fluoropolymer Polytetrafluoroethylene, ETFE; glass fiber filled Polytetrafluoroethylene, ETFE; graphite filled Polytetrafluoroethylene, ETFE; bronze filled Polytetrafluoroethylene, ETFE; graphite filled Filled ETFE fluorocarbon ABS Acrylonitrile-butadiene-styrene terpolymer, ABS Unsaturated polyesters, glass filled, UP Granmont Inc./ Montedison Plastics Mfg. Co. EMS-American Grilon EMS-American Grilon EMS-American Grilon EMS-American Grilon EMS-American Grilon EMS-American Grilon Emser Ind. EMS-American Grilon EMS-Chemie AG EMS-Chemie AG EMS-Chemie AG Emser-Werke EMS-Chemie AG EMS-Chemie AG EMS-American Grilon EMS-Chemie AG EMS-Chemie AG EMS-Chemie AG Saplast GE Plastics E. I. du Pont de Nemours Ausimont Inc. Ausimont Inc. Ausimont Inc. Ausimont Inc. Ausimont Inc. Ausimont Inc. Ausimont Inc. Miwon Hannam Haysite Reinforced Plastics Polyethylene; filled, PE CCA Compounding High crystallinity polypropylene with isotacticity Chiso Corp. 99 %, broad MWD Auto cross-linkable PE ABB Polymer Comp. Polyurethane elastomer, PUR resins ICI Polyurethanes Elastomers Hercules Cellulose acetate, CA Hercules (continued) Appendix IV: Trade Names of Polymers and Their Blends Hercules K-type Herculoid Hercuprene Hetron Hevea-Plus HF-2230 HHW, HHP Hi-D Hi-Fax Hi-Zex Hicond-2000 Hicond-X HiFax HiGlass Hiloy 100 Hiloy 400 Hiloy 440 Hiloy 600 Himod PU GL Histat-X Hitalex Hitanol HiVal HMS 1000 Hoslapren Ethyl cellulose, EC Cellulose nitrate, CN Thermoplastic rubber, TPE Unsaturated polyester, UP NR/PMMA interpenetrating polymer networks Poly(vinyl chloride), PVC/ABS blends Poly(vinyl chloride) rigid formulations, PVC Polyethylenes, PE High-density polyethylene, HDPE Polyethylenes, PE HDPE/PP electrically conductive alloy Polyethylene, PE Reactor olefinic thermoplastic elastomers, RTPO Glass-filled polypropylene Himont Glass fiber filled polypropylene, PP Glass fiber filled poly(butylene terephthalate), PBT Glass fiber filled poly(ethylene terephthalate), PET Glass fiber-filled polyamide-6, polyamide-612 or polyamide-66, PA Thermoplastic polyurethane, TPU, alloys Electrically conductive polyethylenes, PE Polyethylene Phenol-formaldehyde resin Polyethylenes, HDPE Conductive styrenic alloy Chlorinated polyethylene, CPE Hostacom Filled or reinforced polypropylene, PP Hostadur Poly(ethylene terephthalate), PET Hostadur X PBT/PET alloy Hostaflon Fluoropolymers (PTFE, PFA, ETFE) Hostaflon C2 Polychlorotrifluoroethylene Hostaflon ET Ethylene-co-tetrafluoroethylene, ETFE Hostaflon FEP Tetrafluoroethylene-co-hexafluoropropylene Hostaflon TF Polytetrafluoroethylene, PTFE Hostaflon TFM Modified suspension PTFE 2307 Hercules Hercules J-Von Ashland Chem. Co. Malaysia Georgia Gulf Georgia Gulf Chevron Chem. Hercules Mitsui Petrochem. United Composites United Composites Himont Adv. Materials Comalloy Intl. Corp. Comalloy Intl. Corp. Comalloy Intl. Corp. Comalloy Intl. Corp. Polymer Compos. United Composites Hitachi Hitachi General Polymers HMS Compounds, Inc. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. (continued) 2308 Appendix IV: Trade Names of Polymers and Their Blends Hostaform C POM/TPU alloys Hostaform Hostalen GUR POM copolymer, impact modified, reinforced, etc. Ultrahigh molecular weight PE, UHMWPE Hostalen UHMWPE, HDPE, PP/EPDM, resins and prod. Hostalen PP Polypropylene, PP Hostalit Poly(vinyl chloride), PVC Hostalit Z High-impact PVC/CPE blends Hostalloy 731 Polyolefin alloy, with high abrasion resistance Hostamid Polyamide, transparent, amorphous Hostaphan Hostapren Poly(ethylene terephthalate), PET Chlorinated polyethylene, CPE Hostatec Polyetheretherketoneketone, PEK Hostyren Polystyrene, PS; PS/elastomer blends HPP30GR HTX Hycar PA Hycar Hydrin Hylar 5000 Hylar Mineral/glass fiber-filled polypropylene, PP Polyetherketone Modified acrylic elastomers PVC/nitrile rubber Polyepichlorohydrin elastomer, can be blended with any elastomer, sulfur or peroxide curable Poly(vinylidene fluoride), PVDF Poly(ethylene terephthalate), PET Hypalon Chlorosulfonated PE (CSM) synthetic rubber HyTemp Hytrel Hytrel HA Polyacrylate elastomer, curable or not Thermoplastic polyether-ester block copolymer elastomers, 1,4-butanediol-polybutylene glycolterephthalic acid copolymer, TPE Copolyester/polyacrylate/PET I Icdal Ti40 Idemitsu LCP Idemitsu Polycarb. Idemitsu SC Igelit Polyesterimide Liquid crystal polyester, LCP Polycarbonates, PC PC/ABS, PES blends Poly(vinyl chloride), PVC Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Kalle, Germany Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Ferro Corp. ICI BF Goodrich BF Goodrich Zeon Chemicals, Inc. Ausimont E. I. du Pont de Nemours E. I. du Pont de Nemours Nippon Zeon Co., Ltd. E. I. du Pont de Nemours E. I. du Pont de Nemours Dynamit Nobel Idemitsu Petro Chem Idemitsu Petro Chem Idemitsu Petro Chem Bitterfeld, Germany (continued) Appendix IV: Trade Names of Polymers and Their Blends Illen Instant-Set Polym. Insultruc PIntene/Intex Intol/Intolene Ionac Iotek IPC IPN-Compound Iporka Iropol Poly(butylene terephthalate), PBT/elastomer blend Polyesterimide, PEI Poly(ethylene terephthalate), PET, glass reinforced High-impact acrylic blends Resins Polybutenes, PB Linear low-density polyethylene, LLDPE Rigid poly(vinyl chloride), PVC Ethylene/octene copolymers prepared using the constrained-geometry metallocene catalyst Thermosetting polyurethane, PU Unsaturated polyesters with glass fiber, UP Elastomers Elastomers Ion-exchange resin Ionomers Glass fiber-filled poly(phenylene sulfide), PPS Interpenetrating polymer Urea-formaldehyde, UF, plastic foam Polyester resin Irostic Polyurethane, TPU-adhesive resins IRPS Irrathene Isobam Isolic Isomid Isoplast Isorob/Isothanne Isplen Isplen ITP Iupiace Iupilon Iupilon Polym. All. Iupirex Iupital F40-03 Iupital-FL Polystyrene, PS Polyethylenes cross-linked by radiation, XLPE Copolymer of isobutylene and maleic anhydride water soluble (protective colloids) Acrylic resins Polyesterimide, PEI Polyurethanes Polyurethanes, PU Polypropylene, PP Polypropylene, PP PU/polyester/polystyrene IPN PPE alloys Polycarbonate, PC Polycarbonate/ABS alloys Polyimide Polyoxymethylene, POM Polyoxymethylene, POM, fluoropolymer blends Iupital-FU Polyoxymethylene, POM, elastomer blends Ixan Poly(vinylidene chloride) copolymers, PVDC Imidex Impet Implex Imprez Indopol Innovex Inprima Insite 2309 Dr. Illing GmbH General Electric Co. Hoechst Celanese Corp. Rohm and Haas ICI Polymers Amoco Chem. Co. BP Chem. Ltd. European Vinyls Corp. Dow Plastics Dow Chem. Co. Industrial Dielect. Enimont Enimont Ionac Exxon Chem. IPC ABB Polymer Comp. BASF Plastics Armkem Iroquois Chem. Monon International Inc Huntsman Chem. GE Plastics Kuraray Co., Ltd. Great Eastern Schenectady Chem. Dow Plastics Robbe Repsol Quimica Repsol Quimica SA ICI Mitsubishi Mitsubishi Gas Mitsubishi Gas Ube Industries Mitsubishi Gas Chem. Mitsubishi Gas Chem./Franklin Mitsubishi Gas Chem./Franklin Solvay & Cie SA (continued) 2310 Ixef Ixol Iztavil J J-Plast. Jet-Flex Jonylon JSR Excelloy CB JSR Excelloy GE JSR NE JSR NV Jupilon K K-15NF K-20NF K-Resin K-Resin SB Plastic K-Resin K-Resin K2-30FG K2-30NF K2-50FG Kadel Kadon Kaladex Kalrez Kamax Kane Ace B Kane Ace Kane Ace PA Kane Ace Kane Ace XEL Kane Ace-FM Kaneka CPVC Appendix IV: Trade Names of Polymers and Their Blends Semi-aromatic polyamide, PA, polyarylamides, with GF or mineral Polyetherpolyol halogened (for PU) Poly(vinyl chloride), PVC Thermoplastic elastomer, TPE Acrylonitrile-ethylene/propylene-styrene copolymer Polyamide-6, polyamide-66, PA ABS/polycarbonate, alloys Polycarbonate/AES, alloys NBR/EPDM blends NBR/poly(vinyl chloride), alloys Polycarbonate, PC MBS (now Paraloid™) Graphite fiber-filled polyethersulfone, PES Glass fiber-filled polyethersulfone, PES Butadiene-styrene copolymer, SBR Styrene-butadiene copolymer, SB Styrene-butadiene copolymer, SB Styrene/butadiene bl. copolymer Phillips Glass-reinforced polyetheretherketone, PEEK Graphite fiber-reinforced polyetheretherketone Graphite fiber-reinforced polyetheretherketone Polyetherketone, aromatic, PEAK Solvay & Cie SA Solvay & Cie SA Polimeros de Mexico J-Von Multibase, Inc. BIP Chem. Ltd./ Polymix Japan Synth. Rubber Japan Synth. Rubber Japan Synth. Rubber Japan Synth. Rubber Mitsubishi Chem. Thermofil, Inc. Thermofil, Inc. Phillips Chemicals Phillips 66 Co. Phillips Petrol. Chem. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Amoco Performance Products ABS/SMA blends Monsanto Chem. Co. Poly(ethylene 2,6-naphthalene dicarboxylate) ICI Films Perfluoro elastomer parts, TFE/PVME blend E. I. du Pont de Nemours Polyacrylates, polymethacrylates, and imidized Rohm and Haas/Ato poly(methyl methacrylate)s Haas Methacrylate-butadiene-styrene, MBS, modifiers Kanegafuchi for clear PVC (impact strength improvers) Chemicals MBS acrylics Kanegafuchi Chemicals Acrylic processing aids Kanegafuchi Chemicals Polyamide chlorinated Kanegafuchi Chemicals Poly(vinyl chloride) cross-linked, XLPVC Kanegafuchi Chemicals Acrylic low gloss impact modifiers for PVC Kanegafuchi Chemicals Poly(vinyl chloride) chlorinated resins, XLPVC Kanegafuchi Chemicals (continued) Appendix IV: Trade Names of Polymers and Their Blends Kaneka ABS/PVC alloys compatibilized with a-methyl styrene-methyl methacrylate copolymer Poly(vinyl chloride) chlorinated resins, XLPVC Kaneka Teralloy, PVC HDT modifiers Kapton 300H Polyimide, PI, electrical and thermal insul. film Kapton H Kasobond Kasothan PI, (pyromellitic anhydride/ diaminodiphenylether) Polyurethane elastomers for adhesives, PUR Polyurethane thermoplastic, TPU Kaurit-Leim Kayocel Urea-formaldehyde glue, UF Cellulose compounds KC 1257 PVC alloy with glutarimide acrylic copolymer for hot-fill bottles Poly(vinyl chloride), PVC, rigid, high impact Poly(vinylidene fluoride/chlorotrifluoroethylene) PCTFE fluoroelastomer Polychlorotrifluoroethylene, PCTFE PVDF/PCTFE blend Glass-filled poly(butylene terephthalate), PBT Kaneka Enplex KC1000 Kel-F Elastomer Kel-F Kel-F Kel-F Kelanex Kelburon Keldax Kelon Kelprox Kelrinal Keltan Keltan TP Kematal Kenflex Kerimide Keripol Kermel Kermel Kevlar Keysor KF Polymer Kibisan PN Reactor-blended PP/EPDM; RTPO for selfsupporting car bumpers Filled polyethylenes, PE 2311 Kanegafuchi Chemicals Kanegafuchi Chemicals Kanegafuchi Chemicals E. I. du Pont de Nemours E. I. du Pont de Nemours Lu-Kas Polym. Chemie Lu-Kas Polym. Chemie BASF Plastics Henley-McKenzie Feimann Keysor-Century Keysor-Century Kellogg, USA 3M Ind. Chem. 3M 3M Hoechst Celanese Corp. DSM Polymers Int. E. I. du Pont de Nemours Mineral-reinforced polyamides, PA Lati Eng. Thermoplast. Thermoplastic olefinic elastomers, TPO DSM Polymers Int. Chlorinated, rubber (CM) DSM Polymers Int. Thermoplastic elastomers, EPDM, PP/EPDM DSM Polymers Int. PP/EPDM blends with fillers DSM Polymers Int. Polyoxymethylene (acetal), POM Hoechst Celanese Corp. Hydrocarbon resins Kenrich Polyimide, PI, for laminating and molding (TS) Nippon Polyimide Polyester resins Vynckier Poly(m-phenyleneisophthalamide), PPA Rhoˆne Poulenc Polyamide-imide; fibers, PAI Rhoˆne Poulenc Poly(p-phenylene terephthalamide); fibers, resins E. I. du Pont de Nemours Poly(vinyl chloride), PVC Keysor-Century Poly(vinylidene fluoride), PVDF Kureha Acrylonitrile-styrene-acrylate copolymer, ASA Chi Mei Ind. Co. Ltd. (continued) 2312 Appendix IV: Trade Names of Polymers and Their Blends Kibisan Kinel KN-220 Koblend Styrene-acrylonitrile copolymer, SAN Filled bis-maleimide-based molding polyimides Polyethylenes, PE Polycarbonate/AES and PC/ABS alloys Koblend PCA Kodapak PET Kodapak Kodar PETG Polycarbonate/ABS blends Poly(ethylene terephthalate), PET Poly(butylene terephthalate), PBT PETG, a thermoplastic copolyester of 1,4 cyclohexylene glycol and mixture of iso- and terephthalic acids Thermoplastic polyesters Polyester fiber Poly(ethylene terephthalate), PET Polybishydroxymethylcyclohexaneterephthalate Polyvinylpyrrolidone, PVP Unsaturated polyesters, UP Poly(vinyl chloride)/PVF blends Thermoplastic fluoropolymer alloy Kodar Kodel Kodel-10 Kodel-2 Kollidon Koppers Koroseal Korton Kostil BV Kostil Kralastic Kralastic FVM Kraton Kraton D1101 Kraton D1107 Kraton D1116 Kraton D1320X Kraton D2103 Kraton FG Kraton G Kraton G1650 Kraton G1701 K-Resin Krystaltite Krynac Krynac NV Krynac Xi Krynac XN KUI Kureha KF Kydene/Kydex Styrene-acrylonitrile copolymer, SAN, reinforced Styrene-acrylonitrile copolymer, SAN Acrylonitrile-butadiene-styrene terpolymers, ABS ABS/Poly(vinyl chloride) alloys Thermoplastic elastomers, TPE SBS three block thermoplastic elastomer SIS three block thermoplastic elastomer (SB)n multi block thermoplastic elastomer (SI)n multi block thermoplastic elastomer SBS/HIPS alloys SEBS functionalized with maleic or succinic anhydride (a PA impact modifier) SEBS blends SEBS three block thermoplastic elastomer SEP three block thermoplastic elastomer Styrene/butadiene block copolymer Poly(vinyl chloride) film, PVC Nitrile rubber, NBR; AN ¼ 19–50 % NBR/Poly(vinyl chloride) alloys (34 % AN) Carboxylated NBR with i ¼ 1–9 % carboxylic NBR lightly cross-linked with AN ¼ 29–35 % Liquid crystal polyester, LCP PVDF fluorocarbon, poly(vinylidene fluoride) Poly(vinyl chloride)/Poly(methyl methacrylate) alloys Chi Mei Ind. Co. Ltd. Rhoˆne-Poulenc Chevron Chem. ECP Enimont Polym./ EniChem Montedipe Milano Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Eastman Chem. Eastman Chem. Eastman Chem. Eastman Chem. BASF Plastics Koppers Co., Inc. BF Goodrich Norton Performance Plast. Montepoˆlimeri Montepoˆlimeri Uniroyal Uniroyal/Sumitomo Shell Chem. Co. Shell Chem. Co. Shell Chem. Co. Shell Chem. Co. Shell Chem. Co. Shell Chem. Co. Shell Chem. Co. Shell Chem. Co. Shell Chem. Co. Shell Chem. Co. Phillips Petrol. Allied Signal Inc Polysar/Bayer AG Polysar/Bayer AG Polysar/Bayer AG Polysar/Bayer AG Bayer Kureha Corp. Rohm and Haas (continued) Appendix IV: Trade Names of Polymers and Their Blends Kydex lOO Kynar L L-030 Z L-20 FG L-20 NF L-30 FG L-30 NF L-40 AF L-9900 L.C.P. L1, L2. L3 Lacovyl Lacovyl Lacovyl Lacovyl Lacqrene Lacqrene Lacqrene Lacqsan Lacqtene HD Lacqtene Lacqtene LX Lacqvyl Ladene Laminac Lanital LARC-TPI LARC-13 Laril Larodur Larton Lastane Lastiflex Lastil Lastilac 09-11 Lastilac Lastirol Lasulf Latamid 6 Latamid 12 Latamid 66 Latamid 68 Poly(vinyl chloride)/acrylic alloy sheets Poly(vinylidene fluoride), PVDF Polypropylene, PP Poly(phenylene ether), PPE, glass fiber filled Poly(phenylene ether), PPE, graphite filled Poly(phenylene ether), PPE, glass fiber filled Poly(phenylene ether), PPE, graphite filled Poly(phenylene ether), PPE, aluminum filled Poly(phenylene ether), PPE, filled Liquid crystal polymers, LCP 2313 Kleerdex Co. Elf Atochem Aristech Chem. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. E. I. du Pont de Nemours Poly(phenylene ether), PPE, glass fiber filled Thermofil, Inc. Poly(vinyl chloride), PVC, bulk polymerized Elf Atochem Poly(vinyl chloride), PVC, emulsion polymerized Elf Atochem Poly(vinyl chloride), PVC, suspension polymerized Elf Atochem Vinyl chlorine-co-vinyl acetate, VC/VAc Elf Atochem Crystal, high-impact polystyrene, HIPS Elf Atochem Polystyrene, PS Elf Atochem Styrene-acrylonitrile copolymer, SAN Elf Atochem Styrene-acrylonitrile copolymer, SAN Aquitaine, France High-density polyethylene, HDPE Elf Atochem Low-density polyethylene, LDPE Elf Atochem Linear low-density polyethylene, LLDPE Elf Atochem Polyvinylchlorine, PVC Elf Atochem LLDPE, MDPE, PS resins (all grades) SABIC Marketing Ltd. Polyester resin Cyanamid Fiber from milk protein, CS SNIA Viscosa, Italy Polyimides, PI NASA/Mitsui Toatsu Chem. Polyimides, PI, for structural adhesives to metal NASA Langley RC Modified poly(phenylene ether), m-PPE, alloys Lati Eng. Thermoplast. Acrylic resins BASF Plastics Reinforced poly(phenylene sulfide), PPS Lati Eng. Thermoplast. Polyurethane elastomers, PUR Lati Eng. Thermoplast. Poly(vinyl chloride)/terpolymer alloy Lati Eng. Thermoplast. SAN; reinforced or not Lati Eng. Thermoplast. ABS/polycarbonate alloy Lati Eng. Thermoplast. ABS; reinforced or not Lati Eng. Thermoplast. Polystyrene, HIPS Lati Eng. Thermoplast. Polysulfone, PSU Lati Eng. Thermoplast. Polyamide-6; reinforced or not, PA-6 Lati Eng. Thermoplast. Polyamide-12; reinforced or not, PA-12 Lati Eng. Thermoplast. Polyamide-66; reinforced or not, PA-66 Lati Eng. Thermoplast. Polyamide-68; reinforced or not, PA-68 Lati Eng. Thermoplast. (continued) 2314 Latan Latene EP Latene HD Latene Later Latilon Lavasint LCP LDPE Le Vinychlore Leacril Leguval Leguval Leguval Lekutherm Leona HR100 Levaflex Levapren Lewatit Lexan Lexan PPC Lexan WR Lexan XT LF-1 Limera LISA Litrex LLD Lomod Lonox Lotader AX Lotader Lotrene Lotrex Lotryl LP LPP LR 3320 Lubricom Lubricomp Appendix IV: Trade Names of Polymers and Their Blends Polyoxymethylene; reinforced or not, POM Impact modified polypropylene, PP High-density polyethylene, HDPE Polypropylene; reinforced or not, PP Reinforced polyester resins Polycarbonate; reinforced or not, PC Ethylene-vinyl alcohol copolymer, EVAl Liquid crystal polymers, LCP Low-density polyethylene, LDPE Poly(vinyl chloride) compounds, PVC Polyacrylonitrile, PAN Unsaturated polyester, UP, for SMC or BMC Unsaturated polyester resin, UP Unsaturated polyester, UP Epoxy resins, EP Polyamide-6,6, foam grade + 30 % glass fiber Thermoplastic elastomers, TPE Ethylene-vinyl acetate copolymer, EVAc Ion-exchange resins Polycarbonate resins or blends, toughened by PO or elastomers; reinforced or not Polyphthalate-carbonate resins or blends, PPC Fluorocarbon polytetrafluoroethylene, PTFE Poly(carbonate-co-silicone) copolymer Thermoplastic polyesters Styrenic blends with a variety of polymers: PS, PVC, PMMA, ABS, PPE; reinforced or not Polycarbonate-based light conducting polymers Low-density polyethylene, LDPE Linear low-density polyethylene, LLDPE Copolyetherimide esters elastomer blends, PBT/ SBS, TPE Polyethylene, PE Lati Eng. Thermoplast. Lati Eng. Thermoplast. Lati Eng. Thermoplast. Lati Eng. Thermoplast. Lati Eng. Thermoplast. Lati Eng. Thermoplast. Bayer AG RTP Co. Dow Chem. Co. Saplast ACSA, Italy Bayer AG/Miles DSM Bayer AG/Miles Bayer AG/Miles Asahi Chemical Bayer AG/Miles Polysar/Bayer AG Bayer AG/Miles GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics Dainippon Ink & Chem. Bayer AG/Miles PCD France Dow Chem. Co. GE Plastics Union Carbide Co., Inc. EEVA-glycidylmethacrylate, E-EA-GMA GMA Norsolor/Elf Atochem content ca. 8 wt% Ethylene-ethylacryalate-vinyl acetate, EEVA Norsolor/Elf Atochem Low-density polyethylene, LDPE S.F.PE LLDPE and VLLDPE S.F.PE EBA and EDA copolymers Elf Atochem Polyethylenes, PE Aristech Chem. Calcium carbonate-filled polypropylene, PP Ferro Corp. Thermoplastic elastomer, TPE GE Plastics – Comalloy Lubricated, wear-resistant engineering polymers, ICI/LNP Eng. Plastics filled or not, viz., PAs (continued) Appendix IV: Trade Names of Polymers and Their Blends Lubricomp A Lubricomp Fulton/K Lubriloy Lucalen Lucalor Lucel Lucite Lustran Elite Lustran FRABS Lustran SAN Lustran Ultra Lustrex Lustropak Lutonal Luvican Luvitherm Luxis Lycra ABS/PTFE or PDMS with 0–30 % glass fiber POM + 0–25 PTFE, 0–2 % PDMS, filler Internally lubricated resins Ethylene/acrylic acid/acrylate copolymers, EAA Chlorinated poly(vinyl chloride), CPVC Polyoxymethylene (acetal), POM Poly(methyl methacrylate) and copolymers, PMMA Acrylonitrile-butadiene-styrene terpolymer, ABS Ethylene copolymer/bitumen blend Poly(vinyl chloride), PVC Poly(vinyl chloride) compounds, PVC Poly(vinyl chloride) resin, PVC Poly(methyl methacrylate), PMMA Polypropylene, PP Phenol-formaldehyde resins, PF Ethylene-vinyl acetate copolymer, EVAc LDPE blends with polyisobutylene Polyethylenes: LDPE, LLDPE, MDPE, HDPE Thermoplastic polyesters; reinforced or not ABS alloys Polyurethanes, PU Polyurethanes, PU Acrylic resin Styrene-acrylonitrile copolymers and blends, SAN, ASA SAN blended with grafted acrylic ester elastomer, ASA, and its blends PPE/styrene-butadiene copolymer blend, reinforced with up to 30 wt% glass fiber or not ABS, SAN, alloys with PVC, etc. Acrylonitrile-butadiene-styrene terpolymer, ABS, high gloss, general purpose ABS, low gloss, high flow grades ABS, flame-retardant grades Styrene-acrylonitrile copolymer ABS, for injection molding Polystyrene, PS Acrylonitrile-butadiene-styrene terpolymers, ABS Polyvinyl ethers Polyvinylcarbazole, PVK Poly(vinyl chloride) foil, PVC Polyamides, PA-66 Diisocyanates/polyether elastomeric fibers Lynex PPE/polyamide blends Lucky ABS Lucobit Lucoflex Lucolene/Lucorex Lucovyl Lucryl Luparen Luphen Lupolen Lupolen O 250H Lupolen Lupox Lupoy Lupragen/Lupranat Lupranol/Lupraphen Luprenal Luran Luran S Luranyl Lustran Lustran ABS 2315 ICI/LNP Eng. Plastics ICI/LNP Eng. Plastics ICI/LNP Eng. Plastics BASF Plastics Elf Atochem S.P.C.I. E. I. du Pont de Nemours Standard Polymers BASF Plastics Pe´chiney, France Elf Atochem Elf Atochem Canada BASF Plastics BASF Plastics BASF Plastics BASF A.