当日配布資料(713B)

ᙌኡǹȩȃǸƷஊဇ᝻เ҄
ƱʻࢸƷૼ‫᧏ޒ‬
Ტ᭗ჷ‫ ܖٻ‬ᠾ‫ܖ‬ᢿ ᠾ‫ܖ‬ᅹ ౕ௎ᅹ‫ܖ‬dzȸǹᲣ
ϱ૙੉ ࠊි ᒍଢ
1
⎇ⓥ⢛᥊
ᙌኡ⇟∏⇩⇞↗↞≢
ᙌኡ⇟∏⇩⇞≋⁂⁅≌
ஊೞཋ≋⇷∑⇽↙↘≌․•⁩⁦‗
໯ೞཋ≋‫ظ‬૰≌ ․•⁩⁦‗
≋⇥∑⇕⅚⇑⇐∐∙⅚⇑∑⇛⇊⇮↙↘≌
൦Ў
ᙌኡ⇟∏⇩⇞
‫׎‬ϋ…
•ɢ⇮∙‡࠰
ग़ۧჄ≝‣••ɢ⇮∙‡࠰
•⁩⁦‗
≋ᛢ᫆≌
∝؈ᇌ‫ئ‬৑↝ᄩ̬ⅻ‫׉‬ᩊ
∝໲Ҳ‫ئ‬৑↝ᄩ̬ⅻ‫׉‬ᩊ
∝இኳϼЎᝲ↚↷↺⇙⇟⇮⇈⇩⇽
؈ᇌϼЎ≋ϼЎᝲ
„•••ό‡⇮∙≌
2
⎇ⓥ⢛᥊
ϐМဇඥ⇁౨᚛ↈ↺࣏ᙲ
⇷∑⇽Ў໲Ҳ
≋‫≌⃹••‫‬
ᙌኡ⇟∏⇩⇞
≋⁂⁅≌
ᙌኡ⇟∏⇩⇞໲Ҳ໋
⁂⁅⁓⁥⁚
ϐဃ‫ظ‬૰
⇢⇐∏⇊⇮ӳ঺
3
ᣂᛛⴚ䈱ၮ䈫䈭䉎⎇ⓥᚑᨐ䊶ᛛⴚ
ᙌኡǹȩȃǸ໲Ҳ໋ƷǼǪȩǤȈ҄
⇑∑⇛⇊⇮
⇑∑⇛⇊⇮
⇥∑⇕
⇥∑⇕
⇈∑⇑∐ϼྸ
∇⇥⇑⇐∐∙
ᙌኡ⇟∏⇩⇞໲Ҳ໋
⇢⇐∏⇊⇮
ʴ߻⇢⇐∏⇊⇮
4
ᙌኡ⇟∏⇩⇞໲Ҳ໋ⅺ↸ᣠ҄⇧⇥∙≐⇢⇐∏⇊⇮⇰⇴ᙐӳ˳
⇥∑⇕
ᣠ҄⇧⇥∙
⇈∑⇑∐ϼྸ
∇⇥⇑⇐∐∙
ᙌኡ⇟∏⇩⇞໲Ҳ໋
ᣠ҄⇧⇥∙≐⇢⇐∏⇊⇮
⇰⇴ᙐӳ˳
5
ᣠ҄⇧⇥∙≐⇢⇐∏⇊⇮⇰⇴ᙐӳ˳
ᣠ҄⇧⇥∙
⇢⇐∏⇊⇮
6
The Chemical components of PS ash
Al2O3
Fe 2O3
TiO 2
CaO
MgO
Na2O
36.3
34.2
0.62
21.5
0.19
5.22
1.48
wt%
600
Acetaldehyde (ppm)
PSash
SiO 2
㹢UV ON
500
400
PSash
300
nanocomposite
200
100
0
0
50
100
150
Time(min)
Ԉბ∝ЎᚐೞᏡ⇁ஊↈ↺ೞᏡ஬૰↝оᙌ
7
ᓥ᧪ᛛⴚ䈫䈠䈱໧㗴ὐ
⇷∑⇽
⁆⁛⁁․
‵⁓‵⁁‥
‫⃹••‫‬໲Ҳ
⇷∑⇽Ў↗
໯ೞ঺Ў↝Ўᩉ
໯ೞ঺Ў
⇷∑⇽
∝⇷∑⇽Ў↝ஊј෇ဇ ⁷
∝໲Ҳ⇟∀∞⇟ ⁷
Ўᩉⅻ‫׉‬ᩊ
8
ஜᄂᆮ↖↞∝∝∝
⇊⇐∙෩˳
⇷∑⇽Ў↗
໯ೞ঺Ў↝Ўᩉ
⇊⇐∙෩˳↗↞≢
N
+
CH 3
Cl
N
H 3C
-
∝˯ᗡໜ≋‣‧•⃹ˌɦ≌↝ஊೞ‫ط‬
∝ᔕൢ‫ן‬ⅻ⇢∓
∝ᩊ༓ࣱ
∝᭗ⅳ༏‫ܖ҄∝ࣱܭܤ‬ႎ‫ࣱܭܤ‬
∝∐⇛⇊⇕∑ӧᏡ
࿢‫ↆↄ↳↚ؾ‬ⅳ๋д↗ↆ↕දႸ
9
ஜᄂᆮ↖↞∝∝
⇷∑⇽Ў↗
໯ೞ঺Ў↝Ўᩉ
⇊⇐∙෩˳
1ͲbutylͲ3Ͳmethylimidazolium chloride
H3C
N
+
N
ClCH3
⇡∑∓∞⇟↝๋ᚐⅻӧᏡ
J.Am.Chem.Soc.124,4974Ͳ4975(2002)
Richard P. Swatloski etc.
