化学科講演会のお知らせ
講 演 題 目 ： "Chemical
Reactivity
of
Indenyl-Ruthenium Vinylidene Complexes"
講師：Professor Hui-Ling Sung
(National Taiwan Normal University)
日時：2 月 23 日（月）
15 時 30 分より
場所：南 7 号館 7 階セミナー室
Summary: We synthesized a series of ruthenium
vinylidene complexes, which are stable in solid
state but display high reactivity in the reaction with
organic reagents. Cyclopropenyl or furyl ruthenium
complexes could be generated via deprotonation of
these vinylidene complexes. N-coordinated
ruthenium complexes can be obtained by reaction
of vinylidene complexes with TMSN3. Furthermore,
when the reaction occurred in cyclopropenyl
ruthenium complexes with TMSN3, various
substitutes of the three-member ring presented
different chemical reactivity.
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