Content of the thesis - Hiroshima University

学位論文要約
Construction of Sequence-Controlled Supramolecular Polymers
Formed by Unique Molecular Recognition
(特異な分子認識により配列制御された超分子ポリマーの合成)
平尾 岳大
Department of Chemistry, Graduate School of Science, Hiroshima University
Content of the thesis
Chapter I General Introduction
I-1 Supramolecular Chemistry
I-2 Supramolecular Polymers
I-3 Overview of the Present Thesis
I-4 References
Chapter II Supramolecular Fullerene Polymers and Networks
II-1 Introduction
II-2 Synthesis of di- and tritopic host molecules and dumbbell-shaped fullerenes
II-3 Molecular Association of calix[5]arene hosts and dumbbell-shaped fullerenes
II-4 Supramolecular polymerization of di- and tritopic hosts
and dumbbell-shaped fullerenes
II-5 Morphologies of supramolecular polymers in the solid state
II-6 Conclusion
II-7 Experimental
II-8 References
Chapter III Supramoelcular Porphyrin Polymers
III-1 Introduction
III-2 Synthesis of heteroditopic monomers
III-3 Host-guest complexation between bisporphyrin and TNF of
heteroditopic monomer
III-4 Supramolecular polymerization of heteroditopic monomer
III-5 Morphology of supramolecular polymers in the solid state
III-6 Conclusion
III-7 Experimental
III-8 References
Chapter IV Supramoelcular Porphyrin Networks
IV-1 Introduction
IV-2 Supramolecular polymerization of heteroditopic
Zn(II)bisporphyrin monomer
IV-3 Supramolecular cross-linking of porphyrin
supramolecular polymer
IV-4 Elastic properties of cross-linked supramolecular polymer
IV-5 Morphological study in the solid state
IV-6 Conclusion
IV-7 Experimental
IV-8 References
Chapter V Sequence-Regulated Supramolecular Terpolymer
V-1 Introduction
V-2 Synthesis of monomers
V-3 Specific host-guest complexation
V-4 Formation of supramolecular terpolymer
V-5 Morphological study in the solid state
V-6 Conclusion
V-7 Experimental
V-8 References
Acknowledgements
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