List of Publications
2014/12/17
2014
120. “Copper-Catalyzed Regiodivergent Silacarboxylation of Allenes with Carbon Dioxide and a Silylborane”
Yousuke Tani, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
J. Am. Chem. Soc., in press.
119. “Copper-Catalyzed Silylative Allylation of Ketones and Aldehydes Employing Allenes and Silylboranes”
Yousuke Tani, Tatsuya Yamaguchi, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
Chem. Lett., in press.
118. “Enhancement of Phosphorescence and Unimolecular Behavior in the Solid State by Perfect Insulation of Platinum–
Acetylide Polymers”
Hiroshi Masai, Jun Terao, Satoshi Makuta, Yasuhiro Tachibana, Tetsuaki Fujihara, Yasushi Tsuji
J. Am. Chem. Soc., 136, 14714-14717 (2014).
117. “Synthesis of an Organic–Soluble –Conjugated [3]–Rotaxane via Rotating Glucopyranose Units in Permethylated
–Cyclodextrin”
Jun Terao, Yohei Konoshima, Akitoshi Matono, Hiroshi Masai, Tetsuaki Fujihara, and Yasushi Tsuji
Beilstein J. Org. Chem., 10, 2800-2808 (2014).
116. “New Synthetic Methods of −Conjugated Inclusion Complexes with High Conductivity”
Jun Terao, Yasushi Tsuji
J. Incl. Phenom. Macrocycl. Chem., 80, 165-175 (2014).
115. “Copper-Catalyzed Alkyl–Alkyl Cross-Coupling Reactions Using Hydrocarbon Additives: Efficiency of Catalyst and
Roles of Additives”
Takanori Iwasaki, Reiko Imanishi, Ryohei Shimizu, Hitoshi Kuniyasu, Jun Terao, Nobuaki Kambe
J. Org. Chem., 79, 8522-8532 (2014).
114. “Cobalt-Catalyzed Carboxylation of Propargyl Acetates with Carbon Dioxide”
Keisuke Nogi, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
Chem. Commun., 50, 13052-13055 (2014).
113. “Copper-Catalyzed Borylative AllylAllyl Coupling Reaction”
Kazuhiko Semba, Naoto Bessho, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
Angew. Chem. Int. Ed., 53, 9007-9011 (2014).
112. “Palladium-Catalyzed Formal Arylacylation of Allenes Employing Acid Chlorides and Arylboronic Acids”
Kenta Tatsumi, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
Chem. Commun., 50, 8476-8479 (2014).
111. “Insulated -Conjugated Metallopolymers”
Hiroshi Masai, Jun Terao, Yasushi Tsuji
Tetrahedron Lett., 55, 4035-4043 (2014).
110. “Encapsulation by Cyclic Porphyrin Dimers using Various Interaction Modes”
Jun Terao, Yusuke Chiba, Tetsuaki Fujihara, Yasushi Tsuji
Chem. Lett., 43, 1374-1376 (2014).
109. “Synthesis and Redox Response of Insulated Molecular Wire Elongated through Iron-Terpyridine Coordination
Bonds”
Jun Terao, Takuro Hosomi, Hiroshi Masai, Wakana Matsuda, Shu Seki, Tetsuaki Fujihara, Yasushi Tsuji
Chem. Lett., 43, 1289-1291 (2014).
108. “Molecular Wiring Method Based on Polymerization or Co-polymerization of an Insulated π-Conjugated Monomer”
Jun Terao, Kyouhei Homma, Youhei Konoshima, Masateru Taniguchi, Yuuki Kimoto, Masayo Horikawa, Yasuhisa Naito,
Tetsuaki Fujihara, Yasushi Tsuji
Bull. Chem. Soc. Jpn., 87, 871-873 (2014).
107. “Nickel-Catalyzed Double Carboxylation of Alkynes Employing Carbon Dioxide”
Tetsuaki Fujihara, Yuichiro Horimoto, Taiga Mizoe, Fareed Sayyed, Yosuke Tani, Jun Terao, Shigeyoshi Sakaki, Yasushi
Tsuji
Org. Lett., 16, 4980-4963 (2014).
106. “Regioselective Transformation of Alkynes Catalyzed by a Copper Hydride or Boryl Copper Species”
Tetsuaki Fujihara, Kazuhiko Semba, Jun Terao, Yasushi Tsuji
Catal. Sci. Technol., 4, 1699-1709 (2014).
105. “Synthesis of One-Dimensional Metal-Containing Insulated Molecular Wire with Versatile Properties Directed toward
Molecular Electronics Materials”
Hiroshi Masai, Jun Terao, Shu Seki, Shigeto Nakashima, Manabu Kiguchi, Kento Okoshi, Tetsuaki Fujihara, Yasushi Tsuji
J. Am. Chem. Soc., 136, 1742-1745 (2014).
104. “Iron Oxide Catalyzed Reduction of Acid Chlorides to Aldehydes with Hydrosilanes”
Cong Cong, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
Catal. Commun., 50, 25-28 (2014).
103. “Synthesis of Functionalized Insulated Molecular Wires by Polymerization of an Insulated π-Conjugated Monomer”
Jun Terao, Kyohei Homma, Youhei Konoshima, Rika Imoto, Hiroshi Masai, Wakana Matsuda, Shu Seki, Tetsuaki Fujihara,
Yasushi Tsuji
Chem. Commun. 50, 658-660 (2014).
