DENTAURUM GmbH & Co. KG
Safety Data Sheet
according to Regulation (EC) No 1907/2006
Orthocryl-liquid
Print date: 05.03.2014
Page 1 of 8
Product code: 161-100
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Orthocryl-liquid
Further trade names
Article no.: 160-501-00, 160-502-00, 160-600-00, 161-100-00, 161-127-00, 161-128-00, 161-129-00,
161-130-00, 161-131-00, 161-132-00, 161-150-00, 161-300-00, 161-350-00, 161-911-00, 161-912-00
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Health services.
1.3. Details of the supplier of the safety data sheet
Company name:
Street:
Place:
Telephone:
e-mail:
DENTAURUM GmbH & Co. KG
Turnstr. 31
D-75228 Ispringen
+49 7231 803 0
[email protected]
Internet:
www.dentaurum.com
Further Information
Emergency telephone:
07:00 - 16:15 (Mo - Do), 07:00 - 13:15 (Fr)
16:15 - 18:00 (Mo - Do), 13:15 - 18:00 (Fr)
Telefax: +49 7231 803 295
+49 7231 803 184
+49 7231 803 0
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Indications of danger: F - Highly flammable, Xi - Irritant
R phrases:
Highly flammable.
Irritating to respiratory system and skin.
May cause sensitisation by skin contact.
GHS classification
Hazard categories:
Flammable liquid: Flam. Liq. 2
Skin corrosion/irritation: Skin Irrit. 2
Respiratory/skin sensitization: Skin Sens. 1
Specific target organ toxicity - single exposure: STOT SE 3
Hazard Statements:
Highly flammable liquid and vapour.
Causes skin irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
2.2. Label elements
Hazardous components which must be listed on the label
methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate; methyl methacrylate
ethylene dimethacrylate
Signal word:
Pictograms:
Revision No: 1,90
Danger
GHS02-GHS07
GB - EN
Revision date: 05.03.2014
DENTAURUM GmbH & Co. KG
Safety Data Sheet
according to Regulation (EC) No 1907/2006
Orthocryl-liquid
Print date: 05.03.2014
Hazard statements
H225
H315
H317
H335
Page 2 of 8
Product code: 161-100
Highly flammable liquid and vapour.
Causes skin irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Chemical characterization
methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate; methyl methacrylate
red, pink-transparent : colour index S.R.111, colour index S.R.52
green: colour index S.B.97, S.Y.93
blue: colour index S.B. 97
yellow: colour index S.Y. 93
hot pink: colour index D.V.26, D.V.31
türkis: colour index S.B.44
Hazardous components
EC No
CAS No
Index No
REACH No
Quantity
Chemical name
Classification
GHS classification
201-297-1
80-62-6
methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate; methyl methacrylate
F - Highly flammable, Xi - Irritant R11-37/38-43
607-035-00-6
Flam. Liq. 2, STOT SE 3, Skin Irrit. 2, Skin Sens. 1; H225 H335 H315 H317
202-617-2
97-90-5
ethylene dimethacrylate
Xi - Irritant R37-43
607-114-00-5
STOT SE 3, Skin Sens. 1; H335 H317
219-470-5
2440-22-4
2-(2H-Benzotriazol-2-yl)-p-cresol
Xi - Irritant R43-53
> 90 %
< 10 %
<1%
Skin Sens. 1B, Aquatic Chronic 1; H317 H410
Full text of R and H phrases: see Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
After inhalation
Remove casualty to fresh air and keep warm and at rest. Medical treatment necessary.
After contact with skin
After contact with skin, wash immediately with: Water and soap. Subsequently wash again with:
Polyethylene glykol 400. Take off immediately all contaminated clothing. Medical treatment necessary.
Revision No: 1,90
GB - EN
Revision date: 05.03.2014
DENTAURUM GmbH & Co. KG
Safety Data Sheet
according to Regulation (EC) No 1907/2006
Orthocryl-liquid
Print date: 05.03.2014
Page 3 of 8
Product code: 161-100
After contact with eyes
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After ingestion
If swallowed, immediately drink: Water. Caution if victim vomits: Risk of aspiration! Immediately get
medical attention.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Water spray. Carbon dioxide (CO2). Foam. Extinguishing powder.
Extinguishing media which must not be used for safety reasons
High power water jet.
5.2. Special hazards arising from the substance or mixture
Combustible. Vapours may form explosive mixtures with air.
5.3. Advice for firefighters
Wear a self-contained breathing apparatus and chemical resistant suit.
Additional information
Use water spray/stream to protect personnel and to cool endangered containers. Use a water spray jet
to knock down vapours/gases/mists. Contaminated fire-fighting water must be collected separately. Do
not empty into drains or the aquatic environment.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Remove all sources of ignition. Provide adequate ventilation. Do not breathe vapour.
