.,:'."
-v
SAFETY DATA
Flamemaster
13576 Desmond
Pacoima,
Corp.
JANUA~Y
SlIT
File: CS3100A GSA 7-10
Potting
2014
Compound/
Base
Street
CA 91331 - USA
Section -1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
1.1. Product Identifier: CS-3100 PT A BASE (ALL TY~ESAND CLASSES)
- Product Name: Potting Compound { Base compound Part-A
- Product reference: CS-3100 PT A BASECompound
'
1.2. Product Use:
- Electrical Potting Com ound
1.3. Manufacturer's
Name:
1.3.1 Suppliers Name ( if not manufacturer)
CAGE Code: 14439
CAGE Code:
OZ5S6
Flamemaster Corp.
Sealpak Company, Inc.
Chem Seal Division
2301 N. Hoover Rd
13576 Desmond Street
Wichita, KS
67205-1025
Pacoima, CA 91333 - USA
Technical Contact:
1.4. Emergency Telephone:
Flamemaster Corp.
Chemtrec - Chemtrec International
800-424-9300 ( North America)
Tel: 818-890-1401
703-527-3887 (Outside North America))
Fax: 818-890-6001
www.f1amemaster.com
Specification
MIL-PRF-8SI16G
CS3100 lYl CU-alZCART
NSN:
CS31001Y1CU-<lT.
8030-00-181-7884
CS3100TY2CU
8030-00-631-8013
60Z CART
CS31001Y2CLi
8030-00-200-8341
CS3100TY2Cl21/2
CS31001Y2Cl3
QT. KIT
8030-00-881-5238
PT
CS31OO1Y2C12 QT KIT
8030-00-297-6677
8030-00-174-2597
QT. KIT
CS3100TY2Cl3
8030-00-684-8790
ALL TYPES&CLASSES
Base PTA
KIT
CS31001Y1CL2QT.
8030-00-148-7362
CS31001Y2CU
GAL KIT
8030-00-823-7953
. CS31OO1Y2CL2 GALKIT
CS31001Y1Ci3GALKlT
8030-01-175-3479
CS31001Y2CU
PT. KIT
8030-01-805-9875
CS31001Y2Cl2
60Z CART•
8030-01-383-4992
8030-00-286-9035
1/2 GAL. KIT CS31001Y2CL2
8030-00-5~5-2271
KIT
CS31001Y2CU
2.5 OZCART
8030-00-881-2618
CS31001Y2CU
PT.KIT
8030-21-805-9875
c:S31001Y2Cl31/2
PT KIT
8030-00-616-7696
1/2 PT. KIT
5970-00-814~394
"
Section -2. HAZARD ( S) IDENTIFICATION
Flammable
Possible adverse risk to the fetus.
Skin and eye irritant.
Harmful if swallowed.
Harmful if inhaled.
Possible harm to aquatic organisms.
May cause long term adverse effects in the aquatic environment.
Section -3. COMPOSITION {INFORMATION
ON INGREDIENTS
Chemlcar family: Mixture of organic compounds
For the hazards of the composition, (SDS see Section 2).
GHS ClASSIFICATION:LlQUID POlYSULFIDE POlYMER
1/ OSHA HAZARDS: TARGET ORGAN EFFECT,IRRITANT,FlAMMABLE
LIQUID
EYEIRRITATION (CATEGORY2)
SKIN IRRITATION (CATEGORY 2)
SPECIFICTARGET ORGAN TOXICITY-SINGLEEXPOSURE-(CATEGORY3)
AQUATIC, CHRONIC(CATEGORY 3)
This sds is provided
situations.
knowledge.
without
The conditions
any warranty
expressed
of handling,storage,
or implied
use and disposal
regarding
are beyond
its correctness
our control
or suitability
for specific
and may be beyond
our
Page 1 of 6
GHS CLASSIFICATIONIN ACCORDANCEWITH 29 CFR 1910 (OSHA HCS):TOLUENE
FLAMMABLE LIQUIDS (CATEGORY2),H225
SKIN IRRITATION (CATEGORY2),H315
REPRODUCTIVETOXICITY (CATEGORY2),H361
SPECIFICTARGET ORGAN TOXICITY-SINGLEEXPOSURE-(CATEGORY3),CENTRAL NERVOUSSYSTEM,H336
SPECIFICTARGET ORGAN TOXICITY-REPEATEDEXPOSURE(CATEGORY2),H373
ASPIRATION HAZARD (CATEGORY1),H304
ACUTE AQUATIC TOXICITY (CATEGORY2),H401
SUBSTANCE
H&P STATEMENTS
CAS
EINECS/ELINCS
68611-50-7
POLYMER
% by weight in the product
LIQUID POLYSULFIDE-POLYMER< 71%
H319,H335,H315,H412,H223,
P210 P270 P305+P351+P338
+P313,P306+P361,P370+P260
TOLUENE (Methylbenzene)
<12%
H225,H304,H315,H319,H332,H336,
H361,H371,H401,
P210P260,P281,P301 +P310,P305+
203-625-9
108-88-3
P351+ P338,P331
Section -4. fiRST-AID MEASURES
General: When in doubt or symptoms persist, seek medical attention. Have Safety Data Sheet information
available. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air, if breathing has stopped, administer artificial respiration. Give nothing by mouth,
seek immediate medical attention.
