國立東華大學教師個人基本資料表 e-mail:[email protected] 學歷/畢業:美國俄亥俄州立大學化學博士 (1991.08) 張秀華 A. H. H. Chang 現職/起迄:國立東華大學化學系教授 (2010.02) 到任年月份(東華):2000 年 8 月 研究領域:物理化學、理論化學 ■ 期刊論文(2009~2014): 1. “A laboratory study on the thermally induced transformation of hydrogen cyanide (HCN) to the cyanogen anion (CN(-)) in Solar System analog ices”, C. S. Jamieson, A. H. H. Chang, R. I. Kaiser,* Adv. Space Res. 43, 1446 (2009) (IF=1.183, ▼:4). 2. “Probing the Ignored Elimination Channel of Br2 in the 248 nm Photodissociation of 1,1-Dibromoethylene by Cavity Ring-Down Absorption Spectroscopy”, P. C. Lee, P. Y. Tsai, M. K. Hsiao, K. C. Lin,* C. H. Huang, and A. H. H. Chang, Chem. Phys. Chem. 10, 672 (2009) (IF=3.349, ▼:5). 3. “Photodissociation of dibromoethanes at 248 nm: an ignored channel of Br2 elimination” Hsin-Lung Lee, Ping-Chen Lee, Po-Yu Tsai, King-Chuen Lin*, H. H. Kuo, P. H. Chen, and A. H. H. Chang,* J. Chem. Phys. 130, 184308 (2009) (IF=3.164, ▼:9). 4. “Synthesis of Interstellar 1,3,5-Heptatriynylidyne, C7H( X 2 ), via the Neutral-Neutral Reaction of Ground State Carbon Atom, C(3P), with Triacetylene, HC6H ( X 1 g )” by B. J. Sun, C. H. Huang, M. F. Tsai, H. L. Sun, L. G. Gao, Y. S. Wang, Y. Y. Yeh, Y. H. Shih, Z. F. Sia, P. H. Chen, R. I. Kaiser, and A. H. H. Chang,* J. Chem. Phys. 131, 104305 (2009) (IF=3.164, ▼:2). 5. “A theoretical study on the reaction of ground state cyano radical with propylene in Titan’s atmosphere” by C. H. Huang, R. I. Kaiser, and A. H. H. Chang,* J. Phys. Chem. A 113, 12675 (2009) (IF=2.771, ▼:4). 6. “Structural isomerism of luminescent dinuclear Pt(II)-Thiolate diimines” Biing-Chiau Tzeng,* Tse-Hao Chiu, Sun-Yi Lin, Chieh-Min Yang, Tsung-Yi Chang, C. H. Huang, A. H. H. Chang, and Gene-Hsiang Lee, Crystal Growth & Design 9, 5356 (2009) (IF=4.689, ▼:6). 7. “Photodissociation of Gaseous Acetyl Chloride at 248 nm by Time-resolved Fourier-transform Infrared Spectroscopy: the HCl, CO and CH2 Product Channels” Yu-Ting Liu, Chia-Yun Liu, Ming-Tsang Tsai, King-Chuen Lin,* Y. H. Shih and A. H. H. Chang, J. Phys. Chem. A 114, 7275 (2010)( (IF=2.771, ▼:5). 8. “A chemical dynamics, kinetics, and the theoretical study on the reaction of the cyano radical radical (CN; X2Σ+) with phenylacetylene (C6H5CCH; X1A1)”C. J. Bennett, S. Morales, S. D. Le Picard, A. Canosa, I. R. Sims,* Y. H. Shih, A. H. H. Chang, X. Gu, F. Zhang, R. I. Kaiser* Phys. Chem. Chem. Phys. 12, 8737 (2010) (IF=3.829, ▼:5). 9. “Determination of ionization energies of CnN (n=3-14) clusters: Vacuum-ultraviolet (VUV) photoionization experiments and theoretical calculations” Oleg Kostko, Jia Zhou, Musahid Ahmed,* Bian Jian Sun, Jie Shiuan Lie, A.H.H. Chang, and Ralf I. Kaiser Astrophys. J. 717, 674 (2010) (IF=6.733, ▼:3) 10. “Vertex and edge truncated octahedron gold crystal: N-alhylimidazole and silver(I) ion controlled morphology transformation” S. J. Hsu, Padi Y. S. Su, L. Y. Jian, A. H. H. Chang I. J. B. Lin* Inorg. Chem. 49, 4149 (2010) (IF=4.593, ▼:5). 