Status of Bio2G and Gasification testing at GTI Dr. Björn Fredriksson Möller E.ON Gasification Development AB Contents 1. Background & status update 2. Technology options in Bio2G – gas cleaning 3. GTI testing 4. Next step – Alkali model for hot gas cleaning system 5. Conclusions 2 SGC International Seminar on Gasification 2014 - Bio2G October 15 Bio2G – A reference plant in Sweden for production of bioSNG by thermal gasification Facts - Production capacity 200 MWbio-SNG (1,6 TWh/yr) + heat & electricity - Forest residues as feed stock - To be located in Malmö/Landskrona - Awarded for NER300 support; 203 M€ available Technology - Pressurized O2-blown gasification (Andritz, FI) - Gas cleaning and methanation, (Haldor Topsoe, DK) Project is awaiting decisions on the long-term policy instruments for biofuels 3 SGC International Seminar on Gasification 2014 - Bio2G October 15 A new concept – but mainly based on mature technology Forest Fuel Transport Fuel Dryer Reception/Preparation/Storage Auxiliary systems Steam Cooling water, District Heating, Bulk material, etc Boiler/Turbine Electricity Air Separation Unit (ASU) Dry biofuel Oxygen Clean syngas Compression Gas conditioning Gas Cleaning CO2 Removal Synthesis gas (CH4 H2 CO tar, etc.) Methanation CH4 H2O Process diagram Bio2G 4 SGC International Seminar on Gasification 2014 - Bio2G October 15 Gasification Drying Compression Biogas (Biomethane) Technology options in Bio2G – dust cleaning and reforming “Clean” tar reforming Gasification Cooling ~850°C Dust cleaning (HGF) ~550-850°C Reforming Cooling ~800-900°C => Verification test at GTI for “Clean” tar reforming performed, further analysis at SFC-CDGB. Slipstream HGF operated at 700 °C “Dusty” tar reforming Gasification Reforming ~850°C ~800-900°C Cooling Dust cleaning (Bag) ~250°C => Reformer with improved dust handling installed in Skive during 2014 5 SGC International Seminar on Gasification 2014 - Bio2G October 15 GTI test facility – an integrated biorefinery pilot plant => Test facility for TIGAS production of gasoline from biomass 6 SGC International Seminar on Gasification 2014 - Bio2G October 15 Hot filtration of syngas – fullstream filter @ 500 °C => Smooth operation from hot gas filters during the duration of test. Performance requirement fully met. 7 SGC International Seminar on Gasification 2014 - Bio2G October 15 Hot filtration of syngas – slipstream filter @ 700 °C => A total of more than 150 hrs operation, no solid slipping and no clogging behaviour. Appearance of dust differs with temperature. 8 SGC International Seminar on Gasification 2014 - Bio2G October 15 Alkali dust collection behind slip stream filter Alkali Probe Temperatures Test 2 600 550 500 TC1 °C TC2 TC3 450 TC5 TC6 400 350 300 2013-10-22 19:00 2013-10-23 19:00 2013-10-24 19:00 => Alkali probe cooled to a sliding temperature profile exposed to cleaned gas flow. 9 SGC International Seminar on Gasification 2014 - Bio2G October 15 2013-10-25 19:00 Next step: Alkali model for hot gas cleaning system Main aim: Model and reproduce result from GTI testing using mathematical modelling. Verification with results from ash analysis from fullstream filter ash, slipstream filter ash, as well as deposits from alkali probe. Project performed within SFC – CDGB with support from SFC – B4G on thermodynamic alkali modelling Partners: KTH, UmU, LTU, E.ON & Andritz 10 SGC International Seminar on Gasification 2014 - Bio2G October 15 Conclusion Bio2G still awaiting market/political signals supporting growth of vehicle gas market NER300 production support for Bio2G awarded – up to 203 M€ available Successful testing of gas filtering (as well as gasification and tar reforming) at GTI in Chicago – two viable technical options for gas cleaning at hand Experimental results from GTI have brought a better understanding of alkali behaviour and are important for further design considerations. It will also support further modelling work planned at SFC. Acknowledgement: Thanks to GTI, Haldor Topsoe and Andritz/Carbona 11 SGC International Seminar on Gasification 2014 - Bio2G October 15
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