Eye contact: Irrigate with clean, fresh water for at least ~5 minutes, holding the eyelids apart, and seek medical attention.
Skin contact: Remove contaminated clothing. Wash skill thoroughly with soap and water or use recognized skin
cleaners. Do NOT use aromatic solvents, thinners or petroleum products .
. Ingestion: ·If accidentally swallowed obtain immediate
medical attention.
Keep at rest. Do. NOT induce vomiting. Never
give anything by mouth to an unconscious person.
Section -5. FIRE-FIGHTING MEASURES
Extinguishing
agents
Recommended:
Universal resistant foam, C02, water, powder.
Agents to avoid: None known
Attention
Fire will produce dense black smoke. Exposure to decomposition products may cause a Health Hazard. Fire fighters should
wear self-contalned breathing apparatus.
Water mist may be used to cool closed containers to prevent pressure build-up and possible auto-ignition and explosion
when exposed to extreme heat.
Do not weld, flame cut or expose to extreme heat or ignition sources, empty containers which have contained flammable
products.
Do not allow run-off from fire fighting to enter drains or water courses.
Section-6.
ACCIDENTAL RELEASEMEASURES
Eliminate sources of ignition, ventilate the area. Avoid breathing vapors by using appropriate
respiratory
protective
equipment. Refer to protective measures listed in sections 7 & 8.
Collect spill with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a
suitable container for disposal in accordance with local regulations (see section 13). Do not allow to enter drains or
watercourses.
Clean-up with a detergent/ water mix; avoid use of aromatic solvents. If the product enters drains or watercourses, inform
authority with jurisdiction in accordance with state / local regulations.
This sds is provided
situations.
knowledge.
without
The conditions
any warranty
expressed
of handling,storage,
:or implied
use and disposal
regarding
are beyond
its correctness
our control
or suitability
for specific
and may be beyond
our
Page 2 of 6
Section -7. HANDLING AND STORAGE
7;1 Handling:
No smoking, eating and drinking during handling.
Keep containers tightly closed. Prior to movement containers which are opened should be carefully resealed.
Avoid skin and eye contact. Avoid inhalation in case of exposure to vapor and spray mist.
Handle and open containers with care to avoid spilling of contents. Never use pressure to empty; container is not a
pressure vessel. Clean or discard contaminated clothlngandlshoes.
Preparation may charge electrostatically; always use grounding! bonding! earthing leads when transferring contents of
containers. Operators should wear antistatic footwear and clothing, and floors should be electrically conductive.
Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation
of flammable or explosive concentrations of vapor in air, and avoid vapor concentration higher than the Occupational
Exposure limits.
Use in areas from which local sources of ignition have been excluded. Electrical equipment including lighting should be
protected to the appropriate standard. Isolate from sources of heat, sparks and open flame. Non-sparking tools are
recommended.
7.2 Storage:
Observe label precautions. Store between 32/F and 95/F ( O/C and 35/C) in a dry, clean and well ventilated place, away
from 'Sources of heat, ignition, and direct sunlight. For flash points below 23 °C store in an area constructed to the
appropriate standard
8. EXPOSURE CONTROLS I PERSONAL PROTECTION
8.1 Engineering measures:
Avoid the inhalation of vapors, spray mist and particulates.
extraction
as to keep air-borne concentration
If local/area
ventilation
Achieve by local exhaust ventilation
below the 'Occupational Exposure limits (OEL).
is not sufficient to comply with OEl, suitable (NIOSH) respiratory
provide suitable (NIOSH) respiratory
providing good general
protection
when sanding, grinding or otherwise
protection
to be provided. Always
abrading cured material.
8.2 Exposure limits
Work place exposure limits ( 8 hour)
_.. !.
Substance
!
ALIPHATIC POlYSUlFIDE-POlYMER
TOLUENE (Methylbenzene)*
".
< 60%
< = 12%
OSHA
ACGIHTWA
I
Not known
Not known
100 ppm
50ppm
* can be absorbed through skin
8.3 Personal protection
All Personal Protective Equipment, including Respiratory. Protection, used to control exposure to hazardous substances
must be selected to meet the requirements
Respiratory
protection
:
Appropriate
respiratory
protection
regulatory
of OSHA Regulations.
equipment
should be selected according to the type of contaminants,
(OSHA / NIOSH) and manufacturers
instructions
following
including proper fitting of devices.
Hand protection:
For prolonged or repeated contact, recommend
gloves type: polyvinyl alcohol, nitrile rubber, latex rubber (some
people may exhibit sensitivity to Latex). Barrier creams may help to protect exposed areas of the skin. However, they
should not be applied post exposure.