102. “Synthesis and Characterization of Ruthenium(II) Complexes with Dendritic N-Heterocyclic Carbene Ligands”
Tetsuaki Fujihara, T. Nishida, Jun Terao, Yasushi Tsuji
Inorg. Chim. Acta, 409，174-178 (2014).
2013
101. “Design principle for increasing charge mobility of -conjugated polymers using regularly localized molecular orbitals”
Jun Terao, Akihisa Wadahama, Akitoshi Matono, Tomofumi Tada, Satoshi Watanabe, Shu Seki, Tetsuaki Fujihara, Yasushi
Tsuji
Nat. Commun. 4, 1691 (2013).
日経産業新聞（4 月 10 日 6 面），京都新聞（4 月 10 日 25 面），および日刊工業新聞（4 月 10 日 23 面）
京都大学 HP：http://www.kyoto-u.ac.jp/ja/news_data/h/h1/news6/2013/130410_2.htm
100. “Copper-Catalyzed Borylation of -Alkoxyallenes with Bis(pinacolato)diboron: Efficient Synthesis of 2-Boryl-1,3butadienes”
Kazuhiko Semba, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
Angew. Chem. Int. Ed., 52, 12400-12403 (2013).
99. “Palladium-Catalyzed Reduction of Carboxylic Acids to Aldehydes with Hydrosilanes in the Presence of Pivalic
Anhydride”
Tetsuaki Fujihara, Cong Cong, Jun Terao, Yasushi Tsuji
Adv. Synth. Catal., 355, 3420-3424 (2013).
98. “Copper-Catalyzed Highly Selective Hydroboration of Allenes and 1,3-Dienes”
Kazuhiko Semba, Masaaki Shinomiya, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
Chem. Eur. J., 19, 7125-7132 (2013).
97. “Palladium-Catalyzed Formal Hydroacylation of Allenes Employing Acid Chlorides and Hydrosilanes”
Tetsuaki Fujihara, Kenta Tatsumi, Jun Terao, Yasushi Tsuji
Org. Lett., 15, 2286-2289 (2013).
96. “Nickel-Butadiene Catalytic System for the Cross-Coupling of Bromoalkanoic Acids with Alkyl Grignard Reagents: A
Practical and Versatile Method for Preparing Fatty Acids”
Takanori Iwasaki, Kiyokazu Higashikawa, Vutukuri P. Reddy, Willbe W. S. Ho, Yukari Fujimoto, Koichi Fukase, Jun Terao,
Hitoshi Kuniyasu, Nobuaki Kambe
Chem. Eur. J., 19, 2956-2960 (2013).
95. “Nickel-Catalyzed Coupling of Thiomethyl-Substituted 1,3-Benzothiazoles with Secondary Alkyl Grignard Reagents
Arash Ghaderi, Takanori Iwasaki, Asuka Fukuoka, Jun Terao, Nobuaki Kambe
Chem. Eur. J., 19, 2951-2955 (2013).
2012
94. “Copper-Catalyzed Silacarboxylation of Internal Alkynes by Employing Carbon Dioxide and Silylboranes”
Tetsuaki Fujihara, Yousuke Tani, Kazuhiko Semba, Jun Terao, Yasushi Tsuji
Angew. Chem. Int. Ed., 51, 11487-11490 (2012).
93. “Palladium-Catalyzed Reduction of Acid Chlorides to Aldehydes with Hydrosilanes”
Tetsuaki Fujihara, Cong Cong, Tomohiro Iwai, Jun Terao, Yasushi Tsuji
Synlett, 23, 2389-2392 (2012).
92. “Copper-catalyzed Coupling Reaction of Unactivated Secondary Alkyl Iodides with Alkyl Grignard Reagents in the
Presence of 1,3-Butadiene as an Effective Additive”
Ruwei Shen, Takanori Iwasaki, Jun Terao, Nobuaki Kambe
Chem. Commun., 48, 9313-9315(2012).
91. “Palladium-Catalyzed Esterification of Aryl Halides Using Aryl Formates without the Use of External Carbon Monoxide”
Tetsuaki Fujihara, Tomoya Hosoki, Yuko Katafuchi, Tomohiro Iwai, Jun Terao, Yasushi Tsuji
Chem. Commun., 48, 8012-8014 (2012).
90. “Nickel-Catalyzed Carboxylation of Aryl and Vinyl Chlorides Employing Carbon Dioxide”
Tetsuaki Fujihara, Keisuke Nogi, Tinghua Xu, Jun Terao, Yasushi Tsuji
J. Am. Chem. Soc., 134, 9106-9109 (2012).
89. “Synthesis of Insulated Pt-alkynyl Complex Polymer”
Jun Terao, Hiroshi Masai, Tetsuaki Fujihara, Yasushi Tsuji
Chem. Lett., 41, 652-653 (2012).
88. “Copper-Catalyzed Highly Selective Semihydrogenation of Nonpolr Carbon-Carbon Multiple Bonds Using a Silane and
an Alcohol”
Kazuhiko Semba, Tetsuaki Fujihara, Tinghua Xu, Jun Terao, Yasushi Tsuji
Adv. Synth. Catal., 354, 1542-1550 (2012).
