研究業績リスト
投稿論文
(1)
A. Ueno, Y. Kayaki, and T. Ikariya, “Heterolysis of NH-Indoles by Bifunctional Amido
Complexes and Applications to Carboxylation with Carbon Dioxide”, Organometallics, 33,
4479–4485 (2014).
(2)
T. Ikariya and Y. Kayaki, “Hydrogenation of Carboxylic Acid Derivatives with Bifunctional
Ruthenium Catalysts”, Pure Appl. Chem., 86, 933–943 (2014).
(3)
J. Moritani, Y. Hasegawa, Y. Kayaki, and T. Ikariya, “Aerobic Oxidative Desymmetrization of
meso-Diols with Bifunctional Amidoiridium Catalysts Bearing Chiral N-Sulfonyldiamine
Ligands”, Tetrahedron Lett., 55, 1188–1191 (2014).
(4)
S. Hase, Y. Kayaki, and T. Ikariya, “NHC-Gold(I) Complexes as Effective Catalysts for
Carboxylative Cyclization of Propargylamines with Carbon Dioxide”, Organometallics, 32,
5285–5288 (2013).
(5)
A. Ueno, Y. Kayaki, and T. Ikariya, “Cycloaddition of Tertiary Aziridines and Carbon Dioxide
Using
a
Recyclable
Organocatalyst,
1,3-Di-tert-butylimidazolium-2-carboxylate:
A
Straightforward Access to 3-Substituted 2-Oxazolidones”, Green Chem., 15, 425–430 (2013).
(6)
Y. Sato, Y. Kayaki, and T. Ikariya, “Efficient Dynamic Kinetic Resolution of Racemic
Secondary Alcohols by a Chemoenzymatic System Using Bifunctional Iridium Complexes with
C–N Chelate Amido Ligands”, Chem. Commun., 48, 3635–3637 (2012).
(7)
N. Miyamoto, T. Tsukahara, Y. Kachi, M. Harada, Y. Kayaki, T. Ikariya, and Y. Ikeda,
“Studies on Solubility of Uranyl Complexes in Supercritical Carbon Dioxide and Its
Controlling Factors Using UV-Visible and
17
O- and
19
F-NMR Spectroscopy”, J. Nucl. Sci.
Technol., 49, 37–46 (2012).
(8)
T. Touge, T. Hakamata, H. Nara, T. Kobayashi, N. Sayo, T. Saito, Y. Kayaki, and T. Ikariya,
“Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer
Hydrogenation and H2 Hydrogenation”, J. Am. Chem. Soc., 133, 14960–14963 (2011).
(9)
S. Kamezaki, S. Akiyama, Y. Kayaki, S. Kuwata, and T. Ikariya, “Asymmetric
Nitrile-Hydration wuth Bifunctional Ruthenium Catalysts Bearing Chiral N-Sulfonyldiamine
Ligands”, Tetrahedron: Asymmetry, 21, 1169–1172 (2010).
(10) T. Ikariya, S. Kuwata, and Y. Kayaki, “Aerobic Oxidation with Bifunctional Molecular
Catalysts”, Pure Appl. Chem., 82, 1471–1483 (2010).
(11) Y. Kayaki, N. Mori, and T. Ikariya, “Palladium-Catalyzed Carboxylative Cyclization of
α-Allenyl Amines in Dense Carbon Dioxide”, Tetrahedron Lett., 50, 6491–6493 (2009).
1
(12) Y. Kayaki, M. Yamamoto, and T. Ikariya, “N-Heterocyclic Carbenes as Efficient
Organocatalysts for CO2 Fixation Reactions”, Angew. Chem. Int. Ed., 48, 4194–4197 (2009).
Selected as a Hot Paper.
(13) S. Shirai, H. Nara, Y. Kayaki, and T. Ikariya, “Remarkable Positive Effect of Silver Salts on
Asymmetric Hydrogenation of Acyclic Imines with Cp*Ir Complexes Bearing Chiral
N-Sulfonylated Diamine Ligands”, Organometallics, 28, 802–809 (2009).
(14) T. Seki, Y. Kokubo, S. Ichikawa, T. Suzuki, Y. Kayaki, and T. Ikariya, “Mesoporous
Silica-catalysed Continuous Chemical Fixation of CO2 with N,N’-Dimethylethylenediamine in
Supercritical CO2: Efficient Synthesis of 1,3-Dimethyl-2-imidazolidinone”, Chem. Commun.,
349–351 (2009).