Eye protection
:
Use safety glasses with side shields to protect against splashes. Face shields may also be worn.
Skin protection:
Protective clothing made of antistatic
and fire resistant fibers. All parts of the body should be washed after contact. Use
good hygiene and industrial practices, keep working clothes clean.
This sds is provided
situations.
knowledge.
without
The conditions
any warranty
expressed-or implied
of handling,storage,
use and disposal
regarding
are beyond
its correctness
our control
or suitability
for specific
and may be beyond
our
Page 3 of 6
9. PHYSICALAND CHEMICAL PROPERTIES
• Physical state at: 68
- Flash point:
2
F (20
130 • F(54·
2
C) Liquid
• Ph: 8.5
C) Method: TCC
- Volatile by Volume %: 4
- Specific gravity at: 68· F (20 • C) 1.6 g/cm3
- Vapor pressure at: 68
• Vapor Density: 3.1
• Color: Off white to white
• Lower Explosive limit (% vol.): 1.3 (toluene)
.·Appearance:
-Upper Explosive limit '(% vol.): 7.1 (toluene)
-Odor: Polysulfide Odor
• Miscibility
• Boiling Point: 23fF
in water at 20
2
C: not miscible
2
F (20
2
C) 2 mm Hg
Paste
10. STABILITY AND REACTIVITY
Stable under recommended storage and handling conditions (see SDSsection 7). In case of combustion,
produce hazardous decomposition products such as :
• H2S,CO, C02, S02, SMOKE, SOOT
- carbon monoxide
- Sulfur oxides
may
11. TOXICOLOGICAL INFORMATION
There are no data available on the preparation
itself. See (SDSSections 3 and 15) for details.
Exposure to component solvents vapors at concentrations in excess of the stated Occupational Exposure limits may
result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on
kidney, liver and central nervous system.
Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness, and in extreme cases loss of
consciousness.
Repeated or prolonged contact with the preparation may cause Defatting of the skin resulting in non-allergic dermatitis and
absorption through the skin.
The liquid splashed in the eyes may cause irritation
and damage.
12. ECOLOGICAL INFORMATION
There is no data available on the preparation
Sections 3 and 15)
I
itself. Do not allow the product to enter drains or water ways. See (SDS
ii
13. DISPOSALt:ONSIDERATIONS
Recommended incineration
or land fill as hazardous waste per Federal, State and local regulations.
React with curing agent and dispose of as hazardous waste per Federal, State and local regulations. Recommended
incineration
or land fill.
14. TRANSPORT INFORMATION
DOT: § 172.101 HAZARDOUS MATERIALS TABLE
lATA:
UN Number: 1133
Proper Shipping Name: Adhesives
labels: Flammable Liquid
UN Number: 1133
Proper Shipping Name: Adhesives
Labels: Flammable liquid
Hazard Class: 3 Subclass: NO
Packaging Group: III
Passenger Air Packing Instruction: 309
Passenger aircraft: 60 liter (16 gallon)
Cargo Air Packing Instruction: 310
Cargo aircraft only: 220 liter (58 gallon)
IMDG:
Hazard Class: 3 Subclass: NO
Packaging Group: III
limited Quantity: Passenger aircraft: 60 Liter (16 gallon)
cargo aircraft only: 220 Liter (58 gallon)
Vessel stowage: A
ERG: 128
NMFC: 4620 SUB.5 - CL.60
Schedule B # 3506.91.0000
This sds is provided
situations.
knowledge.
without
The conditions
any warranty
of
expressed
handling.storage,
UN Number: 1133
Proper Shipping Name: Adhesives
Label: 3
Hazard Class: 3 Subclass: NO
. Packaging Group: III
EMS No: F, E - 5, 0
or implied
use and disposal
regarding
are beyond
its correctness
our control
or suitability
for specific
and may be beyond
our
Page 4 of 6
15. REGULATORY
INFORMATION
USRegulationsFederal
_
,---------------------------------------------------------------------------------------------------------~--------------------,
I - chemical(s)subjectto the reporting
! ChemicalName ! - CASNo
! Weight % I Threshold limit
!I requirementsof section313 otTitle III !•
:I
!I
!I
:I
and of 40 CFR372 (SARA):
:
:
:
I
I
I
,
:I
II
TOLUENE I:
108-88-3
II 5%- 12% II
1.0%
:
I (Methylbenzene) :
:
I
I
!
I
II
:I
:
,-----------------------------------------------t--------------------t--------------------t---------------~--------------------1
:
:lIQUID POLYMER!
I
•
68611-50-7
I
I
:50%-75%
!UNKNOWN
!