87. “Copper-Catalyzed Highly Regio- and Stereoselective Directed Hydroboration of Unsymmetrical Internal Alkynes:
Controlling Regioselectivity by Choice of Catalytic Species”
Kazuhiko Semba, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
Chem. Eur. J., 18, 4179-4184(2012).
86. “Iridium-Catalyzed Addition of Aroyl Chlorides and Aliphatic Acid Chlorides to Terminal Alkynes”
Tomohiro Iwai, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
J. Am. Chem. Soc., 134, 1268-1274 (2012).
85. “Single Molecule Conductance of -Conjugated Rotaxane: New Method for Measuring Stipulated Electric Conductance
of -Conjugated Molecular Wire Using STM Break Junction”
Manabu Kiguchi, Shigeto Nakashima, Tomofumi Tada, Satoshi Watanabe, Susumu Tsuda, Yasushi Tsuji, Jun Terao
Small, 8, 726-730 (2012).
84. “Synthesis of Insulated Molecular Wire by Click Polymerization”
Jun Terao, Kazuya Kimura, Shu Seki, Tetsuaki Fujihara, Yasushi Tsuji
Chem. Commun., 48, 1577-1579(2012).
Highlighted in Contributors to the Emerging InvestigatorsIssue 2012
Highlighted in ACS Noteworthy Chemistry
2011
83. “Transition Metal Catalyzed Alkylation at sp3-, sp2-, and sp-Carbons”
Nobuaki Kambe, Jun Terao, Takanori Iwasaki
J. Synth.Org. Chem. Jpn., 69, 1192-1203 (2011) .
82. “Permethylated Cyclodextrin-based Insulated Molecular Wires”
Jun Terao
Polym. Chem., 2, 2444-2452 (2011).
81. “-Conjugated Molecules Covered by Permethylated Cyclodextrins”
Jun Terao
Chem. Record, 11, 269-285 (2011).
80. “Kinetic Studies of the Ni-catalyzed Cross-coupling of Alkyl Halides and a Tosylate with Butyl Grignard Reagent in the
Presence of 1,3-Butadiene”
Takanori Iwasaki, Asako Tsumura, Takehiro Omori, Hitoshi Kuniyasu, Jun Terao, Nobuaki Kambe
Chem. Lett., 40, 1024-1026 (2011).
79. “Silver-Catalyzed Regioselective Carbomagnesiation of Alkynes with Alkyl Halides and Grignard Reagents”
Nobuaki Kambe, Yuusuke Moriwaki, Yuuki Fujii, Takanori Iwasaki, Jun Terao
Org. Lett., 13, 4656-4659 (2011).
78. “Pd-catalyzed Cross-coupling Reactions of Alkyl Halides”
Nobuaki Kambe, Takanori Iwasaki, Jun Terao
Chem. Soc. Rev., 40, 4937-4947 (2011).
77. “Ruthenium-catalyzed Ring-closing Metathesis Accelerated by Long-range Steric Effect”
Tetsuaki Fujihara, Yoshikazu Tomike, Toshiyuki Ohtake, Jun Terao, Yasushi Tsuji
Chem. Commun., 47, 9699 -9701(2011).
76. “Synthesis of Head-to-tail-type Cyclodextrin-Based Insulated Molecular Wire”
Jun Terao, Kazuhiro Ikai, Nobuaki Kambe, Shu Seki, Akinori Saeki, Kento Ohkoshi, Tetsuaki Fujihara, Yasushi Tsuji
Chem. Commun., 47, 6816-6818 (2011).
75. “Cross-coupling of Grignard Reagents with Alkyl Halides or Tosylates by the Use of Nickel or Palladium Containing
Perovskite”
Surya Prakash Singh, Takanori Iwasaki, Jun Terao, Nobuaki Kambe
Tetrahedron Lett., 52，774-776 (2011).
74. “Palladium(II) Complexes Bearing a Salicylaldiminato Ligand with Hydroxyl Group: Synthesis, Structure,
Deprotonation, and Catalysis”
Yusuke Murata, Hiroyuki Ohgi, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
Inorg. Chim. Acta, 368, 237-241 (2011).
73. “Palladium-Catalyzed Hydroesterification of Alkynes Employing Aryl Formates without the Use of External Carbon
Monoxide”
Yuko Katafuchi, Tetsuaki Fujihara, Tomohiro Iwai, Jun Terao, Yasushi Tsuji
Adv. Synth. Catal., 353, 475-482 (2011).
72. “Copper-Catalyzed Hydrocarboxylation of Alkynes Using Carbon Dioxide and Hydrosilanes”
Tetsuaki Fujihara, Tinghua Xu, Kazuhiko Semba, Jun Terao, Yasushi Tsuji
Angew. Chem. Int. Ed., 50, 523-527 (2011).
2010
71. “Nickel Catalyzed Regioselective Carbomagnesation of Methylenecyclopropanes through Site Selective Carbon-Carbon
Bond Cleavage Reaction”
Jun Terao, Masahiro Tomita, Surya Prakash Singh, Nobuaki Kambe
Angew. Chem. Int. Ed., 49, 144-147 (2010).