-G. BASF Plastics BASF Plastics S.P.C.I. S.P.C.I. Elastogran France Elastogran France BASF Plastics BASF Plastics BASF Plastics BASF Plastics Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. BASF Plastics BASF Plastics BASF Plastics Westover Color Chem. E. I. du Pont de Nemours Asahi Chemical (continued) 2316 M M-2014 M-511, M-521 MA 5000 Mablex MABS MAC Macepreg Maflex Magnacomp Magnum Makroblend DP Makroblend EC 900 Makroblend Makroblend PR Makroblend UT Makrofol Makrolon Malecca Malon Maragla Maranyl Marlex Marlex BMN Marlex CL Marlex CP Marlex EHM Marlex ER Marlex GP Marlex HGL Marlex PE Marnyte Marvalloy Marvylan Marvyloy MAT-20FG Mater-Bi MB 1000 MC 2100 MDI Megarad Megol Appendix IV: Trade Names of Polymers and Their Blends Thermoset melamine, MF MBS modifiers for PC, PEST, PVC Polystyrene, PS ABS/polycarbonate alloys Glass fiber-reinforced ABS Glass fiber-reinforced polyoxymethylene, POM Preimpregnated polyesters Butadiene-styrene copolymer, SB Polyamide-6 filled with barium ferrite Acrylonitrile-butadiene-styrene terpolymer, ABS Polycarbonate/PET/HDPE alloys; general purpose PVC/elastomer, high-impact blends PBT/elastomer Polycarbonate/PBT or PET alloys Polycarbonate/PET/ABS alloys, filled or not Polycarbonate films, PC or PC/PVF Polycarbonate, PC, and impact-modified PC, containing <6 % butyl acrylate-methacrylate elastomer; blends reinforced or not SMI blends with ABS or PBT Thermoplastic polyesters Epoxy resins, EP Impact modified, PA-66 or PA-6/elastomer blends, mineral filled Polyethylenes, PE Polyethylene, PE Polyethylene, PE Polypropylene, PP Polyethylene, PE Mineral-filled polyethylene, PE Polypropylene, PP Polypropylene, PP Polyethylene, PE Poly(ethylene terephthalate); glass filled or not, PET Acrylic-modified polystyrene Poly(vinyl chloride) compounds, PVC ABS/poly(vinyl chloride) alloys Glass fiber-filled polyoxymethylene, POM Starch-based biodegradable thermoplastics Unsaturated polyesters, UP Polystyrene, PS Polyurethane, PU Polycarbonate, PC Elastomeric compounds ICI/Fiberite Kaneka Chevron Chem. Mazzucchelli Cell. Modified Plastics Modified Plastics Mecelec Holding Sic Plastics France LNP Engineering Dow Chem. Co. Bayer AG/Miles, Inc. Bayer AG/Miles, Inc. Bayer AG/Miles, Inc. Bayer AG/Miles, Inc. Bayer AG/Miles, Inc. Bayer AG/Miles, Inc. Bayer AG/Miles, Inc. Denki Kagaku MA Industries Acme Div. of Allied ICI Adv. Mater. Phillips 66 Co. Phillips 66 Co. Phillips 66 Co. Phillips 66 Co. Phillips 66 Co. Phillips 66 Co. Phillips 66 Co. Phillips 66 Co. Phillips 66 Co. Bamberger Polymers Marval Industries L.V.M. France DSM Modified Plastics Novamont Mar Bal Inc. Chevron Chem. Dow Dow Chem. Co. Polymix (continued) Appendix IV: Trade Names of Polymers and Their Blends Melacoll Melan Meldin 2001 Meldin 2021 Meldin 2030 Melinar PET Melinex Melinite Melmex Melochem Melolam Melopas Meraklon Merlon Mertex Metablen P-522 Melamine-formaldehyde resins, MF Melamine-formaldehyde, urea-formaldehyde Polyimide, PI; for high-temperature electrical parts PI + 15 % graphite; high-temperature applications PI + 30 % PTFE; high-temperature bearings Poly(ethylene terephthalate), PET Poly(ethylene terephthalate) films, PET Poly(ethylene terephthalate), PET Melamine-formaldehyde molding powders, MF Melamine-formaldehyde, MF Melamine-formaldehyde laminating resins, MF Melamine molding compound, MF Polypropylene, PP Polycarbonate, PC; PC/PO blends TPU blends Acrylic processing aid for PVC blow molding Metablen P-570 Acrylic processing aid for PVC siding Metamarble Methafil Methocel Methylon MG-6 Mikrothene FE, MU Mikrothene FN Mikrothene HD, MD Milastomer Milkon Millathane Mindel Polycarbonate/PMMA alloy Mica- or glass fiber-filled polymethylpentene Ethyl and methyl cellulose Phenolic resin, PF Silica-filled epoxy resins, EP Ethylene-vinyl acetate copolymer, EVAc Polyolefins, PO Polyethylenes, PE TP elastomer PPS/PTFE blend Thermoplastic polyurethane elastomer, TPE Polysulfone, PSF or PSO, blends; filled or not Mindel A Mindel B Minlon Polysulfone/ABS blends; filled or not Polysulfone/PET blends; filled or not PA-66 or PA-66/ionomer alloy + mineral/glass Mipolam Miramid Miraspin Mirathen Mirlon MN-6 MN-6/6 Moatek Poly(vinyl chloride), PVC Polyamides, PA Polyethylenes, PE Low-density polyethylene, LDPE Polyamide, PA Glass fiber-filled polyamide-6, PA-6 Glass fiber-filled polyamide-66, PA-66 Ethylene-butene-1, or octene-1, copolymer 2317 Piesteritz Henke Furon Dixon Furon Dixon Furon Dixon ICI Adv. Mater. ICI Films ICI Adv. Mater. BIP Chemicals Ltd. C.P.R.I. Ciba-Geigy Ltd. Ciba-Geigy Ltd. Montecatini Bayer AG/Miles Bayer AG/Miles Mitsubishi Rayon Co., Metco Mitsubishi Rayon Co., Metco Teijin Chem. Ltd. Akzo/DSM Dow Cain Chem. Inc. Dexter Corp. Quantum Chem. Quantum Chem. Quantum Chem. Mitsui Tribol. Ind. Inc. TSE Industries, Inc. Amoco Performance Product Amoco Chem. Co. Amoco Chem. Co. E. I. du Pont de Nemours Dynamit Nobel Soprochim Mitsui Petrochem. Soprochim Viscose Suisse Modified Plastics Modified Plastics Idemitsu Petrochem. (continued) 2318 Appendix IV: Trade Names of Polymers and Their Blends Mobil MX Mobil Mobil PS Modar Modylen Moldex A Moltopren Monkalloy P Monocast Moplen Mor-Thane Morthane Polystyrenes, PS Polyethylenes, PE Polystyrenes, PS Urethane-modified acrylic resin PP copolymer/EPDM blends ABS/polycarbonate alloy Foam material based on polyurethane, PU PC/ABS alloys with glass fiber PA directly polymerized into shapes PP homopolymers and copolymers with ethylene Thermoplastic polyurethanes, TPU Thermoplastic polyurethane, TPU Morvanflex Mowicoll Thermoplastic elastomers, TPE Poly(vinyl acetate) dispersions, PVAc Mowilith Poly(vinyl acetate), PVAc Mowiol Poly(vinyl alcohol), PVAl Mowital Poly(vinyl butyral), PVB MPBT-FG Glass fiber-filled polybutylene terephthalate, PBT Phenolic resin, PF Glass fiber filled polycarbonate, PC Glass fiber filled polypropylene, PC PA/PPE alloys Glass fiber-filled poly(phenylene ether), PPE Glass fiber-filled polysulfone, PSU Polypropylene SEBS (Kraton G)-based TPEs Polystyrene, PS, HIPS Polypropylene SAN copolymer Acrylonitrile-butadiene-styrene copolymer ABS Reinforced polypropylene, PP Vinyl compounds Polycarbonates and PC/ABS alloys Polyethylene-polyester multilayer film Polystyrene/elastomer blends Poly(ethylene terephthalate) film, PET MPC MPC-FG MPP-FG MPPE MPPO-FG MPSL-FG Multi-Flam Multi-Flex Multi-Hips Multi-Pro Multi-San Multibase ABS Multibase Multibase MultiChem Multilon Multipet MX-5350 Mylar Mobil Chem. Co. Mobil Chem. Co. Mobil Chem. Co. ICI Chem. Polym. Tiszai Vegyi Komb. Anic Bayer AG/Miles Monsanto-Kasei Co. Polymer Corp. Himont/Montedison Morton Thiokol Morton International, Inc S.P.2.I Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Hoechst Celanese Corp. Modified Plastics Rogers Corp Modified Plastics Modified Plastics Asahi Chem. Ind. Modified Plastics Modified Plastics Multibase, Inc. Multibase, Inc. Multibase, Inc. Multibase, Inc. Multibase, Inc. Multibase, Inc. Multibase, Inc. Multibase, Inc. Colorite Plastics Teijin Chem. Ltd. Wihuri Oy Wipak Mobil E. I. du Pont de Nemours (continued) Appendix IV: Trade Names of Polymers and Their Blends N N05FG N15-40NF N3-20FG N40fm N40MF N5 N6-30MF N66G-30 N8-30FG N9-30FG Nafion Nalcite NAP Polyamide-6 with 5 % glass fiber, PA-6 Polyamide-610 with 40 % graphite fiber, PA-610 Polyamide-66 with 20 % glass fiber, PA-66 Polyamide-6 with 40 % glass fiber and mineral Polyamide-6 with 40 % mineral, PA-6 PA/ABS alloys containing up to 30 wt% GF Polyamide-612 with 30 % mineral, PA-612 Polyamide-66 with 30 % glass fiber, PA-66 Polyamide-11 with 30 % glass fiber, PA-11 Polyamide-12 with 30 % glass fiber, PA-12 Perfluorinated membranes Neo Cis Neo-zex Neoflon FEP Neoflon PCTFE Neoflon PFE Neoflon PVDF Neopolen Neopolen Neoprene Ion-exchange resin Polyarylate, amorphous; 3,30 , 5,50 -tetramethyldihydroxydiphenylmethane copolymer Polypropylene, PP Poly(styrene-co-methyl methacrylate), transparent Poly(methyl methacrylate-co-styrene), transparent Polyethylenes, PE Polyisoprene Polycarbonate (recycled) Polyester resins for paints and varnishes “Nylon-Clay Hybrid”; polyamide-6 with montmorillonite particles 0.1–0.2 nm diameter; nanometer composite developed by Toyota Research Corp. Elastomers Polyethylenes, PE Fluorinated ethylene-propylene, FEP Polychlorotrifluoroethylene, PCTFE Perfluoroalkoxyether, PFE Poly(vinylidene fluoride), PVDF PE/polypropylene foam Polystyrene/polyethylene, PS/PE, blend Polychloroprene, CR Neoprene Synthetic polychloroprene rubber Neosepta F Neoxil Neste Oxo Neste Polystyrene Neste PP Ionic fluoropolymer membrane Unsaturated polyester resin, UP Plastisols, PVC Polystyrene, PS Polypropylene, PP Napryl NAS 30 NAS 50 Natene Natsyn Naxell Naxols/Naxoreses NCH 2319 Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Polymer Composites Thermofil, Inc. Thermofil, Inc. E. I. du Pont de Nemours National Aluminate Kanegafuchi Chem. Pe´chiney, France Novacor Chemicals Novacor Chemicals Pe´chiney, France Goodyear MRC Polymers Convert Ube Industries, Ltd. Enimont/Safic-Alcan Mitsui Petrochem. Daikin Daikin Daikin Daikin BASF Plastics BASF Plastics E. I. du Pont de Nemours E. I. du Pont de Nemours Tokoyama Soda DSM Neste Chim. Neste Chim. Neste Chim. (continued) 2320 Newcon New TPI Niax Nike Nipoflex Niopolon Nipeon AL Nipol AR Nipol Carboxylated Nipol DP 5120P Nipol Appendix IV: Trade Names of Polymers and Their Blends Nissan 1000–3000 Nitriflex Nitrilene Nitron Nitrovin Nivionplast Reactor made TPO/PP alloys for car bumpers Polyimides; reinforced or not, PI Polyether from glycerin or hexane-1,2,6-triol Cellulose nitrate, CN Ethylene-vinyl acetate copolymer Polyethylene ABS/poly(vinyl chloride) (50 %) alloy Polyacrylate elastomers Nitrile rubbers lightly carboxylated, NBR NBR modifiers for clear PVC Nitrile elastomers, NBR, AN ¼ 21–51 % also liquids, powders, or crumbs NBR/PVC (30–50 %) elastomeric alloys plasticized or not Acrylonitrile-butadiene-isoprene elastomers; grade DN-224 contains 50 % DOP Polyethylenes, PE Acrylonitrile-butadiene-styrene copolymer, ABS Poly(vinyl chloride)/BR/ABS alloys Cellulose nitrate, CN Nitrile or polyurethane rubber/PVC, alloys Polyamides, PA-6, PA-66 Nivionplast Noblen Noblen Nolimid 32 Nomex Polyamide-6, PA-6 Polypropylene, PP Polypropylene; filled or not, PP Polyimides; for junction coatings, PI Poly(m-phenyleneisophthalamide) fibers, PPA Norasol Norchem Norchem Norchem Nordbak 7451 Nordel Polycarboxylate, water soluble Polyethylenes, PE Polyethylenes, reinforced or not, PE Polyolefins: LDPE, HDPE, LLDPE, PP Epoxy or polyurethane EPDM, hydrocarbon rubbers Norsodyne Norsoflex Norsolene Norsomix Norsophen Norsorex Polyester resins Polyethylenes: LLDPE and VLLDPE C-9 hydrocarbon resins, PE Polyester resin compounds Phenol-formaldehyde resins, PF Polynorbornene elastomers Nortuff Norvinyl Polypropylene, PP Poly(vinyl chloride), PVC Nipol Polyblends Nipol Terpolymer Chiso Corp. S.P.C.I. Union Carbide Co. Punda Inc. Toyo Soda Toyo Soda Zeon Kasei Co. Nippon Zeon Co., Ltd. Nippon Zeon Co., Ltd. Nippon Zeon Co., Ltd. Nippon Zeon Co., Ltd. Nippon Zeon Co., Ltd. Nippon Zeon Co., Ltd. Nissan Chem. Ind. A. Schulman, Inc. Rhein Chemie Monsanto Chem. Co. Vi-Chem Corp. ECP Enimont Polymeri EniChem Mitsubishi Petrochem. Sumitomo Chem. Co. Rhoˆne-Poulenc E. I. du Pont de Nemours Elf Atochem Quantum Chem. Norchem, Inc. Enron Chem. Co. Rexnord Chem. E. I. du Pont de Nemours Norsolor/Please S.F.PE Elf Atochem Norsolor Norsolor Cyanamid/Atochem/ Nippon Zeon Co. Quantum Chem. Co. Norsk Hydro/Hydro PLast (continued) Appendix IV: Trade Names of Polymers and Their Blends Noryl Noryl BN Noryl FN Noryl GFN Noryl GTX Noryl Plus Nova PC Novablend Novablend 4510 Novacor Novaccurate Novadur Novadur ST520 Novalar Novalast Novalene Novalene RF Novalloy 9000 Novalloy-A Novalloy-B Novalloy-S Novamate A Novamate B Novamid Novamid ST220 Novamid X21 Novapet Novapol Novapol LD Novapol LL Novapol, HD Novapps Novarex AM Novarex Novatec P Novatec Novex Novimide Novodur Novolac PPE thermoplastic blends, reinforced or not PPE/HIPS alloys; reinforced or not Foamable PPE/HIPS alloys Glass fiber-filled PPE/HIPS alloys PA/PPE(30 %) blend, reinforced or not PPE/HIPS/PA alloys Polycarbonate, PC; with flame retardant or not Poly(vinyl chloride), PVC; rigid PVC alloy with glutarimide acrylic copolymer for hot-fill bottles – Liquid crystal polyester with glass fiber or not Poly(butylene terephthalate), PBT Poly(butylene terephthalate) with 20 % acrylic rubber Elastomeric grafting copolymer to be used in ABS, PVC, PC, PBT, TPU, EP, acrylics, etc., for improvement of impact strength and ductility Thermoplastic olefins, TPE TPO compound from recycled PE or PP; 50–90 Shore A durometer TPO/TPE impact modifier for PE or PP Poly(vinyl chloride)/ABS alloy, PVC/ABS 2321 GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics Nova Polymers, Inc. Novcor Novatech Plastics & Chem. Novacor Mitsubishi Chem. Mitsubishi Chem. Mitsubishi Chem. Nova Polymers, Inc. Nova Polymers, Inc. Nova Polymers, Inc. Nova Polymers, Inc. Novatech Plastics & Chem. PA-6 or PA-66 blends with ABS Daicel Chem. Ind., Ltd. PBT blends with ABS, reinforced or not Daicel Chem. Ind., Ltd. ABS/polycarbonate blends, reinforced or not Daicel Chem. Ind., Ltd. AAS/polycarbonate blends Mitsubishi Chem. ABS/polycarbonate blends Mitsubishi Chem. Polyamides Mitsubishi Chem. Polyamide/elastomer blends Mitsubishi Chem. Semi-aromatic amorphous polyamide Mitsubishi Chem. Poly(ethylene terephthalate) with glass fiber or not Mitsubishi Chem. Polyethylenes Novacor Low-density polyethylene, LDPE Novacor Linear low-density polyethylene, LLDPE Novacor High-density polyethylene, HDPE Novacor Poly(phenylene sulfide) blends Mitsubishi Chem. PC/elastomer with glass fiber or not Mitsubishi Chem. Polycarbonates, PC Mitsubishi Chem. Polypropylenes, PP Mitsubishi Chem. Polyethylenes, PE Mitsubishi Chem. Low-density polyethylene, LDPE BP Chemicals Limited Epoxy resins, EP Furane Products Acrylonitrile-butadiene-styrene terpolymer, ABS Bayer AG/Miles Phenol-formaldehyde resins, PF Perstorp Bakelite S.A. (continued) 2322 Novolen KR Novolen Novolen Novon Nucrel Nupol NX-7000 NX-9000 Ny-Kon Nybex Nycoa 1485 Nycoa 2084 Nycoa 7551 Nydur Nylafil G Nylafil J-1 Nylafil J-2 Nylamid Nylatron GS Nylon Nylon 6T Nylon 7000 Nylon Celanese Nylon Nylon MXD Nyltex Nypel Nyref Nyrim O Oldodur Oldofill Oldoflex Oldotherm Appendix IV: Trade Names of Polymers and Their Blends Polypropylene/EPR blend Polypropylene, PP, also filled and reinforced Rubber modified PP/PE blend Based on starch, biodegradable polymers for extrusion, injection molding, or thermoforming Ethylene-methacrylic acid copolymer, EMAA BASF Plastics BASF Plastics BASF Plastics Warner-Lambert/ Novon Co. E. I. du Pont de Nemours Thermoset acrylics Freeman Chem. Corp. PPE/PA-6 alloys for automobile applications Mitsubishi Gas Chem. PPE/polyamide-66 alloys Mitsubishi Gas Chem. PA-6 or PA-66 internally lubricated with MoS2 LNP Eng. Plastics Polyamides, PA-6,PA-66, impact modified Ferro Corp. Polyamide-6 with PE toughened blends Nylon Corp. of America Polyamide-6 with EEA toughened blends Nylon Corp. of America Polyamide-6 with EPR toughened blends Nylon Corp. of America Polyamide, PA/PO blends, fiber reinforced or not Bayer AG/Miles Polyamide-6/elastomer; glass or carbon fibers Akzo/DSM/WilsonFiberfil Polyamide-66/elastomer; glass or carbon fibers Akzo/DSM/WilsonFiberfil Polyamide-610/elastomer blend; glass fibers Akzo/DSM/WilsonFiberfil Polyamide-6 or polyamide-66; reinforced or not, Polymer Service PA Polyamides; glass, mineral, or MoS2, in shapes Polymer Corp. Poly(hexamethylenediamine-terephthalic acid) Hoechst Celanese Corp. Polyamide/elastomer blend Hoechst Celanese Corp. Polyamides; reinforced or not, PA Hoechst Celanese Corp. Generic name for polyamides, PA E. I. du Pont de Nemours Polyamides, PA Mitsubishi Gas Polyamides, PA Vecoplas Polyamide-6; reinforced or not, PA-6 Allied Signal Inc Semicrystalline polyamides N-MXD6, PA-N Solvay & Cie SA PA-block copolymers DSM Integral-skin-rigid foams Packing foams Integral skin, flexible foams Rigid foams Buesting & Fasch Co. Buesting & Fasch Co. Buesting & Fasch Co. Buesting & Fasch Co. (continued) Appendix IV: Trade Names of Polymers and Their Blends Orgalloy R 6600 Orgamide Orgasol Orgater Orlon TPO blend of PE, PP, and a-olefin random copolymer. Filled polypropylene PP/EPDM – elastomer/binder blends Polyisobutylene, PIB Polyvinylisobutyl ether, PVI Isobutylene-styrene copolymer (9:1) Polyisobutylene, PIB Ethylene-maleic anhydride, EMA copolymers Acrylic resins Epoxy resins, EP Polypropylene/TPO alloys, reinforced Ethylene-vinyl acetate copolymers, EVAc Polyamide/polypropylene recycled alloys, PA/PP Polyphosphazene Polycarbonate, PC Polypropylene/polyamide-6, CO2, H2O barrier Polypropylene/polyamide-6 alloys, PP/PA-6 with up to 30 wt% GF Polypropylene/polyamide-66 alloys, PP/PA-66 Polyamide-6, PA-6 Ultrafine powder polyamides, PA PBT, PBT/EVA/PEBA alloys Polyacrylonitrile, PAN Oroglas OS0100 OS2000 Owens-Corning EOxy 3700 Polyacrylates and polymethacrylates Epoxy resins, EP Epoxy resins, EP Unsaturated polyesters, UP Poly(vinyl chloride), PVC Oxyblend Poly(vinyl chloride), PVC, elastomer blends Oxyclear Poly(vinyl chloride) rigid formulation, PVC Oxyclear 4190 Oxyester Oxytuf PVC alloy with glutarimide acrylic copolymer for hot-fill bottles Polyurethanes, PU Poly(vinyl chloride), PVC/EPDM blends P P-2000 P-9900P-xyBG P-xyCC P-xyFG Unsaturated polyesters, UP Polypropylene; filled or not, PP Polypropylene with xy wt% glass beads, PP Polypropylene with xy wt% CaCO3, PP Polypropylene with xy wt% glass fibers, PP Oleflex Olehard Ontex ABX, APE Oppanol B Oppanol C Oppanol O Oppanol Optema Optix Opto 90 Optum Orevac Orgablend Orgaflex Orgalan Orgalloy R 60ES Orgalloy R 6000 2323 Showa Denko K. K. Chiso America Dexter Corporation. BASF Plastics. BASF Plastics. BASF Plastics BASF Plastics Exxon Chem. Plaskolite ICI/Fiberite Ferro Corp. Elf Atochem Elf Atochem Elf Atochem Elf Atochem Elf Atochem Elf Atochem Elf Atochem Elf Atochem Elf Atochem Elf Atochem E. I. du Pont de Nemours Rohm and Haas Dexter Corp. Dexter Corp. Owens/Corning Occidental Chem. Corp. Occidental Chem. Corp. Occidental Chem. Corp. Occidental Chem. Corp. H€ uls AG Occidental Chem. Corp. Industrial Dielect. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. (continued) 2324 P-xyMF P-xyMI P-xyTC P.M.C. P1-xyFG P1120 PA66-110 PAF-200 to 600 Palapreg Palatal Palesit Panapol Panlite Pantalast Paracril AZO Parad Paraglas Paralac Paraloid EXL-3361 Paraloid EXL-3657 Paraloid EXL-4151 Paraloid HT-510 Paraloid Paraplast 8000 Paraplex Parastyren Parel Parlon Parylene C Parylene D Parylene N PAS-2 Pax-Plus Paxon Paxon Pax-Plus PBF-300 PBT-5008 PBTGL-30 PC-00B PC-100 PC-12 Appendix IV: Trade Names of Polymers and Their Blends Polypropylene with xy wt% mineral, PP Polypropylene with xy wt% mica, PP Polypropylene with xy wt% talc, PP Gel coats Polypropylene with xy wt% of glass fiber, PP Polypropylene filled with mineral and glass, PP Polyamide-66; filled or not, PA-66 Polyoxymethylene with 10–30 wt% glass, POM SMC/BMC resins, resin system Unsaturated polyester resins, UP Silicones Polybutylene, PB Polycarbonates; filled or not, PC Poly(vinyl chloride), PVC/EVAc alloys Nitrile rubber/Poly(vinyl chloride), NBR/PVC alloy Photopolymer, resistant and dielectric Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Synres-Almoco Thermofil, Inc. MA Industries MRC Polymers Inc. Polyfil, Inc. BASF Plastics BASF Plastics S.P.C.I. Exxon Chem. Teijin Chem. Ltd. Pantasote Inc. Uniroyal Chemical E. I. du Pont de Nemours Cast acrylic sheet, PMMA Degussa AG Polyester resin, UP ICI Adv. Mater. Acrylic impact modifier for PC and its blends Rohm and Haas MBS impact modifier for PC and its blends Rohm and Haas Polyglutarimide for alloying PC with polyamide Rohm and Haas Polyacrylic-imide modifier for PVC bottles Rohm and Haas Poly(methyl methacrylate-butadiene-styrene) Rohm and Haas MBS (old Acryloid™) Epoxy resins, EP Hexcel Corp. Polyester resin Rohm and Haas Styrene-butadiene copolymer, SBR Paraisten Kalkki Oy Polypropylene oxide elastomers Nippon Zeon Co., Ltd. Chlorinated rubber, RUC Hercules Poly(monochloro-p-xylene) Union Carbide Co., Inc. Poly(dichloro-p-xylene) Union Carbide Co., Inc. Polyparaxylene Union Carbide Co., Inc. Polyphenylsulfide-sulfone Phillips HDPE/polyisobutylene blends Allied-Signal Corp. Polyethylene/polyisobutylene, PE/PIB, blends Allied-Signal Corp./ Paxon PE/elastomer blends Allied-Signal Corp./ Paxon Poly(butylene terephthalate), glass filled, PBT Polyfil, Inc. Poly(butylene terephthalate); filled or not, PBT Mitsubishi Chem. Poly(butylene terephthalate), 30 % glass filled, PBT Polymer Compos. Polycarbonate; filled or not, PC Plastic Materials Polycarbonate; filled or not, PC MRC Polymers, Inc. Epoxy resins, EP Dexter Corp. (continued) Appendix IV: Trade Names of Polymers and Their Blends PC-18 PCC-800 PCCE-5154 PCF-800 PCGL-30 PDC-400 PDF-400 PE-1007 to 5976 PE-2FR Pebar Pebax Pedigree 433 PEF-400 Pekema Pelaspan Pellethane Pellethane 2102 Pellethane 2103 Pellethane 2352 Pellethane 2355 Pellethane 2363 Pellets Pelprene Pensrene EN Penton PEO Perbunan C Perbunan N Latex Perbunan N Pergut Periston Perlenka Perlon Perlon U PermaStat 100 PermaStat 2500 PermaStat 2700 PermaStat 4000 Permutit Perspex Perstorp Grade 151 Perstorp Grade 751 Polyurethane (TS) Polycarbonate; carbon fiber filled, PC Thermoplastic polyester Polycarbonate; glass fiber filled, PC Polycarbonate, 30 % glass filled, PC Poly(phenylene sulfide) with carbon fibers, PPS Poly(phenylene sulfide) with glass fibers, PPS Polyethylenes, PE Polyethylenes; filled or not, PE Blends of polyolefins (HDPE, PP) with high nitrile resin, Barex™ TPE polyether block amide; GF filled or not Unsaturated polyester, UP Polyethylene with glass fibers, PE Poly(vinyl chloride), PVC Polystyrene, expandable Polyurethane TPU, ABS/TPU, TPE Polyester-polycaprolactone Polyether TPU Thermoplastic elastomer, TPU Polyester TPU Thermoplastic polyurethane, TPU Polyurethane, TPU Aliphatic-b-aromatic polyester copolymer IPN of poly(phenylene sulfide) and TS resin 2325 Dexter Corp. Polyfil, Inc. Eastman Chem. Prod. Polyfil, Inc. Polymer Compos. Polyfil, Inc. Polyfil, Inc. Chevron Chem. Reichhold Chem., Inc. BP Chemicals Elf Atochem P. D. George Co. Polyfil, Inc. Punda Inc. Dow Chem. Co. Upjohn/Dow Chem. Dow Chem. Co. Dow Chem. Co. Dow Chem. Co. Dow Chem. Co. Dow Chem. Co. Fimor Toyobo Corp. Dainippon Ink & Chem. Poly(2,2-dichloromethyltrimethylene ether) Hercules Polyethylene oxide Seitetsu Kagaku Polychloroprene elastomer, CR Bayer AG/Miles Anionic latices of nitrile rubber, NBR; 45–50 % Polysar/Bayer AG solids; AN ¼ 18–48 % Nitrile rubber, NBR; AN ¼ 18–48 % Polysar/Bayer AG Diverse resins Bayer AG Polyvinylpyrrolidone Bayer AG/Miles Polyamide-6, PA-6 AKU, Netherlands Generic name for polyamide-6, PA-6 Bayer AG/Miles Polyurethane, PU Bayer AG/Miles Polypropylene, with 0 % and 10 % glass fiber RTP Co. Polycarbonate/ABS alloys RTP Co. Styrenic elastomer resins RTP Co. Polyphthalamide with 0 % and 30 % glass fiber RTP Co. Ion-exchange resin Permutit Co. Cast, extruded PMMA sheet ICI Chem. Polym. Ltd. Urea-formaldehyde, UF Perstorp, Inc. Melamine-formaldehyde, MF Perstorp, Inc. (continued) 2326 PET Azdel Pet PETGL-30 Petlon Petra Petra 130 Petra 230 Petrarch PTFP Petron Petrothene Petsar Pevalon Pevikon PGF-400 PHC-600 Phenoxy PHF-400 Philprene PI-730 Pibiflex Pibiter Pioloform PIQ PKF-400 PL-25 Plaper Plaskon Plaslube Plaslube AC Plaslube J Plaslube NY Plastadur Plastalloy Plastylene Platabond Platamid Plathen Platherm Platilon Platon Appendix IV: Trade Names of Polymers and Their Blends Polypropylene with 35 % glass fiber, PP Thermoplastic polyesters Poly(ethylene terephthalate), 30 % glass filled, PET Poly(ethylene terephthalate) glass/mineral filled Poly(ethylene terephthalate), PET Poly(ethylene terephthalate), glass filled, PET Poly(ethylene terephthalate), glass/mineral filled Polytetrafluorethylene, PTFE Poly(ethylene terephthalate) LDPE, LLDPE, HDPE, PP, EVAc; filled or not PET/PC/acrylic blends with 30 % glass fiber Azdel Inc. ICI Polymer Compos. Bayer AG/Miles Allied Signal Inc Allied Signal Inc Allied-Signal Inc. Petrarch Systems Mobay Quantum Chem. Co. Novacor Chemicals Inc. Poly(vinyl alcohol) May & Baker Poly(vinyl chloride) resins, PVC Norsk Hydro/Hydro PLast Glass-filled poly(phenylene ether), PPE Polyfil, Inc. Carbon fiber-filled polysulfone, PSU Polyfil, Inc. Bisphenol-A/epichlorohydrin copolymer Amoco Performance Glass-filled polysulfone, PSU Polyfil, Inc. Styrene-butadiene thermoplastic copolymer, SBR Phillips 66 Co. Polyimide; glass or carbon fiber filled, PI ICI/Fiberite Poly(butylene terephthalate), PBT copolymers Enimont PBT homopolymers or blends; filled or not Montepolimeri/ EniChem Polyvinyl acetal, butyral, and formal Wacker-Chemie Polyimide, electronic coatings, PI Hitachi Glass-filled ABS Polyfil, Inc. Acrylics Plaskolite, Inc. Styrene-butadiene copolymer, SBR Mitsubishi Monsanto Thermoset resins: alkyd, DAP, epoxy, phenolic Plaskon Electronic Lubricated resins Akzo/DSM Polyoxymethylene with 15 % fluorocarbon, POM Akzo/DSM PC, PA-66, PSU; lubricated materials with GF Akzo/DSM Polyamide-66 with 5 % MoS2, PA-66 Akzo/DSM Phenol-formaldehyde, PF Soprochim Polysulfone alloys with short glass fiber, PSU Akzo/DSM Polyethylene, PE Pichney-Saint-Gobain Copolyamides, hot melts Elf Atochem Copolyamides, hot melts Elf Atochem Polyethylene hot melt, PE Elf Atochem Deutschland Copolyamides, hot melts Elf Atochem TPU and nylon films Elf Atochem Deutschland PET, polyamide-6 monofilaments Elf Atochem Deutschland (continued) Appendix IV: Trade Names of Polymers and Their Blends Plenco Diallyl phthalate, phenolics, polyesters Plexalloy Plexar Plexidur Plexiglas PMMA/ABS alloys PO-based adhesives Poly(acrylonitrile-co-methyl methacrylate) Acrylic, methacrylic resins and blends Plexiglas G, V, MC Plexigum Pliocord VP Latex Pliofilm Pliogrip Pliolite Pluracol Pluronics Plyophen PMF-400 PNC-400 PO Pocan 7913 Pocan Pocan-S POF-400 Polane T, HST Poliblend NH Polidux Polifil Acrylic, methacrylic resins and copolymers Acrylate and methacrylate resins Vinylpyridine copolymer Hydrochloride rubber Polyurethane adhesives, PU Styrene-butadiene copolymers Polyether polyols Ethylene oxide-propylene oxide copolymers, EPO Phenolic resin, Glass-filled polyamide-66, PA-66 Carbon fiber-filled polyamide-66, PA-66 Polypropylene, PP PBT/PC/elastomer alloys Poly(butylene terephthalate), PBT, PBT/ABS PBT/elastomer blends Glass-filled polyamide-6, PA-6 Urethane coatings Polypropylene/polyamide blend; reinforced or not ABS, SAN, polystyrenes Polypropylene + mineral, talc, calcium carbonate Urea-formaldehyde resins, UF Urea-based cellulose-containing compound Polybutene, hydroxyl terminated Specialty polyols Diallyl phthalate; glass or mineral filled Polyethylene, PE Acrylonitrile-butadiene-styrene terpolymer, ABS PE, PP, PVC, PA, ABS color concentrates Carbon black concentrates Chemically modified POs Pollopas Polloplas Poly BD Poly G Poly-Dap Poly-Eth Polyac Polybatch Polyblak Polybond Polycarbafil G Polycast Polychem 100 Polyclear Polycarbonate; filled with glass, metal, carbon Poly(vinylidene fluoride)/poly(methyl methacrylate) blends for electrets Phenolic resins filled with glass, wood, etc. Polyethylene terephthalate, PET Polycol Poly(vinyl chloride) compound, PVC 2327 Plastics Engineering Co. Rohm and Haas DSM Rohm and Haas Roehm GmbH/ AtoHaas Rohm and Haas Rohm and Haas Goodyear Chemicals Goodyear Chemicals Ashland Chemicals Goodyear Chemicals BASF Plastics Wyandotte Chem. Cain Chem. Inc. Polyfil, Inc. Polyfil, Inc. MA Industries Bayer AG/Miles Bayer AG/Miles/Albis Bayer AG/Miles Polyfil, Inc. Sherwin-Williams Co Poliresins SpA Aiscondel Polifil, Inc. Dynamit Nobel Dynamit Nobel Elf Atochem Olin Chemicals Industrial Dielect. Gulf Oil Primex A. Schulman, Inc. A. Schulman, Inc. PB Performance Polymers Akzo/DSM Royalite Budd Co. Hoechst Celanese Corp. Elf Atochem (continued) 2328 Polycomp Polycomp Polydene Polydet Appendix IV: Trade Names of Polymers and Their Blends PPS or PET/PTFE blends PTFE filled with PPS or PAr blends Poly(methyl methacrylate)/PVC alloy GRP plates (polyester) LNP Corp. LNP Corp. A. Schulman, Inc. Mitras Kunstoffe GmbH Polydur Thermoplastic polyurethane, TPU Dynamit Nobel/A. Schulman Polyfil – Polyfil Polyfine – Tokuyama Soda Polyflam X Flame-retarded resins; X ¼ ABS, PS, PE, PP, etc. A. Schulman, Inc. Polyflon Polytetrafluoroethylene, PTFE Daikin Polyfort Polypropylene; filled with mineral, glass, PP A Schulman Inc. Polyimide Polyimide, PI Upjohn Co. Polylac Acrylonitrile-butadiene-styrene terpolymer, ABS Chi Mei Industrial Co. Polylite Unsaturated polyester resin, UP Reichhold Ltd. Polyloy Polyamide-6 or polyamide-6,6/PO or TPO blends Dr. Illing GmbH Polyman ABS or SAN/PVC compounds A. Schulman, Inc. Polyman 506, 509, etc. Poly(vinyl chloride)/ABS high-temperature alloys A. Schulman, Inc. Polyman 551 Polyolefin, PO A. Schulman, Inc. Polyman 552 SAN/PO blends A. Schulman, Inc. Polymer XE 3055 Polyamide blends, PA EMS-Chemie AG Polymin Polyethyleneimine BASF Plastics Polyox Polyethylene oxide Union Carbide Polypenco Acrylic Cast acrylic rods Polymer Corp. Polypenco Nylon 101 PA-66 reinforced or not (rods or sheets) Polymer Corp. Polypenco Q200.5 Cross-linked PS (rods or sheets) Polymer Corp. Polypenco Torlon Polyamide-imide in rods or plates Polymer Corp. Polypro J Polypropylene; filled or not, PP Mitsui Petrochem. Polypro KS Polypropylene; filled or not, PP Tokuyama Soda Co. Polypur APU Long fiber-reinforced TPU alloys A. Schulman, Inc. Polyrex P Polystyrene, PS Chi Mei Industrial Polyrite PP Unsaturated polyester with glass fiber, UP Polyply, Inc. Polysar Bromobutyl Bromobutyl rubber, BIIR Polysar/Bayer AG Polysar Butyl Butyl rubber, BR Polysar/Bayer AG Polysar Chlorobutyl Chlorobutyl rubber, CIIR Polysar/Bayer AG Polysar EPDM EPDM rubbers with ethylene/propylene Polysar/Bayer AG ratio ¼ 58/42 to 75/25 Polysar Polystyrene, PS Novacor Polysar PS with 4–8 % polybutadiene blend Novacor Polysar S Emulsion SBR with 23.5 % bound styrene Polysar/Bayer AG Polysar SS Emulsion SBR with 64 % bound styrene Polysar/Bayer AG Polysizer Poly(vinyl alcohol), PVAl Showa Highpolymer Polystyrol Polystyrene/polybutadiene alloys, HIPS, styrene- BASF Plastics butadiene copolymer, SBR, etc. Polysulfon Poly(bisphenol-A/dichlorodiphenylsulfone) Shell Chem. Co. (continued) Appendix IV: Trade Names of Polymers and Their Blends Polythene Polytron Polytrope TPP Polyval Polyvest Polyvin Polyviol Poticon PP-C1CC PP-C2TF PP-G2MF PP-HFG PPO Prester Prevail Prevex Prevex P2A, V3A Prevex PMA, PQA Prevex S33 Primacor Primef Primex PRL-ABS PRL-Acetal PRL-Nylon PRL-PC PRM Pro-Fax Pro-Seal Procom Procond-H Profil Profil Proloy Propafilm Propak Propathene Propathene PP Propiofan PS 50 Polyethylenes, PE (high pressure) 2329 E. I. du Pont de Nemours Electroconductive Poly(vinyl chloride) alloys BF Goodrich TPO alloys, PP/EPDM A. Schulman, Inc. Poly(vinyl alcohol), PVAl Unitika Kasei Polybutadiene, PB H€ uls AG Poly(vinyl chloride) compounds, PVC A. Schulman, Inc. Poly(vinyl alcohol), PVAl Wacker-Chemie PA-66, POM, PBT, PA-6 with potassium titanate Biddle Sawyer Corp. Polypropylene with calcium carbonate, PP Reichhold Chem., Inc. Polypropylene with talc, PP Reichhold Chem., Inc. Polypropylene with mica, PP Reichhold Chem., Inc. Polypropylene with glass fiber, PP Reichhold Chem., Inc. Poly(2,6-dimethyl-phenylene ether), PPE GE Plastics Polyester polyurethanes, TPU SPRA Neste Polyesters TPU/ABS alloys Dow Plastics PPE alloys GE Plastics PA/PPE-copolymer blends with glass fiber GE Plastics PPE-copolymer-based blends with HIPS GE Plastics Polyamide/PPE-copolymer alloys GE Plastics EAA copolymer, EEA-type adhesives Dow Chem. Co. Poly(phenylene sulfide), PPS, with GF, CF, or Solvay & Cie SA mineral fillers Poly(vinyl chloride), PVC Primex ABS; glass filled or not Polymer Resources Acetal; glass filled or not, POM Polymer Resources Polyamide-6 or polyamide-66; glass filled or not, Polymer Resources PA Polycarbonate; glass filled or not, PC Polymer Resources Polymer reflective material; PC/acrylic Dow Plastics multilayer metallic-like sheets PP homopolymers, copolymers with ethylene and Himont Canada PP/EPR blends Epoxy resins, EP Prod. Res.