“DissolutionofCellulosewithIonicLiquids”
ᣂᛛⴚ䈱․ᓽ䊶ᓥ᧪ᛛⴚ䈫䈱Ყセ
⇊⇐∙෩˳
⇊⇐∙෩˳
ϐМဇ
ϐМဇ
⇎⇥⇴∞∑
‣••⃹
ℊ
⇷∑⇽Ў⇁๋ᚐ
䊌䊦䊒ಽ䈫ήᯏᚑಽ䈱ಽ㔌
໯ೞ঺Ў↝ϐМဇ
⇷∑⇽঺Ў↝ϐМဇ
11
⇎⇥⇴∞∑ชь
⁂⁆‸‷↼ኡ↖
↼ᢅ
‫ׅ‬ӓↆ↎໯ೞ঺Ў
‫ׅ‬ӓↆ↎⇷∑⇽঺Ў
12
※⁠⁦⁗⁠⁥⁛⁦䋨⁕⁢⁥䋩
䌘✢࿁᛬
ᙌኡ⇟∏⇩⇞
‫ׅ‬ӓↆ↎໯ೞ঺Ў
••⃹↖໲঺ↆ↎
໯ೞ঺Ў
‧
‣‧
․‧
‥‧
…‧
‧‧
‫ׅ‬ӓↆ↎
⇷∑⇽঺Ў
․㱔‚㫦‛
13
≻ዴ‫ׅ‬৵
‫ׅ‬ӓↆ↎⇷∑⇽঺Ў
※⁠⁦⁗⁠⁥⁛⁦≋⁕⁢⁥≌
••
‧••
…••
‥••
․••
‣••
•
•
‣•
․•
‥•
…•
‧•
․ₘ‚⁳‛
⇈∈∑⇻⇇⇟≋᩼୒ឋ≌
•
Ӓࣖ଺᧓↗‫ׅ‬ӓྙ↝᧙̞
‣••
໯ೞ঺Ў‫ׅ‬ӓྙ
‫ׅ‬ӓྙ≋≉≌
‪•
•
ஊೞ঺Ў‫ׅ‬ӓྙ
…•
․•
•
•
‥
‫‫‬
଺᧓≋⁚≌
᬴ܱவˑ≝⇊⇐∙෩˳᣽․•⁙⅚ᙌኡ⇟∏⇩⇞᣽‣⁙⅚ટਉ․‧•⁤⁢ 15
Ӓࣖ଺᧓↗‫ׅ‬ӓྙ↝᧙̞
‣••
‫ׅ‬ӓྙ≋≉≌
‪•
ዮ‫ׅ‬ӓྙ
•
…•
․•
•
•
‥
‫‫‬
଺᧓≋⁚≌
᬴ܱவˑ≝⇊⇐∙෩˳᣽․•⁙⅚ᙌኡ⇟∏⇩⇞᣽‣⁙⅚ટਉ․‧•⁤⁢ 16
⇊⇐∙෩˳↗⇎⇥⇴∞∑↝‫ׅ‬ӓ
‫ׅ‬ӓↆ↎‴‿※‵
∓∞⇥∐∞⇎⇶∃−∞⇥∞
↼෩
‫ׅ‬ӓ⇎⇥⇴∞∑
ᔕသவˑ≝ᔕသภࡇ …•⃹
ᚨ‫ןܭ‬щ …‒⁚⁢⁓
17
‫ׅ‬ӓↆ↎⇊⇐∙෩˳↝ϐМဇ᬴ܱ
ஊೞ঺Ў‫ׅ‬ӓᏡ
‣
•†
‧
•†‧
•†․‧
•
‣
․
‥
᬴ܱ‫ׅ‬ૠ≋‫≌ׅ‬
…
ஊೞ঺Ў‫ׅ‬ӓᏡ≠N‫ׅ‬Ⴘ↝ஊೞ঺Ў‫ׅ‬ӓྙ / 1‫ׅ‬Ⴘ↝ஊೞ঺Ў‫ׅ‬ӓྙ
ᗐቯ䈘䉏䉎↪ㅜ
