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PdV = d ( PV )
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H = U + PV ÔÖ
d ( H − TS ) = 0
T, Pā:ûB‡
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T, Pā:û„p1
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( dG )T , P = 0
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Gm, g [ J mol]
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ng [ mol]
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Gm, l [ J mol]
nl [ mol]
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zÉ Gibbs ÜçòßöÚ G Ž×Å
G = nl Gm, l + ngGm, g
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G = H − TS
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∴ dG = VdP − SdT
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bC:É.$ dT = 0 ÔÖ
dG = VdP
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G [ J/mol ]
Gm, g
P : 101.3 kPa
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71 バトルBGM前半-02