Avoid contact with skin, eye and clothing. Wear personal protection equipment.
6.2. Environmental precautions
Do not empty into drains or the aquatic environment. Explosion hazard.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Collect mechanically. Treat the assimilated material according to the section on waste disposal.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling
In case of open handling equipment with built-in suction must be used. Do not breathe vapour.
Vapours are heavier than air and will spread at floor level. Provide fresh air.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking. Use explosion-protected machinery, apparatus,
suction equipment, appliances etc. Use only non-sparking tools.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed. Keep in a cool, well-ventilated place. Keep away from sources of ignition
- No smoking. Keep/Store only in original container. Protect against: Light. Do not store at
temperatures over: 30°C
Advice on storage compatibility
Do not store together with: Material, rich in oxygen, oxidizing.
SECTION 8: Exposure controls/personal protection
Revision No: 1,90
GB - EN
Revision date: 05.03.2014
DENTAURUM GmbH & Co. KG
Safety Data Sheet
according to Regulation (EC) No 1907/2006
Orthocryl-liquid
Print date: 05.03.2014
Page 4 of 8
Product code: 161-100
8.1. Control parameters
Exposure limits (EH40)
CAS No
Substance
80-62-6 Methyl methacrylate
ppm
mg/m³
50
100
fibres/ml
Category
Origin
208
TWA (8 h)
WEL
416
STEL (15 min)
WEL
8.2. Exposure controls
Occupational exposure controls
In case of open handling equipment with built-in suction must be used. Do not breathe vapour.
Protective and hygiene measures
Take off immediately all contaminated clothing. Protect skin by using skin protective cream. After work,
wash hands and face. When using do not eat or drink. Avoid contact with skin and eyes. Store work
clothing separately.
Respiratory protection
Do not breathe vapour.
Hand protection
Recommendation:
Dermatril Single-use gloves. NBR (Nitrile rubber). 0,11 mm
penetration time (maximum wearing period): 0 min.
REF 162-907-00 (7/S), REF 162-908-00 (8/M), REF 162-909-00 (9/L)
----------------------------------------Camapren 720, CR (polychloroprenes, Chloroprene rubber). 0,65 mm
penetration time (maximum wearing period): > 10 min, KCL
Eye protection
Wear eye/face protection.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state:
Colour:
Odour:
liquid
various, depending on coloration
like: ester
Test method
Changes in the physical state
Melting point:
-48 °C
100,3 °C
Boiling point:
Flash point:
10 °C DIN 51755
Lower explosion limits:
Upper explosion limits:
2,1 vol. %
12,5 vol. %
Ignition temperature:
430 °C DIN 51794
Vapour pressure:
(at 20 °C)
Density (at 20 °C):
Water solubility:
(at 20 °C)
Solubility in other solvents
mixable with most organic solvent cleaners
40 hPa
Revision No: 1,90
0,94 g/cm³
15,9 g/L
GB - EN
Revision date: 05.03.2014
DENTAURUM GmbH & Co. KG
Safety Data Sheet
according to Regulation (EC) No 1907/2006
Orthocryl-liquid
Print date: 05.03.2014
Page 5 of 8
Product code: 161-100
Partition coefficient:
Distribution coefficient (n-octanol / water)
(log P O/W): 0,7
Viscosity / dynamic:
(at 20 °C)
Brookfield 0,6 mPa·s
9.2. Other information
Relative vapour density at 20 °C (air=1): > 1
SECTION 10: Stability and reactivity
10.3. Possibility of hazardous reactions
Reacts with : Reducing agents. Heavy metals. Peroxides. Radical former.
In case of warming: Polymerization.
10.4. Conditions to avoid
Keep away from heat. Ignition hazard.
10.6. Hazardous decomposition products
none/none
Further information
Thermal decomposition: at room temperature none/none
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity
Acute toxicity (inhalant): 7093 ppm 4h
CAS No
Chemical name
Exposure routes
80-62-6
Method
Dose
Species
Source
methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate; methyl methacrylate
oral
LD50
mg/kg
> 5000
Rat.
dermal
LD50
mg/kg
> 5000
Rabbit.
Irritation and corrosivity
Irritant effect on the skin: Not an irritant. 24h
Irritant effect on the eye: Not an irritant.
Following inhalation: Lung irritation. Coughing. shortage of breath.
Sensitising effects
May cause sensitization by inhalation and skin contact.
Carcinogenic/mutagenic/toxic effects for reproduction
Longterm experiments do not indicate carcinogenic effects. No experimental indications of
mutagenicity in-vitro exist.
