Optical closure – Are we there yet? Ina Lefering David McKee Marine Optics and Remote Sensing Group University of Strathclyde MASTS ASM, 3rd - 5th September 2014 Introduction Methods Results Conclusion Optical closure in-situ IOPs depth profile absorption, attenuation, backscattering In-situ radiometry Ina Lefering Hydrolight well established radiative transfer model above surface Ed sub-surface Eu MASTS ASM, 4th Sep 2014 modelled light fields Ed, Eu, Lu depth profiles 2 Introduction Methods Results Conclusion Inherent Optical Properties (IOPs) • absorption a(λ), attenuation c(λ), backscattering bb(λ) • Properties of the medium, i.e. water, phytoplankton, minerals and coloured dissolved organic materials (CDOM) Yellow colour of CDOM 0.6 • IOPs determine how light propagates under water and how light is reflected from the surface Determine ocean colour remote sensing signals 0.5 absorption [m -1] • PSICAM photometer 0.4 0.3 0.2 0.1 0 400 500 600 wavelength [nm] 700 800 CDOM absorption Ina Lefering MASTS ASM, 4th Sep 2014 3 Introduction Methods Results Conclusion Absorption coefficients • absorption is a fundamental physical property of seawater; important for photochemistry, primary production and solar heating • absorption of natural water samples is hard to measure quantitatively due to scattering from particles • existing methods, such as spectrophotometer, filter pads or ac-9 are limited by systematic scattering errors Coloured solutions (no scattering) Ina Lefering Particles in suspension scatter light in all directions MASTS ASM, 4th Sep 2014 4 Introduction Methods Results Conclusion Submersible IOP sensors ac-9 – reflective tube absorption meter, 9 wavelengths Ina Lefering MASTS ASM, 4th Sep 2014 5 Introduction Methods Results Conclusion Scattering correction for ac-9 Flat NIR absorption is negligible wavelength-independent scattering Zaneveld NIR absorption is negligible wavelength-independent phase function Semi-empirical based on estimation of ‘true absorption’ from PSICAM - NIR absorption is NOT zero Monte Carlo Ina Lefering iterative approach estimation of wavelength dependent VSF based on scattering and backscattering measurements measurements - NIR absorption is NOT zero MASTS ASM, 4th Sep 2014 6 Introduction Methods Results Conclusion West Coast of the UK – June 2012 Wide range of different water masses: CDOM-rich fresh water (Loch Lochy) coccolithophore bloom (Rockall trough) sediment dominated coastal waters Reasonably clear case 1 waters Ina Lefering MASTS ASM, 4th Sep 2014 7 Introduction Methods Results Conclusion In-situ radiometry surface Reflectance 0.025 TriOS – hyperspectral radiometers Ina Lefering 0.02 0.015 0.01 0.005 0 MASTS ASM, 4th Sep 2014 400 600 wavelength [nm] 800 8 Introduction Methods Results Conclusion Model performance 10 10 -1 10 -2 10 -3 Zaneveld -1 modelled R Monte Carlo -2 -2 10 measured R -3 -2 10 measured R modelled R modelled R 10 10 10 -1 10 -2 10 -3 Semi-empirical -2 10 measured R Ina Lefering MASTS ASM, 4th Sep 2014 9 Introduction Methods Results Conclusion Model performance 0.12 Zaneveld 0.1 Monte Carlo modelled R 0.12 0.08 0.06 0.04 0.02 0 0 0.06 0.12 0.04 0.05 measured R 0.1 Semi-empirical 0.1 0.02 coccolithophore bloom 0 0 0.05 measured R 0.1 modelled R modelled R 0.1 0.08 0.08 0.06 0.04 0.02 0 0 Ina Lefering MASTS ASM, 4th Sep 2014 0.05 measured R 0.1 10 Introduction Methods Results Conclusion IOP corrections a @ 715nm [m-1] 0.06 Monte Carlo semi-empirical 0.04 0.02 0 -0.02 1 bb @715 0.02 2 3 4 5 6 7 8 9 10 11 12 13 14 15 station number 3 4 5 6 7 8 9 10 11 12 13 14 15 station number bb715 0.01 0 1 Ina Lefering 2 MASTS ASM, 4th Sep 2014 11 Introduction Methods Results Conclusion Conclusion • Generally good agreement between modelled and measured light fields over a wide range of different water masses • ac-9 scattering corrections provide similar levels of optical closure in most cases • Underestimation of modelled surface reflectance for stations with high backscattering coefficient e.g. coccolithophore bloom • Corresponding results from Monte Carlo ac9 correction point to scattering phase function as possible source of error Ina Lefering MASTS ASM, 4th Sep 2014 12 Introduction Methods Results Conclusion Future work • Investigating the degree of optical closure for depth profiles of Ed, Lu and Eu • Improving the Monte Carlo correction for waters with high backscattering coefficient • Integrating a correction for the backscattering into Monte Carlo correction Ina Lefering MASTS ASM, 4th Sep 2014 13 Introduction Methods Results Conclusion Thank you Acknowledgements References • McKee D, Piskozub J, Roettgers R, Reynolds RA (2014). Evaluation and Improvement of an Iterative Scattering Correction Scheme for in situ Absorption and Attenuation Measurements. Journal of atmospheric and oceanic technology 30: 1527 - 1541, http://dx.doi.org/10.1175/JTECH-D-1200150.1 • Röttgers R, McKee D, Wozniak SB (2013). Evaluation of scatter corrections for ac-9 absorption measurements in coastal waters. Methods in Oceanography 7: 21-39 • WETLabs, Absorption and attenuation meter (ac-9), User’s Guide. • Zaneveld, J. R. V., Kitchen, J. C., Moore, C. M., 1994. The scattering error correction of reflecting-tube absorption meters. Ocean Optics XII, J. S. Jaffe, Ed., International Society for Optical Engineering (SPIE Proceedings, Vol. 2258), 44–55. Ina Lefering MASTS ASM, 4th Sep 2014 14
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