Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 Page 1 of 11 Part-no. 93165267 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product group: Others Catalogue-no.: 15 03 305 Dichtungsmasse Sealing compound Matériau d‘étanchéité 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Used in the automobile industry. For processing instructions, please see annex safety data sheet. 1.3. Details of the supplier of the safety data sheet Company name: Adam Opel AG Place: D 65423 Rüsselsheim Telefax: +49-6142/ 749-503 e-mail: Responsible Department: [email protected] IFZ Ingenieurbüro und Consulting GmbH Telefon: +49 30 2904897-10 Telefax: +49 - 30 / 2904897-20 Internationale Hotline: +49 6131 19240 United Kingdom +44 870 600 626 / 0870 600 6266 1.4. Emergency telephone number: Further Information No more data. SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Regulation (EC) No. 1272/2008 Hazard categories: Serious eye damage/eye irritation: Eye Irrit. 2 Hazard Statements: Causes serious eye irritation. 2.2. Label elements Regulation (EC) No. 1272/2008 Signal word: Warning Pictograms: Hazard statements H319 Causes serious eye irritation. Precautionary statements P262 Do not get in eyes, on skin, or on clothing. P264 Wash hands / face thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Revision No: 1,25 GB - EN Revision date: 04.10.2016 Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 P305+P351+P338 P337+P313 Page 2 of 11 Part-no. 93165267 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Special labelling of certain mixtures EUH208 Contains 3-Aminopropyltriethoxysilane. May produce an allergic reaction. 51 % of the mixture consists of ingredient(s) of unknown acute toxicity. The product hardens in the presence of moisture and gives off methanol . Provide adequate ventilation and/or an exhaust system. See safety data sheet for further information. Additional advice on labelling The product is classified and labelled in accordance with the EC directives or respective national laws. 2.3. Other hazards Contains epoxy constituents. See information supplied by the manufacturer. On contact with water or humidity formation of: methanol (Highly flammable. Toxic by inhalation, in contact with skin and if swallowed.). SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization Contains calcium carbonate. The product hardens in the presence of moisture and gives off methanol . Hazardous components CAS No Chemical name EC No Quantity Index No REACH No Classification according to Regulation (EC) No. 1272/2008 [CLP] 2768-02-7 Trimethoxyvinylsilane 1 -< 3 % 220-449-8 01-2119513215-52 Flam. Liq. 3, Acute Tox. 4, STOT RE 2; H226 H332 H373 2530-83-8 [3-(2,3-Epoxypropoxy)propyl]- trimethoxysilane <2% 219-784-2 Eye Dam. 1; H318 67-56-1 Methanol 200-659-6 < 1.0 % 603-001-00-X Flam. Liq. 2, Acute Tox. 3, Acute Tox. 3, Acute Tox. 3, STOT SE 1; H225 H331 H311 H301 H370 ** 919-30-2 3-Aminopropyltriethoxysilane <1% 213-048-4 Acute Tox. 4, Skin Corr. 1B, Skin Sens. 1; H302 H314 H317 Full text of H and EUH statements: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General information In case of feeling unwell: Obtain medical attention. Show this safety data sheet to the doctor in attendance. If unconscious, place the person in the recovery position and seek medical advice immediately. Do not administer liquids to the unconscious person and avoid vomiting. Revision No: 1,25 GB - EN Revision date: 04.10.2016 Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 Page 3 of 11 Part-no. 93165267 Protection is needed for the First Aider. (protective gloves, chemical-resistant; safety glasses) When vapors or aerosols: Use breathing apparatus. Eye wash fountains and safety showers must be easily accessible. After inhalation Remove the victim into fresh air. In case of irregular breathing or respiratory arrest: Oxygen or artificial respiration, if needed. Lay the affected person down, and keep her or him warm and calm. If symptoms persist, call a physician. After contact with skin Wash off with soap and plenty of water immediately. Remove all contaminated clothes and shoes. In the case of skin irritation or allergic reactions see a physician. After contact with eyes Rinse with plenty of water immediately, also under the eyelids, for at least 15 minutes. Protect unharmed eye. Remove contact lenses after the first 1 - 2 minutes and continue flushing. Consult an ophthalmologist immediately. Eye wash. After ingestion Clean mouth with water and drink plenty of water afterwards. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Call a physician immediately. 4.2. Most important symptoms and effects, both acute and delayed Severe eye irritation, irritation of the respiratory tract. May cause skin irritation. May produce an allergic reaction. Methanol: May cause: Conjunctivitis, dizziness, insomnia, gastrointestinal disturbance, visual disturbances. 