∝ࡑూཋϼྸ২ᘐ
∝ᙌኡ⇟∏⇩⇞↝ஊј෇ဇ
∝໯ೞ঺Ў ℉ ࿢‫ؾ‬෋҄஬૰
∝⇷∑⇽঺Ў ℉ ⇻⇉∑∆⅚ጞዜ
ဃЎᚐࣱ⇽∏⇟⇧⇩⇕
19
ᗐቯ䈘䉏䉎ᬺ⇇
∝Мဇᎍ∝‫ݣ‬ᝋ
ⅎ ࡑూཋϼྸ২ᘐ
℉ ᙌኡ˟ᅈ≋⇡∑∓∞⇟ጞዜ⇁Мဇↆ↎ⅳ˟ᅈሁ≌
ⅎ ᣠ҄⇧⇥∙‟⇢⇐∏⇊⇮⇰⇴ᙐӳ˳
℉ ࿢‫ؾ‬෋҄஬Мဇ˖ಅ
Ӌᎋ≝ᣠ҄⇧⇥∙ࠊ‫ᙹئ‬೉ ℉ ኖ‧••Εό
20
ታ↪ൻ䈮ะ䈔䈢⺖㗴
∝ ᭗ⅳቬࡇ ℉ Ўᩉ⇁ᩊↆⅾↆ↕ⅳ↺
∝ ⇙⇟⇮᩿ ℉ ⇊⇐∙෩˳↝͌െ≋ᚾᕤ≝ኖ…‧„•••ό‡⁝⁙≌
∝ ⇎⇳∑⇔∞᩿ ℉ ໲Ҳϼྸ↷↹↱Ⴞ⇎⇳∑⇔∞↚ↈ↺࣏ᙲ
ʻࢸ⅚ቬࡇ‫ݣ‬ሊ⅚⇙⇟⇮᩿ⅹ↷↢Ⴞ⇎⇳∑⇔∞᧙ↈ↺౨᚛⇁ᘍⅳ⅚
⇽∏∙⇮−⇿∑↚ᢘဇↆ↕ⅳⅾ‫ئ‬ӳ↝வˑᚨ‫⇁ܭ‬ᘍ→↕ⅳⅾ⅛
21
ડᬺ䈻䈱ᦼᓙ
∝
∝
∝
ᙌኡ⇟∏⇩⇞Ўᩉ২ᘐ⇁‫ݰ‬λↆ↎ⅳ˖ಅ
ϐМဇ⇡∑∓∞⇟⇁Мဇↆ↎ⅳ˖ಅ
࿢‫ؾ‬෋҄஬↚⇱∞⇠⇁ஊↈ↺˖ಅ
ɥᚡ↚ᛆ࢘ↈ↺˖ಅ↚↞ஊј↙২ᘐ↗ᎋⅷ↸↻↺⅛
22
ᧄᛛⴚ䈮㑐䈜䉎⍮⊛⽷↥ᮭ
䊶⊒᣿䈱ฬ⒓䋺శ⸅ᇦᵴᕈ䉕᦭䈜䉎㉄ൻ䉼䉺䊮䈱ౣ↢ᣇᴺ
෸䈶㉄ൻ䉼䉺䊮䊷䉷䉥䊤䉟䊃ⶄว૕䈱⵾ㅧᣇᴺ
䊶಴㗿⇟ภ䋺․㗿 2004-123254
䊶಴㗿ੱ䋺ᗲᇫ⋵䇮ㅺ⷗ᓆ↵䇮ᗲᇫ⋵⚕䊌䊦䊒Ꮏᬺળ䇮
䊥䊮䊁䉾䉪ᩣᑼળ␠
䊶⊒᣿⠪䋺ㅺ⷗ᓆ↵䇮ዊ⼱⦟ᄥ㇢䇮ጊᧄᔀ䇮Ꮢᶆ⧷᣿䇮
⑔၂ౝᥙ䇮᳗ፉቁ૞䇮ජ႐㆐ᄦ䇮᫪የቯ๺
23
䈍໧䈇ว䉒䈞వ
᭗ჷ‫ܖٻ‬
‫׎‬ᨥ∝‫؏ע‬ᡲઃ⇡∙⇥∞
ܲՃ૙੉ τ᪽ ദබ
≷≨≯ •‪‪‟‪……‟‪‫‣‫‬‪
≩≤≻ •‪‪‟‪……‟‪‧‧
⁗‟ ⁓⁛⁞ ⁚⁡⁖⁡≣⁝⁡⁕⁚⁛‟⁧†⁓⁕†⁜⁢
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