(15) T. Tsukahara, Y. Kachi, Y. Kayaki, T. Ikariya, and Y. Ikeda, “1H-, 13C-, and 19F-NMR Studies
on Molecular Interactions of CO2 with β-Diketones and UO2(β-diketonato)2DMSO Complexes
in Supercritical CO2”, J. Phys. Chem. B, 112, 16445–16454 (2008).
(16) Y. Kayaki, T. Suzuki, and T. Ikariya, “Utilization of N,N-Dialkylcarbamic Acid Derived from
Secondary Amine and Supercritical Carbon Dioxide:
Stereoselective Synthesis of Z Alkenyl
Carbamates with a CO2–Soluble Ruthenium–P(OC2H5)3 Catalyst”, Chem. Asian J., 3,
1865–1870 (2008).
(17) Y. Kayaki, H. Ikeda, J.-I. Tsurumaki, I. Shimizu, and A. Yamamoto, “Catalytic Behavior of
Cationic Hydridoruthenium(II) Complex, [RuH(NH3)(PMe3)4]+, in H2-Hydrogenation and
Transfer Hydrogenation of Imines”, Bull. Chem. Soc. Jpn., 81, 1053–1061 (2008).
Selected as
a BCSJ Award Article.
(18) S. Arita, T. Koike, Y. Kayaki, and T. Ikariya, “Aerobic Oxidation of Alcohols with
Bifunctional Transition Metal Catalysts Bearing C–N Chelate Ligands”, Chem. Asian J., 3,
1479–1485 (2008).
(19) S. Arita, T. Koike, Y. Kayaki, and T. Ikariya, “Synthesis and Reactivities of Cp*Ir Amide and
Hydride Complexes Bearing C–N Chelate Ligands”, Organometallics, 27, 2795–2802 (2008).
(20) S. Arita, T. Koike, Y. Kayaki, and T. Ikariya, “Aerobic Oxidative Kinetic Resolution of
Racemic Secondary Alcohols with Chiral Bifunctional Amido Complexes”, Angew. Chem. Int.
Ed., 47, 2447–2449 (2008).
Selected as VIP (Very Important Paper).
(21) Y. Kachi, Y. Kayaki, T. Tsukahara, T. Ikariya, and Y. Ikeda, “Comparative Studies on
Exchange Reactions of Hexafluoroacetylacetonate in Bis(hexafluoroacetylacetonato)(dimethyl
sulfoxide)dioxouranium(VI) in Nonaqueous Solvent and Supercritical CO2”, Inorg. Chem., 47,
349–359 (2008).
2
(22) Y. Kayaki, Y. Shimokawatoko, and T. Ikariya, “Synthesis of Ruthenium(II) Complexes
Containing Hydroxymethylphosphines and Their Catalytic Activities for Hydrogenation of
Supercritical Carbon Dioxide”, Inorg. Chem., 46, 5791–5797 (2007).
(23) Y. Kayaki, M. Yamamoto, and T. Ikariya, “Stereoselective Formation of α-Alkylidene Cyclic
Carbonates via Carboxylative Cyclization of Propargyl Alcohols in Supercritical Carbon
Dioxide”, J. Org. Chem., 72, 647–649 (2007).
(24) Y. Kachi, T. Tsukahara, Y. Kayaki, T. Ikariya, J. Sato, and Y. Ikeda, “Raman Spectral Shifts of
CO2 as Measure of CO2-philicity of Solutes in Supercritical Carbon Dioxide”, J. Supercrit.
Fluids, 40, 20–26 (2007).
(25) Y. Kayaki, M. Yamamoto, T. Suzuki, and T. Ikariya, “Carboxylative Cyclization of
Propargylamines with Supercritical Carbon Dioxide”, Green Chem., 8, 1019–1021 (2006).
(26) T. Tsukahara, Y. Kachi, Y. Kayaki, T. Ikariya, and Y. Ikeda, “Spectroscopic Study on
Solubility
of
UO2(β-diketonate)2dmso
Trifluoroacetylacetonate,
Complexes
Hexafluoroacetylacetonate;
(β-diketonate
dmso
=
=
Dimethyl
Acetylacetonate,
Sulfoxide)
in
Supercritical Carbon Dioxide”, J. Supercrit. Fluids, 39, 6–12 (2006).