Additional information on tests
The classification was undertaken in accordance with the calculation method governed by the
Preparations Directive (1999/45/EC).
SECTION 12: Ecological information
12.1. Toxicity
Algae toxicity:EC50: 37 mg/l 8d
Bacterial toxicity: Pseudomonas putida 100 mg/l
Revision No: 1,90
GB - EN
Revision date: 05.03.2014
DENTAURUM GmbH & Co. KG
Safety Data Sheet
according to Regulation (EC) No 1907/2006
Orthocryl-liquid
Print date: 05.03.2014
CAS No
Page 6 of 8
Product code: 161-100
Chemical name
Aquatic toxicity
80-62-6
Method
Dose
h Species
Source
methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate; methyl methacrylate
97-90-5
Acute fish toxicity
LC50
> 79 mg/l
96 Oncorhynchus mykiss
Acute crustacea toxicity
EC50
69 mg/l
48 Daphnia magna
Acute fish toxicity
LC50
15,95 mg/l
96 Brachydanio rerio (zebrafish)
Acute crustacea toxicity
EC50
44,9 mg/l
48 Daphnia magna
ethylene dimethacrylate
12.2. Persistence and degradability
Not easily bio-degradable (according to OECD-criteria).
Further information
Do not empty into drains or the aquatic environment.
The classification was undertaken in accordance with the calculation method governed by the
Preparations Directive (1999/45/EC).
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Advice on disposal
Carry out a burning of harzardous waste according to official regulations.
Waste disposal number of used product
WASTE ORGANIC SOLVENTS, REFRIGERANTS AND PROPELLANTS (except 07 and 08); waste
140603
organic solvents, refrigerants and foam/aerosol propellants; other solvents and solvent mixtures
Classified as hazardous waste.
Contaminated packaging
Water (with cleaning agent). Completely emptied packings can be re-cycled.
SECTION 14: Transport information
Land transport (ADR/RID)
14.1. UN number:
1247
14.2. UN proper shipping name:
METHYL METHACRYLATE MONOMER, STABILIZED
14.3. Transport hazard class(es):
3
14.4. Packing group:
II
Hazard label:
3
Classification code:
Limited quantity:
Transport category:
Hazard No:
Tunnel restriction code:
F1
LQ4
2
339
D/E
Other applicable information (land transport)
E2
Marine transport (IMDG)
14.1. UN number:
Revision No: 1,90
1247
GB - EN
Revision date: 05.03.2014
DENTAURUM GmbH & Co. KG
Safety Data Sheet
according to Regulation (EC) No 1907/2006
Orthocryl-liquid
Print date: 05.03.2014
Product code: 161-100
14.2. UN proper shipping name:
METHYL METHACRYLATE MONOMER, STABILIZED
14.3. Transport hazard class(es):
3
14.4. Packing group:
II
Hazard label:
3
Special Provisions:
Limited quantity:
EmS:
1L
F-E, S-D
Page 7 of 8
Other applicable information (marine transport)
E2
Air transport (ICAO)
14.1. UN number:
1247
14.2. UN proper shipping name:
METHYL METHACRYLATE MONOMER, STABILIZED
14.3. Transport hazard class(es):
3
14.4. Packing group:
II
Hazard label:
3
Limited quantity Passenger:
1L
IATA-packing instructions - Passenger:
IATA-max. quantity - Passenger:
IATA-packing instructions - Cargo:
IATA-max. quantity - Cargo:
305
5L
307
60 L
Other applicable information (air transport)
E2
: Y305
14.5. Environmental hazards
Dangerous for the environment:
no
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulatory information
Water contaminating class (D):
1 - slightly water contaminating
SECTION 16: Other information
Full text of R phrases referred to under Sections 2 and 3
11
Highly flammable.
37
Irritating to respiratory system.
37/38
Irritating to respiratory system and skin.
43
May cause sensitisation by skin contact.
53
May cause long-term adverse effects in the aquatic environment.
Full text of H statements referred to under Sections 2 and 3
H225
Highly flammable liquid and vapour.
H315
Causes skin irritation.
Revision No: 1,90
GB - EN
Revision date: 05.03.2014
DENTAURUM GmbH & Co. KG
Safety Data Sheet
according to Regulation (EC) No 1907/2006
Orthocryl-liquid
Print date: 05.03.2014
H317
H335
H410
Page 8 of 8
Product code: 161-100
May cause an allergic skin reaction.
May cause respiratory irritation.
Very toxic to aquatic life with long lasting effects.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
The receiver of our product is singulary responsible for adhering to existing laws and regulations.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)
Revision No: 1,90
GB - EN
Revision date: 05.03.2014