Flame Retardants

Flame Retardants
Non-Halogen Phosphoric Acid Esters
Products
Formula
Color
APHA
Colorless
clear liquid
≦30
1.215±
0.005
≦0.2
Colorless
clear liquid
≦20
1.071±
0.003
≦0.05
Appearance
O=P(OCH3)3
25
TEP
O=P(OC2H5)3
[ mPa・s /25˚C ]
Flash
Point
˚C
Containers
Description
Uses
Relatively low boiling point.
Completely soluble in water.
Low viscosity.
High phosphorus content.
Good compatibility with various synthetic resins. Plasticizer with flame retarding for thermosetting resins such as rigid polyurethane foam
and unsaturated polyester resins.
Soluble in organic solvent as well as water.
Low viscosity.
Water
Content %
≦0.2
P%
≧21.0
180 ~ 195
《101kPa》
≦-70
[2.0]
22.1
—
220kg
Drum
—
1.403±
0.002
—
—
216
《101kPa》
-56
[1.6]
17.0
111
210kg
Drum
—
—
Chloride
not cause
turbidness
Melting
Point ˚C
48.5≦
399
《101kPa》
—
225
25kg
Paper bag
*500kg
Color after
heated
150˚C ×1hr・APHA
≦60
Volume
resistivity
30˚C Ω cm
≧5x109
241 ~ 255
《0.53kPa》
-35
[58]
8.4
240
220kg
Drum
182
TPP
Triphenyl phosphate
White
flake
—
≦0.03
Colorless
to light
O=P(OC6H4CH3)3
yellowish
368 clear liquid
≦50
1.170±
0.010
≦0.05
≦0.10
1.557±
0.003
Colorless to
yellowish
clear liquid
≦200
1.145±
0.025
≦0.1
≦0.15
1.552±
0.003
—
—
240 ~ 260
《0.27kPa》
-15
[172]
7.6
253
220kg
Drum
Colorless to
light
yellowish
OC6H4CH3
clear liquid
340
≦50
1.210±
0.005
≦0.05
≦0.15
—
—
—
245
《0.53kPa》
-30
[36]
9.1
240
220kg
Drum
326
TCP
Tricresyl phosphate
TXP
Trixylenyl phosphate
O=P[OC6H3(CH3)2]3
410
O=P
―
CDP
―
Cresyl diphenyl
phosphate
(OC6H5)2
9.5
Bringing heat resistance and electric insulation
property to polyvinylchloride.
Flame retarding.
Very high performance for extreme pressure Plasticizer with flame retarding for agricultural
polyvinylchloride film, phenol resin, epoxy
in addition to lubrication.
resin and various engineering plastics.
Low volatility.
Non-flammable hydraulic oil.
High performance for water resistance.
Additive for extreme pressure lubricant oil.
Flame retarding.
Good extreme pressure lubrication same as
TCP.
Effective in polyvinylchloride.
Plasticizer with flame retarding for
Bringing cold resistance and stain resistance.
polyvinylchloride, phenolic resin, epoxy resin
Higher phosphorus content, lower viscosity
and various engineering plastics.
and better flame retarding than TCP.
Resin Modifiers
*Flexible container bag
Non-Halogen Phosphoric Acid Polyesters (1)
Products
Aromatic
polyphosphate
CR-741
Aromatic
polyphosphate
PX-200
Aromatic
polyphosphate
11
O=P(OC6H5)2
|
O
C6H4
O
|
O=P(OC6H5)2 Principal
ingredient
(C6H5O)2P(O)OC6H4C(CH3)2
C6H4OP(O)(OC6H5)2
Principal
ingredient
[(CH3)2C6H3O]2P(O)OC6H4OP(O)
[OC6H3(CH3)2]2
Typical Properties
Freezing
Point
˚C
Viscosity
mPa・s /25˚C
P
%
Flash
Point
˚C
P%
≧10.5
-13
—
10.9
—
—
4~5
2,300
《40 ˚C》
Melting
point ˚C
≧92
P%
≧8.7
—
—
Appearance
Color
APHA
Colorless to
light
yellowish
clear liquid
≦80
1.306±
0.010
≦0.5
≦0.15
Viscosity
mPa・s /25˚C
500 ~ 800
Colorless to
yellowish
clear liquid
—
1.260±
0.010
≦0.2
≦0.10
White
powder
to granule
—
—
≦1.0
—
Containers
Description
Uses
302
220kg
Drum
High performance for heat resistance and
lower volatility than TPP and TXP, due to its
condensed structure.
8.9
334
220kg
Drum
Flame retardant for various engineering
High hydrolytic stability and heat resistance plastics and synthetic fiber.
and bringing high insulation property.
9.0
308
25kg
Paper bag
Others
CR-733S
Formula
Specifications
Specific
Acid
Water
Gravity
value
Content
20/20˚C KOH mg/g
%
Metal Extractants
—
O=P(OC6H5)3
Flaky solid material.
Good compatibility with nitrocellulose, Plasticizer with flame retarding for phenolic
acetylcellulose and polyvinylchloride.
resin, epoxy resin, various engineering
Low volatility.
plastics, acetate plastics and synthetic rubber.
Bringing water resistance and oil resistance.