(27) O. Ihata, Y. Kayaki, and T. Ikariya, “Aliphatic Poly(urethane-amine)s Synthesized by
Copolymerization of Aziridines and Supercritical Carbon Dioxide”, Macromolecules, 38,
6429–6434 (2005).
(28) O. Ihata, Y. Kayaki, and T. Ikariya, “Double Stimuli-responsive Behavior of Aliphatic
Poly(urethane-amine)s Derived from Supercritical Carbon Dioxide”, Chem. Commun.,
2268–2270 (2005).
(29) O. Ihata, Y. Kayaki, and T. Ikariya, “Control of Thermoresponsive Behavior of
Poly(urethane-amine)s Prepared by Copolymerization of Supercritical Carbon Dioxide and
Aziridines”, Jpn. J. Polym. Sci. Tech. (Kobunshi Ronbunshu), 62, 196–199 (2005). (Japanese).
(30) Y. Kayaki, T. Koda, and T. Ikariya, “A Highly Effective (Triphenyl phosphite)palladium
Catalyst for a Cross–Coupling Reaction of Allylic Alcohols with Organoboronic Acids”, Eur. J.
Org. Chem., 4989–4993 (2004).
(31) K. Hiwatari, Y. Kayaki, K. Okita, T. Ukai, I. Shimizu, and A. Yamamoto, “Selective Oxidative
Carbonylation of Amines to Oxamides and Ureas Catalyzed by Pallladium Complexes”, Bull.
Chem. Soc. Jpn., 77, 2237–2250 (2004). Named as a Selected Paper.
(32) T. Tsukahara, Y. Kayaki, T. Ikariya, and Y. Ikeda, “13C-NMR Spectroscopic Evaluation of the
Affinity of Carbonyl Compounds for Carbon Dioxide under Supercritical Conditions”, Angew.
Chem. Int. Ed., 43, 3719–3722 (2004).
3
(33) Y. Kayaki, T. Koda, and T. Ikariya, “A Halide-Free Dehydrative Allylation Using Allylic
Alcohols Promoted by a Palladium-Triphenyl Phosphite Catalyst”, J. Org. Chem., 69,
2595–2597 (2004).
(34) O. Ihata, Y. Kayaki, and T. Ikariya, “Synthesis of Thermoresponsive Polyurethane from
2-Methylaziridine and Supercritical Carbon Dioxide”, Angew. Chem. Int. Ed., 43, 717–719
(2004).
(35) Y. Kayaki, Y. Shimokawatoko, and T. Ikariya, “Amphiphilic Resin-Supported Ruthenium(II)
Complexes as Recyclable Catalysts for the Hydrogenation of Supercritical Carbon Dioxide”,
Adv. Synth. Catal., 345, 175–179 (2003).
(36) Y. Kayaki, T. Suzuki, Y. Noguchi, S. Sakurai, M. Imanari, and T. Ikariya, “NMR Observation
of Trialkylphosphite-Palladium(II) and -Ruthenium(II) Complexes in Supercritical Carbon
Dioxide”, Chem. Lett., 31, 424–425 (2002).
(37) Y. Kayaki, H. Tsukamoto, M. Kaneko, I. Shimizu, A. Yamamoto, M. Tachikawa, and T.
Nakajima, “Experimental and Theoretical Studies on the Course of CO Insertion into Pt–C and
Pd–C
Bonds
in
+
Neutral
and
Cationic
-
[MR{P(CH3)3}2(s)] BF4 (M = Pt, Pd,
Complexes,
[MR(Cl){P(CH3)3}2]
and
R = CH3, C6H5, s = coordinated solvent)”, J.
Organomet. Chem., 622, 199–209 (2001).
(38) Y. Kayaki, T. Suzuki, and T. Ikariya, “Water-Soluble Trialkylphosphine-Ruthenium(II)
Complexes as Efficient Catalysts for Hydrogenation of Supercritical Carbon Dioxide”, Chem.
Lett., 30, 1016–1017 (2001).