70. “Transition-Metal-Catalyzed Additions of Carbonyl Functionalities to Alkynes”
Tetsuaki Fujihara, Tomohiro Iwai, Jun Terao, Yasushi Tsuji
Synlett, 2537-2548 (2010).
69. “Synthesis of Highly Insulated Molecular Wires by Polymerization of Organic Soluble Linked Symmetrial [3]-Rotaxane
as a Monomer”
Jun Terao, Susumu Tsuda, Keisuke Tsurui, Nobuaki Kambe
Macromol. Sympo., 297, 54-60 (2010).
68. “Iridium-Catalyzed Annulation of N-Arylcarbamoyl Chlorides with Internal Alkynes”
Tomohiro Iwai, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
J. Am. Chem. Soc., 132, 9602-9603 (2010).
67. “Synthesis of Linked Symmetrical [3]Rotaxane Having an Oligomeric Phenylene Ethynylene Unit as a -Guest via
Double Sonogashira Cross-coupling”
Jun Terao, Akihisa Wadahama, Tetsuaki Fujihara, Yasushi Tsuji
Chem. Lett., 39, 518-519 (2010).
66. “Preparation and Characteristic Control of Conducting Polymer/Metal Oxide Nano-hybrid Films for Solar Energy
Conversion”
Yasuhiro Tachibana, Satoshi Makuta, Yasuhide Otsuka, Jun Terao, Susumu Tsuda, Nobuaki Kambe, Susumu Kuwabata
Cer. Eng. and Sci. Proc., 30, 35-49 (2010).
65. “Palladium-Catalyzed Intermolecular Addition of Formamides to Alkynes”
Tetsuaki Fujihara, Yuko Katafuchi, Tomohiro Iwai, Jun Terao, Yasushi Tsuji
J. Am. Chem. Soc., 132, 2094-2098 (2010).
64. “Copper-Catalyzed Hydrosilylation with Bowl-Shaped Phosphane as a Ligand: Preferential Reduction of a Bulky Ketone
in the Presence of an Aldehyde without Protection”
Tetsuaki Fujihara, Kazuhiko Semba, Jun Terao, Yasushi Tsuji
Angew. Chem. Int. Ed., 49, 1472-1476 (2010).
2009
63. “Insulated Molecular Wire with Highly Conductive -Conjugated Polymer Core”
Jun Terao, Yuji Tanaka, Susumu Tsuda, Nobuaki Kambe, Masateru Taniguchi, Tomoji Kawai, Akinori Saeki, Shu Seki
J. Am. Chem. Soc., 131, 18046-18047 (2009).
62. “Ni-Catalyzed Regioselective Three-Component Coupling of Alkyl Halides, Arylalkynes, or Enynes with Ar-M (M =
MgX, ZnX)”
Jun Terao, Fumiaki Bando, Nobuaki Kambe
Chem. Commun., 7336-7338 (2009).
61. “Synthesis of Organic-Soluble Conjugated Polyrotaxanes by Polymerization of Linked Rotaxanes”
Jun Terao, Susumu Tsuda, Yuji Tanaka, Kento Okoshi, Tetsuaki Fujihara, Yasushi Tsuji, Nobuaki Kambe
J. Am. Chem. Soc., 131, 16004-16005 (2009).
Highlighted in Synfacts, 2, 165, (2010). NPG Asia Materials featured highlight
60. “Noncatalytic Conversion of C-F Bonds of Benzotrifluorides to C-C Bonds Using Organoaluminum Reagents”
Jun Terao, Misaki Nakamura, Nobuaki Kambe
Chem. Commun., 6011-6013 (2009).
Highlighted in Hot Articles
59. “Organic Conducting Wire Formation on a TiO2 Nanocrystalline Structure: towards Long-lived Charge Separated
Systems”
Yasuhiro Tachibana, Satoshi Makuta, Yasuhide Otsuka, Jun Terao, Susumu Tsuda, Nobuaki Kambe, Shu Seki, Susumu
Kuwabata
Chem. Commun., 4360-4362 (2009).
58. “Silver-Catalyzed Carbomagnesiation of Teminal Alkynes and Enynes in the Presence of 1,2-Dibromoethane”
Yuuki Fujii, Jun Terao, Yuichiro Kato, Nobuaki Kambe
Chem. Commun., 1115-1117 (2009).
57. “Synthesis of a Linked [1]-[1]Rotaxane”
Susumu Tsuda, Jun Terao, Keisuke Tsurui, Nobuaki Kambe
Chem. Lett., 38, 190-191(2009).
56. “Synthesis of an Organic-Soluble π-Conjugated [1]Rotaxane”
Susumu Tsuda, Jun Terao, Nobuaki Kambe
Chem. Lett., 38, 76-77 (2009).
55. “Nickel-Catalyzed Cross-Coupling of Unactivated Alkyl Halides and Tosylate Carrying a Functional Group with Alkyl
and Phenyl Grignard Reagents”
Surya Prakash Singh, Jun Terao, Nobuaki Kambe
Tetrahedron Lett., 50, 5644–5646 (2009).
54. “Synthesis of Linked Symmetrical [3] and [5]rotaxanes Having an Oligomeric Phenylene Ethynylene (OPE) core
Skeleton as a -Conjugated Guest via Double Intramolecular Self-inclusion”
Susumu Tsuda, Jun Terao, Yuji Tanaka, Tomoka Maekawa, Nobuaki Kambe
Tetrahedron Lett., 50, 1146-1150 (2009).