I
I
I
Aii"7;~~;in-gC~n-stit~;~ts-;;;-~~;;:h~;~;;r~~s-pe~4FED:sli):-3i3-Alic~~-stit~;~ts_;;~iist_;(rt;TscAi~~;~t~ry;-c~mPi~te-------"-mixture is excludedPerTSCAPar.710.4(d) 95 (6) (7) Comstituentsare not listed in TSCA12bCORR.lIST
USRegulationsState
-------r-------------------------r---------------r-------------------------,
:I----------------------~--------~------------------CaliforniaProposition 65 :
:
I:
:
'
TOLUENE
'
108-88-3
' 5%- 12%'
unknown
: (Developmental- Female) :
:
::
I-------------------------------~-------------------------~---------~---------------~--------------~-------------------------:
:Massachusetts
:
TOLUENE':
108-88-3
: 5%-12%:
unknown
:
'
:
:
:-------------------------------~-------------------------~-------------------------~--------------~-------------------------1
I
TOLUENE
:
108-88-3
: 5%-12%:
unknown
I------------~------------------~-------------------------~-------------------------t--------------1r-------------------------,
:Pennsylvania
l
TOLUENE
:
108-88-3
: 5%- 12% l
unknown
:
I----------------------
~-------
IRhodeIsland
: -
:
:NewJersey
~
TOLUENE
:
~--------------~
108-88-3
l
5%- i2%:
-----------------1 :
unknown
I-------------------------------~-------------------------~-------------------------~--------------~-------------------------1
I CaliforniaProposition65 :LlQUIDPOlYMER .!
68611-50-7
: 50%-75% :
l
l-------------------------~-------------------------~---------------l
: (Developmental- Female) :LIQUIDPOlYMER
:
68611-50-7
: 50%-75% :
unknown
1-------------------------------1-------------------------~-------------------------t--------------1r-------------------------:
lLlQUIDPOLYMER
:
68611-50-7
f 50%-75%:
unknown
I-------------------------------~-----------------------~------------------------~--------------~-------------------------1
:NewJersey
:L1QUIDPOLYMER -I:
68611-50-7
i 50%-75% i
unknown
:-------------------------------~-------------------------~-------------------------~-------------~-------------------------J
[Pennsylvania
!LlQUIDPOLYMER
!
68611-50-7
I 50%-75%!
unknown
I-------------------------------~----------------------~--~-------------------------t--------------1r-------------------------1
f:RhodeIsland
JlLiQUIDPOLYMER~-i I:
Ll 50%-75%: JL
68611-50-7
unknown
IMassachusetts
canada
!
:
:
l
i
i
1:
:
I,,
}
ClassB- Flammable
TOLUENE
'!I
II
:
Oass 0 - Poisonous and Infectious
materials Division Z: Materials causing
Other Toxic Effects DZA TOLUENE DZB-
I
TOLUENE
:
Liquid Polysulfide Polymer CAS#68611-SD-7
:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SOS
contains all of the information required by CPR.
listed National Pollutant ReleaseInventory (NPRI):TOLUENE
CAS:108-88-3
liquid PolysulfJde Polymer cas#6861l-S0-7
16.OTHERINFORMATION
NFPA
HMIS
PPE
This sds is provided without any warranty expressed i0r
implied regarding its correctness or suitability for specific
I
situations. The conditions of handling,storage, use and disposal are beyond our control and may be beyond our
knowledge.
Page 5 of 6
Full text of P statements with NQassociated to this compound:
•
•
•
•
•
•
•
•
•
•
•
P101+Pl02+P103: If medical advice is needed, have product container or label at hand. Keep out of reach of children.
Read label before use
P202: Do not handle until all safety precautions have been read and understood
P210: Keep away from heat/sparks/open flames and hot surfaces-No Smoking
P240:Ground/bond container and receiving equipment
P261+P262+P263+P264:Avoid breathing dust/fumes/gas/mist/vapours/spray.Do
not get in eyes, on skin, or on
clothing. Avoid contact during pregnancy/while nursing. Wash thoroughly after handling.
P270+P271+P273: Do not eat drink or smoke when using this product. Use only outdoors or in a well ventilated area.
Avoid release to the environment.
P281+P280: Use personal protective equipment as required. Wear protective gloves/ protective clothing!
eye protection/face protection
P301+P310+P331: If swallowed: Immediately call i! POISON CENTERor doctor/physician. Do not induce vomiting.
P305+P351+P338+P315: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,if present
and easy to do. Continue rinsing. Get lrnmediatemedlcal
advice attention.
P304+P340+P314: If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell
P342+P340+P315: If experiencing respiratory symptoms: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Get immediate medical advice/attention.
P302+P352: If on skin: Wash with plenty of soap and water
P306+P361: If on clothing: Remove/ take off immec;liately all contaminated clothing
P402+P403+P404: Store in a dry place. Store in a well ventilated space. Store in a closed container.
P233+P234+P235: Keep container tightly closed. ~eep only in original container. Keep cool.
Full text of H statements with N!!appearingii~ Section 3:
H412: Harmful to aquatic life with long lasting effects
•
H360Fd: May damage fertility. Suspected of damaging the unborn child.
•
H373: May cause damage to organs through prolonged or repeated exposure.
•
H304: May be fatal if swallowed and enters airways.