4.3. Indication of any immediate medical attention and special treatment needed Symptomatic treatment (decontamination and vital functions). If necessary, contact poisson centre. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Carbon dioxide (CO2), dry powder, sprayed water stream. Use a sprayed water stream to fight a large fire. (or alcohol-resistant foam) Unsuitable extinguishing media High volume water jet. 5.2. Special hazards arising from the substance or mixture The product is combustible. Burning produces obnoxious and toxic fumes. In the event of a fire, the following substances may be formed: silicon dioxide, carbon monoxide (CO) and carbon dioxide (CO2), traces of incompletely burned hydrocarbons, nitrogen oxides (NOx), formaldehyde. The inhalation of hazardous decomposition products may cause serious health damage. 5.3. Advice for firefighters In the event of fire, wear self-contained breathing apparatus. Full protective flameproof clothing. Clothing for firefighters which comply with the European norm EN 469 (including helmet, protective boots, protective gloves) provide a basic protection for accident with chemicals. Avoid contact with this material during fire fighting operations . If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. Additional information The combustion gases are partially condensed with the water used to extinguish the fire and end up as a contaminant in this water. Contaminated extinguishing water and soil must be disposed of in accordance with official regulations. SECTION 6: Accidental release measures Revision No: 1,25 GB - EN Revision date: 04.10.2016 Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 Page 4 of 11 Part-no. 93165267 6.1. Personal precautions, protective equipment and emergency procedures Provide adequate ventilation and/or exaust ventilation. Remove all sources of ignition. Wear personal protective equipment. Avoid contact with skin and eyes. Do not breathe in vapours. Keep unprotected people away. Slipping hazard due to leakage. 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. 6.3. Methods and material for containment and cleaning up Prevent further leakage or spillage if safe to do so. Take up mechanically and collect in suitable container for disposal. Dispose of the material collected according to regulations. 6.4. Reference to other sections See also section 8, 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling After use: Containers keep tightly closed. Provide sufficient air exchange and/or exhaust in work rooms. Do not inhale large amounts of the vapours released at the beginning of the curing process (contact with humid air). Avoid contact with skin, eyes and clothing. Avoid spillage and leakage due to the risk of slipping . Wear suitable protective clothing. See section 8. Wash hands and face before breaks and immediately after handling the product. Wash contaminated skin areas thoroughly with soap and water . Advice on protection against fire and explosion Keep product and empty container away from heat and sources of ignition. Do not smoke. Take precautionary measures against static discharges. Use a spark-free tool. Do not burn, or use a cutting torch on the empty drum. Further information on handling Contains epoxy constituents. See information supplied by the manufacturer. 7.2. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Store in original container. Pay attention to storage conditions on the label. Keep containers tightly closed in a cool, well-ventilated place. Keep in a dry place. Keep away from open flames, hot surfaces, and sources of ignition. The product may only come into contact with suitable materials. Store product upright. Do not drop. Avoid shock and friction. Always keep in containers made from the same material as the original one. Do not re-use empty containers. Advice on storage compatibility Protect from humid air and water. The product hardens in the presence of moisture and gives off methanol. Further information on storage conditions Protect from heat and direct sunlight. Smoking in the storage rooms is forbidden. Total storage period: 12 months / Storage temperatures (°C): +25 7.3. Specific end use(s) No data available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Revision No: 1,25 GB - EN Revision date: 04.10.2016 Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 Page 5 of 11 Part-no. 93165267 Exposure limits (EH40) CAS No Substance 1317-65-3 Calcium carbonate, respirable 67-56-1 Methanol ppm mg/m³ - fibres/ml Category Origin 4 TWA (8 h) WEL - - STEL (15 min) WEL 200 266 TWA (8 h) WEL 250 333 STEL (15 min) WEL Additional advice on limit values The product hardens in the presence of moisture and gives off methanol. 