53. “Iridium-Catalyzed Addition of Acid Chlorides to Terminal Alkynes”
Tomohiro Iwai, Tetsuaki Fujihara, Jun Terao, Yasushi Tsuji
J. Am. Chem. Soc., 131, 6668-6669 (2009).
Highlighted in Synfacts, 8, 875, (2009). JACS Select
52. “A Triarylphosphine Ligand Bearing Dodeca(ethyleneglycol) Chains: Enhanced Efficiency in the Palladium-catalyzed
Suzuki-Miyaura Coupling Reaction”
Tetsuaki Fujihara, Syouhei Yoshida, Jun Terao, Yasushi Tsuji
Org. Lett., 11, 2121-2124 (2009).
Highlighted in Synfacts, 8, 935, (2009).
2008
51. “Plutinum-Catalyzed Regio- and Stereoselective Arylthiolation of Internal Alkynes”
Fumikazu Yamashita, Hitoshi Kuniyasu, Jun Terao, Nobuaki Kambe
Org. Lett., 10, 101-104 (2008).
50. “Cu-Catalyzed Regioselective Carbomagnesiation of Dienes and Enynes with sec- and tert-Alkyl Grignard Reagents”
Hirohisa Todo, Jun Terao, Hideyuki Watanabe, Hitoshi Kuniyasu, Nobuaki Kambe
Chem. Commun., 1332-1334 (2008).
49. “Carbon-Carbon Bond Forming Reactions Using Alkyl Fluorides”
Jun Terao, Hirohisa Todo, Hiroyasu Watabe, Aki Ikumi, Yoshiaki Shinohara, Nobuaki Kambe
Pure Appl. Chem., 80, 941-951 (2008).
48. “Titanocene-Catalyzed Regioselective Alkylation of Styrenes with Grignard Reagents Using -Bromoethyl Ethers,
Thioethers, or Amines”
Jun Terao, Yuichiro Kato, Nobuaki Kambe
Chem. Asian J., 3, 1472-1478 (2008).
47. “Titanocene-Catalyzed Alkylative Dimerization of Vinyl Grignard Reagent Using Alkyl Halides”
Yuuki Fujii, Jun Terao, Yuichiro Kato, Nobuaki Kambe
Chem. Commun., 5836-5838 (2008).
46. “Cross-Coupling Reaction of Alkyl Halides with Grignard Reagents Catalyzed by Ni, Pd, or Cu Complexes with a Carbon Ligand(s)”
Jun Terao, Nobuaki Kambe
Acc. Chem. Res., 41, 1545-1554 (2008).
2007
45. “Cu-Catalyzed Cross-Coupling Reaction of Grignard Reagents with primary-Alkyl Chlorides: Remarkable Effect of
1-Phenylpropyne”
Jun Terao, Hirohisa Todo, Shameem Ara Begum, Hitoshi Kuniyasu, Nobuaki Kambe
Angew.Chem. Int. Ed., 46, 2086-2089 (2007).
Highlighted inSynfacts, 5, 536, (2007).
44. “Cross-coupling of Alkyl Halides with Grignard Reagents Using Nickel and Palladium Complexes Bearing η3-Allyl
Ligand asCatalysts”
Jun Terao, Yoshitaka Naitoh, Hitoshi Kuniyasu, Nobuaki Kambe
Chem. Commun., 825-827 (2007).
43. “Conversion of a (sp3)C-F Bond of Alkyl Fluorides to (sp3)C-X (X = Cl, C, H, O, S, Se, Te, N) Bonds Using
OrganoaluminiumReagents”
Jun Terao, Shameem Ara Begum, Yoshiaki Shinohara, Masahiro Tomita, Yoshitaka Naitoh, Nobuaki Kambe
Chem. Commun., 855-857 (2007).
42. “Transition Metal Catalyzed Carbon-Silicon Bond Forming Reactions Using Chlorosilanes Promoted by Grignard
Reagents”
Jun Terao, Nobuaki Kambe
Chem. Record, 7, 57-67 (2007).
41. “Nickel-catalyzed Dimerization Coupling Reactions of vinyl Grignard Reagents with 3, 4-Membered Cyclic Ethers and
Chlorosilanes”
Yuuki Fujii, Jun Terao, Hiroyasu Watabe, Hiroyuki Watanabe, Nobuaki Kambe
Tetrahedron, 63, 6635-6641 (2007).
40. “Silylation and Alkylation of Allenes Using Chlorosilanes and Alkyl Halides in the Presence of Palladium Catalyst and
Grignard Reagents”
Yuuki Fujii, Jun Terao, Hitoshi Kuniyasu, Nobuaki Kambe
J. Organomet. Chem., 692, 375-381 (2007).
39. “N-Carbonylation of Lithium Azaenolates of Amides, Formamides, Ureas, and Carbamates with Carbon Monoxide
Mediated by Selenium”
Shin-ichi Fujiwara, Kazuhiro Okada, Yasukazu Shikano, Yoshihiko Shimizu, Tsutomu Shin-ike, Jun Terao, Nobuaki Kambe,
Noboru Sonoda
J. Org. Chem., 72, 273-276 (2007).
38. “Conversion of (sp3)C-F Bonds of Alkyl Fluorides to (sp3)C-Heteroatom (Heteroatom = I, SR, SeR, TeR) Bonds by the
Use of Magnesium Reagents Having Heteroatom Substituents”
Shameem Ara Begum, Jun Terao, Nobuaki Kambe
Chem. Lett., 36,196 (2007).