(39) Y. Kayaki, Y. Noguchi, and T. Ikariya, “Enhanced Product Selectivity in the Mizoroki-Heck
Reaction Using a Supercritical Carbon Dioxide-Liquid Biphasic System”, Chem. Commun.,
2245–2246 (2000).
(40) A. Yamamoto, Y. Kayaki, K. Nagayama, and I. Shimizu, “Chemistry of Monoorganopalladium
Complexes Relevant to Catalysis”, Synlett, 925–937 (2000).
(41) K, Mikami, S. Matsukawa, Y. Kayaki, and T. Ikariya, “Asymmetric Mukaiyama Aldol
Reaction of a Ketene Silyl Acetal of Thioester Catalyzed by a Binaphthol–Titanium Complex
in Supercritical Fluoroform”, Tetrahedron Lett., 41, 1931–1934 (2000).
(42) T. Ikariya, Y. Kayaki, Y. Kishimoto, and Y. Noguchi, “Highly Efficient Carbonylation
Reactions of Organic Halides in Supercritical Carbon Dioxide”, Prog. Nucl. Energy, 37,
429–434 (2000).
(43) Y. Kayaki, Y. Noguchi, S. Iwasa, T. Ikariya, and R. Noyori, “An Efficient Carbonylation of
Aryl Halides Catalysed by Palladium Complexes with Phosphite Ligands in Supercritical
Carbon Dioxide”, Chem. Commun., 1235–1236 (1999).
4
(44) R. Kakino, K. Nagayama, Y. Kayaki, I. Shimizu, and A. Yamamoto, “Formation of a
Palladalactone Complex by C–O Bond-Cleavage of Diketene Promoted by a Zerovalent
Palladium Complex”, Chem. Lett., 28, 685–686 (1999).
(45) Y.
Kayaki,
I.
Shimizu,
and
A.
Yamamoto,
“Synthesis
and
Properties
of
Dimethylbis(Phosphite)Palladium(II) and Monomethylbis(phosphite)palladium(II) Complexes”,
Bull. Chem. Soc. Jpn., 70, 1141–1147 (1997).
(46) Y. Kayaki, I. Shimizu, and A. Yamamoto, “Removal of a Palladium-Bound Tertiary Phosphine
Ligand with Silver(I) Salts to Generate Cationic Monoorganopalladium(II) Complexes Having
One Trimethylphosphine Ligand”, Bull. Chem. Soc. Jpn., 70, 1135–1140 (1997).
(47) Y. Kayaki, I. Shimizu, and A. Yamamoto, “Comparison of the Reactivities of Neutral and
Cationic Organopalladium Complexes Toward CO, Isocyanides, and Olefins”, Bull. Chem. Soc.
Jpn., 70, 917–927 (1997).
(48) Y. Kayaki, I. Shimizu, and A. Yamamoto, “Reactivities of Neutral and Cationic
Organopalladium Complexes”, Chem. Lett., 24, 1089–1090 (1995).
(49) Y. Kayaki, F. Kawataka, I. Shimizu, and A. Yamamoto, “Remarkable Rate Enhancement in CO
Insertion
into
+
Pd-C
Bond
by
Generating
Cationic
Organopalladium
Complexes
-
(PdR(S)L2) BF4 (R = Alkyl Group, S = Acetone, L = Phosphine-Ligands) from Neutral
Monoorganopalladium Complexes (PdR(X)L2) (X = Halide)”, Chem. Lett., 23, 2171–2174
(1994).
(50) F. Kawataka, Y. Kayaki, I. Shimizu, and A. Yamamoto, “Synthesis and Thermolysis Behavior
of Monoethylpalladium Complexes, EtPd(X)(PMe3)2 (X = Electronegative Ligands)”,
Organometallics, 13, 3517–3524 (1994).
総説・解説論文
(1)
碇屋隆雄, 榧木啓人, 「金属ヒドリド試薬を猛追する分子触媒―水素によるエステル
還元反応」, 化学, 67, [9], 66–67 (2012).
(2)
Y. Kayaki, T. Ikariya, “Bifunctional Molecular Catalysts with Cooperating Amine/Amido
Ligands”, TCI MAIL, 147, 2–9 (2012).
(3)
碇屋隆雄, 榧木啓人, 「協奏機能分子触媒の化学」, TCI メール, 147, 2–11 (2010).