& Chem. Polypropylene, PP, PP/PA semi-IPNs ICI Materials – Plast. Polypropylene, PP United Composites Polypropylene + CaCO3, talc, mica, carbon, etc. Wilson-Fiberfil Polypropylene with glass or carbon fiber, PP Akzo/DSM ABS/polycarbonate alloys GE Plastics Oriented PP film, OPP ICI Films Polypropylene PolyPacific Polypropylene, PP, toughened PP/EPR blends ICI Materials – Plast. Polypropylene, PP ICI Materials – Plast. Polyvinylpropionate BASF Plastics Polystyrene, PS Huntsman Chem. (continued) 2330 Appendix IV: Trade Names of Polymers and Their Blends PSF PU-21713 PUGL Pulse PVC-Semicon PVC360 PXM Pyralin Styrene-acrylonitrile copolymer with glass, SAN Polypropylene, PP, rubber modified alloy Polyurethane with glass fiber, TPU Polycarbonate/ABS, PC/ABS (30 %) alloy Conductive PVC Poly(vinyl chloride), PVC Polyetherketone Polyimide; laminates and electronics coating, PI Pyratex Pyre-ML Elastomers Polyimide, PI; wire enamel Pyrotex Q Q2 Phenolic resins with asbestos Q-TEL QuaCorr Resin Quatrex Quiana Quimcel Quirvil R R-570 R-9900 R-xyAF R-xyFG R-xyMF R-xyNF R2-9900 R2-xyFG R2-xyNF R4-9900 R9-2039 RA-059 Radel A Radel AG Radel R Radlite Raplan Ravemul Ravikral PA from 1,4-bis-aminomethylcyclohexane and suberic acid Encapsulating EP or PU resins Thermoset furan resins with glass fiber Electronic grade epoxy resins, EP Polyamide fiber from trans, trans diaminodicyclohexylmethane and dodecanedioic acid Cellulose nitrate, CN Poly(vinyl chloride), PVC Acrylic resins Polycarbonate, PC Polycarbonate with xy wt% aluminum, PC Polycarbonate with xy wt% glass fiber, PC Polycarbonate with xy wt% mineral, PC Polycarbonate with xy wt% graphite fiber, PC Polycarbonate, PC/PBT alloy Polycarbonate with xy wt% glass fiber, PC Polycarbonate with xy wt% graphite fiber, PC Polycarbonate, PC/SMA alloy Epoxy resins, EP Polyolefin, PO Polyarylethersulfone, PAES, [f–O–f-SO2-ff-SO2-] Polyarylsulfone; filled, PAS Polyfil, Inc. Ferro-Eurostar Polymer Composites Sumitomo Dow Ltd. ABB Polymer Comp. Exxon Chem. Amoco E. I. du Pont de Nemours Bayer E. I. du Pont de Nemours Raymark Indust. Div. Eastman/USA Chemque QC Chem., Inc Dow Chem. Co. E. I. du Pont de Nemours Punda Inc. Rumianca SpA Richardson Polymer Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Dexter Corp. Himont, Inc. Amoco Performance Products Amoco Performance Products Polyphenylsulfone, PSU Amoco Performance Products Glass fiber-reinforced PC/PBT blends Azdel Inc. Elastomers Polymix Poly(vinyl acetate), PVAc Enimont Acrylonitrile-butadiene-styrene terpolymer, ABS EniChem (continued) Appendix IV: Trade Names of Polymers and Their Blends Ravinil RBC 2000 RDZ RE2038/9 Reapox Regulus Reichhold TPR Ren RP-1774 Ren-Flex Ren-Flex-726 Renalal Reny Replay Repolem, Ecocryl Reprean Resarit Resartglas Resiglas Resin 18 Resin PVC Resin S, trans, etc. Resinmec Resinol Type A, F, etc. Resolite Restirolo Retain Revinex Rex Flex-D Rexene PE Rexene PP Rexflex Rhodester Rhodia 2331 Poly(vinyl chloride), PVC, suspension polymers European Vinyls Corp. Epoxy resins, EP; filled or not RBC Ind. Acrylics/PC opaque blends Cyro Industries Epoxy resins, EP Dexter Corp. Epoxy resins, EP Rea Industrie Thermoplastic polyimides; thermoformable film Mitsui Toatsu Chem., Inc. Thermoplastic elastomers: PO/EPDM blend Reichhold Chem., Inc. Epoxy resins, EP; filled or not Dexter Corp. Thermoplastic elastomers, TPO, PP/EPDM Dexter Corp. Polyolefins, PO Dexter Corp. Acetal copolymer, POM Hoechst Celanese Corp. Polyamides, PA-66 Mitsubishi Polystyrene Huntsman Acrylic and vinylic emulsions Elf Atochem Ethylene copolymers Discas Poly(methyl methacrylate), PMMA powder Resart-IHM AG Poly(methyl methacrylate), PMMA sheets Resart-IHM AG Unsaturated polyester with glass fiber, UP Kristal Kraft, Inc. Poly-alpha-methylstyrene Amoco Chem. Co. Poly(vinyl chloride), PVC Georgia Gulf Epoxy resins, EP; filled or not Furane Products Polyamides, polypropylene Amoco Chem. Co. Polyethylenes, PE Allied Resinous Urea-formaldehyde, UF Polystyrene, PS Polyethylene/polystyrene-based recycled blends Carboxylated rubber Thermoplastic elastomers; filled or not, TPO Polyethylenes, PE Polypropylenes, PP Polypropylene Cellulose acetate, CA Cellulose-2.5 acetate, CA Rhodiaceta-nylon Polyamide-6,6, PA-66 Rhodopas Rhodorsil Rhodoviol Rhovyl Styrene-butadiene copolymer, SBR Silicones Poly(vinyl alcohol), PVAl Poly(vinyl chloride), PVC Ciba-Geigy, GB Societa Italiana Resine Dow Plastics Doverstrand Dexter Corp. Rexene/El Paso Prod. Rexene/El Paso Prod. Rexene Rhoˆne-Poulenc Soc. Rhodiaceta, France Soc. Rhodiaceta, France Rhoˆne-Poulenc Rhoˆne-Poulenc Rhoˆne-Poulenc Soc. Rhodiaceta, France (continued) 2332 Riblene Riblene Rigidex Rigidite Rigipore Rigolac Rilsan A Rilsan AVR Rilsan B Rilsan ESY Rilsan Rimplast Rimplast Rimplast PTUE Risilan AZM Risilan BZM Riston Riteflex Riteflex BP RNYxy Robetanche Robfill/Robflex Robinsectisol Rocalene Rodran Rogers HT Rogers RX 1 Rogers RX 300 Ronfalin Ronfalin Ronfaloy E Ronfaloy P Ronfaloy V Ropet Rosite 3250 BMC Roskydal Roto Flame Rotothene R- Appendix IV: Trade Names of Polymers and Their Blends Ethylene-vinyl acetate copolymers, EVA ECP EniChem Polymeri Polyethylenes: LDPE, LLDPE, and VLLDPE ECP EniChem Polymeri High-density polyethylene, HDPE BP Chemicals Limited Carbon, aramid, glass fiber filled BASF PLASTICS Expandable polystyrene, PS BP Chemicals Limited Polyester resins Showa Highpolymer Polyamide-12, PA-12, or blends with PEBA Elf Atochem Polyamide-11 with Tm ¼ 175 C (rotomolding) Elf Atochem Polyamide-11, PA-11 Elf Atochem Polyamide-11 for electrostatic spraying Elf Atochem Polyamide-11, polyamide-12, PA-6.6/PEBA Elf Atochem PA-6,6 or PA-12/silicone, reinforced or not LNP Corp./Petrarch Sys. Polyurethane/silicone IPN, reinforced or not LNP Corp./Petrarch Sys. Silicone-modified TPU, aromatic ether H€ uls AG Polyamide-12 with glass/graphite fibers, PA-12 Elf Atochem Polyamide-11 with glass/graphite fibers, PA-11 Elf Atochem Photopolymer film resistant E. I. du Pont de Nemours Thermoplastic elastomer and blends Hoechst Celanese Corp. Poly(butylene terephthalate), PBT, alloys with a Hoechst Celanese thermoplastic elastomer Corp. Polyamide-6 with xy wt% glass fiber, PA-6 Ferro Corp. Polyurethanes, PU Robbe Polyurethanes, PU Robbe Polyurethanes, PU Robbe Reinforced polypropylene, PP R.M.P. Liquid crystal polyester, LCP Unitika Phenolics with glass fiber Rogers Corp. Diallyl phthalate with filler, DAP Rogers Corp. Phenolics; filled with glass, wood, mineral, etc. Rogers Corp. Acrylonitrile-butadiene-styrene copolymer, ABS DSM Acrylonitrile-butadiene-styrene/polycarbonate DSM Acrylonitrile-butadiene-styrene/EPDM alloy DSM Acrylonitrile-butadiene-styrene/PET alloy DSM Acrylonitrile-butadiene-styrene/Poly(vinyl DSM chloride) Poly(ethylene terephthalate), PET/PMMA alloys Rohm and Haas Unsaturated polyester with glass fiber, UP Rostone Corp. UP lacquer resins Bayer AG/Miles Polyethylene, PE Rototron Corp. Polyethylenes; filled or not, PE Rototron Corp. (continued) Appendix IV: Trade Names of Polymers and Their Blends Rotothon XP-I Rovel 747 Rovel Royalcast Royalcast Royalene Royalene Royalite Royalite Royalite R 11 Royaltherm Royaltuf 372 Royaltuf 465 Royaltuf Royaltuf XN6G Roylar A-863 RPC-440 RPI 504 EP Polypropylene, PP for rotational molding Polycarbonate, PC/AES blends Styrene-acrylonitrile copolymer, SAN, blended with saturated olefinic elastomer, EPR Elastomers Polyurethanes, thermoset (TS) EPDM for modification of HDPE Polyethylene, PE, or polypropylene, PP Acrylonitrile-butadiene-styrene terpolymers, ABS Poly(vinyl chloride)/PMMA alloys Polycarbonate/ABS alloys EPDM modified with silicone EPDM grafted with SAN EPDM functionalized with maleic anhydride Modified EPDM EPDM grafted with polyamide-6 Polyether-polyurethenes, PU Acrylic, PMMA Polycarbonate-based alloys RPI 507 EP RPI 602 EP Polypropylene/EPDM-type TPO blends Polyamide-66-based alloys RPI RPPxy RPS RT 700 RT/duroid RTA-Polymer RTD RTP 200 TFE RTP 200C RTP 200D RTP 200H RTP 300 TFE RTP 600 RTP 800 RTP 900 RTP 1000 RTP 1300 RTP ESD RTP PWB Rucon Rucothane Polyolefin, PO/EPDM blends Polypropylene with xy wt% glass fiber, PP Polystyrene, PS-reactive Cellulose (Viscose) Polytetrafluoroethylene with glass fiber, PTFE Rigid TP alloys Impact-modified acrylics Polyamide-66/PTFE/PDMS; filled or not Polyamide-11/PTFE (20 %); filled or not Polyamide-612/PTFE ( 20 %); filled or not Polyamide/PTFE ( 20 %); filled or not Polycarbonate/PTFE/PDMS; filled or not ABS/PTFE or PDMS; filled or not POM/PTFE or PDMS; filled or not PSF/PTFE (15 %); filled or not PBT/PTFE(15 %); filled or not PPS/PTFE ( 20 %); filled or not Polyarylsulfone with glass fiber Polyarylsulfone with glass fiber Poly(vinyl chloride), PVC TPU, polyurethane thermoplastic elastomers 2333 Rototron Corp Dow Chem. Co. Dow Chem. Co. Safic-Alcan Uniroyal Chemical Uniroyal Chemical US-Rubber, USA Uniroyal Chemical Uniroyal Chemical Uniroyal Chemical Uniroyal Chemical Uniroyal Chemical Uniroyal Chemical Uniroyal Chemical Uniroyal Chemical Uniroyal Chemical Richardson Polymer Research Polymers Intl. Dexter Corp. Research Polymers Intl. Dexter Corp. Ferro Corp. Dow Chem. Co. Glanzstoff, Germany Rogers Corp. Republic Plast. Co. Cyro Industries RTP Co. RTP Co. RTP Co. RTP Co. RTP Co. RTP Co. RTP Co. RTP Co. RTP Co. RTP Co. RTP Co. RTP Co. Hooker Hooker Chem. Corp. (continued) 2334 Rulan Rumiten Runite SST R€ utaform Rutapal Rutaphen Rutapox Rutapur RX RX ENG. TS RX RxLoy Rylon Rylon PPS Rynite PBT Rynite Rynite SST Ryton Ryulex C S S-660 S-xyFG S-xyMF S-xyNF Sabre Sadisol Saflex Sanrex Santoprene Sapedur Saran Saran Saranex Sarlink 1000 Sarlink 2000 Sarlink 3000 Sarlink TPE Sarnylene Appendix IV: Trade Names of Polymers and Their Blends Polyethylene with filler, PE E. I. du Pont de Nemours Polyethylenes, PE Rumianca SpA Poly(ethylene terephthalate) + 35 wt% glass, PET E. I. du Pont de Nemours Aminoplasts: MF, MPF, melamine-polyester, etc. Hoechst Celanese Corp. Polyester resins, UP Bakelite GmbH Phenol-formaldehyde, resorcinol-formaldehyde Bakelite GmbH Epoxy resins, EP Bakelite GmbH Polyurethane resins, PU Bakelite GmbH Acrylonitrile-butadiene-styrene copolymer, ABS Resin Exchange Phenolic and diallyl phthalate molding materials Rogers Corp Poly(phenylene sulfide), PPS/PTFE blend Intl. Polym. Corp. Polyolefin alloys for medical applications Ferro Corp. Polyphenylene sulfide, PPS Phillips Petrol. Co. Polyphenylene sulfide, PPS Phillips Petrol. Co. Poly(butylene terephthalate)/elastomer alloys E. I. du Pont de with up to 30 wt% glass fibers Nemours PBT or PET/elastomer with up to 35 wt% mica E. I. du Pont de and glass fibers Nemours Poly(ethylene terephthalate)/elastomer alloys E. I. du Pont de Nemours Poly(p-phenylene sulfide); filled or not, PPS Phillips Petrol. Co. Polycarbonate/acrylonitrile-butadiene-styrene Dainippon Ink & Chem. Unsaturated polyester with glass fiber, UP Polysulfone with xy wt% glass fiber, PSU Polysulfone with xy wt% mineral, PSU Polysulfone with xy wt% graphite fiber, PSU Polycarbonate, PC, alloys with PET or PBT Polyurethanes, polyols, isocyanates Polyvinylacetal, PVAc Styrene-acrylonitrile copolymer, SAN Polypropylene/EPDM or EPM, dynamically vulcanized thermoplastic elastomers, TPO Poly(vinyl chloride) compounds, PVC PVDC with at least 80 % vinylidene chloride PVDC with at least 80 % vinylidene chloride Poly(vinylidene chloride), PVDC, and PVDC/PO TPE; oil-resistant PP/PB blends TPE; low permeability PP/BR blends TPE; multipurpose PP/EPDM Thermoplastic elastomers, TPE Poly(vinyl chloride) compounds, PVC ICI/Fiberite Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Dow Chem. Co. Robbe Monsanto, USA Mitsubishi Monsanto Monsanto Chem. Co. Saplast (generic name) Dow Chem. Co. Dow Chem. Co. DSM; Novacor DSM; Novacor DSM; Novacor DSM; Novacor Plastic Auvergne (continued) Appendix IV: Trade Names of Polymers and Their Blends Sarnymousse Satellite Satinflex Poly(vinyl chloride) compounds, PVC HDPE blown film system Poly(vinyl chloride) super elastomers, PVC Scarab Schulamid GB Schulamid GF Urea-formaldehyde, UF, molding powders Polyamide-6 with glass beads, PA-6 Polyamide-6 or polyamide-66 with glass fibers, PA-6 or PA-66 Polyamide-66 with mineral, PA-66 Polyamide-6 with glass fiber/mineral, PA-6 Polyethylene resins, PE Polyethylene resins, PE Acrylonitrile-butadiene-styrene copolymer, ABS Polyethylene resins, PE Polyethylene resins, PE Polyamide/polyolefin, PA/PO, blends High-density polyethylene, HDPE Polystyrene foam, EPS Acrylonitrile-butadiene-styrene copolymer, ABS Polystyrene, PS Adhesives Epoxy resins, EP Epoxy resin, EP Polyester film Poly(vinyl acetate), PVAc Poly(vinyl chloride), PVC Polyurethanes, isocyanates Thermoplastic elastomer, TPE Conductive TPE Polyamide blend Schulamid MF Schulamid MWG Schulman 9HD Schulman 9PE Schulman ABS Schulman CP Sclair Sclar Scolefin Sconapor Sconatex Scopyrol Scotch-Grip Scotchcast Scotchcote Scotchpak Scovinat Scovinyl Scuranate SEBS-Compound SEBS-Semicon Selar Barrier Resin Selar OH Selar PA Selar PT Selar PT Selar RB SFP Shell DP Shell Shinko-Lac G Shinko-Lac GH 2335 Plastic Auvergne Filmaster Inc. Alpha Chem. & Plastics BIP Chemicals Ltd. A. Schulman, Inc. A. Schulman, Inc. A. Schulman, Inc. A. Schulman, Inc. A. Schulman, Inc. A. Schulman, Inc. A. Schulman, Inc. A. Schulman, Inc. Du Pont Canada Du Pont Canada Buna AG Buna AG Buna AG Buna AG 3M Canada Inc 3M, USA 3M Canada Inc 3M Canada Inc Buna AG Buna AG Rhoˆne-Poulenc ABB Polymer Comp. ABB Polymer Comp. E. I. du Pont de Nemours EVAl resins for oxygen barrier film (blend) E. I. du Pont de Nemours Amorphous PA for oxygen barrier film (blend) E. I. du Pont de Nemours Polyester resins for barrier films (blend) E. I. du Pont de Nemours Polyethylene terephthalate blend, PET, (blend) E. I. du Pont de Nemours PA/HDPE concentrates for O2 barrier PO films E. I. du Pont de Nemours Polystyrene, PS Huntsman Chem. Polyisobutylene resins, PIB Shell Chim. PP, PS, PVC resins Shell Chim. Poly(butylene terephthalate); filled or not, PBT Mitsubishi Rayon Co. Acrylonitrile-butadiene-styrene copolymer, ABS Mitsubishi Rayon Co. (continued) 2336 Shinkolite A Sholex Shore Shuman 500 Shuman 700 Shuman 780 Shuman 800 Shuman 900 Shuman 6000 Shuman SP Shutane Shuvinite Sicalit Sicoflex Sicol Sicostrol Sicron Silastic Silastomer Silflex Silixol Silmar Silopren Siltem Sinkral Sinvet Sirester Sirester Sirfen Sirit Siritle Sirotherm Sirtene SKS Skybond 700 Skygreen Skyprene SMA Snevyl Appendix IV: Trade Names of Polymers and Their Blends Acrylic sheets, PMMA Polyethylene Polyester elastomers, TPE Mitsubishi Rayon Co. Showa Denko K. K. E. I. du Pont de Nemours Polypropylene, PP Philip Shuman & Sons Acrylonitrile-butadiene-styrene copolymers, ABS Philip Shuman & Sons Poly(vinyl chloride)/ABS alloy, PVC/ABS Philip Shuman & Sons Polystyrene, PS Philip Shuman & Sons Polycarbonate, PC Philip Shuman & Sons Polyethylene, PE Philip Shuman & Sons Poly(phenylene ether), PPE alloy Philip Shuman & Sons Poly(vinyl chloride)/TPU alloy Reichhold Chem., Inc. Poly(vinyl chloride)/ABS alloy Reichhold Chem., Inc. Cellulose acetate, CA Sic Plastics Acrylonitrile-butadiene-styrene copolymers, ABS Sic Plastics Plastisols, PVC Enimont Polystyrene; reinforced or not, PS Sic Plastics Poly(vinyl chloride) compositions, PVC European Vinyls/ Montedison Silicones Dow Chem. Co. Silicones Dow Chem. Co. Silicone, TS Furane Products Silicones, MQ Convert Unsaturated polyesters, UP Silmar Silicone rubber, MQ Bayer AG/Miles Siloxane-etherimide copolymers and blends GE Plastics Acrylonitrile-butadiene-styrene copolymers, ECP Enimont Polym./ ABS EniChem Polycarbonate, PC Anic; ECP EniChem Polymeri Polyester resins SIR France Polyester resins SIR France Phenol-formaldehyde resins, PF SIR France Urea-formaldehyde resins, UF SIR France Urea-formaldehyde resins, UF SIR France Ampholytic polyelectrolyte ICI Polyethylene, PE Societa Italiana Resine Copolymers from butadiene USSR Polyimides; laminating varnish, PI Monsanto Biodegradable polyethylene succinate/adipate for Sukyong Industries injection or extrusion CR elastomers Tosoh, Harcros Chemicals Styrene maleic anhydride, SMA Elf Atochem Poly(vinyl chloride) compositions, PVC Sebuca (continued) Appendix IV: Trade Names of Polymers and Their Blends Snialene Snialoy AP06 Snialoy BP06 Sniamid Sniater Snissan Snlatal Soablen/Soarlex Soarnol Soarnol EVOH SF Soetene Sokalan CP2 Sol T Solef 1000 Solef 8800 Solimide Solprene Solucryl Solvic Somel Soreflon Sowpren Spandex Spanzelle Specflex Spectra Spectrim HF Spectrim HF-80 Spectrim HT Spectrim RD SPX SRIM ST-801 ST-Nylon Stabar Stadlite Staloy N Stamylan HD or LD Polypropylene, PP 2337 SNIA Tecnopolimeri SpA Polyamide-66 with PP toughened blends Nylon Corp. of America Polyamide-6 with PP toughened blends Nylon Corp. of America Polyamide-6, polyamide-66, PA-6, PA-66 SNIA Tecnopolimeri SpA Poly(butylene terephthalate), PBT SNIA Tecnopolimeri SpA Acrylonitrile-butadiene-styrene copolymer, ABS SNIA Tecnopolimeri SpA Polyoxymethylene (acetal), POM SNIA Tecnopolimeri SpA Ethylene-vinyl acetate copolymer, EVAc Nippon Synthetic EVA copolymer Nichimen Ethylene-vinyl alcohol, EVAl Elf Atochem Low-density polyethylene, LDPE Sogo Polyelectrolyte BASF SBS and SIS block copolymers Enarco Elastomers Co. Poly(vinylidene fluoride), PVDF Solvay & Cie SA Poly(vinylidene fluoride), PVDF, with filler Soltex/Solvay & Cie SA Polyimide foam, PI Ethyl Corp Branched (SB)n or (SI)n block copolymers Phillips Petrol. Acrylates and methacrylates UCB Soc. Poly(vinyl chloride), PVC Solvay & Cie SA TPO thermoplastic elastomer, PP/EPDM Colonial Polytetrafluoroethylene, PTFE Rhoˆne-Poulenc Polychloroprene, CR USSR Elastic PU fibers (generic name) Spandex fiber Courtaulds PU elastomer Dow Chem. Co. UHMWPE gel-spun fibers AlliedSignal Inc. Thermoplastic polyurea Dow Chem. Co. Thermoplastic polyurethane, TPU Dow Chem. Co. Thermoplastic polyurea Dow Chem. Co. Polyurethane; filled or not, TPU Dow Chem. Co. PP/EPR elastomer Mitsubishi Polyurethane, PU Mobay Corp. Polyamide elastomer blends DuPont Polyamide/ionomer(?) blends Toray PES and PEEK films ICI Films Phenol-formaldehyde resin, PF Hitachi Acrylonitrile-butadiene-styrene/PA alloys DSM Polymer Int. High or low-density polyethylene, PE DSM Polymer Int. (continued) 2338 Stamylan LD Stamylan P Stamylex Stamyroid Stanuloy ST Stanyl Stapron Stapron C Stapron E Stapron N Stapron S Star Star X Staramide-Glass Staramide-Mineral Starcoat Starflam ABS Starflam PA6; PA66 Starflam PBT Starglas ABS Starglas PBT Starglas PC Starglas PE Starglas POM Starglas PSU Starglas SAN Starpylen Stat-Kon M Statcon Stereon Stilon Strathox Stratyl Stycast Stycone Sterpon Stypol Styrafil Styroblend Styrocell Appendix IV: Trade Names of Polymers and Their Blends Low-density polyethylene, LDPE Polypropylene, PP Linear low-density polyethylene, LLDPE Modified amorphous polypropylene, PP Poly(ethylene terephthalate), PET, modified or blended with polycarbonate Polyamide-4,6 and its blends, PA-46 Rubber-modified SMA polymers Polycarbonate/acrylonitrile-butadiene-styrene Polycarbonate/PET or PBT with PB as impactmodifier; for interior automobile door panels Polyamide-6, PA-6, alloys with ABS with impact-modified PA-phase Rubber modified amorphous SMA with glass fiber reinforcements or not Reinforced thermoplastic resins, e.g., ABS, SAN PA-6,PA-46, or PA-66 with an impact modifier, glass fiber reinforced or not Glass fiber-filled polyamide-6, PA-6 Mineral-filled polyamide-6, PA-6 Gel-coat ABS blend, flame retarded, glass reinforced or not PA-6 or PA-66/brominated polystyrene, impact modified, glass or mineral reinforced or not PBT blend, flame retarded, glass reinforced Acrylonitrile-butadiene-styrene with glass fiber Glass fiber filled poly(butylene terephthalate), PBT Glass fiber filled polycarbonate, PC Glass fiber filled HDPE Reinforced polyoxymethylene, POM Glass fiber-filled polysulfone, PSU Reinforced SAN Glass fiber-filled thermoplastic resins PP with electrostatic discharge Electrostatic dissipative materials Triblock SBS thermoplastic elastomer Acrylonitrile-butadiene-styrene/polycarbonate Epoxy resins, EP Unsaturated polyester, UP Epoxy; filled or not, EP Polystyrene, PS alloys Polyester resins, UP Unsaturated polyesters; filled or not, UP Polystyrene with fillers, PS Polystyrene, PS, blends with PE or PB Expandable polystyrene, EPS DSM Polymer Int. DSM Polymer Int. DSM Polymer Int. DSM Polymer Int. MRC Polymers, Inc. DSM Polymer Int. DSM Polymer Int. DSM Polymer Int. DSM Polymer Int. DSM Polymer Int. DSM Polymer Int. Ferro-Eurostar Ferro-Eurostar Ferro Corp. Ferro Corp. Chanet Paints Ferro-Eurostar Ferro-Eurostar Ferro-Eurostar Ferro Corp. Ferro Corp. Ferro Corp. Ferro Corp. Ferro Corp. Ferro Corp. Ferro Corp. Ferro-Eurostar LNP Eng. Plastics LNP Firestone Co. USSR Technibat Pe´chiney, France Emerson & Cuming United Compos. Convert Freeman Chem. Corp. Akzo/DSM BASF Plastics Shell Chem. (continued) Appendix IV: Trade Names of Polymers and Their Blends Styrodur Styroflex Styrofoam Styrol Styrolux Styron Styroplus Styropol Styropor Styruvex Sulfil G Sulfil J-1100 Sulfil J-1300 Sulfil J-1800 Sumigraft Sumikathene Sumikon Sumilit SX Sumipex Sumiploy Sunloid Sunloid KD Sunloid New Ace Sunloid PC Sunprene Suntec Suntra Supec Supec CTX530 Supec CTX540 Superec P Supec W331 Superohm Supralen Supraplast Suprel Suprel SVA Surlyn Surlyn 7930 Extruded rigid