37. “Pd-Catalyzed Coupling Reaction of Allyl and Propargyl Ethers with Chlorosilanes”
Yoshitaka Naitoh, Fumiaki Bando, Jun Terao, Kazutaka Otsuki, Hitoshi Kuniyasu, Nobuaki Kambe
Chem. Lett., 36, 236 (2007).
36. “The First Definitive Evidence of Insertion of Terminal Alkyne into ArS-Pt Bond: “o-Halogen Effect” in Ar under
Stoichiometric and Catalytic Reactions”
Hitoshi Kuniyasu, Fumikazu Yamashita, Jun Terao, Nobuaki Kambe
Angew.Chem. Int. Ed., 46, 5929-5933 (2007).
2006
35. “Reactions of α,β-Unsaturated Thioesters with Platinum(0): Implication of a Dual Mechanism Leading to the Formation
of Acyl Platinum”
Yasuhiro Minami, Tomohiro Kato, Hitoshi Kuniyasu, Jun Terao, Nobuaki Kambe
Organometallics, 25, 2949-2959 (2006).
34. “The First Definitive Example of Oxidative Addition of Acyclic Vinyl Selenide to M(0) Complex”
Hitoshi Kuniyasu, Tomohiro Kato, Masafumi Inoue, Jun Terao, Nobuaki Kambe
J. Organomet. Chem., 691, 1873-1878 (2006).
33. “β-cis-SAr Effect on Decarbonylation from α,β-Unsaturated Acyl and Aroyl Complexes”
Tomohiro Kato, Hitoshi Kuniyasu, Takamichi Kajiura, Yasunori Minami, Atsushi Ohtaka, Masanori Kinomoto, Jun Terao,
Hideo Kurosawa, Nobuaki Kambe
Chem Commun., 868-870 (2006).
32. “Cis-to-trans Isomerization Promoted by Pyridine as a Crucial Step for the Selective Preparation of TransPt(SAr)(Cl)(PPh3)2”
Fumikazu Yamashita, Hitoshi Kuniyasu, Jun Terao, Nobuaki Kambe
Inorg. Chem., 45, 1399-1404 (2006).
31. “Pd-catalyzed Thiocarbamoylation of Terminal Alkynes with Sulfenamide and Carbon Monoxide”
Hitoshi Kuniyasu, Tomohiro Kato, Shigehito Asano, Jia-Hai Ye, Ohmori Takumi, Masaski Morita, Hiroshi Hiraike, Shinichi Fujiwara, Jun Terao, Hideo Kurosawa, Nobuaki Kambe
Tetrahedron Lett., 47, 1141-1144 (2006).
30. “Self-Organized Interconnect Method for Molecular Devices”
Masateru Taniguchi, Yoshihiro Nojima, Kazumichi Yokota, Jun Terao, Kimihiko Sato, Nobuaki Kambe, Tomoji Kawai
J. Am. Chem. Soc., 128, 15062-15063 (2006).
29. “Transition Metal-Catalyzed C-C Bond Formation Reactions Using Alkyl Halides”
Jun Terao, Nobuaki Kambe
Bull. Chem. Soc. Jpn., 79, 663-672 (2006).
2005
28. “Pt-Catalyzed Regio- and Stereoselective Furylthiolation of Alkynes”
Takayoshi Hirai, Hitoshi Kuniyasu, Shigetoshi Asano, Jun Terao, Nobuaki Kambe
Synlett, 1161-1163 (2005).
27. “Zr-Catalyzed Coupling Reaction of Alkyl Halides, Tosylates, and Sulfates with β-Phenethyl Grignard Reagents via
Styrene-Zirconate Intermediates”
Jun Terao, Shameem Ara Begum, Akihiro Oda, Nobuaki Kambe
Synlett, 1783-1785 (2005).
26. “Ni-Catalyzed Alkylative Dimerization of Vinyl Grignard Reagents Using Alkyl Fluorides”
Jun Terao, Hiroyasu Watabe, Nobuaki Kambe
J. Am. Chem. Soc., 127, 3656-3657 (2005).
Highlighted in Synfacts, 0, 71, (2005).
2004
25. “Nickel-Catalyzed Novel Coupling Reaction of Allyl Ethers with Chlorosilanes, Alkyl Tosylates, or Alkyl Halides
Promoted by Vinyl Grignard Reagent Leading to Allylsilanes or Alkenes”
Jun Terao, Hiroyasu Watabe, Hiroyuki Watanabe, Nobuaki Kambe
Adv. Synth. Catal., 346, 1674-1678 (2004).
24. “Nickel-Catalyzed Cross-coupling Reaction of Alkyl Halides with Organozinc and Grignard Reagents Using 1,3,8,10Tetraenesas Additives”
Jun Terao, Hirohisa Todo, Hideyuki Watanabe, Aki Ikumi, Nobuaki Kambe
Angew. Chem., Int. Ed., 43, 6180-6182 (2004).