(4)
碇屋隆雄, 榧木啓人, 「次代を拓く− 工業材料キーワード２８ 超臨界流体」, 工業
材料, 58[1], 48–49 (2010).
(5)
碇屋隆雄, 榧木啓人, 「キーワード５０ 超臨界流体」, 工業材料, 56[1], 84–85 (2008).
5
(6)
碇屋隆雄, 榧木啓人, 「超臨界二酸化炭素を活用する二相系触媒反応」, 化学, 59[8],
68–69 (2004).
(7)
井畑理, 榧木啓人, 碇屋隆雄, 「40 °C で溶解する機能性高分子 − 超臨界二酸化炭素
で合成、カプセル材料に適用も− 」, 工業材料, 52[8], 76–79 (2004).
(8)
榧木啓人, 碇屋隆雄, 「グリーンケミストリーを指向した超臨界流体有機合成法」, 有
機合成化学協会誌, 61, 472–483 (2003).
(9)
T. Ikariya and Y. Kayaki, “Supercritical Fluids as Reaction Media for Molecular Catalysis”,
Catal. Surv. Jpn., 4, 39–50 (2000).
(10) 碇屋隆雄, 榧木啓人, 「超臨界 CO2 を利用した CO2 固定化」, 工業材料, 48[8], 64–68
(2000).
(11) 榧木啓人, 山本明夫, 「触媒活性種モデルとしての有機パラジウム錯体の合成と反応
性」, 有機合成化学協会誌, 56, 96–106 (1998).
著 書 (1)
榧木啓人, 碇屋隆雄, 「低環境負荷有機合成の概要」, 新しい溶媒を用いた有機合成, 第１章,S&T 出版, pp. 1–8 (2013).
(2)
榧木啓人, 碇屋隆雄, 「超臨界二酸化炭素を用いた二酸化炭素固定̶ 水素化反応」, 新
しい溶媒を用いた有機合成, 第２章第１節, S&T 出版, pp. 11–18 (2013).
(3)
榧木啓人, 碇屋隆雄, 「超臨界二酸化炭素を用いた二酸化炭素固定̶ 付加反応」, 新
しい溶媒を用いた有機合成, 第２章第２節, S&T 出版, pp. 19–28 (2013).
(4)
榧木啓人, 碇屋隆雄, 「超臨界二酸化炭素を溶媒に用いた溝呂木̶ Heck 反応」, 新し
い溶媒を用いた有機合成, 第２章第５節, S&T 出版, pp. 48–55 (2013).
(5)
T.
Ikariya
and
Y.
Kayaki,
“Rhodium,
[N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-
4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4,-cyclopenta
dien-1-yl ]-, Stereoisomer”, in e-EROS Encyclopedia of Reagents for Organic Synthesis, John
Wiley&Sons,
RN01400,
(2012).
DOI:
10.1002/047084289X.rn01400;
Online
ISBN:
978047084289
(6)
碇屋隆雄、榧木啓人,「グリーン反応媒体̶ 超臨界流体：二酸化炭素の固定化」, 最新
グリーンケミストリー 持続的社会のための化学, 御園生誠・村橋俊一編, 講談社, pp.
219–227 (2011).
6
(7)
榧木啓人, 「不斉水素化反応」,触媒調製ハンドブック, エヌ・ティー・エス, pp. 351-357
(2011). (8)
榧木啓人, 他共著, 「化学事典」, 斉藤隆夫監修, 旺文社(2010). (9)
榧木啓人, 碇屋隆雄, 「超臨界流体中における触媒反応」, 第 5 版 実験化学講座 25 触媒化学電気化学, 丸善, pp. 173–183 (2006).
(10) Y. Kachi, Y. Kayaki, T. Tsukahara, T. Ikariya, and Y. Ikeda, “Kinetic Study on Exchange
Reaction
of
Hexafluoroacetylacetonate
in
Bis(hexafluoroacetylacetonato)(dimethyl
19
sulfoxide)dioxouranium(VI) in Supercritical CO2 by F NMR”, in Recent Advances in Actinide
Science, eds. by I. May, R. Alvares, and N. Bryan, RSC Publishing, pp.566–568 (2006).