11. “Crossed Molecular beam Study On the Ground State Reaction of Atomic Boron with Hydrogen Cyanide” Brant Jones, Pavlo Matsyutenko, Nung C. Su, A. H. H. Chang, Ralf I. Kaiser* J. Phys. Chem. A 114, 8999 (2010) (IF=2.771, ▼:0). 12. “Untangling the Chemical Dynamics of the Reaction of Boron Atoms, 11B(2Pj), with Diacetylene, C4H2(X1Σg+) –A Crossed Molecular Beams and Ab Initio Study” Pavlo Maksyutenko, Fangtong Zhang, Ralf I. Kaiser,* Shih Hua Chen, Chang Cheih Wu, A.H.H. Chang,* J. Phys. Chem. A 114, 10936 (2010) (IF=2.771, ▼:1). 13. “An Experimental and Theoretical Study on the Ionization Energies of Polyynes (H-(CC)n-H; n = 1 - 9)” Ralf I. Kaiser, Bian Jian Sun, Hong Mao Lin, A. H. H. Chang, Alexander M. Mebel, Oleg Kostko, Musahid Ahmed Astrophys. J. 719, 1884 (2010) (IF=6.733, ▼:4). 14. “I2 Molecular Elimination in Single-photon Dissociation of CH2I2 at 248 nm by Using Cavity Ring-down Absorption Spectroscopy” Shun-Yi Chen, Po-Yu Tsai, Hsiang-Chin Lin, Chia-Ching Wu, King-Chuen Lin*, B. J. Sun and A. H. H. Chang, J. Chem. Phys. 134, 034315 (2011) (IF=3.164, ▼: 3 ). 15. “Photodissociation Gas-phase Photodissociation of CH3CHBrCOCl at 248 nm: Detection of Molecular Fragments by Time-Resolved FT-IR Spectroscopy: The HCl, HBr, and CO Product Channels” Chia-Yun Liu, Ming-Tsang Tsai, Po-Yu Tsai, Yu-Ting Liu, and King-Chuen Lin*, S. Y. Chen and A. H. H. Chang, Chem. Phys. Chem. 12, 206 (2011)(IF=3.349, ▼:2). 16. “A crossed beam and ab initio investigation of the reaction of boron monoxide (11BO;X2Σ+) with acetylene (C2H2;X1Σg+)” Dorian S. N. Parker, Fangtong Zhang, Pavlo Maksyutenko, Ralf. I. Kaiser,* S. Y. Chen, and A. H. H. Chang Phys. Chem. Chem. Phys. 13, 8560 (2011)(IF=3.829, ▼:6). 17. “PH-Dependent Spectroscopic and Luminescent Properties and Metal-Ion Recognition Studies of Re(I) Complexes Containing 2-(2’-Pyridyl)benzimidazole and 2-(2’-Pyridyl)benzimidazolate” Biing-Chiau Tzeng,* Bo-So Chen, Chang-Kai Chen, Yuan-Ping Chang, Wen-Chian Tzeng, Tsung-Yi Lin, Gene-Hsiang Lee, Pi-Tai Chou,* Yu-Jie Fu, A. H. H. Chang,* Inorg. Chem. 50, 5379 (2011)(IF=4.593, ▼:5). 18. “A Crossed Molecular Beams, Low Temperature Kinetics, and Theoretical Investigation of the Reaction of the Cyano Radical (CN) with 1,3-Butadiene(C4H6)-A Route to Complex Nitrogen-Bearing Molecules in Low Temperature Extraterrestrial Environments” Sébastien B. Morales, Christopher.J. Bennett, Sébastien D. Le Picard,* André Canosa, Ian R. Sims,* B. J. Sun, P. H. Chen, A. H. H. Chang,* Alexander M. Mebel,* Xibin Gu, Fangtong Zhang, and Ralf I. Kaiser,* Astrophys. J. 742, 26 (2011) (IF=6.733, ▼:7). 19. “A crossed beam and ab initio investigation on the formation of vinyl boron monoxide (C2H3BO; X1A’) via reaction of boron monoxide ((BO)-B-11);X2Σ+) with ethylene (C2H4;X2Ag)” D. S. N. Parker, F. T. Zhang, P. Maksyutenko, R. I. Kaiser,* S. H. Chen, A. H. H. Chang,* Phys. Chem. Chem. Phys. 14, 11099 (2012) (IF=3.829, ▼:4). 20. “Molecular elimination of Br2 in photodissociation of CH2BrC(O)Br at 248 nm using cavity ring-down absorption spectroscopy” He Fan, Po-Yu Tsai, King-Chuen Lin,* Cheng-Wei Lin, Chi-Yu Yan, Shu-Wei Yang, and A. H. H. Chang,* J. Chem. Phys. 137, 214304 (2012) (IF=3.164, ▼:0). 