polystyrene, PS PS fiber Polystyrene, PS plastic foam Polystyrene, PS Styrene-butadiene copolymer, SBR Polystyrene, PS, and impact-modified PS, HIPS Polystyrene, PS, blends with polybutadiene, PB Styrene-butadiene copolymer, SBR Expandable polystyrene, EPS Styrene-acrylonitrile copolymer, SAN Polysulfone with long glass fibers, PSU Polyethersulfone with glass fibers, PES Poly(phenylene sulfide) with fillers, PPS PET or PBT with glass fibers Poly(vinyl chloride), PVC Polyethylenes, PE Epoxy resins Poly(vinyl chloride), PVC Acrylic resins, PMMA PES, PES/PEEK-modified blends Acrylonitrile-butadiene-styrene terpolymers, ABS Poly(vinyl chloride)/PMMA alloy Poly(vinyl chloride) sheets, PVC Polycarbonate, PC sheet, films Poly(vinyl chloride)-based elastomers, PVC/ elastomer Polyethylene Poly(phenylene sulfide), PPS resin Poly(phenylene sulfide) and blends with PEI, PPE 2339 BASF Plastics Ndd. Seekabelwerke Dow Chem. Co. Idemitsu BASF Plastics Dow Chem. Co. BASF Plastics Carl Gordon Ind. BASF Plastics Coplex Akzo/DSM Akzo/DSM Akzo/DSM Akzo/DSM Sumitomo Chem. Co. Sumitomo Chem. Co. Sumitomo Bakelite Sumitomo Chem. Co. Sumitomo Chem. Co. Sumitomo Chem. Co. Tsutsunaka Plastics Tsutsunaka Plastics Tsutsunaka Plastics Tsutsunaka Plastics Mitsubishi Kasei/A. Schulman Asahi Chemical Co. Sunk Yong GE Plastics/Toso Susteel Poly(phenylene sulfide)/PEI blends with 30 % GF GE Plastics Poly(phenylene sulfide)/PEI blends with 40 % GF GE Plastics Acrylonitrile-butadiene-styrene/polycarbonate Mitsubishi-Monsanto Poly(phenylene sulfide)/PTFE blends with 30 % GF GE Plastics Ethylene-propylene copolymer, EPR A. Schulman, Inc. Polyethylenes, PE (pipes) Mannesmann, Germany Thermoset resins: resorcinol-formaldehyde, etc. O.F.A.C.I. Styrene-acrylonitrile grafted on PVC, SAN or Vista Chemical Co. ABS/PVC alloys Poly(vinyl chloride)/a-methyl styrene-ABS Vista Chemical Co. Ionomer resins E. I. du Pont de Nemours Lithium grade ionomer resin E. I. du Pont de Nemours (continued) 2340 Surlyn 8020 Surlyn 9020 Surlyn A Susteel SVM Sylon FX Syn-Flex Synergy Synolite Synprene Synres Syntewax Synthetic ABS Syspur/Systanat Systemer S Systol T T-xyCF T-xyCG T-xyFG T-xyNF T-xyNG Tactix Taffen Taflite Tafmer Appendix IV: Trade Names of Polymers and Their Blends Sodium grade ionomer resin E. I. du Pont de Nemours Zink grade ionomer resin E. I. du Pont de Nemours Ionomer, ethylene-acrylic acid copolymer E. I. du Pont de Nemours Poly(phenylene sulfide), PPS Toso Susteel Aromatic polyamides USSR Fluoropolymer, thermoset (TS) 3M Ind. Chem. Polyolefin compounds, PO Synergistics Ind Polyamide-6/PPE blends Allied-Signal Inc. Unsaturated polyester resin, UP DSM Plastics Thermoplastic rubber compounds, TPE Synergistics Ind Specialty olefins, PO Quality Service Technology Acrylonitrile-butadiene-styrene terpolymer, ABS Comiel SpA Polypropylene with calcium carbonate, PP Reichhold Chem., Inc. Polyurethane, PU Soprochim Polypropylene/polyamides, reinforced or not Showa Denko K. K. Polyurethane, PU Soprochim Taitalac Taktene Tallerand Tamcin PP TAP-MR Tarpee Polyphenylene sulfide, PPS + xy% graphite fiber Polyphenylene sulfide with xy% carbon/glass Polyphenylene sulfide with xy wt% glass fiber Polyphenylene sulfide with xy wt% graphite fiber Polyphenylene sulfide with xy% glass/graphite High performance EP elastomeric resins Thermoplastic composites Polystyrene, PS-g-EPDM blends Metallocene-made linear low-density polyolefin with strictly controlled comonomer placement Metallocene-made linear low-density polyolefin with 1 % acidic groups, used for compatibilization Acrylonitrile-butadiene-styrene terpolymer, ABS Butadiene rubber, BR; based on co-catalyst Poly(vinyl chloride), PVC Polypropylene, PP Polyisocyanate thermoplastics Polyethylene laminated sheet, PE TDI TE-1004 Techniace TA Techniace TB Polyurethane, PU Epoxy with metallic fillers, EP Polyamide/ABS alloys Poly(butylene terephthalate)/ABS alloys Tafmer A Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Thermofil, Inc. Dow Chem. Co. Exxon Chem. Mitsui Toatsu Mitsui Petrochemicals Mitsui Petrochemicals Taita Chem. Co. Polysar/Bayer AG Tallerand Chem. Reichhold Chem., Inc. Urylon Development Hagihara Industries Inc. Dow Dexter Corp. Sumitomo Dow, Ltd. Sumitomo Dow, Ltd. (continued) Appendix IV: Trade Names of Polymers and Their Blends Techster Techster T Techtron PPS Tecnoflon Tecnoprene Tecoflex Tecolite KM Tediflex/Tedilast ABS/polycarbonate alloys, T-series ¼ heat and impact resistant, H-series ¼ high heat and impact resistant, W-series ¼ weather and impact resistant, F-series ¼ flame and impact resistant Thermoplastic polyurethane/ABS alloys Poly(p-phenylene diphenylether terephthalamide) Polyamide-66/elastomer, with filler or not, PA-66 Polyamide-66, 6/elastomer, with filler or not Polyamide-6/elastomer, with filler or not Polyamide-610/elastomer, with filler or not Polyamide-6, polyamide-66, polyamide-610 impact modified, glass fiber or mineral reinforced or not Polyesters: PBT, PET, and blends Poly(butylene terephthalate), PBT/elastomer blends Polyphenylene sulfide, PPS rods or plates Fluoroelastomers; PVDF/PHFP blends Glass fiber-reinforced polypropylene Polyurethane, PU Phenolic-filled thermosets, PF Polyurethane, PU, formulated systems Tedipur Polyurethane, PU, formulated systems Teditherm/Tedirim Polyurethane, PU, formulated systems Tedlar Polyvinyl fluoride, PVF, film Tedur Tefabloc/Tefaprene Tefanyl Teflon Polyphenylene sulfide, PPS, with glass/mineral Elastomers Poly(vinyl chloride) compounds, PVC Fluoropolymers; PTFE, PFA, FEP Teflon FEP Tetrafluoroethylene-co-hexafluoropropylene, FEP Teflon PFA Fluorocarbon, perfluoroalkoxy resin, PFA Teflon TFE Polytetrafluoroethylene, PTFE Tefzel Modified ethylenetetrafluoroethylene copolymer Teijinconex Teknor Apex Telcar Tempalloy Temprene TempRite Poly(m-phenyleneisophthalamide), PPA Poly(vinyl chloride), PVC PP/EPDM, TPO elastomeric blends Polypropylene with fillers, PP Poly(vinyl chloride)/nitrile rubber (15–40 phr) Chlorinated PVC, CPVC Techniace TC Techniace TU Technora Technyl A Technyl B Technyl C Technyl D Technyl 2341 Sumitomo Dow, Ltd. Sumitomo Dow, Ltd. Teijin Ltd. Rhoˆne Poulenc Rhoˆne Poulenc Rhoˆne Poulenc Rhoˆne Poulenc Rhoˆne Poulenc Rhoˆne Poulenc Rhoˆne Poulenc Polymer Corp. Enimont Enimont Thermedics, Inc. Toshiba Chem. Prod. ECP Enimont Polymeri ECP Enimont Polymeri ECP Enimont Polymeri E. I. du Pont de Nemours Bayer AG/Miles Thermoplastiques C. T. Thermoplastiques C. T. E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours Teijin, Ltd. Teknor Apex Teknor Apex Comalloy Intl. Corp. Piltec Group BF Goodrich (continued) 2342 Appendix IV: Trade Names of Polymers and Their Blends Temprite LC Tenac Tenite Tenite 000 Tenite 200 Tenite 300 Tenite 5000 Tenite Acetate Tenite Butyrate Tenite P7673 Tenite Pet Tenite Polypropion Tenite Propionate Tenite PTMT Tenite Tenneco 2710 Tenneco Teracol Poly(vinyl chloride) compounds, PVC Polyoxymethylene, POM Polyolefins, cellulosics, CAB Cellulose acetate, CA Cellulose butyrate, CB Cellulose propionate, CP Polyallomer Cellulose acetate, CA Cellulose acetate-butyrate, CAB Polyallomer Thermoplastic polyesters, PET Cellulose acetate-propionate, CAP Cellulose propionate, CP Polytetramethylene terephthalate, PTMT PVAc, PVB, PVPr Polyallomer Poly(vinyl chloride)/EVA blends Polyoxytetramethylene glycol Terathane Polyether glycol, PEO Terblend B Terblend S Terblend Terital Teritherm Terlenka Terluran Terluran Terlux ABS/polycarbonate, PC, blend ASA/polycarbonate, PC, blend Styrene copolymer blends Poly(ethylene terephthalate), PET Polyesterimide, PEI Poly(ethylene terephthalate), PET ABS blends with acrylic rubber Acrylonitrile-butadiene-styrene terpolymers, ABS Clear methyl methacrylate-acrylonitrilebutadiene-styrene, MABS Polyester film Poly(ethylene terephthalate), PET Polyetheretherketone, PEEK Poly(ethylene terephthalate) filled, PET Polytetrafluoroethylene, PTFE Polyethylene, PE Polyamide-6; PA-66, with filler or not, PA-6; PA-66 Poly(vinyl acetate) Acrylic polyelectrolyte Polyurethanes Polycarbonate/polyester-PU, PC/TPU alloys Polyester-PU alloys with PC Fully or partially hydrogenated nitrile rubber, NR, with AN ¼ 33–43 % Terphane Terylene Tetra-Temp PEEK Tetrafil J-1800 Tetrafluor Tetralene UHMW Texalon/Texapol Texicote Texigels Texin Texin 3000 Texin 4000 Therban/Tornac Polyplastic Asahi Chemical Ind. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Eastman Chem. Prod. Tenneco Polymers Tenneco Polymers E. I. du Pont de Nemours E. I. du Pont de Nemours BASF Plastics BASF Plastics BASF Plastics Montefibre, Italy P. D. GeorgeE´. Co. AKU, Netherlands BASF Plastics BASF Plastics BASF Plastics Rhoˆne Poulenc ICI Adv. Mater. Tetrafluor, Inc. Akzo/DSM Tetrafluor, Inc. Tetrafluor, Inc. Texapol Corp. Scott Bader Scott Bader Bayer AG/Miles, Inc. Bayer AG/Miles, Inc. Bayer AG/Miles, Inc. Polysar/Bayer A (continued) Appendix IV: Trade Names of Polymers and Their Blends Therban Thermaflo Thermaflo Thermalloy Thermid IP-600 Thermocomp Thermocomp AF Thermocomp BF Thermocomp DL Thermocomp PDX Thermocomp RFL Thermocomp RL Thermolan 2000 Elastomers Poly(vinyl chloride) footwear compounds, PVC Thiorubber, TR, compound Acrylonitrile-butadiene-styrene, ABS blends Polyimide, PI, structural adhesive Reinforced engineering polymer compounds with either glass or carbon fibers Acrylonitrile-butadiene-styrene, ABS, with fillers Styrene-acrylonitrile cop., ABS, with fillers Polycarbonate, PC/PTFE 13 %/silicone 2 % PEEK/PTFE (20 %) alloys Polyamide-66/silicone 5 % blends Polyamide-66/PTFE 13 %/Rimplast Polypropylene/EPDM blends Thermolan 3000 EPDM/polypropylene blends Thermomanto Thermoset Thiokol Extruded EPS insulation boards Epoxy resins with fillers, EP Poly(ethylene chloride-co-sodium sulfide) Thornel THV-Fluoroplastic Graphite yarn Terpolymer of tetrafluoroethylene, hexafluoropropylene and vinylidene fluoride (processing at 130 C) Polypropylene, PP Poly(vinyl chloride); rigid, calendered, PVC Ultrahigh molecular weight PE, UHMWPE Polyurethane sheet, PU Polyethylenes, filled or not, PE TI-4000 Tinolex Tivar (Series) Tivar-Thane Tonen Polyeth Tool WDC Topalloy Topas Toplex Toprene Toray PBT Torelina Torlon Torlon 4000 Torlon 7000 Torolithes Toso LCP Epoxy resin with aluminum, EP – Cyclic, amorphous co-polyolefin, COC, optical grade for compact disks (metallocene based) Polycarbonate/ABS alloy Poly(phenylene sulfide), PPS Poly(butylene terephthalate), with glass or not, PBT Poly(phenylene sulfide), PPS Polyamide-imide, PAI; modified PAI with PTFE, for electrical connectors, valves, bushings, parts, etc. Polyamide-imide + PTFE + graphite Polyamide-imide + PTFE + glass/graphite fiber Thermoset polyester resins, UP Liquid crystal polyester, LCP 2343 Bayer Evode Plastics Ltd. Evode Plastics Ltd. CdF Chimie Nat. Starch @ Chem. LNP Engineering LNP Corp. LNP Corp. LNP Corp. LNP Corp. LNP Corp. LNP Corp. Mitsubishi Petrochem. Mitsubishi Petrochem. Dow Europe Thermoset Plastics E. I. du Pont de Nemours Union Carbide Co. 3M Aristech Chem. Tins Ind. Co. Ltd. Menasha Corporation Menasha Corporation Tonen Petrochem./ TCA Plastics Furane Products TCA Plastics Hoechst/Mitsui Petrochemicals Multibase, Inc. Tonen Petrochem. Toray Industries Toray Industries Amoco Chem. Co. Amoco Chem. Co. Amoco Chem. Co. Routhan Soc. Nouv. Toso (continued) 2344 Total Butyl Total Plast Toyarac Toyoflon Toyolac Appendix IV: Trade Names of Polymers and Their Blends Toyolac ASG20 TPO 900 TPP 10GB TPR TPX Trans-4 Traytuf Trefsin Elastomers Thermoplastic elastomers; EPDM/PO blends, etc. Acrylonitrile-butadiene-styrene, ABS Polytetrafluoroethylene, PTFE Acrylonitrile-butadiene-styrene, ABS also polycarbonate/ABS Styrene-acrylonitrile, SAN with glass fiber Polypropylene/EPDM blends Polypropylene alloy with talc, paintable Thermoplastic cross-linked rubber for PP Polymethylpentene, PMP trans-1,4-Polybutadiene Poly(ethylene terephthalate) with TiO2, PET Thermoplastic elastomers, TPR, PP/BR Trespaphane Biaxially oriented polypropylene film, BOPP Trevira Triax 1000 Poly(ethylene terephthalate) fiber, PET Polyamide-6 or polyamide-66, PA-6 or PA-66 blends with acrylonitrile-butadiene-styrene, ABS Polyamide-6/ABS blends Polyamide-66/ABS ¼ 1:1 blends Polyamide-6,66/acrylonitrile-butadiene-styrene PC/acrylonitrile-butadiene-styrene, ABS Poly(vinyl chloride)/a-methyl styrene-ABS (available as Suprel SVA from Vista Chemical Co.) Polyimide/polytetrafluoroethylene, PI/PTFE Poly(phenylene sulfide)/polytetrafluoroethylene Cellulose acetate, CA Silicone-based paints and coatings – Poly(vinyl chloride) alloys, PVC Polyamide resins, PA Polyamide-63-T, PA-63-T Poly(trimethylhexamethylene terephthalamide) Polyethylene, PE Cellulose ether Cellulose nitrate, CN Phenol-formaldehyde resins, PF Polystyrene, PS Phenolic resins Phenolic-based binder Poly(vinyl chloride), rigid or plasticized, PVC Poly(vinyl chloride), foamed, PVC Poly(vinyl chloride), PVC Triax 1120 Triax 1125 Triax 1180 Triax 2000 Triax CBE Tribolon Tribolon XT Tricel Triplus TPR 178 Typlax Trivin Trogamid Trogamid Trogamid T Trolen Trolit AE Trolit F Trolitan Trolitul Trolon Trolon Trosiplast Trovicel Trovidur Total Chim. Total Chim. Toyo, Japan Toyo, Japan Toray Industries Toray Industries Reichhold Chem., Inc. Ferro Corp. Uniroyal Chemical Mitsui Petrochem. Phillips Goodyear Advanced Elastomer Systems Hoechst Celanese Corp. Hoechst Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. Tribol. Ind. Inc. Tribol. Ind. Inc. Bayer AG/Miles GE Plastics Typlax Vi-Chem Kingsley & Keith H€ uls AG Dynamit Nobel Dynamit Nobel Dynamit Nobel Dynamit Nobel Dynamit Nobel Dynamit Nobel H€ uls AG Dynamit Nobel Dynamit Nobel H€ uls AG Dynamit Nobel (continued) Appendix IV: Trade Names of Polymers and Their Blends Trovitherm Trubyte Tuffak Tuffax Tuflin Tufpet Tufprene Tufrex VB Twaron Tybrene Tylac Poly(vinyl chloride) sheets, PVC Acrylic-based IPN for artificial teeth Polycarbonate sheet, PC Polycarbonate, PC Second-generation Unipol-type LLDPE Poly(ethylene terephthalate) Triblock SBS thermoplastic elastomer ABS/Poly(vinyl chloride), PVC alloys Poly(p-phenyleneisophthalamide), PPA Acrylonitrile-butadiene-styrene terpolymer Poly(vinyl chloride), PVC/BR blends Tylose Tynex Cellulose ether Polyamide-6,6, PA-66 Typlax Tyril Tyrin Tyvek Thermoplastic Elastomers Styrene-acrylonitrile copolymer, SAN Chlorinated PE elastomers and resins, CPE Spunbonded olefin fiber, PO U U-Polymer U-polymer U-xyFG Ube Ube 3000 Ube Alloy CA700 Ube Nylon Ube Polypro Ube, Ubec Ucardel P4174 Ucecoat Ucecryl Ucefix Uceflex Udel Udel GF Udel P Udel P-1700 Udel-X Ugikral UHMWPE 900 Polyarylate, amorphous Polyarylate Polyurethane with xy wt% glass fiber, PU – Polyamide-12, modified, PA-12 Polypropylene/polyamide, PP/PA blend Polyamide-6 or polyamide-66, modified, PA-6, PA-66 Polypropylene, PP Polyethylenes, PE Polysulfone/SAN blend Polyurethane, PU Acrylates and methacrylates Polyurethane, PU Polyurethane, PU Bisphenol-A polysulfone, PSF (or PSO) Polysulfone with glass fiber, PSF Bisphenol-A polysulfone, PSF PSF + 10 % anhydride-terminated PSF + 50 % PA-6 (or PA-66), with PA being the matrix PSU/PA-6 or PA-66 experimental alloys, with 10 wt% anhydride-terminated PSU Acrylonitrile-butadiene-styrene copolymer, ABS Ultrahigh molecular weight PE, UHMWPE 2345 Dynamit Nobel Dentsply International Rohm and Haas Rohm and Haas Union Carbide Toyobo Corp. Asahi Mitsubishi-Monsanto Akzo NV Dow Chem. Co. Standard Brands Chemicals Kalle, Germany E. I. du Pont de Nemours Typlax Products Dow Chem. Co. Dow Chem. Co. E. I. du Pont de Nemours Unitika Unitika Thermofil, Inc. Ube Industries Inc. Ube Industries Inc. Ube Industries Inc. Ube Industries Inc. Ube Industries Inc. Ube Industries Inc. Amoco Performance UCB Soc. Com. UCB Soc. Com. UCB Soc. Com. UCB Soc. Com. Amoco Chem. Co. Amoco Chem. Co. Amoco Chem. Co. Amoco Chem. Co. Amoco Chem. Co. GE Plastics Himont (continued) 2346 Ultem Appendix IV: Trade Names of Polymers and Their Blends Ultramid Terluran Ultranyl Ultrapas Ultrapek Ultrason E Ultrason S Ultrason E Ultrason Ultrason S Ultrastyr OSA Polyetherimide, PEI, and its blends, e.g., with PC, TP Polyetherimide with glass fiber, PEI Polyetherimide copolymer, PEI Polyetherimide copolymer, PEI Polyetherimide/polycarbonate alloy, PEI/PC PEI/PC blends (unreinforced) PEI/PC blends (unreinforced) PEI/PPC blends (unreinforced) PEI blends with polyphenylene ether Polyethylene, PE ASA/PBT blend PET or PBT/PC/elastomer blends PBT/SAN, ABS, or ASA blends, with up to 30 wt% glass fiber Poly(butylene terephthalate), PBT, and impactmodified PBT Polyoxymethylene, POM, acetal Polyoxymethylene/thermoplastic polyurethane, POM/TPU, alloys, with 10–30 wt% TPU Polyurethane sheet, PU Polyamide-66, PA-66/elastomer, with glass fiber, mineral filler or not Polyamide-6, PA-6/elastomer; with glass fiber, mineral filler or not Copolyamide-6/66, PA-6,66/elastomer; 15 or 30 wt% mineral filled Polyamide, PA-66/ASA alloys PA-6, PA-66, PA-610; blends, reinforced Polyamide-610; with glass fiber or not Semi-aromatic polyamide-6/66, PA-66 T, or PARA with elastomer; 30 wt% glass fiber or mineral filled Polyamide, PA-66/ABS alloys PA-66/PPE alloys, reinforced or not Melamine-based molding compound Polyaryletherketone, PAEK (PEKEKK, PEK) Polyether sulfone, PES Polysulfone, PSF (or PSO) Polyethersulfone, 30 wt% glass fiber, PES Polyethersulfone, PES, alloys Polysulfone, 30 wt% glass fiber, PSU SAN-EPDM/ABS or PC alloys Ultrastyr Special styrene copolymers Ultem 2000 Ultem 5000 Ultem 6000 Ultem 8000 Ultem LTX Ultem ATX Ultem HTX Ultem PEI/PPO Ultra-Wear Ultrablend Ultrablend KR Ultrablend S Ultradur B Ultraform Ultraform Ultralastic Ultramid A Ultramid B Ultramid C Ultramid Lurans Ultramid Ultramid S Ultramid T GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics Polymer Corp. BASF Plastics BASF Plastics BASF Plastics BASF Plastics BASF BASF Plastics Menasha Corporation BASF Plastics BASF Plastics BASF Plastics BASF Plastics BASF Plastics BASF Plastics BASF Plastics BASF Plastics BASF Plastics Dynamit Nobel BASF Plastics BASF BASF BASF Plastics BASF Plastics BASF Plastics ECP Enimont Polymeri ECP Enimont Polymeri (continued) Appendix IV: Trade Names of Polymers and Their Blends Ultrathene Ultrax Ultryl Ultzex Unichem Unidene Union Carbide Unipol PP Unirez Unitika Unival DMDA UP Upilex Uradil Urafil J Uraflex Uralac Uralite Uramex Uramul Uravin Urecoll Ureol Urepan Urochem Urtal Urylon US0028 Uvecryl V V440 Vacrel Valox Valox 200 Valox 300 Valox 400 Valox 500 Valox 700 Valox 800 Valox 815 Valox 9000 2347 Ethylene-vinyl acetate, reinforced or not, EVAc USI Chemicals Co./ Quantum Liquid crystal polymers, LCP BASF Plastics Poly(vinyl chloride) Phillips