(11) T. Tsukahara, Y. Kachi, Y. Kayaki, T. Ikariya, and Y. Ikeda, “Solubility of
UO2(β-diketonato)2DMSO Complexes (β-diketonate = acetylacetonate, trifluoroacetylacetonate,
hexafluoroacetylacetonate; DMSO = dimethyl sulfoxide) in Supercritical CO2”, in Recent
Advances in Actinide Science, eds. by I. May, R. Alvares, and N. Bryan, RSC Publishing,
pp.563–565 (2006).
(12) 榧木啓人, 碇屋隆雄, 「超臨界 CO2 を活用した有機合成反応の新展開」, 超臨界流体
の最新応用技術 環境保全・高分子加工・各種合成反応, エヌ・ティー・エス, pp. 21–43
(2004).
(13) Y. Kayaki and A. Yamamoto, “1,1-Insertion into Metal-Carbon Bond”, in Fundamentals of
Molecular Catalysis eds. by A. Yamamoto and H. Kurosawa, Elsevier, pp. 373–409 (2003).
(14) T. Ikariya and Y. Kayaki, “Organic and Catalytic Reactions in Supercritical Carbon Dioxide”,
in Supercritical Fluids-Molecular Interactions, Physical Properties, and New Applications, eds.
by Y. Arai, T. Sako, and Y. Takebayashi, Splinger–Verlag, pp. 381–403 (2001).
(15) 碇屋隆雄, 榧木啓人, 「超臨界二酸化炭素の利用技術」, 超臨界流体− 環境浄化とリ
サイクル・高効率合成の展開− , 佐古猛編著, アグネ承風社, pp. 123–137 (2001).
(16) 碇屋隆雄, 榧木啓人, 「超臨界媒体を使う有機合成」, 環境触媒とグリーンケミスト
リー（普及版：環境にやさしい化学技術の開発、2006 年刊行）, 御園生誠監修, シー
エムシー, pp. 249–272 (2000).
(17) 榧木啓人, 碇屋隆雄, 「超臨界二酸化炭素を用いる固定化技術」, CO2 固定化・隔離の
最新技術（普及版：CO2 固定化・隔離技術、2006 年刊行）, 乾智行監修, シーエムシー,
pp. 162–172 (1999). 7
特許
(1)
「触媒又は前駆体並びにこれらを利用した二酸化炭素の水素化方法及びギ酸塩の製造
方法」, 亘理龍, 榧木啓人, 平野伸一, 松本伯夫, 碇屋隆雄, 特願 2014-172384（平成 26
年 9 月 日出願）
(2)
「1,3-ジアルキル-2-イミダゾリジノン類の製造方法」, 關 祐威, 小久保慶陽, 鈴木智
之, 榧木啓人, 碇屋隆雄, 市川真一郎, 特許第 5380051 号（平成 25 年 10 月 4 日登録）
(3)
「α-アルキリデン-1,3-ジオキソラン-2-オン類の製造方法」, 榧木啓人, 碇屋隆雄, 特許
第 4368289 号（平成 21 年 9 月 4 日登録）
(4)
「超臨界流体測定用フロー型ＮＭＲセルシステム」, 榧木啓人, 碇屋隆雄, 櫻井智司,
今成司, 特願 2003-397666・特開 2005-156447（平成 15 年 11 月 27 日出願・平成 17 年 6
月 16 日公開）
(5)
「5-アルキリデン-2-オキサゾリジノン類の製造方法」, 榧木啓人, 碇屋隆雄, 特許第
4307103 号（平成 21 年 5 月 15 日登録）
(6)
「2-オキサゾリジノン類の製造方法」, 榧木啓人, 碇屋隆雄, 特許第 4268424 号（平成
21 年 2 月 27 日登録）
(7)
「ポリウレタン共重合体の製造方法」, 榧木啓人, 井畑理, 碇屋隆雄, 特許第 4056408
号（平成 19 年 12 月 21 日登録）
(8)
「アリル化合物の製造方法」, 榧木啓人, 碇屋隆雄, 特許第 4104402 号（平成 20 年 4 月
4 日登録）
(9)
「超臨界流体測定用ＮＭＲセル」, 榧木啓人, 碇屋隆雄, 今成司, 櫻井智司, 特許第
4313513 号（平成 21 年 5 月 22 日登録）
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