3A14 Cold UV Spectroscopy of Protonated Dibenzylamine-Crown Ether Pseudo-Rotaxanes in the Gas Phase (Hiroshima Univ.) ○Yoshiya Inokuchi and Takayuki Ebata CE CE 1 [1] CE 2 QIT [2] dibenzylamine•H + , dBAMH + ~10 K dBAMH + –CE 2 [3] 3 CE dBAMH + CE 24C8 [1] dBAMH + •PF 6 – CE ESI OPIG1 QIT 100 QIT ~4 K 90 QIT UVPD 3 dBAMH dBAMH + CE 37300–37500 cm –1 UVPD 3 4 dBAMH + UVPD 3 A B CE 37200–37600 cm –1 18C6 1 1 15C5 25 cm –1 1 12C4 24C8 3 dBAMH + 12C4 dBAMH dBAMH + C 15C5 NH 2 + CE UVPD + CE 18C6 B 24C8 A UVPD dBAMH + 24C8 dBAMH + 24C8 [1] Ashton et al., Chem. Eur. J., 1996, 2, 709. [2] Inokuchi et al., J. Chem. Phys. A, 2015, 119, 8512. [3] Inokuchi et al., Phys. Chem. Chem. Phys., 2015, 17, 25925.
© Copyright 2024 ExpyDoc
