Ꮩ❧䛥䜜䛯ȧඹᙺ⣔㧗ศᏊ Keyword : ඹᙺ⣔㧗ศᏊ䚸᭷ᶵ䜶䝺䜽䝖䝻䝙䜽䝇 ⊂❧⾜ᨻἲே㻌 ≀㉁䞉ᮦᩱ◊✲ᶵᵓ ᄂᆮỉ Ꮡ ඹᙺ⣔㧗ศᏊࡣࠊ᭷ᶵ࢚ࣞࢡࢺࣟࢽࢡࢫࡢศ㔝࡛㠀ᖖ㔜せ࡞≀㉁࡛࠶ࡿࠋ ඹᙺ⣔㧗ศᏊ䛾≀ᛶ䞉ᶵ⬟䛿䚸㧗ศᏊ㙐㛫䛾㟁Ꮚⓗ䛺┦స⏝䛻䛝䛺ᙳ㡪䜢ཷ䛡䜛䚹 ᄂᆮỉ ཀྵẟ ᮏ◊✲䛷䛿䚸ඹᙺ⣔㧗ศᏊ䜢ศᏊ䝺䝧䝹䛷⿕そ䛧䚸㧗ศᏊ㙐㛫䛾㟁Ꮚⓗ䛺┦స⏝䜢 䛻㐽嚙䛩䜛䛣䛸䛻䜘䛳䛶䚸ඹᙺ⣔㧗ศᏊ1ᮏ䛾≀ᛶ䞉ᶵ⬟䜢ᘬ䛝ฟ䛩䛣䛸䜢≺䛳䛯䚹 இέᇢᄂᆮἚἦἕἁἋ 㧗ศᏊ䠍ᮏ䠍ᮏ䜢Ꮩ❧ 䛩䜛䛣䛸䛷䚸䠄䠍䠅䝣䜱䝹䝮 ≧ែ䛷䛾Ⓨග≉ᛶ䚸䠄䠎䠅 ᡂᙧ䞉ຍᕤᛶ䚸䠄䠏䠅䝤䝺 䞁䝗ᛶ䚸䛻ඃ䜜䛯ඹᙺ ⣔㧗ศᏊ䛜ᚓ䜙䜜䛯䚹 䝫䝸䝏䜸䝣䜵䞁䠍ᮏ䜢⿕ そ䛩䜛䛣䛸䛷䚸䝫䝸䝏䜸䝣 䜵䞁䠍ᮏ䛾୰䛷Ⓨ⏕䛩䜛 䜻䝱䝸䜰✀䛾≉ᐃ䛸䛭䛾 ⛣ືᗘ䛾Ỵᐃ䛻ᡂຌ䛧 䛯䚹 ૨ᴾ ྂᴾ 㻌 㻌Angew. Chem. Int. Ed. 2013, 52, 10775. 㻌 J. Am. Chem. Soc. 2010, 132, 14754. 㻌 㧗ศᏊ, 2014, 63, 227. LJƱNJ ܱဇ҄ƷႸ z Ꮩ❧䛥䜜䛯ඹᙺ⣔㧗ศᏊ䛾ྜᡂ䛻ᡂຌ䛧䛯㻌 z Ꮩ❧䛥䜜䛯ඹᙺ⣔㧗ศᏊ䛿䚸ග䞉㟁Ẽ䞉ᶵᲔ䞉⇕ ≉ᛶ➼䛻䛚䛔䛶䚸᪤Ꮡ䛾ඹᙺ⣔㧗ศᏊ䛸䛿䜎䛳䛯䛟 ␗䛺䜛≀ᛶ䜢᭷䛩䜛䛣䛸䜢ᐇド䛧䛯 z㻌 ศᏊ䜶䝺䜽䝖䝻䝙䜽䝇䛾㓄⥺⣲Ꮚ z㻌 䝕䜱䝇䝥䝺䜲䛾Ⓨගᮦᩱ 㧗ศᏊᮦᩱ䝴䝙䝑䝖㻌 ᭷ᶵᮦᩱ䜾䝹䞊䝥㻌 ᮡᏳ㻌 ᠇㻌 E-mail : SUGIYASU.Kazunori䖃nims.go.jp URL : http://www.nims.go.jp/macromol/ 㻌㻌㻌㻌㻌㻌 — 395 —
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