8.2. Exposure controls Appropriate engineering controls Use product only in closed system. Provide adequate ventilation and/or exaust ventilation. Follow the maximum workplace concentration values. If necessary: Local exhaust. Personal protection equipment should comply with the relevant standards, be suitable for purpose, in good condition and maintained as specified. Eye wash Protective and hygiene measures When using, do not eat, drink, or smoke. Keep away from food, drink, and animal food stuffs. Avoid contact with skin and eyes. Do not breathe in vapours. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Remove and wash contaminated clothing before re-use. Contaminated work clothing should not be allowed out of the workplace. Eye wash fountains and safety showers must be easily accessible. Eye/face protection Tightly fitting safety goggles (EN 166) / facial protection. Hand protection Protective gloves, chemical-resistant (EN 374). The manufacturer recommends the following glove materials: butyl rubber. Penetration time of the glove material: > 480 min. Safety gloves should be selected for the actual conditions of use and in accordance with the instructions for use provided by the manufacturer. Please note that the daily use of a chemical glove in practice may be considerably shorter than the permeation time calculated in EN 374 as a result of many different factors (for example temperature). Use tested protective gloves. Protective gloves should be replaced immediately if damaged or in case of signs of wear. Skin protection Wear suitable protective clothing. No rings, watches or similar things should be worn. Product residues can remain and, therefore, can trigger skin reactions. If necessary: Clean thoroughly. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Respiratory protection Only use in well-ventilated areas. Use respiratory equipment when gases, vapours/aerosols form. When the concentration in the air is over the maximum occupational exposure limit, an approved respiratory protection apparatus must be worn. Methanol: Respirator with AX filter - EN 14387 (organic vapours - Boiling point/range < 65°C). In the case of dust or aerosol formation use respirator with filter model A -P2 (according to EN 14387). Environmental exposure controls No data available. Revision No: 1,25 GB - EN Revision date: 04.10.2016 Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 Page 6 of 11 Part-no. 93165267 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: paste grey alcoholic Test method pH-Value: n.a. Changes in the physical state Melting point: n.a. Initial boiling point and boiling range: n.a. Flash point: Sustaining combustion: 63 °C No data available Flammability Solid: No data available. No data available. Gas: Explosive properties No data available. Lower explosion limits: Upper explosion limits: No data available. No data available. Ignition temperature: > 200 °C see below Auto-ignition temperature Solid: Gas: n.a. n.a. Decomposition temperature: No data available. (See section 10.) Oxidizing properties No data available. Vapour pressure: No data available. Density (at 25 °C): 1.24 g/cm³ (water = 1) Water solubility: insoluble Solubility in other solvents No data available. Partition coefficient: No data available. Viscosity / dynamic: (at 25 °C) 300000 mPa·s Vapour density: No data available. (air = 1) Evaporation rate: No data available. 9.2. Other information Solid content: No data available. The product is not self-igniting. Odour threshold value: No data available. SECTION 10: Stability and reactivity Revision No: 1,25 GB - EN Revision date: 04.10.2016 Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 Page 7 of 11 Part-no. 93165267 10.1. Reactivity On contact with water or humidity formation of: methanol. 10.2. Chemical stability Stable under proper storage and handling. 10.3. Possibility of hazardous reactions No dangerous reactions occur under normal storage conditions and in normal use. 10.4. Conditions to avoid Protect from humid air and water. The product hardens in the presence of moisture and gives off methanol. 10.5. Incompatible materials acids, alkalies, water, strong oxidizers 10.6. Hazardous decomposition products Possible decomposition products in case of hydrolysis are: methanol. Decomposes on heating. (at high temperatures) Thermal decomposition can lead to release of irritating gases and vapours. Small amounts of formaldehyde are formed in the presence of air at temperatures above approx. 