Ethylene-4-methylpentene-1 copolymer Mitsui Petrochem Poly(vinyl chloride); with glass fiber or not, PVC Colorite Plastics Elastomers Enimont Polyethylenes; with carbon fibers or not Union Carbide Co., Inc. Corp. Polypropylene, PP Shell Chem. Co. Polyacrylic resin emulsions Unocal Polyamide-6, filled or not, PA-6 Unitika Co. Polyethylene; PE Union Carbide Co., Inc. Corp. Polyarylate/Poly(ethylene terephthalate) blend Unitika Polyimide films; PI ICI Films Polyester resins for paints (aqu. dispersions), UP DSM Polyurethane; glass or carbon fiber filled, PU Akzo/DSM Polyester resins for paints, UP DSM Polyester resins for paints, UP DSM Polyurethane prepolymer resin, PU Kingsley & Keith Polyester resins for paints, UP DSM Poly(vinyl acetate) latices for paints, PVAc DSM TPU/PVC alloy Vi-Chem Urea-formaldehyde, UF BASF Plastics Polyurethane resins, PU Ciba-Geigy Ltd. Polyurethane, PU Bayer Urea-formaldehyde resins, UF C.P.R.I. Acrylonitrile-butadiene-styrene copolymer, ABS Montepolimeri Polyisocyanate thermoplastic, PPI Urylon Development Polyurethane; filled or not, PU Dexter Corp. Acrylic and methacrylic resins UCB Soc. Com. Poly(vinyl chloride) compounds, PVC Photopolymer film soldermask PBT or PET or PCT, resins or blends Poly(butylene terephthalate); unreinforced, PBT Poly(butylene terephthalate); unreinforced, PBT Poly(butylene terephthalate); glass reinforced, PBT PBT/PET alloy; glass reinforced Poly(butylene terephthalate); glass/mineral filled Poly(butylene terephthalate) alloy; glass reinforced PBT/PET alloy; with glass fiber or not Poly(ethylene terephthalate); glass reinforced, PBT Vi-Chem Corp. E. I. du Pont de Nemours GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics (continued) 2348 Valox 9700 Valox HV7000 Valox VCT Valtel, Valtec Valtra Valtra 7023 Valtra HG-200 Vamac Vandar VB-510 VC VE Vector 6000 Vectra A Vectra B950 Vectra V140 Vedril Vekton 6 Vekton 11 Vekton 66 Velponyl/Velporex Venyl Versamid Versamid Versicol Verton Verton DF Verton KA Verton NF Verton OF Verton PF Verton QA Appendix IV: Trade Names of Polymers and Their Blends Polycyclohexyleneterephthalate; glass reinforced Poly(butylene terephthalate) alloy; mineral filled PBT or PET toughened with elastomer Polypropylene, PP Polystyrene, PS, and blends Rubber-modified styrenic blends Styrenic copolymer for injection molding Ethylene-acrylic elastomer, curable with diamines GE Plastics GE Plastics GE Plastics Himont Chevron Chemicals Chevron Chemicals Chevron Chemicals E. I. du Pont de Nemours & Co. PBT/acrylic alloys, reinforced or not Hoechst Celanese Corp. Polypropylene with talc, PP Reichhold Chem., Inc. Poly(vinyl chloride), PVC Borden Chem. Unsaturated vinyl ester, with glass or carbon fiber ICI/Fiberite SB, SBS, SI, and SIS block copolymers Dexco Polymers Liquid crystal polymer, LCP; reinforced or not a Hoechst Celanese copolyester from hydroxy benzoic acid with Corp. hydroxynaphthoic acid LCP copolymer comprising 20 mol% of Hoechst Celanese terephthalic acid, 20 mol% 4-aminophenol, and Corp. 60 mol% of 2-hydroxy-6-naphthoic acid LCP/PPS blends for electrical/electronic parts Hoechst Celanese Corp. Poly(methyl methacrylate)s powder, sheets, PMMA Montedison SpA Polyamide-6; filled or not, PA-6 Norton Performance Polyamide-11, PA-11 Norton Performance Polyamide-66; filled or not, PA-66 Norton Performance Printing resins DSM Polyamides; reinforced or not, PA Vecoplas Polyamide; vegetable oils condensed with amines General Mills Polyamides, PA Henkel Corp Acrylic polyelectrolyte Allied Colloids Long fiber reinforced resins ICI Materials – Plast./ LNP Long fiber reinforced polyamide-66 ICI Materials – Plast./ LNP Long fiber reinforced polyoxymethylene, POM ICI Materials – Plast./ LNP Long fiber reinforced SMA ICI Materials – Plast./ LNP Long fiber reinforced poly(phenylene sulfide), ICI Materials – Plast./ PPS LNP Long fiber reinforced polyamide-66, PA-66 ICI Materials – Plast./ LNP Long fiber reinforced polyamide-610 ICI Materials – Plast./ LNP (continued) Appendix IV: Trade Names of Polymers and Their Blends Verton RF Long fiber reinforced polyamide-66 Verton TF Long fiber reinforced polyurethane, PU Verton WF Verton YA Long fiber reinforced poly(butylene terephthalate) Long fiber reinforced polycarbonate, PC Verton YF Long fiber reinforced polyester Vespel ST Super-tough polyimide with high-impact strength Vespel-SP Polyimide (polypyromellitimide); electrical parts Vestamelt Vestamid Vestamid D; X Vestamid L Vestenamer Vestoblend Vestodur Vestolen A Vestolen BT Vestolen EM Vestolen P Vestolit Vestopal Vestoplast Vestopren Vestoran Vestosint Vestypor Vestyron VFR-10248 Vibraspray Vibrathane Copolyesters Polyamide-12, polyamide-6,12, PA-12 elastomer Polyamide-612; filled or not, PA-612 Polyamide-12; filled or not Trans-polyoctenamer, thermoplastic elastomer Polyamide/PPE alloys, reinforced or not Poly(butylene terephthalate), PBT; reinforced or not High-density polyethylene, HDPE Polybutene, PB EPR- or EPDM-modified polypropylene, PP, containing talc, CaCO3, glass fibers, mineral, or not Polypropylene, PP Poly(vinyl chloride), PVC, rigid and flexible Unsaturated polyester resins, UP Amorphous olefin copolymers, TPO Polyolefin impact modifier, PO PPE blends with HIPS and elastomer Polyamides, PA Expandable polystyrene, EPS GP-PS, HIPS Poly(ethylene terephthalate) with TiO2, PET Elastomers Urethane prepolymers, TS Vibrin Viclan Vicotex 260 Vicotex Victrex D Polyester resins, UP Vinylidene chloride copolymers, PVDC Phenolic prepreg resins Epoxy preimpregnates, EP Polyetheretherketone, with glass or carbon fiber Victrex J Victrex PEEK Polyethersulfone, PES; filled Polyetheretherketone, PEEK; reinforced or not 2349 ICI Materials – Plast./ LNP ICI Materials – Plast./ LNP ICI Materials – Plast./ LNP ICI Materials – Plast./ LNP ICI Materials – Plast./ LNP E. I. du Pont de Nemours E. I. du Pont de Nemours H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls/Nuodex Inc. H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls AG H€ uls AG Goodyear Safic-Alcan Uniroyal Chemical Ltd. Fiberglas Canada ICI Ciba-Geigy Brochier ICI Materials – Plastics/Victrex ICI/LNP Eng. Plastics ICI/LNP Eng. Plastics (continued) 2350 Victrex PES Victrex SRP Victrex VKT Victrex VST Vidar Vifnen VN Vilit Vinapas Vinavil Vinavol Vinex Vinidur Vinika Viniproz Vinnapas Vinnol Vinoflex Vinoflex Vinuran Vipla Viplast Viscose Vista Vistaflex Vistalon 404 Vistalon 2504 Vistanex Vistel Vithane Viton A Viton B Viton Vitrofi Vituf Vivypak/Lighter Vixrex PES Vodcum Volara Volex 410 Appendix IV: Trade Names of Polymers and Their Blends Polyethersulfone, PES; filled, lubricated Liquid crystal polyester, LCP Polyetheretherketone, PEEK/PTFE blend Polyethersulfone, PES/PTFE blends Poly(vinylidene fluoride), PVDF coating powders AAS/Poly(vinyl chloride), PVC alloys Poly(vinylidene chloride) copolymers, PVDC Poly(vinyl acetate), PVAc Poly(vinyl acetate), PVAc Poly(vinyl alcohol), PVAl Poly(vinyl alcohol), PVAl Poly(vinyl chloride), PVC, and impact-modified PVC with 5–15 wt% acrylate-graft copolymer Poly(vinyl chloride)-based elastomers, PVC Poly(vinyl chloride)/PMMA alloys Poly(vinyl acetate), PVAc Poly(vinyl chloride), homo, g and r copolymer., PVC Poly(vinyl chloride), suspension grade, PVC Vinyl chloride-vinyl ether copolymer, PVCAc MBS modifier for poly(vinyl chloride) Poly(vinyl chloride) paste polymers, PVC Poly(vinyl chloride) compositions, PVC Fibers from cellulose Poly(vinyl chloride); filled or not, PVC Thermoplastic elastomers, TPO, PP/EPDM ICI/LNP Eng. Plastics ICI Materials – Plast. ICI Materials – Plast. ICI Materials – Plast. Solvay & Cie SA Hitachi Chem. H€ uls A.-G Wacker Chemie Montecatini Hoechst AG Air Products & Chem. BASF Plastics A. Schulman, Inc. USSR Wacker-Chemie Wacker-Chemie BASF Plastics BASF Plastics BASF Plastics European Vinyls Corp. European Vinyls Corp. (generic name) Vista Chem. Co. Advanced Elastomer System Ethylene-propylene copolymer, EPM Exxon Chem. EPDM terpolymer Exxon Chem. Polyisobutene, PIB Exxon Chem. Rigid PVC blends for injection molding Vista Chemical Co. Polyurethanes, PU Goodyear Vinylidene fluoride/fluoridehexafluoropropylene E. I. du Pont de Nemours PTFE/PHFP/PVDF E. I. du Pont de Nemours Fluoroelastomers E. I. du Pont de Nemours Vetrotex trademark for tissue Vetrotex International Poly(ethylene terephthalate), PET; with TiO2 Goodyear Poly(ethylene terephthalate), PET bottle grades ECP EniChem Polymeri Polyethersulfone, PES; glass/mineral filled LNP Engineering Phenolic resin, PF Cain Chem. Inc. EVA/PP or PE blends Seiksui/Voltek Poly(butylene terephthalate), PBT; glass/mineral Comalloy Intl. Corp. (continued) Appendix IV: Trade Names of Polymers and Their Blends Volex 440 Volex 600 Voloy 100 Voloy 680 Voltalef 300 Voralast Voranol Vulcaprene Vulkollan Vulta Foam Vultex Vybak Vydyne Vydyne M Vydyne R Vygen Vynathene Vyncolite Vynite Vyram Vythene W W-xyFG W-xyNF Wacke VAE Wacker PU Wellamid Wellamid 22 LHI Wellamid FR Wellamid GF Wellamid MR Wellamid MR Wellite Wellpet GF Welvic Wingtack Witcast Witcothane Wofatit WRM WRS Wydyne Poly(ethylene terephthalate), PET; glass/mineral Polyamides-6, polyamide-66, polyamide-612, PA; with glass/mineral Polypropylene; with glass/mineral, PP Polyamide-6,6; with glass/mineral, PA-66 Polychlorotrifluoroethylene, PCTFE Tailored PU elastomers Polyether PU elastomers Polyurethanes, PU Polyurethanes, PU Rigid urethane foam, EPU Latex and compounds Poly(vinyl chloride), PVC Polyamide-66 or polyamide-69 Polyamide-66, PA-66 Polyamide-66 with glass or mineral, PA-66 Poly(vinyl chloride), PVC Ethylene-vinyl acetate copolymer, EVAc Phenol-formaldehyde resins, PF Poly(vinyl chloride)/nitrile rubber alloy PP/diene – TPE elastomeric blends Poly(vinyl chloride), PVC/PU alloy Polyetherimide with xy wt% glass fiber, PEI Polyetherimide with xy wt% graphite fiber, PEI Ethylene-vinyl acetate copolymer, EVAc Polyurethane or silicone elastomers, PU Polyamide-6, polyamide-66, PA-66 Polyamide-66/elastomer, PA-66 blend Polyamide-66 with glass spheres, PA-66 Polyamide-6 or polyamide-66 with glass fiber, PA-6, PA-66 Polyamide-6 or polyamide-66 with glass or mineral, PA-66 Polyamide-66/polyamide-6, PA-6 alloys Poly(butylene terephthalate), PBT; with glass Poly(butylene terephthalate), PBT; with glass Poly(vinyl chloride) compositions, PVC Synthetic polyterpene Polyurethane elastomers, PUR Polyurethane elastomers, PUR Ion-exchange resin Elastomers Polypropylene, PP Polyamides; reinforced or not, PA 2351 Comalloy Intl. Corp. Comalloy Intl. Corp. Comalloy Intl. Corp. Comalloy Intl. Corp. Elf Atochem Dow Chem. Co. Dow Chem. Co. ICI Bayer AG/Miles General Latex General Latex Bakelite Xylonite Monsanto Chem. Co. Monsanto Chem. Co. Monsanto Chem. Co. Vygen Corp. Quantum Chem. Vynckier Dexter Corp. Advanced Elastomers Dexter Corp. Thermofil, Inc. Thermofil, Inc. Wacker Chimie A.-G. Arnaud Promecome Wellman Inc. Wellman Inc. Wellman Inc. Wellman Inc. Wellman Inc. Wellman Inc. Wellman Inc. Wellman Inc. European Vinyls Corp. Goodyear Chem. Eur. Witco Witco VEB Farbenfabrik Safic-Alcan Shell Chem. Co. Monsanto (continued) 2352 X X-28057 Xantar XB-4000 Xenoy Xenoy 1000, 5000 Xenoy 2000 Xenoy 3000 Xenoy 6125 Xenoy DX6302 XL-030 XP-50 XT XT 3055 XT Polymer Xtcon XTPE XTPL NFR-6000 XU XU61513 Xycon Xydar Xydar FC Xydar FSR-315 Xydar RC Xylok Xylon Xyron 200 Xyron A Xyron G Y Y-xyFG Y1-xyFG Yukalon Z Zemid Zenite Zenite Appendix IV: Trade Names of Polymers and Their Blends Epoxy resins with mineral, EP Polycarbonate, PC Polyamide-6 with or without glass, PA-6 PC/PBT/MBA alloys, reinforced or not Polycarbonate, PC:PBT ¼ 1:1 alloys Polycarbonate, PC/PET/MBA alloys Polycarbonate, PC/TPE alloy PET/PC, impact mod.; 0–30 wt% glass fiber Polycarbonate/polyester alloy with carbon fiber Polypropylene, PP Poly(p-methylstyrene-co-isobutylene)-based compatibilizing system Acrylic-based multipolymer blends Polyamide alloys, PA Acrylic-based transparent, high-impact blend Polyester/polyurethane hybrid resin Cross-linkable elastomers and olefins ICI/Fiberite DSM Allied Signal Corp. GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics GE Plastics Aristech Chem. Exxon Chem. Co. Polystyrene with xy wt% glass fiber, PS Polystyrene with xy wt% glass fiber, PS Polyethylenes, PE Thermofil, Inc. Thermofil, Inc. Mitsubishi Petrochem. Cyro Industries EMS-American Grilon Cyro Industries Amoco Chem. Co. Quality Service Technology Thermoplastic elastomer, TPE E. I. du Pont de Nemours TPU/acrylonitrile-butadiene-styrene, ABS alloys Dow Chem. Co. Polyethylene, PE Dow Chem. Co. TPEs/TPU alloys Amoco Chem. Co. Liquid crystal polymer, LCP Amoco Performance Products Liquid crystal polymer, LCP; glass/mineral Amoco Chem. Co. Liquid crystal polymer, LCP; 50 % talc Amoco Chem. Co. Liquid crystal polymer, LCP; glass/mineral Amoco Chem. Co. Aralkyl thermoset resins O.F.A.C.I. Polyamide-66 with a filler, PA-66 Akzo/DSM Poly(phenylene ether) PPE/HIPS alloys Asahi Chem. Ind. Polyamide/PPE/alloys, reinforced or not Asahi Chem. Ind. Polyamide/poly(phenylene ether) PPE alloys Asahi Chem. Ind. – E. I. du Pont de Nemours Polyamide-66, with glass fiber, PA-66 E. I. du Pont de Nemours Wholly aromatic polyester, LCP, HDT ¼ 295 C E. I. du Pont de Nemours (continued) Appendix IV: Trade Names of Polymers and Their Blends Zeo-karb Zeonex Zeonex Zetpol PBZ Zitex G Ion-exchange resin Polymethylpentene, PMP Polyolefin, amorphous, transparent for optical applications: disks, lenses, prism, LCD films, etc. Polyether elastomer Polystyrene, PS/PMMA alloys Plastic clad metal for fiber optic cables Ethylene-vinyl acetate copolymer, EVAc Hydrogenated, nitrile elastomer (HNBR), highly saturated for fuel and solvent resistance HNBR/PVC blends PTFE porous films Zylar High transparency acrylic terpolymers Zylar ST SAN/polybutadiene high transparency alloy Zytel Polyamide-6,10, PA-610 Zytel 71G Polyamide-66/ionomer, PA-66 alloys Zytel 77G Polyamide-6,12/ionomer, PA-612 alloys Zytel 101 Polyamide-66, PA-66 Zytel 105 Polyamide-66, with carbon black, PA-66 Zytel 150 Polyamide-6,12, PA-612 Zytel 300, 400 Polyamide-6,6/ionomer, PA-66 alloys Zytel 3100 Polyamide-6/polyamide-66 alloys Zytel FN Flexible polyamide alloys Zytel GRZ Glass fiber-reinforced PA-66 or PA-612 Zytel ST Impact-modified PA-6 or PA-66 Zytel ST-350 Polyamide-612/elastomer, PA-612 alloys Zeospan Zerlon Zetabond Zetafin Zetpol 2353 Permutit Co. Nippon Zeon Nippon Zeon Co., Ltd. Nippon Zeon Co., Ltd. Dow Chem. Co. Dow Europe Dow Chem. Co. Nippon Zeon Co., Ltd. Nippon Zeon Co., Ltd. Norton Performance Plast. Novacor Chemicals Inc. Novacor Chemicals Inc. E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours E. I. du Pont de Nemours Appendix V: Commercialization Dates of Selected Polymers Year 1868 1900 1909 1915 1926 Code NC CS PF PS AK Polymer Cellulose nitrate; Nixon Casein; Galalith Phenol-formaldehyde; Bakelit Polystyrene; Trolitul Alkyd resins; Glyptal 1927 CA Cellulose acetate fibers; Lumarith 1927 PMA 1928 PVAc Poly(methyl acrylate) Poly(vinyl acetate); Elvacet 1928 1928 1929 1929 Poly(vinyl chloride-co-vinyl acetate) Poly(methyl methacrylate), Plexiglas Styrene-butadiene rubber; Styrolux Urea/formaldehyde resins; Pollopas PVC/Ac PMMA GRS/SBR UF 1930 PAN 1930 CR Polyacrylonitrile Chloroprene rubber; Neoprene 1930 TR Polysulfide rubbers; Thiokol 1931 1931 1931 1932 1932 Poly(vinyl chloride); Trovidur, Vestolit Poly(ethylene glycol) Poly(vinyl alcohol)/formaldehyde fibers Styrene-butadiene rubber Acrylonitrile-butadiene rubber PVC PEG PVAl Buna-S Buna-N L.A. Utracki, C.A. Wilkie (eds.), Polymer Blends Handbook, DOI 10.1007/978-94-007-6064-6, # Springer Science+Business Media Dordrecht 2014 Producer Hyatt Bros. Kritische (France) Bakelit Gesellschaft I. G. Farbenindustrie General Electric Company Canadian Celanese/ Eastman O. Ro¨hm Shawinigan Chemical Ltd. I. G. Farbenindustrie Ro¨hm and Haas I. G. Farbenindustrie Stein Hall Mfg. Company I. G. Farbenindustrie E. I. du Pont de Nemours & Co. Thiokol Chemical Corporation I. G. Farbenindustrie I. G. Farbenindustrie I. G. Farbenindustrie I. G. Farbenindustrie I. G. Farbenindustrie (continued) 2355 2356 Appendix V: Commercialization Dates of Selected Polymers Year Code 1932 UM Polymer Urea/melamine 1933 1933 1933 1934 1934 Poly(ethyl methacrylate) Ethyl cellulose; Methocel Aniline/formaldehyde resins; Cibanite Polychlorotrifluoroethylene; Hostaflon Poly(vinyl formal) PEMA EC AF PCTFE PVFO 1935 PVBO Poly(vinyl butyral) 1936 ABS-A Acrylonitrile-butadiene-styrene; Royalite 1936 MF 1937 PA-66 Melamine/formaldehyde resins Polyamide-66; Nylon 1937 SAN 1937 TPU 1937 TS Styrene-acrylonitrile copolymer; Luran Thermoplastic polyurethane elastomers Thermoset polyesters 1937 PVK Poly-N-vinylcarbazole; Luvican 1938 MF 1938 CAB Melamine-formaldehyde resin; Resart Cellulose acetate butyrate; Tenite 1938 PA-6 1938 PA-66 Poly-e-caprolactam; Perlon Polyhexamethyleneadipamide; Nylon 1939 LDPE 1939 PVDC Low-density polyethylene; Alketh Poly(vinylidene chloride); Saran 1939 PVP 1939 PU Poly-N-vinylpyrrolidone Polyurethane fibers, Perlon U 1940 DAC 1942 UP Diallyl glycol carbonate; CR-38 Unsaturated polyester; Vestopal 1942 PTFE Polytetrafluoroethylene; Teflon TFE 1943 EP 1943 BR Epoxy; Araldite Butyl rubber 1943 HDPE 1943 PDMS High-density polyethylene; Vestolen Polydimethylsiloxane; Dow Corning 1943 PVAl Poly(vinyl alcohol); Vinaviol Producer American Cyanamid Company Ro¨hm and Haas ICI Ciba I. G. Hoechst Shawinigan Chemical Ltd. Shawinigan Chemical Ltd. Naugatuck Chemical Company Ciba E. I. du Pont de Nemours & Co. I. G. Farbenindustrie O. Bayer Marco Chemical Company I. G. Farbenindustrie (BASF) Henkel AG Eastman Kodak Company I. G. Farbenindustrie E. I. du Pont de Nemours & Co. ICI Ltd. Dow Chemical Company Farbenindustrie I. G. Farbenindustrie, Wolfen PPG Company United States Rubber Company E. I. du Pont de Nemours & Co. Ciba-Geigy St. Claire Processing Corporation BASF A.