FePt 26 ii 1-1 1 1-2 FePt Ku = 2 360 KuV [1] Ku V T [K] kbT / 2 kb KuV kbT [1] Ku 2 nm (b) (a) 1-2 (a) L10-FePt (b) A1-FePt 3 1-3 sp2 1985 1991 [12] 1-3 1-4 C76 C78 4 C82 C84 1.03 nm 1-4 [11] [11] La Y 1-5 [11] Co 1-6 [11] CaC2 SrC2 [11] FePt FePt 5 Ca Sr Fe Ni ( ) 1-5 Fe 1-6 Fe 1-4 Smalley [11] [11] 1.7 6 ( ) (ionization) [13] 1-7 7 1-8 8 9 10 M.B.P R.P 2-1 FePt (4mm 2-2 11 4mm 1mm) 2-1 10-2 Torr 3 100 A 4 He N2 Ar Ne 500 Torr H Ni 15kOe H M VSM 50 50 15kOe 700 12 2-3 VSM 2-2-2 JEOL JEM-1011M 13 。 2-4 TEM TEM TEM 2-5 2-5 14 15 2-6 X 2-7 X X (RIGAKU X ATX-G) CuK = 1.5406 16 (2-6) L10-FePt A1 FePt A1 F = fFePt[1+exp{πi(h+k)}+exp{πi(k+l)}+exp{πi(l+h)}] (2-7) f F = fFe[1+exp{ i(h+k)}]+ f Pt[exp{ i(k+l)}+exp{ 17 i(l+h)}] (2-8) 2-2-3-3 [19] Bragg X 1 [19] Bragg 18 2.10 90 - d m X 1 2dsin 1 m 2( 2dsin ( 1 2 3 4dsin )dsin Bragg =n (n ) 1/2) 1 2 1/4 1 ( /2+1) 2 (( +1)/2+1) m m 19 d 90 = t X X X 2dsin m+1 90 A,D,E, M Bragg B X Bragg C B B 90 B B m (m+1) 20 L - 1 21 22 3-1 3-1 3- 1 3-2 3-3 3-4 A1-FePt L10-FePt He N2 Ar Ne FePt He 0.26kOe N2 0.81kOe [16] 1kOe Fe 3-1 3-1 He 23 Pt 3-2 N2 3-3 Ar 24 3-4 Ne 3-5 He Ar Ne 400 200 15kOe 3-5 25 Fitting (a) (b) (c) 3-6 (d) Fitting (c)Ar (d)Ne 26 (a)He (b)N2 3-2 Fitting 3-2 3-7 15kOe 15kOe 1kOe 15kOe 1 kOe 0.02 emu/g 450 477 L10-FePt 3-8 3-9 He Fe [15] 400 500 Fe 27 -Fe -Fe [15] (a) He (b) N2 (c) Ar (d) Ne 3-7 3-8 He 28 3-9 Fe [15] L10-FePt Fe Fe3Pt 770 157 477 L10-FePt A1-FePt 257 0 M Mj 0(K) [emu] Tcj [K] Mj Mj Mj 3-10 3-3 He N2 L10-FePt Ar -Fe A1-FePt L10-FePt 29 (b) (a) (c) (d) 3-10 Fitting (a)He (b)N2 (c)Ar 3-3 (d)Ne [%] 30 3-3 TEM 3-11 N2 3-11 TEM (a)He (b)N2 31 (c)Ar (d)Ne 3-12 He 5.6 nm N2 8.8 nm Ar 3.4 nm Ne 3.6nm N2 TEM FePt (b) (a) (c) 3-12 3-4 (d) (a)He (b)N2 (c)Ar (d)Ne X X He N2 3-13 FePt (110) -Fe 32 3-14 3-15 (201) (110) 3-16 (220) Ar (201) (220) Ne FePt (110) 3-13 He X 3-14 N2 X 33 3-15 Ar X 3-16 Ne X X 38 34 46 a b ( c d ) 3-17 -Fe (110) 44.64 44.3 3-4 3-5 Fe Pt 3-6 He N2 3-17 FePt Fitting X (a)He (b) N2 (c)Ar (d)Ne 35 3-4 X Fitting 3-5 X 3-6 Fe 36 Pt 3-7 X L10-FePt L10-FePt L10-FePt L10-FePt L10-FePt L10-FePt Fe-Pt L10-FePt Pt L10-FePt Fe Ar Fe 35 55 at.% Pt Ne He N2 Pt 3-7 FePt 3-8 TEM Ar He Ar FePt TEM 37 7 10 nm FePt 3-8 He N2 FePt 3-9 N2 He FePt Pt Fe 3827 3-18 Fe Pt 2887 FePt 1000 Fe ( He 24.58 eV N2 15.57 eV Ar 15.76 eV Ne 21.56 eV [20]) ( N2 : 24.3 eV ( 38 ) [20]) 3-9 Pt Fe 3-18 39 40 41 42
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