150°C due to oxidative decomposition. See also section 5. Further information No decomposition if stored and applied as directed. SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicocinetics, metabolism and distribution No data available. Acute toxicity No data is available on the product itself. The following toxicological assessments are based on the toxicological knowledge of the separate components of the product. Methanol: LC50/inhalative/rat: 64000 ppm/4h CAS No Chemical name Exposure route 2768-02-7 67-56-1 919-30-2 Dose Species Source Trimethoxyvinylsilane inhalative vapour LC50 2773 mg/l inhalative aerosol ATE 1.5 mg/l oral LD50 5628 mg/kg rats dermal LD50 15800 mg/kg rabbit inhalative (4 h) vapour LC50 85.26 mg/l rats inhalative aerosol ATE 0.5 mg/l ATE 500 mg/kg Methanol 3-Aminopropyltriethoxysilane oral Irritation and corrosivity Revision No: 1,25 GB - EN Revision date: 04.10.2016 Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 Page 8 of 11 Part-no. 93165267 Causes serious eye irritation. Trimethoxyvinylsilane: The volatile by-products released during the processing may irritate the eyes and respiratory tract. Prolonged or repeated skin contact can have an irritating effect . Sensitising effects May produce an allergic reaction. (3-Aminopropyltriethoxysilane) Contains compounds which contain epoxide. May produce an allergic reaction. Carcinogenic/mutagenic/toxic effects for reproduction No data available. STOT-single exposure No data available. STOT-repeated exposure Ingestion: More severe effects (bladder) if excessive exposure. Aspiration hazard No data available. Additional information on tests On contact with water or humidity formation of: methanol. Toxic by inhalation, in contact with skin and if swallowed. Toxic: danger of very serious irreversible effects through inhalation , in contact with skin and if swallowed. Small amounts of formaldehyde are formed in the presence of air at temperatures above approx. 150°C due to oxidative decomposition. In the case of inhalation formaledyde vapours are harmful to health with concentrations of less than 1ppm. They can irritate the eyes and the respiratory system. Formaldehyde: Toxic by inhalation, in contact with skin and if swallowed. Causes severe caustic burns to skin and eyes. Risk of serious damage to eyes. May produce an allergic reaction. May cause genetic defects. May cause cancer. The following symptoms can occur after inhalation: cough, lung edema. Symptoms may be delayed. SECTION 12: Ecological information 12.1. Toxicity No data is available on the product itself. CAS No Chemical name 2768-02-7 Trimethoxyvinylsilane Aquatic toxicity 67-56-1 [h] | [d] Species Dose Acute fish toxicity LC50 191 mg/l 96 h Oncorhynchus mykiss Acute algae toxicity ErC50 > 100 mg/l 72 h - Acute crustacea toxicity EC50 > 100 mg/l 48 h Daphnia magna Acute fish toxicity LC50 15400 mg/l 96 h Lepomis macrochirus Acute crustacea toxicity EC50 > 10000 mg/l 48 h Daphnia magna Source Methanol 12.2. Persistence and degradability No data available. 12.3. Bioaccumulative potential Partition coefficient n-octanol/water CAS No Chemical name 67-56-1 Methanol Revision No: 1,25 Log Pow -0.77 GB - EN Revision date: 04.10.2016 Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 Page 9 of 11 Part-no. 93165267 12.4. Mobility in soil No data available. 12.5. Results of PBT and vPvB assessment No data available. 12.6. Other adverse effects Contains no organically bonded halogens (AOX), nitrates, heavy metal compounds and formaldehyde. Further information Water-endangering to a small extent. Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. SECTION 13: Disposal considerations 13.1. Waste treatment methods Advice on disposal Disposal in accordance with the official regulations . Hazardous waste incineration. Must be incinerated in a suitable incineration plant authorised under the Environmental Protection Act . Must not be disposed of with domestic waste. Do not let product enter drains. Waste disposal number of waste from residues/unused products WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic 070216 rubber and man-made fibres; waste containing hazardous silicones Classified as hazardous waste. Waste disposal number of used product WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic 070216 rubber and man-made fibres; waste containing hazardous silicones Classified as hazardous waste. Waste disposal number of contaminated packaging WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND 150110 PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste); packaging containing residues of or contaminated by hazardous substances Classified as hazardous waste. Contaminated packaging Disposal in accordance with the official regulations . Empty containers should be transported/delivered using a registered waste carrier for local recycling or waste disposal. Dispose of non-cleansing packaging in the same way as the product. Suitable cleaning agents: alcohol. SECTION 14: Transport information Land transport (ADR/RID) 14.1. UN number: not regulated 14.2. UN proper shipping name: not regulated 14.3. Transport hazard class(es): not regulated 14.4. Packing group: not regulated Other applicable information (land transport) Not classified as dangerous regarding transport regulations. Inland waterways transport (ADN) 14.1. UN number: not regulated 14.2. UN proper shipping name: not regulated 14.3. Transport hazard class(es): not