-G. Dow Corning Corporation Shawinigan Chemical Ltd. (continued) Appendix V: Commercialization Dates of Selected Polymers Year Code 1943 PVCAc Polymer Vinyl copolymers; Vinidur 1945 1947 1948 1948 Cellulose propionate; Forticel Polyurethanes; Perlon U Acrylonitrile-butadiene-styrene latex Acrylic elastomer; Hycar PA CP PU ABS-G ACM 1950 EVA 1950 CSR Ethylene-vinyl acetate copolymer Chlorosulfonated PE; Hypalon 1950 PCTFE 1952 OPET Polychlorotrifluoroethylene Oriented polyethyleneterephthalate film 1953 PET 1954 PVAc/Ph Poly(ethylene terephthalate); Melinite Poly(vinyl acetate)/phthalate 1955 PA-11 1956 PC Polyamide-11; Risilan Bisphenol-A polycarbonate; Macrolon 1956 PCME 1957 PEG Polydichloromethyltrimethylene ether; Penton Poly(ethylene glycol); Carbowax 1957 PP Isotactic Polypropylene; Pro-Fax 1958 DAP/ Allyl unsaturated polyester; Dapon DAIP 1958 SMM Poly(styrene-co-methylmethacrylate); Kamax 1958 UHMWPE Ultrahigh molecular weight polyethylene; Hostalen GUR 1959 CPE Chlorinated polyethylene; Hostapren 1959 POM Polyoxymethylene (Acetal); Delrin 1959 POM 1959 TPU 1960 EVAc Poly(oxymethylene/ethylene); Celcon Thermoplastic polyurethane; Estane Ethylene-vinyl acetate; Elvacet 1960 1960 1960 1960 1960 1961 Cellulose acetate propionate; Tenite Chlorobutyl rubber; Exxon Butyl Ethylene-propylene elastomer; Vistalon Linear low-density polyethylene; Sclair Chlorinated polyether; Penton Polyamide-epichlorohydrin; Hydrin CAP CBR EPR LLDPE – – 1961 Aramid Poly(m-phenyleneisophthalamide); Nomex 2357 Producer Shawinigan Chemical Ltd. Celanese Bayer A.-G. Ro¨hm & Haas B. F. Goodrich Chemical Co. ICI E. I. du Pont de Nemours & Co. Hoechst A.-G. E. I. du Pont de Nemours & Co. ICI C. E. Frosst & Company Thann & Mulhouse Bayer A.-G.; General Electric Co. Hercules Union Carbide Canada Ltd. Hoechst/Montecatini/ Hercules FMC Corporation Ro¨hm & Haas A.-G. Hoechst A.-G./Himont Hoechst A.-G. E. I. du Pont de Nemours & Co. Celanese B. F. Goodrich E. I. du Pont de Nemours & Co. Eastman Kodak Exxon Exxon DuPont-Canada Hercules Inc. Hercules Powder Company E. I. du Pont de Nemours & Co. (continued) 2358 Appendix V: Commercialization Dates of Selected Polymers Year Code 1961 FEP Polymer Fluorinated-ethylene propylene; Teflon FEP 1961 PVDF Poly(vinylidene fluoride); Kynar 1962 SB 1962 ACM Styrene-butadiene block copolymer Acrylate rubber 1962 Phenoxy 1962 PI Polyhydroxyether of bisphenol-A; Phenoxy Polyimides; Kapton 1963 EPDM Ethylene-propylene-diene; Nordel 1963 SMA Styrene-maleic anhydride; Dylark 1963 IO Ethylene copolymer ionomers; Surlyn 1964 EVAc Ethylene-vinyl acetate copolymer; Elvax 1964 EVAc Ethylene-vinyl acetate cop.; Ultrathene 1964 PIAN Isoprene/acrylonitrile rubber 1964 PPE Poly(phenylene ether); PPE 1964 PB 1965 PAI Polybutylene, Vestolen BT Polyamide-imide; Torlon 1965 PBIA Polybenzimidazole 1965 PSF Polysulfone of bisphenol-A; Udel 1965 SBS Poly(styrene-b-butadiene); Kraton D 1965 EP Poly(ethylene-b-propylene); Polyallomer 1965 (blend) PU/polyester; Corfam 1965 PPX Polyparaxylene; Parylene 1965 PMP Poly-4-methyl pentene-1; TPX 1966 PPE blend Poly(phenylene ether); Noryl 1966 PA-12 Polyamide-12; Vestamid 1969 – 1969 PB Amorphous, aromatic PARA; Trogamid Polybutene-1; Duraflex Producer E. I. du Pont de Nemours & Co. Pennwalt Chemical Company Phillips Polymer Corp. Ltd. (Polysar) Union Carbide E. I. du Pont de Nemours & Co. E. I. du Pont de Nemours & Co. Sinclair Petrochemicals Company E. I. du Pont de Nemours & Co. E. I. du Pont de Nemours & Co. U. S. Industrial Chemicals Polymer Corp. Ltd. (Polysar) General Electric Company H€ uls A.-G. Amoco Chemical Corporation Naramco, Materials Div. Union Carbide Corp./ Amoco Shell Chemical Company Eastman Chemical Products E. I. du Pont de Nemours & Co. Union Carbide Company, Inc. ICI/Mitsui Petrochemical Ind. General Electric Company H€ uls A.-G./Emser Werke Dynamit Nobel H€ uls A.-G. (continued) Appendix V: Commercialization Dates of Selected Polymers Year 1969 1969 1970 Code PBT PBT PO Polymer Poly(butylene terephthalate); Celanex Poly(butylene terephthalate); Hostadur Unipol process 1970 LCP 1970 BIIR 1970 PA-612 Poly(p-oxybenzoyl); Ekonol Bromobutyl rubber Polyamide-6,12; Zytel 150 1970 Aramid Poly(p-phenyleneisophthalamide); Kevlar 1971 PASU 1971 PPS Polyarylsulfone; Astrel Poly(phenylene sulfide); Rayton R 1971 1972 1972 1972 1972 Polyarylether; Arylon T Ethylene-vinyl alcohol; Elvanol Liquid crystal polymers; Ekkcel I-2000 Polyethersulfone; Victrex Perfluoro alkoxy polymer; Teflon PFA PAE EVAl LCP PES PFA 1972 ETFE Poly(ethylene-co-tetrafluoroethylene); Tefzel 1972 SB Styrene-butadiene blocks; K-resin 1972 SEBS Poly(styrene-b-ethylene butylene); Kraton G 1973 PVDF 1973 PAr 1976 PPSU 1978 PEEK 1980 APEC Poly(vinylidene fluoride); Dyflon Polyarylate (mixture of i- and t-phthalic acid with bisphenol-A); U-polymer Polyphenylsulfone; BXL, Radel R Polyetheretherketone; Victrex Aromatic polyestercarbonate; Apec 1981 PEBA 1981 TPO 1982 PEI Polyether-block-amide; Pebax Dynamically vulcanized PO blend; Santoprene Polyetherimide; Ultem 1983 1983 1985 1985 Polyarylsulfone; Radel Polybenzimidazole; PBI Polyarylether; Parylen Melt-processable rubber; Acrylyn PAS PBI PAE MPR 1986 PISO 1987 PTES Polyimidesulfone Polythioethersulfone; Amoroon 1987 PA-46 1987 PPMB Polyamide-4,6; Stanyl Poly-p-methylenebenzoate 2359 Producer Celanese Hoechst A.-G. Union Carbide Company, Inc. Carborundum Polysar E. I. du Pont de Nemours & Co. E. I. du Pont de Nemours & Co. 3M Company Phillips Petroleum Company Uniroyal Kuraray Company Ltd. Carborundum ICI Ltd. E. I. du Pont de Nemours & Co. E. I. du Pont de Nemours & Co. Phillips Petroleum Company Shell Chemical Company Dynamit Nobel Unitika Union Carbide/Amoco ICI Ltd. Chemical Werke Albert; Bayer Atochem Monsanto Company General Electric Company Amoco Celanese Corporation Union Carbide E. I. du Pont de Nemours & Co. Celanese Dainippon Ink & Chemicals DSM Amoco (continued) 2360 Year 1989 1991 1992 1994 Appendix V: Commercialization Dates of Selected Polymers Code sPS PPA sPP PENi 1995 COPO Polymer Syndiotactic polystyrene Polyphthalamide; Amodel Syndiotactic polypropylene Polyethernitrile Ethylene-carbon monoxide copolymer Producer Idemitsu/Dow Amoco Sumitomo Chemical Idemitsu Materials Company Shell Chemicals Appendix VI: Notation and Symbols The following list of commonly used notation and symbols is used in the Encyclopedia. They are based on those listed in American National Standard Abbreviations for Use on Drawings and in Text (ANSI Yl.l), American National Standard Letter Symbols for Units in Science and Technology (ANSI Y10), and The Society of Rheology [J. Rheol., 28, 181 (1984)]. Abbreviations A a-c abs aq av BC bcc bct bp C ca cgs CH CMC conc cp CPC cryst CST CTM Amorphous polymer Alternating current Absolute Aqueous Average Block copolymer Body-centered cubic Body-centered tetragonal Boiling point Crystalline polymer Circa (about as much) Old units: centimeter-gram-second Centrifugal homogenizer Critical micelle concentration Concentration Chemically pure Cloud point curve Crystalline Critical solution temperature Cavity transfer mixer L.A. Utracki, C.A. Wilkie (eds.), Polymer Blends Handbook, DOI 10.1007/978-94-007-6064-6, # Springer Science+Business Media Dordrecht 2014 2361 2362 d-c dB dec detd detn dia dil dl -; DLDMA DMF DMG DMSO DP dp DPH DR DS dsc dta ECU ED ed. em emf emu EP EPB epr Eq esca esp esr est(d) estn esu exp ext(d) fcc fp frz FTIR g-mol gc glc Appendix VI: Notation and Symbols Direct current, adj. Decibel Decompose Determined Determination Diameter Diluted Racemic Dimethylacetamide Dimethylformamide Dimethylglyoxime Dimethyl sulfoxide Degree of polymerization Dew point Diamond pyramid hardness Draw ratio Degree of substitution Differential scanning calorimetry Differential thermal analysis Electrochemical unit Effective dose Edited, edition, editor Electron microscopy Electromotive force Electron magnetic unit Engineering polymer Engineering polymer blends Electron paramagnetic resonance Equation Electron-spectroscopy for chemical analysis Especially Electron-spin resonance Estimate(d) Estimation Electrostatic unit Experiment, experimental Extract(ed) Face-centered cubic Freezing point Freezing Fourier transform IR Gram-molecular weight Gas chromatography Gas–liquid chromatography Appendix VI: Notation and Symbols gpc grd hcp hex HPB hplc HRC HV hyg ICT ID Im im intl. ir IU IUPAC l.c. LALLS LCB LCD LCST LED liq ln log m max MEK meq mfd mfg mfr MIBC MIBK min mol mol wt mp MPB ms MTT MW 2363 In old terminology, gel-permeation chromatography; modern term, size exclusion chromatography, sec, should be used instead Ground Hexagonal close-packed Hexagonal Homologous polymer blend High-pressure liquid chromatography Rockwell hardness (C scale) Vickers hardness number Hygroscopic International Critical Table Inside diameter Imaginary part of a complex function Immiscible International Infrared International Unit International Union of Pure and Applied Chemistry Lower case (in printing) Low-angle laser light scattering Long-chain branching Liquid crystal display Lower critical solution temperature Light-emitting diode Liquid Logarithm (natural) Logarithm (common) Miscible Maximum Methyl ethyl ketone Milliequivalent Manufactured Manufacturing Manufacturer Methyl isobutyl carbinol Methyl isobutyl ketone Minute; minimum Mole Molecular weight Melting point (also Tm) Miscible polymer blend Mass spectrum Melt titration technique Molecular weight 2364 MWD mxt na nat NDB neg NG NI NIRT nmr no. NRET NTP oOD OM pp-i-n p., pp. PAB PDB Pe pH phr PICS pm pmr PNDB pos ppb pph ppm ppmv ppmwt PRC pt pwd qv r-f, rf rad rds Re Ref. rh Appendix VI: Notation and Symbols Distribution of MW Mixture Not available Natural Negatively deviating blends Negative Nucleation-and-growth Notched Izod impact strength Notched Izod impact strength at room temperature Nuclear magnetic resonance Number Non-radiative energy transfer Normal temperature and pressure (25 C and 101.3 kPa or 1 atm) Ortho Outside diameter Optical microscopy Para Positive-intrinsic-negative Page, pages Polymer alloys and blends Positively deviating blends Peclet number Negative logarithm of the effective hydrogen ion concentration Concentration in parts per hundred of resin Pulse-induced critical scattering Partially miscible Proton magnetic resonance Positively and negatively deviating blends (sigmoidal) Positive Parts per billion (109) Parts per hundred Parts per million (106) Parts per million by volume Parts per million by weight Particular rheological composition Point; part Powder Quod vide (which see) Radio frequency; adj. and n., respectively Radian Rate-determining step Real part of complex function Reference Relative humidity Appendix VI: Notation and Symbols rms rpm rps RT SANS satn SAXS SCB SCF SD SEC SEM SH SI SIS sol soln soly sp sp gr sr std TEM tex THF tlc trans TREF TW UCST uv v sol var vol vs. WAXS yr Root-mean square Rotations per minute Revolutions per second Room temperature Small-angle neutron scattering Saturation Small-angle X-ray scattering Short-chain branching Self-consistent field Spinodal decomposition Size-exclusion chromatography Scanning electron microscope Strain hardening Le Syste`me International d’Unite´s (International System of Units) Solvent-induced shift Soluble Solution Solubility Specific Specific gravity Steradian Standard Transmission electron microscopy Tex, linear density Tetrahydrofuran Thin-layer chromatography Isomer in which substituents are on opposite sides of double C ¼ C bond Temperature rising elution fractionation Glass temperature width ( C) Upper critical solution temperature Ultraviolet Very soluble Variable Volume Versus, against Wide-angle X-ray scattering Year Notation: Roman Letters A a 2365 Chemical affinity Drop curvature 2366 A2 a c, a T A j, aj as B B B, Bo C ¼ v/g_ coi c 2, C Cp Cv c 3, (3c) Dc D D D D(t, sE) d, di Dc, De DE Dr Ds(sE) dv/s E Ei E e E(t) E(t, «) E+ Ej Eij F f f(x) fO G G G Gy g g* Appendix VI: Notation and Symbols Second virial coefficient Concentration and temperature shift factors Equation constants Distance from spinodal condition; as ¼ 2[(wN)s–(wN)] Thermodynamic interaction parameter; B ¼ w12RT/V1u Mobility Extrudate swell and its value for Newtonian liquid Sprigg’s constant Universal constants in WLF equation Concentration (g/dl) Heat capacity at constant pressure Heat capacity at constant volume Number of external degrees of freedom per macromolecular segment Cahn-Hilliard diffusion constant Droplet deformability; D ¼ (l–b)/(l + b) Diffusion coefficient Tensile compliance Tensile creep compliance Diameter, diameter of ith generation of particles in polydisperse suspensions Capillary and extrudate diameter, respectively Droplet deformability in extensional flow Rotational Brownian diffusion coefficient Steady-state tensile compliance Volume-to-surface average particle diameter Elasticity of the interphase Interaction energy Tensile, or Young’s, modulus Electron Tensile relaxation modulus Tensile stress relaxation modulus Threshold energy of coagulation Activation energy Exchange energy of i-j contact Helmholtz free energy (F ¼ E—TS) Free volume fraction Function of a parameter x Onsager coefficient Gibb’s free energy (G ¼ E — TS + pV ¼ H — TS) Shear modulus (modulus of rigidity) Gravitational constant, G ¼ 6.67 3 1011 N m2/kg2 Gray Acceleration due to gravity; g ¼ 9.80621 m/s2 (see level, lat. 45 ) Concentration gradient at the interface Appendix VI: Notation and Symbols G’(v) G0 y, G00 y G(t) G(t, g) G00 (v) G*(v) H H h H(t) hc ~G H hg HG(s) hT Hz I ID, IM J J J0 (v) J(t) J(t, s) J00 (v) J*(v) J, Jo, Jc° Je Js Js(s) K K kB k kH, kM L L(t) L, L* l, b M m M, Mw, Mn Me Mn Mv Shear storage modulus Yield values for G0 and G00 Shear relaxation modulus Shear stress relaxation modulus Shear loss modulus Complex shear modulus Enthalpy Henry Hydrodynamic shielding parameter Relaxation spectrum Critical separation distance for drop coalescence Reduced Gross relaxation spectrum Partial (or specific) molar enthalpy of component g Gross frequency relaxation spectrum Vertical time-temperature shift factor Hertz Scattering intensity ratio Intensity of emission of the excimer and monomer Hear compliance Joule Shear storage compliance Shear creep compliance Shear creep compliance Shear loss compliance Complex shear compliance Creep compliance, its value at t ¼ 0 and at steady state Equilibrium shear compliance Steady-state shear compliance Steady-state compliance Bulk modulus Kelvin Boltzmann s universal constant Rate constants Huggins, Martin constants of solution viscosity Length of a dispersed particle Retardation spectrum Lamellar thickness Prolate drop half length and half width Mobility constant Strain ratio in asymmetric extension Molecular weight and its weight and number averages Entanglement molecular weight Number-average molecular weight Viscosity-average molecular weight 2367 2368 Appendix VI: Notation and Symbols Mw Ne N nD i n Weight-average molecular weight Number of polymer segments between entanglements Newton (force) Index of refraction (for 20 C and sodium light) “Power law” exponent between melt viscosity and the deformation rate First and second normal stress difference, respectively First normal stress growth function First normal stress decay function First normal stress relaxation function Second normal stress relaxation function Second normal stress growth function Second normal stress decay function Pressure Probability One-particle scatter function Anisometric particle aspect ratio and its generalized value Pascal (pressure) Entrance-exit pressure drop in capillary flow Heat received by the system Wavevector Radius, position variable radius Universal gas constant; 8.31432 J/mol deg Correlation coefficient squared, precision of data Mean square end-to-end distance Ecoil function, R(t, s) ¼ gr/s Radial position of a particle and its critical value Particle diameter-to-capillary diameter ratio Reynolds number Rao constant Trouton ratio; ratio of the extensional to shear viscosity Radius of gyration Ultimate recoil function Entropy Siemens Number of statistical segments per macromolecule Second Tensile recoil coefficient; S(t, sE) ¼ er/sE Specific molar entropy of g Initial slope of the stress growth function in uniaxial extension Specific surface area of ith particle Entropy per unit volume Temperature Time N1, N2 _ N+1 ðt; gÞ _ N1– ðt; gÞ _ N1 ðt; gÞ N2 ðt; g_ Þ N+2 ðt; g_ Þ N2– ðt; g_ Þ P P P(q) p, p* Pa Pe Q q R, r R r2 kr2l R(t, s) r, rc Rc Re RR RT Rg R‘(s) S S s s S(t, sE) sg Si si Sv T t Appendix VI: Notation and Symbols Tg Tm, Tg tp U V v vg vi VL, VS W w wi x x1 or x x2 or y x3 or z xi z 2369 Glass transition temperature Melting point; glass transition temperature Period of rotation for anisometric particles Total energy of the system Volume Specific volume Partial molar (or specific) volume of g Velocity in direction i Ultrasonic velocity; transverse and shear Heat flow (components Wi, i ¼ x, y, z) Weight fraction Weight fraction of specimen i Variable Direction of flow Direction of velocity gradient Neutral direction Mole fraction Coordination number Greek Alphabet (Lower Case, Capital Letter) a, B b, Β g, G d, D e, Ε z, Ζ Z, Η y, (W), Y k, K l, L m, M alpha beta gamma delta epsilon zeta eta theta kappa lambda mu n, Ν x, X p, P r, Ρ s, S t, Τ f, (o), F w, Χ c, C o, O Notation: Greek Letters ai 2a b12 Gij Go Thermal expansion coefficient Convergence angle Slip factor in Lin’s equation Nonrandomness parameter for ij segment placement Critical parameter for droplet breakup nu xi pi rho sigma tau phi chi psi omega 2370 g g_ c , g_ y gR g_ gr(t, s) g‘(s) D DEh DGm, DGel DHm Dl d « « «_ «b «max «r ðt; «_ Þ «‘(sE) «B/«_ B z h ho h‘ hs hr hsp [h] [h]E, [h]E,d hd, hm hi, hsi, hei happ ho,M h*(v) h0 (v) h00 (v) _ h+(t, g) _ h(t, g) h+E ðt; «_ Þ hE– ðt; «_ Þ Appendix VI: Notation and Symbols Shear strain Critical value of g_ for onset of dilatancy or yield Recoverable shear strain Shear rate Recoil strain Ultimate recoil Increment Activation energy of flow Gibbs free energy of mixing and an elastic contribution Heat of mixing Thickness of the interphase Solubility parameter Dielectric parameter Tensile Hencky strain Strain rate ( 0) Maximum Hencky strain at break Maximum filament shrinkage Tensile recoil function Ultimate tensile recoil Biaxial strain/strain rate ( 0) Correlation length; domain size Viscosity Limiting viscosity at zero shear rate, i.e., at the upper Newtonian plateau Limiting viscosity at infinite shear rate, i.e., at the lower Newtonian plateau Viscosity of solvent or of continuous medium Relative viscosity (/s) Specific viscosity (r–1) Intrinsic viscosity Emulsion and deformable droplet emulsion intrinsic viscosity, respectively Viscosity of dispersed and matrix liquid; also 1, 2, respectively Interface viscosity and its shear and extensional components Apparent viscosity Maxwellian viscosity Complex viscosity Dynamic viscosity Out-of-phase component of complex viscosity Shear stress growth coefficient Shear stress decay coefficient Tensile stress growth coefficient Tensile stress decay coefficient Appendix VI: Notation and Symbols hE hB h+B ðt; «_ B Þ hB– ðt; «_ B Þ Q q k L l l ¼ hd/hm m mi m n n, no ns, ne s sij ij sy, syc, syE sc sm _ s+(t, g) _ s (t, g) s(t, g) sE s+B ðt; «_ Þ sB– ðt; «_ Þ s E sB r t ty tz Fi f, fm fmo, fm‘ xij C(t) C1 C2 c +1 ðt; g_ Þ c +2 ðt; g_ Þ 2371 Elongational or tensile viscosity Biaxial extensional viscosity Biaxial stress growth coefficient Biaxial stress decay coefficient Scattering angle Distortion wavelength in capillary instability Ratio of rheological to interface forces; capillarity factor k ¼ sd/n Wavelength Thermal conductivity Viscosity ratio of the dispersed to the matrix phase liquids in polymer blend flow Chemical potential Chemical potential of i Poisson ratio Interfacial tension coefficient Dynamic interfacial tension coefficient and its equilibrium value Side and interfacial energies of a polymeric crystal Shear stress component of the stress tensor Yield shear stress, its value in compression and extension Critical shear stress for droplet break-up Critical shear stress for melt fracture Shear stress growth function Shear stress decay function Shear stress relaxation function Net tensile stress Tensile stress growth function Tensile stress decay function Tensile stress decay coefficient Net stretching stress Density Relaxation time Characteristic time of the yield cluster Lifetime of the density fluctuation Farris volume fraction of component i in the mixture Volume fraction; maximum packing volume fraction Maximum packing volume fraction at shear stress s ! 