23. “Palladium-Catalyzed Dimerizative Disilylation of 1,3-Butadiene with Chlorosilane”
Jun Terao, Akihiro Oda, Nobuaki Kambe
Org. Lett.,6, 3341-3344 (2004).
22. “Nickel-Catalyzed Regioselective Three Component Coupling Reaction of Alkyl Halides, Butadienes, and Ar-M (M =
MgX, ZnX)”
Jun Terao, Shinsuke Nii, Firoz A. Chowdhury, Akifumi Nakamura, Nobuaki Kambe
Adv. Synth. Catal.,346, 905-908 (2004).
21. “Titanocene-Catalyzed Formation of Allylsilanes from Allyl Ethers and Chlorosilanes”
Shinsuke Nii, Jun Terao, Nobuaki Kambe
Tetrahedron Lett., 45, 1699-1702 (2004).
20. “Reaction Pathways of Zirconocene-Catalyzed Silylation of Alkenes with Chlorosilanes”
Jun Terao, Yingshi Jin, Kazushi Torii, Nobuaki Kambe
Tetrahedron, 60, 1301-1308 (2004).
19. “Titanocene-Catalyzed Regioselective Carbomagnesation of Alkenes and Dienes”
Shinsuke Nii, Jun Terao, Nobuaki Kambe
J. Org. Chem., 69, 573-576 (2004).
18. “Synthesis of Poly(para-phenylenevinylene) Rotaxanes by Aqueous Suzuki Coupling”
Jun Terao, Andrew Tang, Jasper J. Michels, Alexander Krivokapic, Harry L. Anderson
Chem. Commun., 56-57 (2004).
17. “Cross-coupling Reaction of Alkyl Halides with Organometallic Reagents Using Transition-Metal Catalysts”
Jun Terao, Nobuaki Kambe
J. Synth. Org. Chem. Jpn., 62, 1192-1203 (2004).
2003
16. “Nickel-Catalyzed Dimerizative Carbosilylation of 1,3-Butadienes with Chlorosilanes and Grignard Reagents”
Jun Terao, Akihiro Oda, Aki Ikumi, Akifumi Nakamura, Hitoshi Kuniyasu, Nobuaki Kambe
Angew. Chem., Int. Ed., 42, 3412-3414 (2003).
15. “Ni- or Cu-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Grignard Reagents”
Jun Terao, Aki Ikumi, Hitoshi Kuniyasu, Nobuaki Kambe
J. Am. Chem. Soc., 125, 5646-5647 (2003).
14. “Titanocene-Catalyzed Alkylation of Aryl-substituted Alkenes with Alkyl Halides”
Jun Terao, Hiroyasu Watabe, Masako Miyamoto, Nobuaki Kambe
Bull. Chem. Soc. Jpn., 76, 2209-2214 (2003).
13. “Pd-catalyzed Cross-coupling Reaction of Alkyl Tosylates and Bromides with Grignard Reagents in the Presence of
1,3-Butadiene”
Jun Terao, Yoshitaka Naitoh, Hitoshi Kuniyasu, Nobuaki Kambe
Chem. Lett., 32, 890-891 (2003).
2002
12. “Nickel-Catalyzed Cross-Coupling Reaction of Grignard Reagents with Alkyl Halides and Tosylates: Remarkable Effect
of1,3-Butadienes”
Jun Terao, Hideyuki Watanabe, Aki Ikumi, Hitoshi Kuniyasu, Nobuaki Kambe
J. Am. Chem. Soc.,124, 4222-4223 (2002).
2001
11. “Formation of 1,4-Disilyl-2-butenes from Vinyl Grignard Reagent and Chlorosilanes Catalyzed by a Titanocene
Complexes”
Hiroyasu Watabe, Jun Terao, Nobuaki Kambe
Org. Lett., 3, 1733-1735 (2001).
10. “Titanocene-Catalyzed Reaction of Alkenes and Dienes with Alkyl Halides and Chlorosilanes”
Jun Terao, Nobuaki Kambe
J. Synth.Org. Chem. Jpn.(Special Issue in English), 59, 1044-1051 (2001).
-2000
9. “Titanocene-Catalyzed Carbosilylation of Alkenes and Dienes Using Alkyl Halides and Chlorosilanes”
Shinsuke Nii, Jun Terao, Nobuaki Kambe
J. Org. Chem., 65, 5291-5297 (2000).
8. “Regioselective Double Alkylation of Styrenes with Alkyl Halides Using a Titanocene Catalyst”
Jun Terao, Koyu Saito, Shinsuke Nii, Nobuaki Kambe, Noboru Sonoda
J. Am. Chem. Soc., 120, 11822-11823 (1998).
7. “Titanocene-Catalyzed Double Silylation of Dienes and Aryl Alkenes with Chlorosilanes”
Jun Terao, Nobuaki Kambe, Noboru Sonoda
Tetrahedron Lett., 39, 9697-9698 (1998).
6. “Zirconocene-Catalyzed Silylation of Alkenes with Chlorosilanes”
Jun Terao, Kazushi Torii, Koyu Saito, Nobuaki Kambe, Akio Baba, Noboru Sonoda
Angew. Chem., Int. Ed., 37, 2653-2656 (1998).