•
•
•
•
•
•
H31S: Causes skin irritation
H336: May cause drowsiness or dizziness
H318: Causes serious eye damage
H302+H332: Harmful if swallowed. Harmful if inhaled
H340+H350: May cause genetic defects. May cause cancer.
H22S: Highly flammable liquid and vapor.
I
I
I
I
I
I
Preparer: .
I
I
I
I
I
[Flamemaster / Compliance
!Rev-A June/09/2010
I
•
[Supersedes (conversion)
Revision Notes: A
konversion to ANSI format
I
I
. I
I
Containers:
!
plastic jars, metal cans
[cartridge kits
I
I
!
limited
Quantity
See SDS Section 14
Maximum container size 50 Gallons /190
liters
End of Safety Data Sheet
This sds is provided without any warranty expressed or implied regarding its correctness or suitability for specific
situations. The conditions of handling,storage,
knowledge.
use ana disposal are beyond our control and may be beyond our
Page 6 of 6
SAFETY DATA SHEET
File: CS3100PT B GSA 07-10
JANUARY 2014
Potting Compound-Catalyst
Flamemaster Corp.
13576 Desmond Street
Pacoima, CA 91331 - USA
Section -1. CHEMICAL PRODUCT AND COMPANY IDENirlFICATION
1.1. Product Identifier: C$-3100 PT B CATALYST (4LLlYPES AND CLASSES)
- Product -Electrical Potting Compound
- Product reference: C$-3100-B
1.2. Product Use:
- POTTING COMPOUND
1.3. Manufacturer's Name:
1.3.1 Suppliers Name ( if not manufacturer)
CAGE Code: 14439
CAGE Code:
OZ5S6
Flamemaster Corp.
Sealpak Company, Inc.
Chem Seal Division
2301 N. Hoover Rd
13576 Desmond Street
Wichita,
Pacoima, CA 91333 - USA
Technical'Contact:
MIL-PRF-8516G
8030-00-181-7884
NSN:
67205-1025
1.4. Emergency Telephone:
Chemtrec - Chemtrec International
800-424-9300 (North America)
703-527-3887 (Outside North America))
Flamemaster Corp.
Tel: 818-890-1401
Fax: 818-890-6001
www.flamemaster.com
Specification:
KS
CS3100TY1CLl 60Z CAR
80.30-00-200-8341
CS31001Y2CL160Z
80.30-0.0-297-6677
CS31001Y2CL21/2 PT
8030-00-684-8790
CS31001Y2CL3QT KIT
CS31100
CATALYST
II
80.30-00-631-80.13
II
CS3lOO1YICf~ QT KIT
80.30-00-148.7362
CS3100TYICL2QT. KIT
8o.30-00-~81-5238
CS3100TY2C,LlQT. KIT
8030-00-1,74-2597
CS.3100TY2CL2QT KIT
80.30-00-823.7953
CS31001Y2CUGALKIT
. 8030-00-286-9035
8()'30-00-5~5-2271
CS31001Y2q.3l/2
GAL
CS3100TY2CL2GAL
KIT
ALL CLASSESAND TYPES
80.30-0.1-175-3479
CS3100TYICL3GALKIT
80.30-01-80.5-9875
CS31001Y2CUPT KIT
8030-01-383-4992
CS3100TY2CL260Z
8030-00-881-2618
CS3100TY2CL1 2.5 02
80.30.-21-805-9875
CS3100TY2CLIPTKIT
8030.-0.0-616-7696
CS31001Y2CL31/2 PT
8030-00-814-0394
CS31001Y2CL21/2f'T
I'
,
Section -2. HAZARD ( S) IDENTIFICATION
Possible adverse risk to the fetus.
Skin and eye irritant.
Harmful if swallowed.
Harmful if inhaled.
Possible harm to aquatic organisms.
May cause long term adverse effects in the aquatic environment,
Section -3. COMPOSITION /INFORMATION
Chemical family:
ON INGREDIENTS
Mixture of organic compounds
For the hazards of the composition,
LEAD DIOXIDE
( SDS see Section 2).
OSHA HAZARDS: OXIDIZER, CARCINOGEN, TARGET ORGAN EFFECT,TOXIC BY INHALATION, HARMFUL BY INGESTION
TERATOGEN,REPRODUCTIVEHAZARD
I
TARGET ORGANS: FEMALE REPRODUCTIVESYSTEM, MALE REPRODUCTIVESYSTEM, NERVES, BLOOD, KIDNEY
GHS CLASSIFICATION: LEAD DIOXIDE
OXIDIZING SOLIDS (CATEGORY3)
ACUTE TOXICllY, ORAL (CATEGORY4)
ACUTE TOXICllY,lNHALATION
(CATEGORY4)
This sds is provided without any warranty expressed or implied regarding its correctness or suitability for specific
situations. the conditions of handling,storage,use
knowledge.