0 and s ! ‘ Thermodynamic interaction coefficient between species i and j Retardation function First normal stress coefficient Second normal stress coefficient First normal stress growth coefficient Second normal stress growth coefficient 2372 Appendix VI: Notation and Symbols c 1– ðt; g_ Þ c 2– ðt; g_ Þ V V v First normal stress decay coefficient Second normal stress decay coefficient Distortion wavelength Vorticity Frequency (rad/s) Subscripts Apparent Binodal Uniaxial extension Glass Counting subscript, inversion or dispersed phase Linear viscoelastic function Mixing, melt, matrix Reference variable Strain hardening Spinodal Suspension Yield app, a B E g i L m R S S s y Superscripts E L + (tilde) * Excess value Lattice gas model Stress growth function Decay function Reduced variable Complex or reducing variable Mathematical Symbols <> P p S Average Multiplication 3.1415926536 Summation Index A Acrylic blends, 1739, 1740, 1785–1789 Acrylonitrile-butadiene-styrene (ABS), 1415–1425 blends, 1739, 1769, 1774, 1811–1813, 1824, 1827, 1852 Acrylonitrile-styrene-acrylate (ASA) blends, 1845 Aerospace, 1444–1445, 1454 Aging determination of, 1359–1360 miscible blends, 1371 two phase systems, 1386 Amorphous, 295–309, 311–315, 318, 319, 325, 326, 331, 338, 340, 343, 345–347, 349–356, 359, 360, 365–368, 371–411, 418, 420, 431, 434 Applications, 1433–1454 ASA. See Acrylonitrile-styrene-acrylate (ASA) blends Automotive, 1435, 1437–1439, 1441, 1448–1452, 1454 Avrami, 325–327, 331, 333–335, 353, 365, 380, 392, 426 B Barrier films, 1162–1163 Batch, 926, 951, 958, 960–961, 985, 986, 990, 998, 1000, 1011 Bent strip ESC test, 1170–1171 Binary blends, 450, 463, 485, 486 Binary polymer blend, 1330, 1333 Biodegradable applications, 1436–1437 Biodegradable polymer blends, 124, 125, 129, 527, 1868–1874 Biomedical, 686, 709, 711–714, 717 Block copolymer, 455–459, 461, 463–465, 470, 471, 481, 485, 488, 490, 492, 494, 498, 502, 503, 505 Breakup, 927–934, 937, 944, 945, 955, 956, 978 Broadband dielectric spectroscopy, 1299–1350 C Carbon nanotube (CNT), 1532–1539, 1542–1547 Cavitation, 1214–1216, 1219–1221, 1225, 1227, 1230, 1231, 1234, 1236–1241, 1243, 1246, 1248, 1252–1257, 1260–1263, 1265, 1266, 1271, 1273–1275, 1277, 1282–1287 Chain dynamics, 1320, 1326, 1329, 1345 Charpy impact, 1054, 1057, 1129 Chlorinated polyethylene, 1402 Clay, 1487–1492, 1495–1497, 1500, 1502, 1503, 1507, 1509–1513, 1516–1523, 1540, 1542, 1546, 1547 CNT. See Carbon nanotube (CNT) Coalescence, 761, 768–769, 791, 794, 797–799, 801, 802, 805–811, 816, 817, 821–823, 826–828, 841, 925, 933, 939, 941, 944–945, 948, 954–956, 958, 989, 1011, 1012 Co-continuous morphology, 879, 889, 891, 899, 902, 915 Co-crystallization, 296, 308, 310, 311, 324, 365, 427, 434 Co-crystallized polymer blends, 1918, 2101–2105 Commercial polymer blends, 20, 123 Commodity polymer resin blends, 71–73 Compatibility, 701, 712, 715 Compatibilization, 447–509, 920, 933, 942, 946, 997–1011, 1737–1744, 1746, 1752, 1761, 1773, 1774, 1776, 1778, 1794, 1801, 1802, 1804, 1810–1812, 1814–1816, 1834, 1837–1839, 1849, 1850, 1874, 1902, 1904 strategies, 520, 521, 529, 566, 605, 640 Compatibilized blends, 1050, 1073, 1091, 1103, 1129, 1165–1168 Compatibilized polymer blend, 522, 529, 532, 533, 536, 583 L.A. Utracki, C.A. Wilkie (eds.), Polymer Blends Handbook, DOI 10.1007/978-94-007-6064-6, # Springer Science+Business Media Dordrecht 2014 2373 2374 Compatibilizer, 521, 523, 529, 530, 532, 533, 556, 559, 562, 569, 570, 573, 582, 586, 587, 596, 597, 606–608, 638, 642 Composition asymmetry, 1344 Compressive strength, 1039–1040 Concentration fluctuations, 1335–1337, 1345, 1348 Concurrent crystallization, 296, 309, 311, 365, 434 Conduction, 1309, 1312–1313 Conductivity, 1035, 1043, 1105–1107, 1127, 1140–1143, 1146–1148, 1179, 1180 Confinement effects, 1301, 1343–1345 Continuous, 922, 926, 944, 956, 958–988, 990, 998, 1004, 1011 Cooperatively rearranging region, 1324, 1336 Copolymer, 942, 943, 950, 962, 985, 989, 992–995, 1004, 1005, 1007–1009 addition, 463, 465, 467, 470, 471, 481, 484, 487, 491, 498, 501, 506 characterization, 542, 551, 554, 560, 580, 612, 615, 639 formation, 519–521, 528, 531–639, 642 homopolymer blends, 457–460 Coupling reaction, 905–906, 911, 912 Cowie-Ferguson (C-F) model, 1365, 1376 Crazing, 1205–1210, 1212, 1213, 1219, 1220, 1225–1227, 1230–1233, 1236, 1238, 1241, 1245, 1252, 1253, 1263–1269, 1273, 1277, 1284–1287 Crosslinks/crosslinking, 680, 686–688, 692, 693, 695–698, 700–702, 704–706, 709, 713, 717 Crystalline, 295, 297–312, 314, 324, 326, 334–336, 340, 341, 344, 355, 360, 366–374, 376, 378, 379, 382, 383, 386, 390–394, 396, 398, 401, 402, 406, 407, 410, 411, 417, 420, 422–430 Crystallization, 291–439, 487, 493–496, 503 Crystals, 296, 304, 309, 311–314, 316, 325, 326, 332, 336–340, 344, 345, 347, 348, 350, 357, 359, 360, 377, 378, 391, 392, 399, 411, 412, 415, 416, 422, 423, 426, 427, 429, 430, 433 Curing, 349, 350, 354, 360–365, 434 Curing reaction, 892, 895 D Damping, 686, 705–708, 710, 711, 714, 715, 717 Deformation, 923–925, 927–929, 931–934, 936–939, 949, 955, 961, 1002, 1011 Index mechanisms, 1205, 1207, 1212, 1216, 1221, 1225–1227, 1232, 1244, 1252–1288 Degradation, 1888–1890, 1893, 1895, 1897, 1899–1902, 1905 Determination of Gc, 1058–1061 Developing opportunities, 1435–1441 Dielectric relaxation, 1301, 1307–1312, 1320–1348 strength, 1144, 1150, 1178, 1304, 1306, 1311, 1322, 1325–1326, 1346 Differential scanning calorimetry, 306, 433 Dispersion, 922, 939–942, 945, 946, 948, 950, 952, 954, 956, 961, 967, 977, 987, 989, 993, 1006, 1012 Distribution, 922, 932, 938, 947, 951, 954, 956, 960, 964, 968, 975–981, 984, 997–1001, 1010 Drop, 921, 926–935, 937–946, 949, 953–958, 961–963, 989, 1012 breakup, 765–768, 799, 804, 806, 807, 816, 817 Dynamic asymmetry, 1343 Dynamic glass transition, 1311, 1322–1326, 1330–1343, 1346 Dynamic heterogeneity, 1333–1334, 1343, 1348 E Elastomeric blends, 1740, 1759–1760, 1790–1800 Electrical, 1434, 1438, 1439, 1442, 1446–1450 Electronics, 1435, 1439, 1440, 1442, 1445–1447, 1449, 1450 Elongational flows, 765, 766, 799, 811, 815, 816, 847–852 Encapsulation, 817, 822, 831 Engineering polymer resin blends, 84 Enthalpy, 1464, 1479 relaxation, 1360–1380, 1386 Entropy, 173, 174, 176–178, 180, 197, 200, 203, 207, 208, 210, 219, 227, 231, 239, 267, 1467, 1479 Equation of state, 174, 177, 179–187, 189, 204–207, 239, 240, 278 Equilibrium melting temperature, 336–340 Experimental determination of interaction parameters, 254, 256–262 Experimental techniques for interface, 483 Extension, 923, 924, 929, 936, 939, 954, 976, 988 Extrusion, 519–521, 525, 526, 530–532, 535, 536, 542–544, 546, 549, 551–553, 555, 558, 560–565, 567, 570–572, Index 2375 577–579, 582, 584, 587, 590–593, 595, 607, 611, 612, 615, 618, 622, 623, 628, 629, 631, 632, 635–638, 640, 642, 933, 951, 955, 958, 959, 962–964, 966, 968, 969, 974, 975, 979, 981, 985, 988–990, 998–1003, 1005 F Fatigue characteristics, 1042–1045 Fibrillation, 766–768, 810, 817, 822–824, 827 Fire retardancy, 1411, 1425 Flexural modulus, 1040, 1049, 1074, 1110, 1111 Flory–Huggins theory, 197–204, 239 Flow-induced orientation, 756–760 Fluid engineering, 1453 Fractionated crystallization, 393, 395–410, 418, 420, 421, 423–425, 430–435 Fracture, 1468, 1470, 1475–1477 Free energy, 173–175, 183, 194, 197, 204, 205, 207, 208, 231, 241–243, 247, 251, 255, 270, 274 of mixing, 877, 892 Frozen free volume, 184 G Gas-lattice model, 207–209 Glass transition temperature (Tg), 1093–1095, 1113, 1115, 1129, 1463, 1464, 1466, 1472, 1917 measurements, 266–271 H Healthcare, 1440–1444 Heat of mixing model/approach, 210–227, 239, 240 Heat stabilizers, 1403 High performance polymer, 1459–1481 History of polymers and their blends, 6 Hoffman Weeks, 336–340, 343, 345, 365 Horizontal burning test, 1128 I Immiscibility, 1463, 1468, 1470, 1476, 1478 Immiscible, 876, 877, 880, 886–891, 896, 905 blends, 295, 366, 372, 373, 377, 378, 389, 402, 414, 418, 422, 434, 729–731, 738, 740–779, 784, 793–852 polymer blends, 450–455, 464, 467, 468, 484, 486 Impact modification, 1753, 1754, 1770, 1779, 1804, 1805, 1814, 1839, 1843, 1867 In situ-formed copolymer, 905–911, 915 Interface, 448–471, 476, 480–493, 495, 501, 506, 922–926, 934, 938, 942–943, 998, 1001, 1011, 1012, 1476 profile, 454, 465 Interfacial polarization, 1313–1314, 1347–1348 tension, 449–452, 454, 456, 458, 460–467, 470–479, 482–487, 491, 492, 501 thickness, 451, 456, 470, 480–482, 485, 490–491 Interfibrillar, 295, 297, 299–303, 364, 365, 402, 434 Interlamellar, 295, 297, 299–304, 306, 307, 312, 313, 315, 332, 356, 364, 365, 402, 434 Interlayer slip, 756, 796, 817, 828–833, 839, 846 Interpenetrating, 677–718 Interpenetrating polymer network (IPN), 678–683, 686, 687, 690–693, 697, 700–702, 704–709, 711, 713–717 Interphase, 447–509, 727, 729, 735–739, 741, 753, 761, 764, 768, 773, 778, 828, 830, 838, 839, 920, 941–944 Interpolymer complexes, 1916 Inverse gas chromatography, 1076, 1093, 1100 IPN. See Interpenetrating polymer network (IPN) Izod impact, 1050–1054, 1069–1071, 1074, 1076, 1077, 1168 J J-integral techniques, 1061–1066 K Kohlrausch, Williams, and Watts (KWW) function, 1382 L Lamellae, 299, 300, 304, 307, 314, 316, 325, 342, 344, 345, 347, 348, 378, 382, 383, 390, 394, 402, 406, 408, 410 Lamellar morphology, 1034, 1167, 1168 Latex interpenetrating polymer network (LIPN), 701–708, 710 Laws of thermodynamics, 175–177 LCP. See Liquid crystal polymer (LCP) LCST. See Lower critical solution temperature (LCST) Light scattering (LS), 192, 193, 239, 257, 261, 263, 264, 278 2376 LIPN. See Latex interpenetrating polymer network (LIPN) Liquid crystal polymer (LCP), 1462, 1467–1470, 1472, 1473, 1475 Localized fluctuations, 1300, 1330 Lower critical solution temperature (LCST), 877, 878, 880–885, 888, 893 behavior, 1916 Luminous transmittance, 1149 M Mechanical, 1486, 1488, 1489, 1497, 1500, 1512, 1513, 1520, 1524, 1530, 1532, 1533, 1544–1547 properties, 1225–1290 relaxation, 1381–1385 Mechanisms of phase separation, 244–252 Melting, 291–439 Melt processing, 519, 522, 525, 528, 536, 541, 550, 584, 630, 642 Microrheology, 733, 741, 746, 762–769, 790, 794, 799–817, 821, 851 Microstructure, 296 Miscible, 877, 888, 890–892, 905, 914, 915 blends, 294–297, 300, 307–309, 313, 319, 324–325, 327, 329, 336–349, 351, 353, 360, 362, 363, 365, 375, 402, 434, 729, 730, 738–740, 779–793, 831, 1468, 1478 polymer blends, 1915–2105 Mixing, 920–964, 967–989, 998–1001, 1010–1012 Modulus, 1469, 1473–1475, 1477 Molecular composite, 1471, 1474, 1478 Morphology, 686–693, 697, 699–705, 707–710, 920, 922, 927, 933, 940–942, 947–958, 963, 967, 968, 977, 984, 985, 991–995, 1002, 1003, 1006, 1486–1490, 1492–1497, 1504, 1513, 1515, 1516, 1520–1522, 1525–1528, 1531, 1532, 1534–1539, 1543, 1546, 1547 control of polymer blend, 876, 915 development, 550, 551, 561, 562, 569, 572, 577, 580, 596, 621, 634, 642, 643 N Nanocomposites, 1412, 1413, 1417 Nanoparticles, 430–434, 1485–1548 Networks, 677–718 NMR methods for polymer blends, 271 Noise reduction, 1156–1159 Non-Newtonian flows, 769–777 Index Nucleating agent, 1117–1119, 1125–1127, 1152 Nucleation and growth (NG), 245, 250–252, 877, 899 O Outlook, 1453–1454 Oxygen scavenger blends, 1741, 1849 P PA. See Polyamides (PA) Packaging, 1434, 1436, 1438, 1449, 1451–1453 PALS. See Positron Annihilation Lifetime Spectroscopy (PALS) Permeability coefficient (P), 1160–1162 Permittivity, 1143–1145, 1178 Petrie–Marshall (P-M) model, 1365, 1376 Phase, 681–683, 686–693, 696, 699–702, 704–707, 709, 711, 714–716 co-continuity, 730–735, 789 diagrams, 172, 180, 187, 189, 190, 197–200, 232, 233, 241–244, 252–258, 262–266, 268–270, 274, 1464 equilibria, 249, 254, 256, 263, 265 separation, 197, 203, 239, 241–255, 257, 262, 263, 265, 266, 274, 277, 295, 324, 344, 345, 349, 355, 357, 358, 360, 362–364, 768, 778–780, 782, 784, 786–793, 798, 804, 805, 831, 844 Phosphorus-based fire retardants, 1418, 1420 Physical aging, 1357–1391 PO. See Polyolefins (PO) Polarization, 1302–1309, 1313–1314, 1319, 1335, 1347–1348 Poly(methyl methacrylate) (PMMA), 1399–1401 Poly(vinyl chloride) (PVC), 1396, 1398–1409 Polyamides (PA), 1396, 1422–1425 blends, 522, 542–580, 1740, 1751–1752, 1773–1774, 1776, 1800–1823, 1837, 1854 Polycarbonate blends, 1741, 1743, 1771–1772, 1819–1820, 1823–1834, 1842 Polyester blends, 545, 580–612 Polyetherimide blends, 588–589 Polyethylene (PE), 1402, 1410–1413, 1559–1716 Polymer, 677–718 alloys, 20, 26, 29, 36–37, 43 miscibility, 1301, 1327–1329, 1333, 1345, 1346 Index nomenclature, 15–19 recycling, 127 Polymerization reaction, 892 Polymer reference interaction site model (PRISM), 238–239, 278 Polyolefins (PO), 1396, 1398, 1409–1413, 1420, 1563, 1566, 1572, 1584, 1607–1608, 1610–1616, 1618, 1636, 1646, 1667–1669, 1671–1676, 1678, 1679, 1681–1716 blends, 527, 545, 547–558, 589–599, 612–613, 615–639, 1739, 1747–1763, 1793 Polyoxymethylene blends, 1835–1836 Polyphenylene ether (PPE) blends, 560–567, 601–605, 612–615, 621–622, 1738, 1741, 1743, 1818, 1820, 1836–1840 Polyphenylene sulfide blends, 568, 605, 614, 639 Polypropylene (PP), 1410–1413, 1423–1425, 1560, 1565, 1568, 1617, 1668–1670, 1672, 1674, 1676–1678, 1681, 1682, 1687, 1688, 1691, 1693–1703, 1705–1707, 1712, 1713 Polystyrene (PS), 1399, 1406–1409, 1413, 1414 Polystyrene or styrene copolymer blends, 573–580, 630–640 Positron annihilation lifetime spectroscopy (PALS), 1368, 1369, 1379, 1385, 1386 PPE. See Polyphenylene ether (PPE) blends PRISM. See Polymer reference interaction site model (PRISM) Pull-in, 905, 909–911 Pull-out, 905, 907–909 PVC. See Poly(vinyl chloride) (PVC) PVT relationships, 179–187, 205 R Reaction-induced phase separation (RIPS), 891–905, 914, 915 Reactive, 920, 942, 950, 955, 957–959, 972, 974, 975, 977–980, 983, 990, 997–1011 blend/blending, 642, 915 compatibilization, 517–647 Recycling, 1438, 1441, 1449, 1453, 1885–1909 Refractive index, 1066, 1067, 1098, 1149–1152, 1155, 1179 Reinforced, 1436, 1440–1441 Reinforcement, 1468, 1469, 1473, 1474 Relaxation rate, 1311, 1322–1327, 1333, 1339 2377 Renewable resources, 1436–1437, 1453 Resistivity, 1105, 1140–1148, 1150, 1180, 1181 Rheology, 725–857, 920, 922, 927, 994, 1002, 1003 RIPS. See Reaction-induced phase separation (RIPS) Rockwell hardness, 1040–1042, 1044, 1179 S SANS. See Small angle neutron scattering (SANS) SD. See Spinodal decomposition (SD) Segmental dynamics, 1306, 1323, 1340, 1343–1345, 1348 Self-concentration, 1328, 1335, 1337–1343, 1345, 1348 Semicrystalline morphology, 292, 295, 304–308, 354–356, 366, 372, 375, 386, 389–391, 393, 424, 427 Semi-interpenetrating network, 1470, 1476–1478 Separation of phase. See Phase, separation Shear, 921, 923–929, 931–942, 944, 945, 947, 951, 953, 954, 959, 961, 968, 969, 973–982, 985, 986, 1002, 1006, 1011, 1012 flow, 741, 747, 749, 753, 756, 765, 766, 776, 788–790, 793, 794, 796, 799, 801, 803, 804, 806–808, 811, 816, 818, 822, 826, 830–847, 851, 852 flow effect for phase diagram, 891, 914 induced mixing, 880, 884, 885 yielding, 1205–1207, 1209–1213, 1215, 1216, 1220, 1226, 1227, 1229–1233, 1236, 1238, 1240, 1241, 1244, 1252, 1253, 1255, 1257–1261, 1265–1269, 1277, 1280, 1283–1288 Silica, 1525–1532, 1539–1540, 1544, 1545 Small angle neutron scattering (SANS), 196, 200, 201, 204, 209, 217, 218, 239, 254–259, 263 Solubility parameters, 174, 219, 227–238, 240, 255 Solvent, 948, 983, 989–997, 999, 1006 resistant polymer blends, 845 Specialty polymer blends, 1741, 1850–1857, 1874 Specialty polymer resin blends, 37, 75–76, 83–84, 87, 95–98 Specific interactions, 1916 Spherulites, 295–297, 299, 300, 304, 307, 309, 312–319, 322, 323, 333, 345, 347, 355, 357–360, 363–366, 2378 372, 373, 378–387, 389, 391–394, 397, 402, 411–414, 419, 426, 430 Spinodal decomposition (SD), 245–250, 877, 889, 890, 892, 914 Stress relaxation, 1374, 1382–1384, 1386 Strong interactions model, 209–210 Styrenic blends, 1739, 1763–1779, 1785, 1837 T Tensile properties, 1037–1039, 1048–1050, 1052, 1074 Ternary polymer blends, 2072, 2078 Theoretical characteristics of interface, 450–471 Thermal degradation, 1398–1401, 1404, 1406, 1407, 1411, 1413, 1415, 1416, 1418, 1420–1422, 1425 Thermal properties of polymer blends Thermodynamics, 726, 730, 735, 736, 738, 747, 749, 768, 777, 787–793, 796–800, 816, 830, 838, 852, 1463, 1470, 1476 potentials, 173–175 Thermoplastic, 680, 686, 692, 693, 698, 705, 709–711, 717 polyester blends, 1828–1833, 1840–1850 polymer blends, 57 Thermoplastic elastomers (TPEs), 1438–1440 Thermoplastic polyolefin (TPO) blends, 1739, 1754–1758 Thermoplastic vulcanizate (TPV) blends, 1791–1800 Index Thermoset blends, 1858–1868 Thermosetting, 349–356, 360–365, 434 Time–temperature superposition, 779–781, 784, 789, 842–844 Tool–Narayanaswamy–Moyniha (TNM) model, 1363, 1369 Toughening, 1204, 1216, 1217, 1220–1253, 1255, 1261, 1266–1268, 1270, 1271, 1273, 1275–1278, 1281–1283, 1286, 1287 Toughness, 1488, 1495–1500, 1505–1507, 1510, 1511, 1513, 1516, 1517, 1520, 1522–1524, 1526, 1527, 1530, 1534, 1537, 1538, 1544, 1546, 1547 TPEs. See Thermoplastic elastomers (TPEs) TPO. See Thermoplastic polyolefin (TPO) blends TPV. See Thermoplastic vulcanizate (TPV) blends Turbidity measurements, 254, 262–263 U Upper critical solution temperature (UCST), 877, 878, 880, 885–886, 892, 893 behavior, 1916, 1918, 2077 V Vertical burning test, 1128–1136 Vinyl resin blends, 1779–1785 Volume relaxation, 1379–1382
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