5. “Zirconocene-Catalyzed Alkylation of Aryl Alkenes with Alkyl Tosylates, Sulfates and Bromides”
Jun Terao, Tsunenori Watanabe, Koyu Saito, Nobuaki Kambe, Noboru Sonoda
Tetrahedron Lett., 39, 9201-9204 (1998).
4. “Synthesis of Internal Acetylenes from Vinylic Tellurides”
Jun Terao, Nobuaki Kambe, Noboru Sonoda
Tetrahedron Lett., 39, 5511-5512 (1998).
3. “Synthesis and Reaction of Vinylic Tellurides”
Jun Terao, Nobuaki Kambe, Noboru Sonoda
Phosphorus Sulphur and Silicon, 136,137 & 138, 637-640 (1998).
2. “Tellurium-Zinc Exchange Reaction. A New Preparative Method of Alkenylzinc Reagents”
Jun Terao, Nobuaki Kambe, Noboru Sonoda
Tetrahedron Lett., 37, 4741-4744 (1996).
1. “A New Preparative Method of Alkenylaluminum Reagents via Tellurium-Aluminum Exchange Reactions”
Jun Terao, Nobuaki Kambe, Noboru Sonoda
Synlett, 779-780 (1996).
「解説」
13.「高い電荷移動度を示すジグザグ型被覆 π 共役ポリマーの合成」
寺尾 潤，的埜 旭隼，和田浜 彰久，藤原 哲晶，辻 康之
化学工業，65, 16-21(2014).
12．「分子エレクトロニクスを指向した被覆型分子ワイヤの合成」
寺尾 潤
高分子, 60, 465(2011).
11. 「被覆型分子ワイヤの合成とその応用」
寺尾 潤
表面, 49(2), 44－57(2011).
10. 「クロスカップリング反応を鍵とする被覆型分子ワイヤの合成」
寺尾 潤
化学工業, 62(3), 46-55(2011).
9.「ナノスケールの分子ワイヤを作る！」
寺尾 潤
化学と教育，58, 262-263(2010).
8. 「π-炭素配位子を用いるハロゲン化アルキル類のクロスカップリング反応の開発」
寺尾 潤、神戸宣明
触媒，51, 360-366(2009)
7. 「被覆共役ポリマーの合成と分子エレクトロニクスへの応用」
寺尾 潤
Organometallic News, No. 2, 44-49(2009).
6. 「MBLA 2006受賞講演ツアーを終えて
寺尾 潤
J. Synth.Org. Chem. Jpn., 66, 389-395 (2008) .
Lecture tour upon receiving the MBLA 2006」
5. 「新しい反応機構を経るクロスカップリング反応の開発」
寺尾 潤、神戸宣明
化学, 62, 17-21 (2007).
4. 「アニオン性錯体を鍵活性種とする新規触媒反応の開発」
神戸宣明、寺尾 潤
生産と技術, 59(3), 55-58 (2007).
3. 「分子間相互作用を利用しないロタキサンの合成」
寺尾 潤
Organometallic News, No. 3, 96 (2006).
2. 「不斉アルキル－アルキルカップリング反応
－光学的に純粋な不斉炭素を有するメチレン鎖の構築手法」
寺尾 潤
化学, 60(2), 65-66 (2005).
1. 「アート型遷移金属錯体の創製と触媒反応への展開
炭素－炭素および炭素－ケイ素結合生成の新手法の開発を目指して」
寺尾 潤
化学と工業, 67, 115-118 (2004).
「著書」
5. 「被覆ポリロタキサンの合成と分子エレクトロニクスへの応用」（分担執筆）
寺尾 潤
シクロデキストリンの科学と技術，シーエムシー出版（監修 寺尾啓二；池田 宰），2014，p 9-18.
4. “Triphenylaluminum”（分担執筆）
Jun Terao
e-EROS Encyclopedia of Reagents for Organic Synthesis, Fuchs, P. L. Ed.; Wiley, 2011.
3.「ハロゲン化アルキル類のクロスカップリング反応を利用する(sp3)炭素－炭素結合生成の新手法（共著）
寺尾 潤，神戸宣明
現代化学増刊最新有機合成化学, 東京化学同人，2005, p 123-135.
2．“1,3-Butadiene as an Efficient Additive for Nickel, Palladium, or Copper-Catalyzed Cross-Coupling Reaction of Alkyl
Halides with Grignard Reagents” （共著）
Jun Terao, Nobuaki Kambe
Catalysts for Fine Chemical Synthesis, Vol. 3, Metal Catalysed Carbon-Carbon Bond-Forming Reactions”, S. M. Roberts, J.
Whittall, P. Mather, P. McCormack (Eds.), John Wiley & Sons, Oxford, 2004, p 128-133.
1. “Zirconocene- or Titanocene Catalyzed Reactions Using Grignard Reagents”（共著）
Jun Terao, Nobuaki Kambe
Latest Frontiers of Organic Synthesis, Y. Kobayashi (Ed.), Research Signpost, 2002, p 25-47.

学術論文

List of publications Original Articles 19) Ethylene

Cyclobutane Synthesis

Mikhail A. Vorotyntsev - Department of Electrochemistry