and: disposal are beyond our control and may be beyond our
Page 1 of 6
REPRODUCTIVETOXICITY (CATEGORY1A)
SPECIFICTARGET ORGAN TOXICITY-REPEATEDEXPOSURE(CATEGORY2)
ACUTE AQUATIC TOXICITY (CATEGORY1)
CHRONIC AQUATIC TOXICITY (CATEGORY1)
LEAD OXIDE
OSHA HAZARDS: CARCINOGEN, TARGET ORGAN EFFECT,TOXIC BY INHALATION,HARMFUL BY INGESTION
TERATOGEN, REPRODUCTIVEHAZARD
TARGET ORGANS: BLOOD, KIDNEY, NERVES,GASTROINTESTINALTRACT, REPRODUCTIVESYSTEM
GHS CLASSIFICATION:LEAD OXIDE
ACUTE TOXICITY, INHALATION (CATEGORY4)
ACUTE TOXICITY, ORAL (CATEGORY4)
SKIN IRRITATION (CATEGORY3)
REPRODUCTIVETOXICITY (CATEGORY1A)
SPECIFICTAGET ORGAN TOXICITY-REPEATEDEXPOSURE(CATEGORY2)
ACUTE AQUATIC TOXICITY (CATEGORY1)
CHRONIC AQUATIC TOXICITY (CATEGORY4)
H&p Statements
SUBSTANCE
" by weight in the product
Lead Dioxide <70%
Lead Oxide
<10%
CAS
EINECS/ELINCS
H272,H302+H332,H360;H373,H410,
P201,P220,p273,P308+P313,PS01
1309-60-0
21S-174-S
H302+H332,H316,H360,H373;H400,
H413<
P201,P273,P308+P313
1317-36-8
215-267-0
,
Section -4. FIRST-AID MEASURES
General: When in doubt or symptoms persist, seek medi'cal attention. Have 'Safety Data Sheet information
available. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air, if breathing has stopped, administer artificial respiration. Give nothing by mouth,
seek immediate medical attention.
Eye contact: Irrigate with clean, fresh water for at least 15 minutes, holding the eyelids apart, and seek medical attention.
Skin contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use recognized skin
cleaners. Do NOT use aromatic solvents, thinners or petroleum products.
Ingestion: If accidentally swallowed obtain immediate
give anything by mouth to an unconscious person.
medical attention.
Keep at rest. Do NOT induce vomiting.
Never
Section -5. FIRE-FIGHTING MEASURES
Extinguishing agents
Recommended:
Universal resistant foam, C02, water, powder.
Agents to avoid: None known
Attention
Fire will produce dense black smoke. Exposure to decomposition products may cause a Health Hazard. Fire fighters should
wear self-contained breathing apparatus.
Water mist may be used to cool closed containers to prevent pressure build-up and possible auto-ignition and explosion
when exposed to extreme heat.
Do not weld, flame cut or expose to extreme heat or ignition sources, empty containers which have contained flammable
products.
Do not allow run-off from fire fighting to enter drains or water courses.
This sds is provided
situations.
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without
the conditions
any warranty
expressed
of handling,storage,use
'or implied
and disposal
regarding
its correctness
are beyond
our control
or suitability
for specific
and may. be beyond
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Page 2 of 6
Section -6. ACCIDENTAL RELEASEMEASURES
Eliminate sources of ignition, ventilate the area. Avoid breathing vapors by using appropriate respiratory protective
equipment. Refer to protective measures listed in sections 7 & 8.
Collect spill with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a
suitable container for disposal in accordance with loca] regulations (see section 13). Do not allow to enter drains or
watercourses.
Clean-up with a detergent! water mix; avoid use of aromatic solvents.
authority with jurisdiction in accordancewith state / local regulations.
If the product enters drains or watercourses,
inform
Section -7. HANDLING AND STORAGE
7.1 Handling:
No smoking, eating and drinking during handling.
Keep containers tightly closed. Prior to movement containers which are opened should be carefully resealed.
Avoid skin and eye contact. Avoid inhalation in case of exposure to vapor and spray mist.
Handle and open containers with care to avoid spilling of contents. Never use pressure to empty; container is not a
pressure vessel. Clean or discard contaminated clothing and shoes.
Preparation may charge electrostatically; always use gr~unding/ bonding/ earthing leads when transferring contents of
.
I
containers. Operators should wear antistatic footweariand clothing, and floors should be electrically conductive.
Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation
of flammable or explosive concentrations of vapor in air, and avoid vapor concentration higher than the Occupational
Exposure Limits.
Use in areas from which local sources of ignition have been excluded. Electrical equipment including lighting should be
protected to the appropriate standard. Isolate from sources of heat, sparks and open flame. Non-sparking tools are
recommended.
7.2 Storage:
Observe label precautions. Store between 32/F and 95/F i( O/C and 35/C) ina dry, dean and well ventilated place, away
from sources of heat, ignition, and direct sunlight. For flash points below 23 ·C store in an area constructed to the
appropriate standard
8. EXPOSURECONTROLS I PERSONAL PROTECTION
8.1 Engineering measures:
Avoid the inhalation of vapors, spray mist and particulates.
extraction
If local
as to keep air-borne concentration
I area
ventilation
below the Occupational
is not sufficient to comply with
provide suitable (NIOSH) respiratory protection
8.2 Exposure limits
Achieve by local exhaust ventilation
oa, suitable
providing good general
Exposure Limits (OEL).