Flame Retardants
—
1.395±
0.002
140
Triethyl phosphate
Typical Properties
Freezing Point
P
˚C
Viscosity %
Boiling
Point
˚C
Plasticizers
and Solvents
TMP
Specifications
Heating Loss Refractive
Acid
%
value
KOH mg/g 125˚C ×3hrs Index n D
Specific
Gravity
20/20˚C
mol.weight
Trimethyl phosphate
《 》: Measurement condition
High hydrolytic stability and heat resistance.
Low volatility.
12
Flame Retardants
Halogen Containing Phosphoric Acid Ester
Products
Formula
Color
APHA
(
―
―
Tris(chloropropyl)
phosphate
)
CH3
O=P OCH CH2Cl 3
Colorless
to light
yellowish
clear liquid
≦50
1.293±
0.005
328
Specifications
Acid
Water
value
Content
KOH mg/g
%
≦0.10
≦0.10
Typical Properties
Heating Loss
%
105˚C ×3hrs
Refractive
Index n D
≦0.30
1.463±
0.003
25
˚C
Viscosity
mPa・s /25˚C
P
%
Halogen
%
Flash
Point
˚C
-40
69
9.5
Cl
32.5
210
Freezing
Point
Containers
250kg
Drum
Description
High hydrolytic stability.
Low volatility.
Uses
Flame retardant for polyvinylchloride,
rigid polyurethane foam, polyester and
epoxy resin.
Products
Formula
Specifications
Specific
Acid
Gravity
value
20/20˚C KOH mg/g
Typical Properties
Water
Content
%
Viscosity
mPa・s /25˚C
Freezing
Point
˚C
P
%
Halogen
%
Flash
Point
˚C
Containers
Description
Uses
—
Colorless to light
yellowish clear liquid
≦150
1.330±
0.010
≦0.30
≦0.10
800 ~
1,100
-10
10.8
Cl
23.5
236
250kg
Drum
High performance for scorch resistance and Flame retardant for various urethane resins
high hydrolytic stability.
such as flexible polyurethane foam, elastomer,
Extremely low volatility.
paint and molded article.
—
Colorless to light
yellowish liquid
—
1.405±
0.015
≦0.5
≦0.15
400 ~
800
-25
13.0
Cl
29.0
213
250kg
Drum
Low volatility and high hydrolytic stability.
Chlorine containing aliphatic
polyphosphate-phosphonate
—
Colorless to light
yellowish clear liquid
—
1.326±
0.010
≦0.10
≦0.10
2,000 ~
6,000
—
12.5
Cl
26.2
214
250kg
Drum
Flame retardant for urethane resins such
Fine containing proportion of phosphorus
as flexible and rigid polyurethane foam,
and halogen.
elastomer, paint, molded article, as well as
High performance for flame retarding and
unsaturated polyester, epoxy resin and acryl
scorch resistance.
resin.
DAIGUARD-550
—
Colorless to yellowish
liquid
≦150
1.362±
0.005
≦0.10
≦0.10
950 ~
1,350
≦15
10.3
Cl
28.3
233
250kg
Drum
Suitable for various flexible polyurethane Suitable for various flexible polyurethane
foams requiring non-flammability.
foams requiring non-flammability.
CR-504L
Chlorine containing
aliphatic polyphosphate
CR-530
Chlorine containing aliphatic
polyphosphate-phosphonate
CR-570
Additive-type flame retardant for
polyurethane foam and others.
Products
Appearance
Color
APHA
Specific
Gravity
20/20˚C
—
Colorless to
yellowish
brown liquid
—
1.225 ~
1.240
—
(Colorless
to yellowish
brown liquid)
—
(1.29)
—
(Colorless
to light
yellowish
clear liquid)
(≦100)
(1.125±
0.005)
Formula
mol.weight
DAIGUARD-580
Non-Halogen aliphatic poly
phosphate
DAIGUARD-610
Non-Halogen aliphatic poly
phosphate
DAIGUARD-880
Non-Halogen aliphatic poly
phosphonate phosphate
13
Specifications
Acid
Water
value
Content
KOH mg/g
%
Typical Properties
Hydroxyl
P
Value
%
KOH mg/g
Viscosity
mPa・s /25˚C
P
%
Freezing
Point
≦0.20
2,500 ~
5,500
—
—
(≦0.1)
(≦0.2)
(800 ~
1,500)
—
—
11
(≦0.2)
(≦0.5)
(150 ~ 350)
(≧14.8)
-4
15.5
≦0.30
˚C
12
Flash
Point
˚C
Containers
Description
193
220kg
Drum
Non-halogen type flame retardant containing
hydroxy group with high performance of
flame retardancy.
≦46
217
220kg
Drum
Non-halogen type flame retardant containing
Flame retardant for urethane resins in general,
hydroxyl group.
such as flexible polyurethane foam, elastomer,
Low viscosity and good processability.
High performance for fogging resistance and paint and processed article.
scorch resistance.
—
217
200kg
Drum
Non-halogen type flame retardant with.
Low viscosity.
High phosphorus content and high
performance of flame retarding.
≦161
Uses
Others
Non-Halogen Phosphoric Acid Polyesters (2)
Resin Modifiers
Color
APHA
Metal Extractants
Appearance
Flame Retardants
Halogen Containing Phosphoric Acid Polyesters
Plasticizers
and Solvents
Appearance
Specific
Gravity
20/20˚C
mol.weight
TMCPP
《 》: Measurement condition
( ): Typical value
14