21. “First detection of the silylgermylene (H3SiGeH) and D4-silylgermylene (D3SiGeD) molecules in low temperature silane-germane ices” A. E. Tomosada, S. Kim, Y. Osamura, S. W. Yang, A. H. H. Chang,* R. I. Kaiser,* Chem. Phys. 409, 49 (2012) (IF=1.957, ▼:0). 22. “Syhtheses and structures of Zr-4 tetrahetral clusters containing direct Zr-Zr bonds: the missing cluster in series Zr-n (n=2-6)” H. H. Yang, C. H. Chien, C. C. Yang, F. C. Liu,* A. H. H. Chang,* G. H. Lee, S. M. Peng, Dalton Transaction, 42, 1168 (2013) (IF=3.806, ▼:0). 23. “On the detection of higher order carbon sulfides (CSx ; x = 4-6) in low temperature carbon disulfide ices” Surajit Maity, Seol Kim, Ralf Kaiser,* Hong Mao Lin, Bian Jian Sun, A. H. H. Chang*, Chem. Phys. Lett. 577, 42 (2013) (IF=2.145, ▼:0). 24. “A crossed molecular beam and ab initio investigation of the exclusive methyl loss pathway in the gas phase reaction of boron monoxide (BO; X-2 Sigma(+)) with dimethylacetylene (CH3CCCH3; X(1)A(1g)) ” R.I. Kaiser, * Surajit Maity, B. B. Dangi, Y. S. Su, B. J. Sun, A. H. H. Chang,* Phys. Chem. Chem. Phys. 16, 989 (2014) (IF=3.829, ▼:0). 25. “Gas Phase Synthesis of the Hitherto Elusive Ethynylsulfidoboron Molecule (HCCBS)” Tao Yang, Dorian S. N. Parker, Beni B. Dangi, Ralf I. Kaiser*, A. H. H. Chang*, Alexander M. Mebel* (submitted). 26. “A Combined Crossed Molecular Beams and Ab Initio Investigation on the Formation of Vinylsulfidoboron (C2H3BS) - The Simplest Olefinic Organosulfidoboron Molecule” Tao Yang, Beni B. Dangi, Dorian S. N. Parker, Ralf I. Kaiser*, Yi An, Shih Hua Chen, A. H. H. Chang* (submitted). 27. “Ruthenium Complexes Bearing Unsymmetric CNC’Pincer Ligands Molecular Structures and Electronic Properties.” Abbas Raja Naziruddin, Chia-Liang Kuo, Wan-Jung Lin, Wei-Hao Lo, Chen-Shiang Lee, Bian-Jian Sun, A. H. H. Chang, Wen-Shu Hwang* (submitted). 28. “Pt(II) Complexes Bearing CCC Pincer Bis(carbene) Ligands - Synthesis, Molecular Structures and Photo-Functional Aspects.” Wan-Jung Lin,a Abbas Raja Naziruddin,a Yu-Hsuan Chen,a Bian-Jian Sun, A. H. H. Chang, Wen-Jwu Wangb and Wen-Shu Hwanga* (submitted). ■ 計畫執行、開授課程、論文指導、研究獎勵等 C. 2007 ~ 2015 年執行之研究計畫 起訖年月 研究計畫名稱 計畫經費 補助單位 96.08~97.07 放光錢幣族(IB)錯化合物之理論探討(1/2) 1,129,000 元 國科會 97.08~98.07 放光錢幣族(IB)錯化合物之理論探討(2/2) 1,155,000 元 國科會 98.08~99.07 分子激發態相關性質之理論探討(1/3) 2,359,000 元 國科會 99.08~100.07 分子激發態相關性質之理論探討(2/3) 1,952,000 元 國科會 100.08~101.07 分子激發態相關性質之理論探討(3/3) 1,929,000 元 國科會 101.08~104.07 分子後電子結構性質之理論探討(1/3) 5,655,000 元 國科會 D. 2005 ~ 2009 年開授課程 學年度 95(上) 課程名稱(必/選) 選修人數 物理化學(三) (必) 量子化學(一) (選) 95(下) 化學動力學 (選) 物化實驗(下) (必) 96(上) 物理化學(三) (必) 量子化學(一) (選) 96(下) 化學動力學 (選) 物化實驗(下) (必) 97(上) 物理化學(三) (必) 量子化學(一) (選) 97(下) 化學動力學 (選) 物化實驗(下) (必) 98(上) 物理化學(三) (必) 量子化學(一) (選) 98(下) 化學動力學 (選) 物化實驗(下) (必) E.2005 ~ 2009 年指導研究生狀況 畢業人數 學年度 碩士班(人) 博士班(人) 94 6 1 3 95 6 2 3 96 6 2 3 97 6 3 3 碩士 博士
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