(NIOSH) respiratory
when sarjlding, grinding or otherwise
protection
to be provided. Always
abrading cured material.
'
Work place exposure limits ( 8 hour)
ii'
Substance
*
lead Dioxide <70%
*
* can
0.OSmg/M3
0.OSmg/M3
I
0.OSmg/M3
Lead oxide <10%
,
ACGIHTLV
OSHA
0.OSmg/M3
be absorbed through skin
lead Dioxide and lead Oxide are In a wetted out dispersion. Exposure limits are based on dust that-Is not present in this composition
8.3 Personal protection
All Personal Protective Equipment, including Respiratory Protection,
must be selected to meet the requirements
Respiratory
protection
:
Appropriate
respiratory
protection
equipment
regulatory (OSHA I NIOSH) and manufacturers
This sds is provided
situations.
knowledge.
without
the conditions
any warranty
used to control exposure to hazardous substances
of OSHA Regulations.
should be selected according to the type of contaminants,
instructions
expressed
of handling,storage,use
following
including proper fitting of devices.
or implied
and disposal
regarding
its correctness
are beyond
our control
or suitability
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and may be beyond
our
Page 3 of 6
Hand protection
:
For prolonged or repeated contact, recommend gloves type: polyvinyl alcohol, nitrile rubber, latex rubber (some people
may exhibit sensitivity to Latex). Barrier creams may help to protect exposed areas of the skin. However, they should not
be applied post exposure.
Eye protection:
Use safety glasses with side shields to protect against splashes. Face shields may also be worn.
Skin protection
:
Protective clothing made of antistatic and fire resistant fibers. All parts of the body should be washed after contact. Use
good hygiene and industrial practices, keep working clothes clean.
9. PHYSICALAND CHEMICAL PROPERTIES
• Physical state at: 68!! F (20 !! C) Liquid
• Flash point:
• Ph: 6.8
200· F (93· C) Method: TCC
.% VOLATILE BY VOLUME 3.0
• Specific gravity at: 68· F (20 • C) 3.0
• Vapor pressure at: 68!! F (20!!
• Vapor Density: N/A
• Color: BROWN
• Lower Explosive Limit (% vol.]: N/A
• Appearance: PASTE
• Upper Explosive Limit '(% voL): N/A
• Odor: NEGLIGIBLEOILY ODOR
• Miscibility
• Boiling Point: Unknown
in water at 20 !! C: NEGLIGIBLE
q
N/A
10. STABILITY AND REACTIVITY
Stable under recommended
storage and handling conditions
produce hazardous decomposition
• Carbon monoxide
(see SDS section 7). In case of combustion,
may
products such as :
• Oxides of nitrogen, Carbon, Lead Oxide and Organics
• Sulfur oxides
11. TOXICOLOGICAL INFORMATION
There are no data available on the preparation itself. See (50S Sections 3 and 15) for details.
Exposure to component solvents vapors at concentrations in excess of the stated Occupational
result in adverse health
Exposure LImits may
12. ECOLOGICAL INFORMATION
There is no data available on the preparation
itself. Do not allow the product to enter drains or water ways. See (SOS
Sections 3 and 15)
13. DISPOSAL CONSIDERATIONS
Recommended incineration
or land fill as hazardous waste per Federal, State and local regulations.
React with base and dispose of as hazardous waste per Federal, State and local regulations. Recommended
incineration or land fill.
14. TRANSPORT IN.FORMATION
DOT: Not regulated
UN Number: Not regulated
lATA: Not regulated
IMDG/IMO:
Not regulated
NMFC: 4620 SUB.S - CL.60
Schedule B # 3506.91.0000
15. REGULATORY INFORMATION
This sds is provided
situations.
knowledge.
without
the conditions
any warranty
expressed
of handling,storage,use
or implied
and disposal
regarding
its correctness
are beyond
our control
or suitability
for specific
and may be beyond
our
Page 4 of 6
.........
_ __ __ ._-----
-------
..
All remaining Constituents are non-hazardous per FED-STD-313 All Constituents are listed in TSCA inventory;
mixture is excluded Per TSCA Par. 710.4 (d) 9S (6) (7) Constituents are not listed in TSCA 12b CORR. LIST
US Regulations State
.
complete
I--------------------------~----~--------------------------r-------------------------r---------------r-------------------------r
: California Proposition 6S:
:
: (DevelopmentalFemale)
L d Dloxld
ea
IOXI e:
:
I
.:
:.