regulated Revision No: 1,25 GB - EN Revision date: 04.10.2016 Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 14.4. Packing group: Part-no. 93165267 Page 10 of 11 not regulated Other applicable information (inland waterways transport) Not classified as dangerous regarding transport regulations. Marine transport (IMDG) 14.1. UN number: not regulated 14.2. UN proper shipping name: not regulated 14.3. Transport hazard class(es): not regulated 14.4. Packing group: n.d.a. Other applicable information (marine transport) Not classified as dangerous regarding transport regulations. Air transport (ICAO-TI/IATA-DGR) 14.1. UN number: not restricted 14.2. UN proper shipping name: not restricted 14.3. Transport hazard class(es): not restricted 14.4. Packing group: n.d.a. Other applicable information (air transport) Not classified as dangerous regarding transport regulations. 14.5. Environmental hazards ENVIRONMENTALLY HAZARDOUS: no 14.6. Special precautions for user Not classified as dangerous regarding transport regulations. 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code No data available. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information Additional information No Substances of Very High Concern (SVHC) according REACH Articel 57. National regulatory information Employment restrictions: Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC). Additional information The national regulations have to be complied with as necessary. 15.2. Chemical safety assessment Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Changes Section: 2, 4, 7, 8, 11, 13 Abbreviations and acronyms n.a. = not applicable n.d. = not determined n.d.a. = no data available ATE = Acute Toxicity Estimate VOC = Volatile organic compounds Revision No: 1,25 GB - EN Revision date: 04.10.2016 Adam Opel AG Safety Data Sheet according to Regulation (EC) No 1907/2006 Sealing compound Print date: 05.10.2016 Page 11 of 11 Part-no. 93165267 SVHC = substance of very high concern REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006 GHS = Globally Harmonized System CLP = Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 Relevant H and EUH statements (number and full text) H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H370 Causes damage to organs. H373 May cause damage to organs (bladder) through prolonged or repeated exposure if swallowed. EUH208 Contains 3-Aminopropyltriethoxysilane. May produce an allergic reaction. Further Information The information is based on present levels of our knowledge. It does not, however, give assurances of product properties and establishes no contract legal rights. The product is to be used exclusively for the applications named in the technical data sheet or in the processing instructions. The receiver of our product is singularly responsible for adhering to existing laws and regulations. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.) Revision No: 1,25 GB - EN Revision date: 04.10.2016 Product information Sealing compound 93165267 – 15 03 305 The product is an RTV (room temperature vulcanizing) silicone liquid gasket developed for flange surfaces that have to withstand extreme vibrations, such as valve covers, oil sumps, water pumps etc. Excellent chemical resistance to engine coolant and engine oil. Application The product shows excellent adhesion even on slightly soiled surfaces. In order to achieve optimum results, however, humidity, grease and other dirt should be removed from the mating surface. According to the joint conditions (width, roughness depths, bumps, etc.), apply a suitable quantity of the silicone evenly on the mating surface and join, position correctly and fix the parts within a period of ten minutes. Excess material can easily be removed with a piece of cloth. The degree of hardening of the silicone varies depending on the layer thickness, the ambient temperature and relative humidity. At +25°C and 55 % relative humidity, the surface starts drying after 15 minutes. Immediate leak tightness for pressure and engine tests is achieved. The application temperature range is in a range of -60°C to +200°C. Special instructions Storage 12 months at +25°C Keep away from direct sun, moisture and heat and store in a well-ventilated place. Safety For handling our products please refer to the instructions on our safety data sheet at www.ifz-berlin.de and the safety instructions on the product label. The receiver of our product is singularly responsible for adhering to existing laws and regulations. 11/25/2013 Adam Opel AG, D-65423 Rüsselsheim, Germany Page | 1 Please note: The data provided above are only intended for general information. Due to the processing, application and storage conditions outside our sphere of influence and the large number of different materials, we provide no guarantee for specific application results.
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