1309 ~60 - 0
:
:
:
<70%:
0
I
I
k
un nown
:
I
I
I-------------------------------~--------------------------r-------------------------r---------------r-------------------------1
!~~~~:~-~:~!!:---------------~-----~~~~-~~~~~~----~-------~:-~~:~?:~-------~----~-?!!~---~----:New Jersey
:
Lead Dioxide':
1309-60-0
:
< 70%
I
unknown
I
•
~
1Pennsylvania
~
1
Lead Dioxide
L
11309-60-0
I-------------------------------~----------_-----------i Lead Dioxide
1
1
~
< 70%
1
unknown
1
__~-------------------------~--------------~-------------------------t
i
1309-60-0
/
< 70%
I
unknown
[Rhode Island
/
,-------------------------------,-------------------------~-------------------------r--------------~-------------------------,
california Proposition 6S I
L d oxld
I
131 36 8
I
10%
I
k
ea OXI e:
7- I
un nown
I (Developmental- Female) I:
I
I < 0 II
:-------------------------------~-------------------------~-------------------------~--------------~-------------------------.
:Massachusetts
I
Lead Oxide
I
1317-36-8
I
<10%
I
unknown
l------------------------------~-------------------------~----------~--------------~--------------~-------------------------1
INew
Jersey
I
Lead Oxide
I
1317-36-8
:
<10%
I
unknown
:------------~------------------1-------------------------~-------------------------~--------------1r-------------------------,
[Pennsvlvania
I
Lead Oxide
1317-36-8
I-------------------------------~--------------------~I
~I <10%: ~-------- unknown
:
I
:Rhode Island
:
lead Oxide
:
1317-36-8
!
<10%:
I
I
I
I
:
I•
unknown
:
.-------------------------------~-------------------------~-------------------------~--------------~-------------------------.
CANADA
Class D - Poisonous and Infectious
materials Division 2: Materials
Causing
Other Toxic Effects:
Lead Dioxide CAS#1309-60-O
Lead Oxide CAS#1317-36-O
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR)and the SDS
contains all of the information required by CPR.Usted National Pollutant ReleaseInventory (NPRI):LeadDioxide caS#1309-6Q-O
LeadOxide cas#1317-36-8
16. OTHER INFORMATION
.,
HEAlTH-1
FLAMMABllITY-1
REACTIVITY-1
PPE-G
HMIS
PPE
Full text of P statements
•
•
•
•
•
•
with N!! associated to this compound:
P101+P102+P103: If medical advice is needed, have product container or label at hand. Keep out of reach of children.
Read label before use
P202: Do not handle until all safety precautions have been read and understood
P210: Keep away from heat/sparks/open flames and hot surfaces-No Smoking
P240:Ground/bond
container and receiving equipment
P261+P262+P263+P264:Avoid breathing dust/fumes/gas/mist/vapours/spray.Do
not get in eyes, on skin, or on
clothing. Avoid contact during pregnancy/while nursing. Wash thoroughly after handling.
P270+P271+P273: Do not eat drink or smoke when using this product. Use only outdoors or in a well ventilated area.
Avoid release to the environment.
P281+P280: Use personal protective equipment as required. Wear protective gloves/ protective clothing!
eye protection/face
protection
P301+P310+P331: If swallowed: Immediately call a POISON CENTERor doctor/physician.
Do not induce vomiting.
P305+P3S1 +P338+P31S: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,if present
and easy to do. Continue rinsing. Get immediate
This sds is provided'
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medical advice attention.
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of handling.storage.use
qr
implied
andldlsposal
regarding
its correctness
are beyond
our control
or suitability
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and may be beyond
our
Page 5 of 6
•
•
•
•
P304+P340+P314: If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention
if you feel unwell
P342+P340+P315: If experiencing respiratory symptoms: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Get immediate medical ~dvice/attention.
P302+P352: If on skin: Wash with plenty of soap and water
P306+P361: If on clothing: Remove/ take off immediately all contaminated clothing
P402+P403+P404: Store in a dry place. Store in atwell ventilated space. Store in a closed container.
P233+P234+P235: Keep container tightly closed. 'Keep only in original container. Keep cool.
Fun text of H statements with Nil associated to this compound:
•
H412: Harmful to aquatic life with long' lasting effects
•
H360Fd: May damage fertility. Suspected of damaging the unborn child.
•
H373: May cause damage to organs through prolonged or repeated exposure.
•
H304: May be fatal if swallowed and enters airways.
•
H315: Causes skin irritation
•
H336: May cause drowsiness or dizziness
•
H318: Causes serious eye damage
•
H302+H332: Harmful if swallowed. Harmful if inhaled
•
H340+H350: May cause genetic defects, May cause cancer.
•
H270: May cause or intensify fire; oxidizer
Preparer-Flamemaster/Compliance
Rev A June 2010
Supercedes(Conversion}
Revision Notes: A
Conversion to ANSI format
Containers: Plastic Jars, Metal Cans, Cartridge Kits
Maximum Container Size: 50 Gallons/190 liters
END OF SAFETYDATA SHEET
This sds is provided
situations.
knowledge.
without
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of handling,storage,use
br implied
and
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regarding
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and may be beyond
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